ES2147199T3 - Formulaciones, metodo y aparato para la generacion controlada de fosfina. - Google Patents
Formulaciones, metodo y aparato para la generacion controlada de fosfina.Info
- Publication number
- ES2147199T3 ES2147199T3 ES93912420T ES93912420T ES2147199T3 ES 2147199 T3 ES2147199 T3 ES 2147199T3 ES 93912420 T ES93912420 T ES 93912420T ES 93912420 T ES93912420 T ES 93912420T ES 2147199 T3 ES2147199 T3 ES 2147199T3
- Authority
- ES
- Spain
- Prior art keywords
- formulation
- water
- phosphide
- phosphine
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 10
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 6
- 229910000073 phosphorus hydride Inorganic materials 0.000 title abstract 3
- 238000009472 formulation Methods 0.000 abstract 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000005952 Aluminium phosphide Substances 0.000 abstract 1
- 239000005953 Magnesium phosphide Substances 0.000 abstract 1
- 239000005662 Paraffin oil Substances 0.000 abstract 1
- PPNXXZIBFHTHDM-UHFFFAOYSA-N aluminium phosphide Chemical compound P#[Al] PPNXXZIBFHTHDM-UHFFFAOYSA-N 0.000 abstract 1
- 239000012159 carrier gas Substances 0.000 abstract 1
- 238000003958 fumigation Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000011872 intimate mixture Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 235000019271 petrolatum Nutrition 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/06—Hydrogen phosphides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catching Or Destruction (AREA)
- Air Bags (AREA)
Abstract
UNA FORMULACION PARA USARLA EN LA GENERACION CONTROLADA DE FOSFITO COMPRENDE UNA MEZCLA INTIMA DE UN FOSFITO PARTICULAR Y UN COMPUESTO INMISCIBLE EN AGUA, TENIENDO LA MEZCLA LA CONSISTENCIA DE UNA PASTA ESTIRABLE O UNA SUSPENSION GRUESA. EL FOSFITO, QUE ES PREFERENTEMENTE FOSFITO DE ALUMINIO O FOSFITO DE MAGNESIO COMPRENDE DEL 65 AL 85% (DE PESO) DE LA FORMULACION. EL COMPUESTO INMISCIBLE EN AGUA ES PREFERIBLEMENTE ACEITE DE PARAFINA, JALEA DE PETROLEO, O UNA MEZCLA DE ESTOS MATERIALES. SE PUEDE INCLUIR EN LA FORMULACION UN AGENTE ACTIVO DE SUPERFICIE. TAL FORMULACION (21, 41) SE PUEDE MANTENER EN UN CARTUCHO (20, 40) Y AÑADIR PROGRESIVAMENTE AL AGUA (13, 33) EN UNA CAMARA DE REACCION (10, 30). ALTERNATIVAMENTE LA FORMULACION SE PUEDE ENVASAR EN UN CONTENEDOR IMPERMEABLE AL AGUA DESDE EL QUE SE PUEDE ELIMINAR UNA REGION PARA EXPONER LA FORMULACION AL VAPOR DE AGUA EN UN FLUJO DE GAS QUE PASA POR AL CONTENEDOR. EL AGUA (13, 33) O EL VAPOR DE AGUA SE ELIMINA O DIFUNDE A TRAVES DEL COMPUESTO INMISCIBLE AL AGUA DE LA FORMULACION, DESPUES REACCIONA CON EL FOSFITO PARA FORMAR FOSFINA. LA FOSFINA MEZCLADA CON EL GAS PORTADOR (NORMALMENTE AIRE), SE PUEDE ALIMENTAR DENTRO DE UN CONDUCTO (15, 55, 66) CONECTADO A UN SILO DE GRANO, PARA LA FUMIGACION DEL GRANO ALMACENADO EN EL MISMO.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPL283092 | 1992-06-05 | ||
| AUPL582192 | 1992-11-16 | ||
| CN93119910A CN1040527C (zh) | 1992-06-05 | 1993-12-17 | 用于产生磷化氢的配制品 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2147199T3 true ES2147199T3 (es) | 2000-09-01 |
Family
ID=36940029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93912420T Expired - Lifetime ES2147199T3 (es) | 1992-06-05 | 1993-06-04 | Formulaciones, metodo y aparato para la generacion controlada de fosfina. |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0643556B1 (es) |
| JP (1) | JPH07507552A (es) |
| CN (1) | CN1040527C (es) |
| AT (1) | ATE191609T1 (es) |
| AU (1) | AU668429B2 (es) |
| BR (1) | BR9306500A (es) |
| CA (1) | CA2137074A1 (es) |
| DE (1) | DE69328361T2 (es) |
| ES (1) | ES2147199T3 (es) |
| GR (1) | GR3033924T3 (es) |
| HU (1) | HU217564B (es) |
| RU (1) | RU2131190C1 (es) |
| WO (1) | WO1993025075A1 (es) |
| ZA (1) | ZA933931B (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5932172A (en) * | 1989-06-27 | 1999-08-03 | Commonwealth Scientific And Industrial Organisation | Fumigation of multiple grain storages from a single source of fumigant |
| US6440390B2 (en) | 1992-06-05 | 2002-08-27 | Commonwealth Scientific And Industrial Research Organisation | Formulations containing a phosphide for use in the controlled generation of phosphine |
| GB9511495D0 (en) * | 1995-06-07 | 1995-08-02 | Degesch De Chile Ltda | Composition, process and apparatus for producing phosphine - containing gas |
| US6047497A (en) * | 1997-03-18 | 2000-04-11 | The Boc Group, Inc. | Gas fumigation method and system |
| WO2000001615A1 (en) * | 1998-07-06 | 2000-01-13 | Electron Transfer Technologies, Inc. | Method and apparatus for the preparation of high purity phosphine or other gas |
| DE19839385A1 (de) * | 1998-08-28 | 2000-03-23 | Horn Pedro Miguel | Verfahren und Vorrichtung zur Verdünnung von Phosphorwasserstoff mit Luft ohne Entzündungsgefahr |
| US7556785B2 (en) | 2003-05-12 | 2009-07-07 | United Phosphorus, Ltd. | Apparatus and method for rapid and continuous generation of phosphine gas |
| EA011354B1 (ru) * | 2005-01-19 | 2009-02-27 | Александр Александрович Арямкин | Способ выработки газа-фумиганта (варианты), композиция для выработки газа-фумиганта (варианты) и способ фумигации (варианты) |
| EP3777531A1 (en) * | 2019-08-12 | 2021-02-17 | Linde GmbH | Method for fumigation, electrically powered vaporizer and system for fumigation |
| CN112806390B (zh) * | 2020-12-31 | 2022-03-11 | 河南省紫风养护发展有限公司 | 一种烟厂储烟熏蒸杀虫用复合杀虫剂及其制备方法、应用 |
| CN113289507B (zh) * | 2021-05-10 | 2023-02-03 | 内蒙古旭阳新材料有限公司 | 一种湿铝粉生产设备及方法 |
| MX2024000640A (es) * | 2021-07-15 | 2024-02-06 | Upl Ltd | Un sistema para generar gas fosfina. |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB333216A (en) * | 1929-05-06 | 1930-08-06 | Charles Ball | Improvements relating to preparations for exterminating rats, mice, and like vermin |
| FR750035A (fr) * | 1932-04-23 | 1933-08-03 | Procédé facilitant les manipulations, l'utilisation et la conservation du phosphure de zinc | |
| SU42271A1 (ru) * | 1934-08-09 | 1935-03-31 | И.И. Волосников | Термос |
| DE880817C (de) * | 1944-11-15 | 1953-06-25 | Riedel De Haeen Ag | Metallphosphidpaste zur Bekaempfung von Schaedlingen, insbesondere Nagetieren |
| BE625186A (es) * | 1961-11-25 | |||
| DE1567520B2 (de) * | 1966-04-07 | 1973-01-04 | Freyberg, Werner, Dr., 6149 Kirschhausen | Verfahren zur Herstellung von Magnesiumphosphid |
| JPS5014785Y2 (es) * | 1973-01-06 | 1975-05-08 | ||
| AR228128A1 (es) * | 1978-06-22 | 1983-01-31 | Freyberg Chem Fab Werner | Dispositivo plaguicida y procedimiento de preparacion de una atmosfera toxica aplicando dicho dispositivo |
| US4227684A (en) * | 1978-10-26 | 1980-10-14 | Opelika Manufacturing Corp. | Sheet folder |
| DE2846832B1 (de) * | 1978-10-27 | 1980-02-07 | Hoechst Ag | Spurenelementduengemittelpasten und Verfahren zu deren Herstellung |
| US4200657A (en) * | 1978-11-09 | 1980-04-29 | Cook James S | Low air flow fumigation method |
| YU45563B (sh) * | 1982-07-26 | 1992-07-20 | Dr. Werner Freyberg Chemische Fabrik Delitia Nachf | Postupak za tretiranje gasom fosfinom rastresitog materijala |
| US4863718A (en) * | 1984-09-19 | 1989-09-05 | Casa Bernardo Ltd. | Process for the elaboration of an insecticide |
| DD271012A3 (de) * | 1987-08-03 | 1989-08-23 | Delicia Veb | Rodentizide paste zur herstellung von koedern zur nagetierbekaempfung |
| AR248331A1 (es) * | 1987-11-27 | 1995-08-18 | Detia Freyberg Gmbh | Procedimiento y aparato para generar una mezcla plaguicida gaseosa de fosfina gaseosa y aire para fumigar con fosfina un ambiente cerrado. |
| AR244505A1 (es) * | 1988-05-14 | 1993-11-30 | Deutsche Ges Schaedlingsbek | Metodo para impedir o retardar la formacion de niveles indeseables de fosfina en un espacio o ambiente, y producto plaguicida para llevar a cabo dicho metodo. |
| GB8811477D0 (en) * | 1988-05-14 | 1988-06-15 | Deutsche Ges Schaedlingsbek | Preventing/delaying formation of undesired phosphine levels |
| CN1048026A (zh) * | 1989-06-15 | 1990-12-26 | 赵世荣 | 多元素复合叶面肥料及制造 |
-
1993
- 1993-06-04 JP JP6500957A patent/JPH07507552A/ja active Pending
- 1993-06-04 CA CA002137074A patent/CA2137074A1/en not_active Abandoned
- 1993-06-04 WO PCT/AU1993/000270 patent/WO1993025075A1/en not_active Ceased
- 1993-06-04 AU AU51616/93A patent/AU668429B2/en not_active Ceased
- 1993-06-04 BR BR9306500A patent/BR9306500A/pt not_active IP Right Cessation
- 1993-06-04 AT AT93912420T patent/ATE191609T1/de not_active IP Right Cessation
- 1993-06-04 EP EP93912420A patent/EP0643556B1/en not_active Expired - Lifetime
- 1993-06-04 HU HU9403462A patent/HU217564B/hu not_active IP Right Cessation
- 1993-06-04 RU RU94046233/04A patent/RU2131190C1/ru not_active IP Right Cessation
- 1993-06-04 ZA ZA933931A patent/ZA933931B/xx unknown
- 1993-06-04 DE DE69328361T patent/DE69328361T2/de not_active Expired - Lifetime
- 1993-06-04 ES ES93912420T patent/ES2147199T3/es not_active Expired - Lifetime
- 1993-12-17 CN CN93119910A patent/CN1040527C/zh not_active Expired - Fee Related
-
2000
- 2000-07-10 GR GR20000401609T patent/GR3033924T3/el not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR9306500A (pt) | 1998-09-15 |
| HUT69290A (en) | 1995-09-28 |
| CN1040527C (zh) | 1998-11-04 |
| EP0643556A1 (en) | 1995-03-22 |
| HU217564B (hu) | 2000-02-28 |
| ZA933931B (en) | 1994-04-13 |
| EP0643556B1 (en) | 2000-04-12 |
| JPH07507552A (ja) | 1995-08-24 |
| AU668429B2 (en) | 1996-05-02 |
| CN1104997A (zh) | 1995-07-12 |
| WO1993025075A1 (en) | 1993-12-23 |
| EP0643556A4 (en) | 1997-07-16 |
| DE69328361T2 (de) | 2000-12-07 |
| RU2131190C1 (ru) | 1999-06-10 |
| DE69328361D1 (de) | 2000-05-18 |
| CA2137074A1 (en) | 1993-12-23 |
| AU5161693A (en) | 1994-01-04 |
| GR3033924T3 (en) | 2000-11-30 |
| ATE191609T1 (de) | 2000-04-15 |
| RU94046233A (ru) | 1996-10-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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