ES2137690T3 - Procedimiento y constituyente catalizador para la copolimerizacion y la homopolimerizacion de olefinas. - Google Patents

Procedimiento y constituyente catalizador para la copolimerizacion y la homopolimerizacion de olefinas.

Info

Publication number
ES2137690T3
ES2137690T3 ES96913547T ES96913547T ES2137690T3 ES 2137690 T3 ES2137690 T3 ES 2137690T3 ES 96913547 T ES96913547 T ES 96913547T ES 96913547 T ES96913547 T ES 96913547T ES 2137690 T3 ES2137690 T3 ES 2137690T3
Authority
ES
Spain
Prior art keywords
olefins
pct
homopolymerization
copolymerization
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96913547T
Other languages
English (en)
Inventor
Amir K Karbasi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis AS
Original Assignee
Borealis AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis AS filed Critical Borealis AS
Application granted granted Critical
Publication of ES2137690T3 publication Critical patent/ES2137690T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/907—Specified means of reacting components of transition metal catalyst

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA LA HOMO Y COPOLIMERIZACION DE OLEFINAS PONIENDO EN CONTACTO UNA O MAS OLEFINAS POLIMERIZABLES CON LA FORMULA GENERAL (I) CH SUB,2}=CR SUB,1}R SUB,2} DONDE R SUB,1}Y R SUB,2}SON IGUALES O DIFERENTES Y SON HIDROGENO O UN ALQUILO C SUB,1}-C SUB,10}, CON UN SISTEMA CATALIZADOR DE POLIMERIZACION OBTENIDO PONIENDO EN CONTACTO AL MENOS LOS COMPONENTES SIGUIENTES: 1) UN PROCATALIZADOR SOLIDO QUE CONTIENE TITANIO (TI), CLORO Y MAGNESIO; 2) UN COCATALIZADOR QUE CONTIENE ALUMINIO (A1) Y UN ALQUILO C SUB,1}-C SUB,10}; Y POSIBLEMENTE 3) UN DONADOR DE ELECTRONES EXTERNO (DE). EL PROCESO INCLUYE ETAPAS EN LAS QUE A) EN AUSENCIA DE OLEFINA POLIMERIZABLE, SE PONEN EN CONTACTO UNA PRIMERA CANTIDAD DE COCATALIZADOR Y AL MENOS LA MITAD DE LA CANTIDAD TOTAL DE PROCATALIZADOR DE MODO QUE LA RELACION MOLAR AL/TI ESTE COMPRENDIDA EN UN INTERVALO DE 0,1-20, CON OBJETO DE OBTENER UN PRODUCTO DE PRECONTACTO; B) SE PONEN EN CONTACTO EL PRODUCTO DE PRECONTACTO, UNA SEGUNDA CANTIDAD DE COCATALIZADOR, Y UNA O MAS OLEFINAS POLIMERIZABLES CONFORME A LA FORMULA (I) PARA PRODUCIR UN PRIMER PRODUCTO DE HOMO O COPOLIMERIZACION O ALTERNATIVAMENTE UN PRODUCTO DE PREPOLIMERIZACION; C) ALTERNATIVAMENTE, SE PONEN EN CONTACTO EL PRODUCTO DE PREPOLIMERIZACION, UNA TERCERA CANTIDAD DE COCATALIZADOR, Y UNA O MAS OLEFINAS POLIMERIZABLES CONFORME A LA FORMULA (I) PARA PRODUCIR UN SEGUNDO PRODUCTO DE HOMO O COPOLIMERIZACION; Y D) SE RECUPERA EL PRIMER PRODUCTO DE HOMO O COPOLIMERIZACION, EL PRODUCTO DE PREPOLIMERIZACION O EL SEGUNDO PRODUCTO DE HOMO O COPOLIMERIZACION.
ES96913547T 1995-05-05 1996-05-06 Procedimiento y constituyente catalizador para la copolimerizacion y la homopolimerizacion de olefinas. Expired - Lifetime ES2137690T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FI952175A FI952175A (fi) 1995-05-05 1995-05-05 Menetelmä ja katalysaattorikomponentti olefiinien homo- tai kopolymeroimiseksi

Publications (1)

Publication Number Publication Date
ES2137690T3 true ES2137690T3 (es) 1999-12-16

Family

ID=8543356

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96913547T Expired - Lifetime ES2137690T3 (es) 1995-05-05 1996-05-06 Procedimiento y constituyente catalizador para la copolimerizacion y la homopolimerizacion de olefinas.

Country Status (13)

Country Link
US (1) US6043324A (es)
EP (1) EP0823919B1 (es)
JP (1) JP3372549B2 (es)
KR (1) KR100381747B1 (es)
CN (1) CN1096471C (es)
AT (1) ATE184292T1 (es)
BR (1) BR9608172A (es)
CA (1) CA2220154A1 (es)
DE (1) DE69604169T2 (es)
EA (1) EA000615B1 (es)
ES (1) ES2137690T3 (es)
FI (1) FI952175A (es)
WO (1) WO1996034899A1 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6394417B1 (en) * 1998-10-09 2002-05-28 Swagelok Co. Sanitary diaphragm valve
FI990283A (fi) 1999-02-12 2000-08-13 Borealis As alfa-olefiinin polymerointikatalysattorisysteemi ja sen käyttö alfa -olefiinien polymerointiin
KR100421551B1 (ko) * 2000-12-16 2004-03-09 삼성아토피나주식회사 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법
US6630544B1 (en) * 2002-04-18 2003-10-07 Equistar Chemicals, Lp Propylene polymerization process with enhanced catalyst activity
ES2309445T3 (es) 2004-12-17 2008-12-16 Borealis Technology Oy Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas.
US7540702B2 (en) * 2005-05-16 2009-06-02 Wilhelm Bahmueller Maschinenbau-Praezisionswerkzeuge Gmbh Device for stacking flat products
CN1863133A (zh) * 2005-07-18 2006-11-15 华为技术有限公司 报文转发方法及装置
US7615596B2 (en) 2005-09-30 2009-11-10 Chevron Phillips Chemical Company Lp Multiple component feed methods and systems
KR20070091444A (ko) * 2006-03-06 2007-09-11 주식회사 엘지화학 올레핀 전중합을 이용한 프로필렌의 중합방법
KR101115170B1 (ko) * 2006-08-21 2012-03-13 주식회사 엘지화학 올레핀 중합용 촉매계 및 이를 이용한 올레핀 중합방법
US20100125124A1 (en) * 2008-11-17 2010-05-20 Fina Technology, Inc. Methods of catalyst activation
KR101769275B1 (ko) 2009-06-19 2017-08-18 바셀 폴리올레핀 이탈리아 에스.알.엘 내충격성 프로필렌 중합체 조성물의 제조 방법
EP2428526A1 (en) 2010-09-13 2012-03-14 Borealis AG Process for producing polyethylene with improved homogeneity
JP5918486B2 (ja) * 2011-07-06 2016-05-18 サンアロマー株式会社 α−オレフィン重合方法
EP2543684B1 (en) * 2011-07-07 2016-12-21 Borealis AG Process for the manufacture of isotactic polypropylene
EP3241611B1 (en) 2016-05-02 2020-03-04 Borealis AG A process for feeding a polymerisation catalyst
RU2738204C2 (ru) * 2016-06-23 2020-12-09 Чайна Петролеум Энд Кемикал Корпорейшн Устройство предварительного контакта катализатора для непрерывной полимеризации олефинов и способ предварительного контакта катализатора
KR102336976B1 (ko) * 2017-07-19 2021-12-07 차이나 페트로리움 앤드 케미컬 코포레이션 시클로트리베라트릴렌 및 이의 유도체를 포함하는 올레핀 중합 촉매
CN115232235B (zh) * 2021-04-25 2024-02-13 中国石油化工股份有限公司 一种烯烃聚合物的制造方法及烯烃聚合物
CN115232236B (zh) * 2021-04-25 2024-05-07 中国石油化工股份有限公司 一种丙烯基共聚物及其制备方法和应用和聚丙烯组合物
CN115246906B (zh) * 2021-04-28 2023-09-15 中国石油化工股份有限公司 烯烃聚合催化剂组分、烯烃聚合催化剂和烯烃聚合方法和应用
CN114891140A (zh) * 2022-04-29 2022-08-12 浙江大学 一种低灰分、高共聚单体含量聚烯烃共聚物的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4376062A (en) * 1979-11-28 1983-03-08 Union Carbide Corporation Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization
JPS59117509A (ja) * 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd オレフインの重合方法
DE3789500T2 (de) * 1987-02-02 1994-08-04 Fina Technology Verfahren zur Verbesserung der Effektivität eines vorpolymerisierten Katalysators.
KR920002488B1 (ko) * 1988-06-17 1992-03-26 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀의 중합방법 및 중합용 촉매
IT1246614B (it) * 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine

Also Published As

Publication number Publication date
AU5649796A (en) 1996-11-21
EP0823919A1 (en) 1998-02-18
EA199700298A1 (ru) 1998-02-26
FI952175A0 (fi) 1995-05-05
WO1996034899A1 (en) 1996-11-07
EP0823919B1 (en) 1999-09-08
DE69604169T2 (de) 2000-04-20
AU694658B2 (en) 1998-07-23
KR100381747B1 (ko) 2003-07-16
CA2220154A1 (en) 1996-11-07
DE69604169D1 (de) 1999-10-14
BR9608172A (pt) 1999-12-07
KR19990008337A (ko) 1999-01-25
EA000615B1 (ru) 1999-12-29
CN1183788A (zh) 1998-06-03
JPH11504957A (ja) 1999-05-11
ATE184292T1 (de) 1999-09-15
CN1096471C (zh) 2002-12-18
US6043324A (en) 2000-03-28
FI952175A (fi) 1996-11-06
JP3372549B2 (ja) 2003-02-04

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