ES2028121T3 - Procedimiento de (co)dimerizacion de un acrilato de alquilo inferior y composicion catalitica. - Google Patents
Procedimiento de (co)dimerizacion de un acrilato de alquilo inferior y composicion catalitica.Info
- Publication number
- ES2028121T3 ES2028121T3 ES198787420078T ES87420078T ES2028121T3 ES 2028121 T3 ES2028121 T3 ES 2028121T3 ES 198787420078 T ES198787420078 T ES 198787420078T ES 87420078 T ES87420078 T ES 87420078T ES 2028121 T3 ES2028121 T3 ES 2028121T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- dimerization
- alkyl acrylate
- catalytic composition
- lower alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 238000006471 dimerization reaction Methods 0.000 title abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical class [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
- B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/465—Preparation of carboxylic acid esters by oligomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/593—Dicarboxylic acid esters having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/12—Olefin polymerisation or copolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCEDIMIENTO Y A UN SISTEMA CATALITICO DE (CO)DIMERIZACION DE UN ACRILATO DE ALQUILO Y, ESPECIALMENTE DE UN COMPUESTO DIENICO CONJUGADO. PRECISANDO MAS, EL PROCEDIMIENTO SE REALIZA EN PRESENCIA DE UNA COMPOSICION CATALITICA FORMADA POR REACCION: A) DE UNA FUENTE DE PALADIO; B) DE UN COMPUESTO DE FOSFORO (III) DE FORMULA PR1R2R3 EN LA CUAL R1,R2 Y R3 REPRESENTAN INDEPENDIENTEMENTE UN RADICAL ALQUILO, CICLOALQUILO, ARILO, ALCOXI, CICLOALCOXI O ARILOXI, Y C) DEL HIDRATO HY AL MENOS, EN EL CUAL EL ANION ASOCIADO Y- PRESENTA UN CARACTER NO COORDINANTE FRENTE A LOS IONES PALADIO. EL PROCEDIMIENTO ES ADECUADO ESPECIALMENTE A LA DIMERIZACION DE ACRILATOS DE METILO O DE ETILO
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8604644A FR2596390B1 (fr) | 1986-03-27 | 1986-03-27 | Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2028121T3 true ES2028121T3 (es) | 1992-07-01 |
Family
ID=9333761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198787420078T Expired - Lifetime ES2028121T3 (es) | 1986-03-27 | 1987-03-20 | Procedimiento de (co)dimerizacion de un acrilato de alquilo inferior y composicion catalitica. |
Country Status (8)
Country | Link |
---|---|
US (2) | US4786623A (es) |
EP (1) | EP0243281B1 (es) |
JP (1) | JPS6317845A (es) |
AT (1) | ATE72225T1 (es) |
DE (1) | DE3776387D1 (es) |
ES (1) | ES2028121T3 (es) |
FR (1) | FR2596390B1 (es) |
SU (1) | SU1574168A3 (es) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2619564B1 (fr) * | 1987-08-19 | 1989-12-08 | Rhone Poulenc Chimie | Perfectionnement au procede de dimerisation catalytique d'un acrylate d'alkyle |
FR2652514A1 (fr) * | 1989-06-22 | 1991-04-05 | Rhone Poulenc Sante | Nouveau catalyseur a base de palladium et son emploi. |
US5099048A (en) * | 1990-09-11 | 1992-03-24 | The University Of North Carolina At Chapel Hill | Rhodium-catalyzed olefin dimerization |
US5099061A (en) * | 1990-09-11 | 1992-03-24 | The University Of North Carolina At Chapel Hill | Rhodium-catalyzed olefin dimerization |
US5227561A (en) * | 1991-08-23 | 1993-07-13 | Shell Oil Company | Co-dimerization of vinyl aromatics with α-monoolefins |
EP0601705B1 (en) * | 1992-12-07 | 1996-11-06 | Ford Motor Company Limited | Catalysts from organo-noble metal precursors |
GB9306366D0 (en) * | 1993-03-26 | 1993-05-19 | Bp Chem Int Ltd | Process for prepariang polyketones |
DE10318697A1 (de) * | 2003-04-24 | 2004-11-25 | Basf Ag | Verfahren zur Hydrierung einer monoolefinisch ungesättigten Verbindung |
DE10328713A1 (de) * | 2003-06-25 | 2005-01-20 | Basf Ag | Verfahren zur Abtrennung eines Homogenkatalysators |
DE10328714A1 (de) * | 2003-06-25 | 2005-01-13 | Basf Ag | Verfahren zur Abtrennung eines Rhodium enthaltenden Homogenkatalysators |
DE10328715A1 (de) * | 2003-06-25 | 2005-01-13 | Basf Ag | Verfahren zur kontinuierlichen Herstellung einer Verbindung, die mindestens zwei funktionelle Gruppen trägt |
US8491238B2 (en) * | 2008-01-30 | 2013-07-23 | Holden America, Inc. | Restraint device for a tire |
CA3000442A1 (en) * | 2009-03-04 | 2010-09-10 | Chevron Phillips Chemical Company Lp | Selective hydrogenation catalyst and methods of making and using same |
RU2466134C1 (ru) * | 2011-06-24 | 2012-11-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Иркутский государственный университет" | Способ получения катионных комплексов палладия |
EP3838907A1 (en) | 2019-12-20 | 2021-06-23 | Polytechnyl S.A.S. | Reactive phosporous contaning flame retardant and intrinsically flame retradant polymer obtainable by polycondensation with it |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2104626C2 (de) * | 1970-02-09 | 1982-07-29 | Mitsubishi Chemical Industries, Ltd., Tokyo | Verfahren zur Herstellung eines Additionsproduktes eines konjugierten Diens und einer Verbindung mit endständiger Venylgruppe |
US4243829A (en) * | 1976-10-04 | 1981-01-06 | Charles U. Pittman, Jr. | Production of 1,7-octadiene from butadiene |
US4318860A (en) * | 1979-09-28 | 1982-03-09 | Atlantic Richfield Company | Preparation of unsaturated monester precursor for pelargonic acid |
US4501822A (en) * | 1982-01-26 | 1985-02-26 | Celanese Corporation | Hydroesterification of 1-alkene |
FR2524341A1 (fr) * | 1982-03-31 | 1983-10-07 | Centre Nat Rech Scient | Catalyseur de dimerisation et/ou de codimerisation de derives acryliques |
US4519954A (en) * | 1982-12-29 | 1985-05-28 | The Standard Oil Company | Leach resistant catalyst useful for the dimerization of acrylic compounds |
US4451665A (en) * | 1982-12-30 | 1984-05-29 | E. I. Du Pont De Nemours And Company | Process for dimerizing acrylates and methacrylates |
DE3336691A1 (de) * | 1983-10-08 | 1985-04-25 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur katalytischen dimerisation von acrylsaeurederivaten und verwendung der erhaltenen dimeren |
GB8428347D0 (en) * | 1984-11-09 | 1984-12-19 | Shell Int Research | Dimerization of olefins |
-
1986
- 1986-03-27 FR FR8604644A patent/FR2596390B1/fr not_active Expired
-
1987
- 1987-03-20 AT AT87420078T patent/ATE72225T1/de not_active IP Right Cessation
- 1987-03-20 US US07/028,569 patent/US4786623A/en not_active Expired - Fee Related
- 1987-03-20 EP EP87420078A patent/EP0243281B1/fr not_active Expired - Lifetime
- 1987-03-20 DE DE8787420078T patent/DE3776387D1/de not_active Expired - Fee Related
- 1987-03-20 ES ES198787420078T patent/ES2028121T3/es not_active Expired - Lifetime
- 1987-03-26 JP JP62072969A patent/JPS6317845A/ja active Granted
- 1987-03-26 SU SU874202277A patent/SU1574168A3/ru active
-
1988
- 1988-06-28 US US07/212,678 patent/US4889949A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3776387D1 (de) | 1992-03-12 |
JPH0548218B2 (es) | 1993-07-20 |
SU1574168A3 (ru) | 1990-06-23 |
FR2596390B1 (fr) | 1989-02-17 |
JPS6317845A (ja) | 1988-01-25 |
ATE72225T1 (de) | 1992-02-15 |
EP0243281A2 (fr) | 1987-10-28 |
EP0243281A3 (en) | 1989-03-29 |
US4889949A (en) | 1989-12-26 |
US4786623A (en) | 1988-11-22 |
FR2596390A1 (fr) | 1987-10-02 |
EP0243281B1 (fr) | 1992-01-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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