ES2157350T3 - Proceso para la produccion de concentrados de tocoferol y tocoferol/tocotrienol. - Google Patents
Proceso para la produccion de concentrados de tocoferol y tocoferol/tocotrienol.Info
- Publication number
- ES2157350T3 ES2157350T3 ES95939870T ES95939870T ES2157350T3 ES 2157350 T3 ES2157350 T3 ES 2157350T3 ES 95939870 T ES95939870 T ES 95939870T ES 95939870 T ES95939870 T ES 95939870T ES 2157350 T3 ES2157350 T3 ES 2157350T3
- Authority
- ES
- Spain
- Prior art keywords
- tocoferol
- concentrates
- tocotrienol
- procedure
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/58—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4
- C07D311/70—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring other than with oxygen or sulphur atoms in position 2 or 4 with two hydrocarbon radicals attached in position 2 and elements other than carbon and hydrogen in position 6
- C07D311/72—3,4-Dihydro derivatives having in position 2 at least one methyl radical and in position 6 one oxygen atom, e.g. tocopherols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyrane Compounds (AREA)
- Fats And Perfumes (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
SE DESCRIBE UN PROCEDIMIENTO MEJORADO DE PREPARACION DE CONCENTRADOS DE TOCOFEROL Y TOCOFEROL/TOCOTRIENOL, A PARTIR DE DESTILADOS DE ACEITES VEGETALES. SE OBTIENEN CONCENTRADOS DE TOCOFEROL, QUE CONTIENEN DEL 20 AL 80% EN PESO DE TOCOFEROL, CON UNA RECUPERACION TOTAL DE TOCOFEROL DEL 72 AL 97%. EL PROCEDIMIENTO COMPRENDE, PRIMERAMENTE, UNA REACCION DE ESTERIFICACION, EN LA QUE LOS ALCOHOLES MAS VOLATILES SE CONVIERTEN EN SUS ESTERES DE ACIDOS GRASOS MENOS VOLATILES. DICHA FASE, ESTA SEGUIDA DE UNA SERIE DE FASES DE DESTILACION, EN LAS QUE LOS COMPONENTES CON PUNTOS DE EBULLICION SUPERIORES EN INFERIORES A LOS DEL TOCOFEROL, SE SEPARAN DE LOS TOCOFEROLES Y OTRAS SUSTANCIAS DE PUNTOS DE EBULLICION SIMILARES. LAS VENTAJAS DEL PROCEDIMIENTO SON QUE LOS CONCENTRADOS DE TOCOFEROL Y TOCOFEROL/TOCOTRIENOL, SE PRODUCEN EFICIENTE Y ECONOMICAMENTE, CON UN NUMERO MINIMO DE FASES, SIN UTILIZACION DE DISOLVENTES, Y CON UNA INVERSION DE CAPITAL RELATIVAMENTE PEQUEÑA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/334,901 US5512691A (en) | 1994-11-07 | 1994-11-07 | Process for the production of tocopherol concentrates |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2157350T3 true ES2157350T3 (es) | 2001-08-16 |
Family
ID=23309363
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95939870T Expired - Lifetime ES2157350T3 (es) | 1994-11-07 | 1995-11-07 | Proceso para la produccion de concentrados de tocoferol y tocoferol/tocotrienol. |
Country Status (18)
Country | Link |
---|---|
US (1) | US5512691A (es) |
EP (1) | EP0790990B1 (es) |
JP (1) | JP4142096B2 (es) |
CN (1) | CN1176920C (es) |
AR (1) | AR000081A1 (es) |
AU (1) | AU4153096A (es) |
BR (1) | BR9509626A (es) |
CA (1) | CA2203550A1 (es) |
CZ (1) | CZ129697A3 (es) |
DE (1) | DE69521437T2 (es) |
ES (1) | ES2157350T3 (es) |
IL (1) | IL115888A0 (es) |
MY (1) | MY111850A (es) |
PT (1) | PT790990E (es) |
SK (1) | SK53397A3 (es) |
TR (1) | TR199501378A2 (es) |
WO (1) | WO1996014311A1 (es) |
ZA (1) | ZA959433B (es) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5582692A (en) * | 1994-10-07 | 1996-12-10 | Artisan Industries, Inc. | Method for the purification of vitamin E |
US5660691A (en) * | 1995-11-13 | 1997-08-26 | Eastman Chemical Company | Process for the production of tocotrienol/tocopherol blend concentrates |
US5703252A (en) * | 1995-12-13 | 1997-12-30 | Henkel Corporation | Recovery of Tocopherols |
US5917068A (en) * | 1995-12-29 | 1999-06-29 | Eastman Chemical Company | Polyunsaturated fatty acid and fatty acid ester mixtures free of sterols and phosphorus compounds |
US5883273A (en) * | 1996-01-26 | 1999-03-16 | Abbott Laboratories | Polyunsaturated fatty acids and fatty acid esters free of sterols and phosphorus compounds |
US6063946A (en) * | 1996-01-26 | 2000-05-16 | Eastman Chemical Company | Process for the isolation of polyunsaturated fatty acids and esters thereof from complex mixtures which contain sterols and phosphorus compounds |
EP0914329B1 (en) * | 1996-07-05 | 2003-05-21 | Unilever N.V. | Method of manufacturing an ester mixture |
DE19652522C2 (de) * | 1996-12-17 | 2000-10-26 | Cognis Deutschland Gmbh | Verfahren zur Gewinnung von Tocopherolen und/oder Sterinen |
EP1051411B1 (en) * | 1998-01-29 | 2002-08-28 | Eastman Chemical Company | Methods for separating a tocol from a tocol-containing mixture |
US6706898B2 (en) * | 1998-01-29 | 2004-03-16 | Archer-Daniels-Midland Company | Methods for separating a tocopherol from a tocopherol-containing mixture |
US6616942B1 (en) | 1999-03-29 | 2003-09-09 | Soft Gel Technologies, Inc. | Coenzyme Q10 formulation and process methodology for soft gel capsules manufacturing |
US6410758B2 (en) | 1999-05-24 | 2002-06-25 | Mcneil-Ppc, Inc. | Preparation of sterol and stanol-esters |
CN1091106C (zh) * | 1999-11-19 | 2002-09-18 | 上海交通大学 | 超临界流体提取浓缩天然维生素e的工艺 |
US6838104B2 (en) * | 2000-12-20 | 2005-01-04 | Archer Daniels Midland Company | Process for the production of tocotrienols |
EP1417288B1 (en) * | 2001-07-23 | 2018-08-29 | Cargill, Incorporated | Method and apparatus for processing vegetable oils |
WO2003037884A2 (en) | 2001-09-19 | 2003-05-08 | Archer-Daniels-Midland Company | Process for separation of tocopherols |
US6673945B2 (en) * | 2001-11-08 | 2004-01-06 | Archer-Daniels Midland Company | Process for production of high purity tocopherols |
IL147942A0 (en) * | 2002-01-31 | 2002-08-14 | Enzymotec Ltd | Method of fractionation of phytosterol esters in oil and products obtained thereby |
US20040030166A1 (en) * | 2002-03-18 | 2004-02-12 | Dick Copeland | Methods for treating deodorizer distillate |
AU2002241324A1 (en) * | 2002-03-28 | 2003-10-13 | Fuji Oil Company, Limited | Fat producing method |
UA78066C2 (en) * | 2002-06-19 | 2007-02-15 | Process for recovery of plant sterols and tocopherols from deodorized distillates | |
IL154381A0 (en) * | 2003-02-10 | 2003-09-17 | Enzymotec Ltd | A composition for reducing blood cholesterol and triglycerides |
US20060233863A1 (en) | 2003-02-10 | 2006-10-19 | Enzymotec Ltd. | Oils enriched with diacylglycerols and phytosterol esters and unit dosage forms thereof for use in therapy |
US20080089877A1 (en) * | 2003-08-14 | 2008-04-17 | Udell Ronald G | Super Absorption Coenzyme Q10 |
AU2004272561A1 (en) * | 2003-09-10 | 2005-03-24 | Eastman Chemical Company | Process for the recovery of a phytolipid composition |
US8124072B2 (en) | 2003-09-29 | 2012-02-28 | Soft Gel Technologies, Inc. | Solubilized CoQ-10 |
US7169385B2 (en) * | 2003-09-29 | 2007-01-30 | Ronald G. Udell | Solubilized CoQ-10 and carnitine |
US8105583B2 (en) * | 2003-09-29 | 2012-01-31 | Soft Gel Technologies, Inc. | Solubilized CoQ-10 |
JP4537761B2 (ja) * | 2004-05-13 | 2010-09-08 | 築野食品工業株式会社 | トコトリエノール含有家禽卵 |
WO2006016363A2 (en) | 2004-08-10 | 2006-02-16 | Enzymotec Ltd. | Mixture of phytosterol ester(s) and 1, 3-diglyceride(s) for use in the treatment of medical conditions |
EP2269998A3 (en) | 2004-08-19 | 2011-03-30 | DSM IP Assets B.V. | Process for the rectification of mixtures of high-boiling air- and/or temperature-sensitive useful products |
JP4930706B2 (ja) * | 2004-10-19 | 2012-05-16 | 味の素株式会社 | 植物組織から得られる油分中の微量成分を濃縮する方法 |
US20070292501A1 (en) * | 2006-06-05 | 2007-12-20 | Udell Ronald G | Chewable soft gelatin capsules |
US20080020022A1 (en) * | 2006-06-05 | 2008-01-24 | Udell Ronald G | Chewable co-enzyme q-10 capsule |
US8343541B2 (en) | 2007-03-15 | 2013-01-01 | Soft Gel Technologies, Inc. | Ubiquinol and alpha lipoic acid compositions |
US8673967B2 (en) * | 2007-05-24 | 2014-03-18 | Loders Croklaan B.V. | Process |
HUE029846T2 (en) * | 2008-10-06 | 2017-04-28 | Sulzer Chemtech Ag | Method and apparatus for separating carboxylic acids and / or carboxylic acid esters |
FR2939689B1 (fr) | 2008-12-15 | 2015-09-04 | Valagro Carbone Renouvelable | Procede d'extraction d'un compose mineur d'un corps gras, notamment d'une huile vegetale ou animale ou de leurs co-produits au moyen de terpene. |
FR2970971B1 (fr) * | 2011-01-31 | 2014-05-30 | Expanscience Lab | Utilisation d'au moins un co-produit de l'industrie du raffinage des huiles vegetales pour obtenir un insaponifiable total purifie d'huile vegetale. |
PL2597142T5 (pl) * | 2011-11-23 | 2020-10-05 | Alfa Laval Corporate Ab | Odkwaszanie tłuszczy i olejów |
PL2684944T3 (pl) | 2012-07-12 | 2015-03-31 | Alfa Laval Corp Ab | Odkwaszanie tłuszczów i olejów |
EP2810940A1 (en) | 2013-06-06 | 2014-12-10 | Sulzer Chemtech AG | A Process to Prepare A Tocopherol Concentrate |
CN104262315A (zh) * | 2014-09-05 | 2015-01-07 | 宁波大红鹰生物工程股份有限公司 | 一种生育三烯酚的分离提纯方法 |
MY193786A (en) * | 2015-01-12 | 2022-10-27 | Ho Sue San David | Recovery of tocopherols/tocotrienols, carotenoids, glycerols, sterols and fatty acid esters from crude vegetable oil and the process thereof |
JP6548087B2 (ja) | 2015-05-18 | 2019-07-24 | 国立大学法人東北大学 | ビタミンe類の選択的な分離方法 |
CN105061384B (zh) * | 2015-08-07 | 2018-02-09 | 宜春大海龟生命科学有限公司 | 一种以精馏‑分子蒸馏耦合方式制备天然维生素e的方法及装置 |
US11014903B2 (en) | 2017-02-17 | 2021-05-25 | Phytochem Products Inc. | Vitamin E production method and vitamin E production device |
WO2019157334A1 (en) | 2018-02-09 | 2019-08-15 | Poet Research, Inc. | Methods of refining a grain oil composition to make one or more grain oil products, and related systems |
CN112437607B (zh) | 2018-05-03 | 2024-07-05 | 可更新能源集团 | 生产生物柴油、柴油范围的烃和由其获得的产品的方法和装置 |
CA3103242C (en) | 2018-06-11 | 2023-08-29 | Poet Research, Inc. | Methods of refining a grain oil composition feedstock, and related systems, compositions and uses |
KR102043442B1 (ko) * | 2019-02-01 | 2019-11-11 | 주식회사 천강 | 지방산 및 유리지방산을 다량 함유한 유지를 촉매를 사용하지 않고 바이오디젤 원료용 저산가 글리세라이드를 제조하는 방법 |
EP4192964A1 (en) | 2020-08-06 | 2023-06-14 | POET Research, Inc. | Endogenous lipase for metal reduction in distillers corn oil |
KR102389517B1 (ko) * | 2020-08-10 | 2022-04-26 | 김진성 | 식물성 유지의 탈취 증류물로부터 토코페롤을 분리하는 방법 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2432181A (en) * | 1944-08-11 | 1947-12-09 | Colgate Palmolive Peet Co | Vitamin recovery |
US3153055A (en) * | 1962-03-20 | 1964-10-13 | Eastman Kodak Co | Process for separating tocopherols and sterols from deodorizer sludge and the like |
US3335154A (en) * | 1963-06-04 | 1967-08-08 | Eastman Kodak Co | Separation of tocopherols and sterols from deodorizer sludge and the like |
US4454329A (en) * | 1980-07-04 | 1984-06-12 | The Nisshin Oil Mills, Ltd. | Process for preparation of tocopherol concentrates |
US5487817A (en) * | 1993-02-11 | 1996-01-30 | Hoffmann-La Roche Inc. | Process for tocopherols and sterols from natural sources |
-
1994
- 1994-11-07 US US08/334,901 patent/US5512691A/en not_active Expired - Lifetime
-
1995
- 1995-11-06 AR AR33412995A patent/AR000081A1/es unknown
- 1995-11-06 IL IL11588895A patent/IL115888A0/xx unknown
- 1995-11-06 MY MYPI95003342A patent/MY111850A/en unknown
- 1995-11-07 ES ES95939870T patent/ES2157350T3/es not_active Expired - Lifetime
- 1995-11-07 SK SK533-97A patent/SK53397A3/sk unknown
- 1995-11-07 WO PCT/US1995/014612 patent/WO1996014311A1/en not_active Application Discontinuation
- 1995-11-07 EP EP95939870A patent/EP0790990B1/en not_active Revoked
- 1995-11-07 CN CNB951969676A patent/CN1176920C/zh not_active Expired - Fee Related
- 1995-11-07 BR BR9509626A patent/BR9509626A/pt not_active Application Discontinuation
- 1995-11-07 ZA ZA959433A patent/ZA959433B/xx unknown
- 1995-11-07 PT PT95939870T patent/PT790990E/pt unknown
- 1995-11-07 TR TR95/01378A patent/TR199501378A2/xx unknown
- 1995-11-07 AU AU41530/96A patent/AU4153096A/en not_active Abandoned
- 1995-11-07 CA CA002203550A patent/CA2203550A1/en not_active Abandoned
- 1995-11-07 JP JP51552596A patent/JP4142096B2/ja not_active Expired - Fee Related
- 1995-11-07 DE DE69521437T patent/DE69521437T2/de not_active Revoked
- 1995-11-07 CZ CZ971296A patent/CZ129697A3/cs unknown
Also Published As
Publication number | Publication date |
---|---|
DE69521437D1 (de) | 2001-07-26 |
BR9509626A (pt) | 1998-01-06 |
PT790990E (pt) | 2001-09-28 |
EP0790990A1 (en) | 1997-08-27 |
JPH10508605A (ja) | 1998-08-25 |
MX9703275A (es) | 1997-07-31 |
SK53397A3 (en) | 1998-05-06 |
DE69521437T2 (de) | 2001-10-18 |
CA2203550A1 (en) | 1996-05-17 |
CN1176920C (zh) | 2004-11-24 |
US5512691A (en) | 1996-04-30 |
CN1171106A (zh) | 1998-01-21 |
EP0790990B1 (en) | 2001-06-20 |
CZ129697A3 (cs) | 1998-02-18 |
AR000081A1 (es) | 1997-05-21 |
MY111850A (en) | 2001-01-31 |
TR199501378A2 (tr) | 1996-06-21 |
IL115888A0 (en) | 1996-01-31 |
AU4153096A (en) | 1996-05-31 |
WO1996014311A1 (en) | 1996-05-17 |
JP4142096B2 (ja) | 2008-08-27 |
ZA959433B (en) | 1996-05-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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