ES2163164T3 - Copolimeros de etileno y olefinas disustituidas geminalmente. - Google Patents

Copolimeros de etileno y olefinas disustituidas geminalmente.

Info

Publication number
ES2163164T3
ES2163164T3 ES97925679T ES97925679T ES2163164T3 ES 2163164 T3 ES2163164 T3 ES 2163164T3 ES 97925679 T ES97925679 T ES 97925679T ES 97925679 T ES97925679 T ES 97925679T ES 2163164 T3 ES2163164 T3 ES 2163164T3
Authority
ES
Spain
Prior art keywords
geminally
coordination
ethylene copolymers
disstituted
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97925679T
Other languages
English (en)
Inventor
Timothy Daniel Shaffer
Jo Ann Marie Canich
Kevin Richard Squire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of ES2163164T3 publication Critical patent/ES2163164T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

SE DESCRIBEN COPOLIMEROS DE ETILENO SUSTANCIALMENTE ALEATORIOS, QUE CONTIENEN AL MENOS 3,0 MOL EN PORCENTAJE DE MONOMEROS DE OLEFINA GEMINALMENTE DISUSTITUIDAS. LOS MONOMEROS DE OLEFINA GEMINALMENTE DISUSTITUIDA PUEDEN REPRESENTARSE POR LA FORMULA GENERICA R 1 = R 2 (R 3 )(R 4 ), EN LA Q UE R 1 ES CH 2 , R 2 ES C, Y R 3 Y R 4 SON, INDEPENDIENTEMENTE, GRUPOS HIDROCARBILO BASICAMENTE LINEALES QUE TIENEN DE 1 A 30 ATOMOS DE CARBONO, O MAS, Y CONTIENEN UN ATOMO DE CARBONO FIJADO DIRECTAMENTE A R 2 . LOS COPOLIMEROS PUEDEN PREPARARSE POR POLIMERIZACION DE COORDINACION, A TRAVES DEL CONTACTO DE AL MENOS UN MONOMERO DE OLEFINA GEMINALMENTE DISUSTITUIDA Y ETILENO, OPTATIVAMENTE CON UNO O MAS MONOMEROS DIFERENTES POLIMERIZABLES DE COORDINACION, CON UN SISTEMA CATALIZADOR QUE COMPRENDE UN MONOCILOPENTADIENILO, COMPONENTE CATALIZADOR METALICO DE TRANSICION DEL GRUPO 4 QUE CONTIENE HETEROATOMOS.
ES97925679T 1996-05-21 1997-05-21 Copolimeros de etileno y olefinas disustituidas geminalmente. Expired - Lifetime ES2163164T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/651,030 US5763556A (en) 1996-05-21 1996-05-21 Copolymers of ethylene and geminally disubstituted olefins

Publications (1)

Publication Number Publication Date
ES2163164T3 true ES2163164T3 (es) 2002-01-16

Family

ID=24611316

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97925679T Expired - Lifetime ES2163164T3 (es) 1996-05-21 1997-05-21 Copolimeros de etileno y olefinas disustituidas geminalmente.

Country Status (10)

Country Link
US (2) US5763556A (es)
EP (1) EP0900242B1 (es)
JP (1) JP2000511226A (es)
CN (2) CN1095853C (es)
AU (1) AU719343B2 (es)
CA (1) CA2248767C (es)
DE (1) DE69707667T2 (es)
ES (1) ES2163164T3 (es)
HU (1) HU222400B1 (es)
WO (1) WO1997044370A1 (es)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100225956B1 (ko) * 1997-01-10 1999-10-15 김영환 아민을 도입한 에이알에프 감광막 수지
US6100354A (en) * 1997-02-24 2000-08-08 Exxon Chemical Patents Inc. Olefin copolymers from bridged bis(arylamido) Group 4 catalyst compounds
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
US6586646B1 (en) * 1997-06-20 2003-07-01 Pennzoil-Quaker State Company Vinylidene-containing polymers and uses thereof
US6124513A (en) 1997-06-20 2000-09-26 Pennzoil-Quaker State Company Ethylene-alpha-olefin polymers, processes and uses
KR20010043881A (ko) * 1998-05-29 2001-05-25 메리 이. 보울러 올레핀의 공중합
JP3587743B2 (ja) 1998-08-26 2004-11-10 株式会社ハイニックスセミコンダクター フォトレジスト単量体とその製造方法、フォトレジスト共重合体とその製造方法、フォトレジスト組成物、フォトレジストパターン形成方法、および、半導体素子。
US6569971B2 (en) * 1998-08-27 2003-05-27 Hyundai Electronics Industries Co., Ltd. Polymers for photoresist and photoresist compositions using the same
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
WO2000052826A2 (en) * 1999-03-04 2000-09-08 Altera Corporation Interconnection and input/output resources for programmable logic integrated circuit devices
JP2002544357A (ja) 1999-05-19 2002-12-24 エクソンモービル・ケミカル・パテンツ・インク 改良された強度、弾性及び低減された透過性を有するイソブチレン系エラストマーブレンド
ATE350418T1 (de) 1999-09-01 2007-01-15 Exxonmobil Chem Patents Inc Atmungsfähiger film und verfahren daraus
US6639020B1 (en) * 1999-09-03 2003-10-28 Exxon Mobil Chemical Patents Inc. Plasticized polypropylene thermoplastics
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) * 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
CA2393327A1 (en) 1999-12-20 2001-06-28 Exxon Chemical Patents Inc. Processes for the preparation polyolefin resins using supported ionic catalysts
KR20010082913A (ko) * 2000-02-22 2001-08-31 박찬구 아미도계 ｉｖ족 금속 착화합물을 이용한 폴리이소부텐의제조방법
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
WO2002000666A1 (en) 2000-06-23 2002-01-03 Exxonmobil Chemical Patents Inc. Siloxy substituted cocatalyst activators for olefin polymerization
CA2424370A1 (en) * 2000-10-19 2002-04-25 Exxonmobil Chemical Patents Inc. Cationic group-3 catalyst system
US6900321B2 (en) * 2000-11-07 2005-05-31 Symyx Technologies, Inc. Substituted pyridyl amine complexes, and catalysts
EP1406761B1 (en) 2001-06-20 2016-11-02 ExxonMobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
US6777514B2 (en) * 2002-08-27 2004-08-17 Exxonmobil Research And Engineering Company Geminally disubstituted olefin-carbon monoxide-ethylene polymer useful as a polyvinyl chloride plasticizer and a method of making same
US7037989B2 (en) * 2003-05-27 2006-05-02 Exxonmobil Chemical Patents Inc. Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
CN103443143B (zh) * 2011-01-19 2017-08-04 道康宁公司 产生甲硅烷基官能化聚烯烃以及结合了甲硅烷基单体的甲硅烷基官能化聚烯烃的方法
KR102441542B1 (ko) * 2019-07-30 2022-09-08 한국과학기술원 탈산소화반응을 이용한 고분자의 합성방법
US11555086B2 (en) * 2019-07-30 2023-01-17 Korea Advanced Institute Of Science And Technology Method of synthesizing hydrocarbon polymers using deoxygenation

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA729279A (en) * 1966-03-01 Shell Oil Company Alpha-alkylstyrene polymers and derivatives thereof
NL50503C (es) * 1937-04-22
US3058963A (en) * 1955-04-07 1962-10-16 Hercules Powder Co Ltd Process for polymerizing olefins
US3013002A (en) * 1960-04-05 1961-12-12 Hercules Powder Co Ltd Polymerization of ethylene with dicyclopentadienyl chromium-metal alkylcatalysts
US3481908A (en) * 1965-08-02 1969-12-02 Monsanto Co Terpolymers of ethylene,a mono-olefin,and an unsaturated amide
FR94183E (fr) * 1967-02-20 1969-07-11 Pneumatiques Procédé de préparation de copolymeres et produits obtenus.
CA849081A (en) * 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
JPS573804A (en) * 1980-06-10 1982-01-09 Mitsui Petrochem Ind Ltd Production of ethylene copolymer
JPH0710900B2 (ja) * 1982-06-18 1995-02-08 エクソン リサーチ アンド エンヂニアリング コムパニー 中級蒸留物燃料油用流動性改良剤
DE3444111A1 (de) * 1984-12-04 1986-06-05 Basf Ag, 6700 Ludwigshafen Anorganische fuellstoffe fuer reaktivkunststoffsysteme
DE3621394A1 (de) * 1986-06-26 1988-01-14 Ruhrchemie Ag Mischpolymerisate des ethylens, verfahren zu ihrer herstellung und ihre verwendung
US5041584A (en) * 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
EP0616618B1 (en) * 1991-12-13 1997-07-02 Exxon Chemical Patents Inc. Ethylene/longer alpha-olefin copolymers
US5329032A (en) * 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
JP2888639B2 (ja) * 1992-04-20 1999-05-10 エクソン・ケミカル・パテンツ・インク エチレン／分枝鎖オレフィンのコポリマー
US5414040A (en) * 1992-09-15 1995-05-09 The Dow Chemical Company Formulated ethylene/α-olefin elastomeric compounds
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US5448001A (en) * 1994-10-07 1995-09-05 Queen's University At Kingston Polymerization of iso-butylene

Also Published As

Publication number Publication date
AU719343B2 (en) 2000-05-04
CN1221581C (zh) 2005-10-05
CN1095853C (zh) 2002-12-11
HUP9902667A3 (en) 2000-08-28
CN1405193A (zh) 2003-03-26
CA2248767C (en) 2003-01-14
CN1218480A (zh) 1999-06-02
HU222400B1 (hu) 2003-06-28
CA2248767A1 (en) 1997-11-27
EP0900242A1 (en) 1999-03-10
AU3074997A (en) 1997-12-09
US5866665A (en) 1999-02-02
DE69707667D1 (de) 2001-11-29
DE69707667T2 (de) 2002-06-20
JP2000511226A (ja) 2000-08-29
EP0900242B1 (en) 2001-10-24
US5763556A (en) 1998-06-09
WO1997044370A1 (en) 1997-11-27
HUP9902667A2 (hu) 1999-12-28

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