ES2147154A1 - Evacuacion de arsenico a partir de soluciones que contienen dioxido de azufre. - Google Patents
Evacuacion de arsenico a partir de soluciones que contienen dioxido de azufre.Info
- Publication number
- ES2147154A1 ES2147154A1 ES9802559A ES9802559A ES2147154A1 ES 2147154 A1 ES2147154 A1 ES 2147154A1 ES 9802559 A ES9802559 A ES 9802559A ES 9802559 A ES9802559 A ES 9802559A ES 2147154 A1 ES2147154 A1 ES 2147154A1
- Authority
- ES
- Spain
- Prior art keywords
- arsenic
- sulfur dioxide
- iron
- removal
- containing solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B30/00—Obtaining antimony, arsenic or bismuth
- C22B30/04—Obtaining arsenic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Removal Of Specific Substances (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
Evacuación de arsénico a partir de soluciones que contienen dióxido de azufre; se trata de un procedimiento que crea un método para eliminar arsénico a partir de soluciones que contienen dióxido de azufre de una manera aceptable para el medio ambiente; este procedimiento oxida primeramente el arsénico, el hierro y el dióxido de azufre contenidos en una solución acuosa con el fin de preparar a la solución para precipitación y mejorar el control del procedimiento; el precipitado neutralizado reciclado forma núcleos en (nuclea a) la solución acuosa oxidada; una base que contiene calcio hace precipitar los productos de neutralización en los materiales nucleados; el precipitado neutralizado final contiene compuestos estables de arseniato férrico. Figura 1.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/987,513 US5820966A (en) | 1997-12-09 | 1997-12-09 | Removal of arsenic from iron arsenic and sulfur dioxide containing solutions |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2147154A1 true ES2147154A1 (es) | 2000-08-16 |
ES2147154B1 ES2147154B1 (es) | 2001-05-16 |
Family
ID=25533334
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES9802559A Expired - Fee Related ES2147154B1 (es) | 1997-12-09 | 1998-12-07 | Evacuacion de arsenico a partir de soluciones que contienen dioxido de azufre. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5820966A (es) |
JP (1) | JP4255154B2 (es) |
AU (1) | AU736759B2 (es) |
CA (1) | CA2255874C (es) |
ES (1) | ES2147154B1 (es) |
FI (1) | FI118802B (es) |
PE (1) | PE20000024A1 (es) |
ZA (1) | ZA9811213B (es) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19811763A1 (de) * | 1998-03-18 | 1999-09-23 | Stadtwerke Karlsruhe Gmbh | Verfahren zur Abtrennung von Arsen |
US7314604B1 (en) * | 1999-09-30 | 2008-01-01 | Billiton Intellectual Property, B.V. | Stable ferric arsenate precipitation from acid copper solutions whilst minimising copper losses |
US6177015B1 (en) | 1999-10-18 | 2001-01-23 | Inco Limited | Process for reducing the concentration of dissolved metals and metalloids in an aqueous solution |
FI110268B (fi) * | 2001-03-09 | 2002-12-31 | Outokumpu Oy | Menetelmä kalsiumin poistamiseksi sinkkiprosessin sulfaattiliuoksista |
JP2006512484A (ja) * | 2002-12-31 | 2006-04-13 | インテック・リミテッド | 硫化物系材料からの金属の回収 |
US6863825B2 (en) | 2003-01-29 | 2005-03-08 | Union Oil Company Of California | Process for removing arsenic from aqueous streams |
US20050194263A1 (en) * | 2004-03-02 | 2005-09-08 | Ronald Miziolek | Electrochemical water purification system and method |
US8066874B2 (en) | 2006-12-28 | 2011-11-29 | Molycorp Minerals, Llc | Apparatus for treating a flow of an aqueous solution containing arsenic |
US7641801B2 (en) | 2007-02-28 | 2010-01-05 | Vale Inco Limited | Method for removing manganese from nickel laterite waste liquors |
JP4822445B2 (ja) * | 2007-07-13 | 2011-11-24 | Dowaメタルマイン株式会社 | 種晶を添加する砒素の処理方法 |
JP4971933B2 (ja) * | 2007-10-02 | 2012-07-11 | Dowaメタルマイン株式会社 | 鉄砒素化合物の製造方法 |
US8349764B2 (en) | 2007-10-31 | 2013-01-08 | Molycorp Minerals, Llc | Composition for treating a fluid |
US8252087B2 (en) | 2007-10-31 | 2012-08-28 | Molycorp Minerals, Llc | Process and apparatus for treating a gas containing a contaminant |
FI120315B (fi) * | 2007-11-27 | 2009-09-15 | Outotec Oyj | Menetelmä pyriittisen, kultaa, kuparia ja arseenia sisältävän rikasteen käsittelemiseksi |
CN101619398B (zh) * | 2009-07-27 | 2011-07-27 | 昭通天元实业有限责任公司 | 一种在硫酸渣中提取砷的方法 |
FI122512B (fi) * | 2011-03-09 | 2012-02-29 | Outotec Oyj | Menetelmä niukkaliukoisen kalsiumarseeniyhdisteen valmistamiseksi |
US9233863B2 (en) | 2011-04-13 | 2016-01-12 | Molycorp Minerals, Llc | Rare earth removal of hydrated and hydroxyl species |
CN102642974B (zh) * | 2012-05-07 | 2014-05-07 | 昆明理工大学 | 一种高酸高氯废水处理方法 |
EP3113859A4 (en) | 2014-03-07 | 2017-10-04 | Secure Natural Resources LLC | Cerium (iv) oxide with exceptional arsenic removal properties |
CN104829014B (zh) * | 2015-06-03 | 2018-01-12 | 南宁市桂润环境工程有限公司 | 一种铅锌工业选矿、冶炼废水的短程膜分离处理工艺 |
CN106746402B (zh) * | 2016-12-19 | 2020-06-02 | 崇义章源钨业股份有限公司 | 处理除砷污泥的方法 |
US11220437B2 (en) | 2018-12-24 | 2022-01-11 | Ecometales Limited | Procedure for obtaining scorodite with a high arsenic content from acidic solutions with high content of sulfuric acid |
WO2020133210A1 (zh) * | 2018-12-28 | 2020-07-02 | 焱鑫环保科技有限公司 | 一种用含砷工业碱渣脱除含硫烟气中硫生产亚硫酸钠的方法 |
CN109942070A (zh) * | 2019-04-19 | 2019-06-28 | 哈尔滨工业大学 | 一种利用亚硫酸盐与铁盐催化氧化体系去除水中砷的方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617562A (en) * | 1970-05-08 | 1971-11-02 | Allen Cywin | Neutralization of ferrous iron-containing acid wastes |
US4241039A (en) * | 1977-12-14 | 1980-12-23 | Dowa Mining Co. Ltd. | Method of removal of arsenic from a sulfuric acid solution |
US4366128A (en) * | 1980-08-22 | 1982-12-28 | Sherritt Gordon Mines Limited | Removal of arsenic from aqueous solutions |
US4622149A (en) * | 1984-05-23 | 1986-11-11 | Inco Limited | Effluent treatment |
US5427691A (en) * | 1992-12-02 | 1995-06-27 | Noranda, Inc. | Lime neutralization process for treating acidic waters |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3738932A (en) * | 1971-04-19 | 1973-06-12 | Bethlehem Steel Corp | Method for treating acid water containing metallic values |
US4465597B2 (en) * | 1981-08-10 | 1997-07-01 | Tetra Tech | Treatment of industrial wastewaters |
JPS59164639A (ja) * | 1983-03-08 | 1984-09-17 | Nippon Mining Co Ltd | ひ素の分離法 |
US4655829A (en) * | 1984-05-03 | 1987-04-07 | Css Management Corp. | Metal recovery process |
US5024769A (en) * | 1988-07-29 | 1991-06-18 | Union Oil Company Of California | Method of treating an arsenic-containing solution |
ZA928157B (en) * | 1991-10-25 | 1993-06-09 | Sasox Processing Pty Ltd | Extraction or recovery of metal values. |
-
1997
- 1997-12-09 US US08/987,513 patent/US5820966A/en not_active Expired - Lifetime
-
1998
- 1998-11-24 PE PE1998001142A patent/PE20000024A1/es not_active Application Discontinuation
- 1998-12-07 ES ES9802559A patent/ES2147154B1/es not_active Expired - Fee Related
- 1998-12-07 CA CA 2255874 patent/CA2255874C/en not_active Expired - Fee Related
- 1998-12-08 JP JP34866598A patent/JP4255154B2/ja not_active Expired - Lifetime
- 1998-12-08 ZA ZA9811213A patent/ZA9811213B/xx unknown
- 1998-12-08 FI FI982657A patent/FI118802B/fi not_active IP Right Cessation
- 1998-12-08 AU AU96988/98A patent/AU736759B2/en not_active Ceased
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617562A (en) * | 1970-05-08 | 1971-11-02 | Allen Cywin | Neutralization of ferrous iron-containing acid wastes |
US4241039A (en) * | 1977-12-14 | 1980-12-23 | Dowa Mining Co. Ltd. | Method of removal of arsenic from a sulfuric acid solution |
US4366128A (en) * | 1980-08-22 | 1982-12-28 | Sherritt Gordon Mines Limited | Removal of arsenic from aqueous solutions |
US4622149A (en) * | 1984-05-23 | 1986-11-11 | Inco Limited | Effluent treatment |
US5427691A (en) * | 1992-12-02 | 1995-06-27 | Noranda, Inc. | Lime neutralization process for treating acidic waters |
Also Published As
Publication number | Publication date |
---|---|
FI982657A0 (fi) | 1998-12-08 |
FI982657A (fi) | 1999-06-10 |
FI118802B (fi) | 2008-03-31 |
ZA9811213B (en) | 1999-06-09 |
ES2147154B1 (es) | 2001-05-16 |
CA2255874C (en) | 2003-05-27 |
JP4255154B2 (ja) | 2009-04-15 |
JP2000203840A (ja) | 2000-07-25 |
CA2255874A1 (en) | 1999-06-09 |
PE20000024A1 (es) | 2000-02-03 |
US5820966A (en) | 1998-10-13 |
AU9698898A (en) | 1999-07-01 |
AU736759B2 (en) | 2001-08-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EC2A | Search report published |
Date of ref document: 20000816 Kind code of ref document: A1 Effective date: 20000816 |
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FD2A | Announcement of lapse in spain |
Effective date: 20180807 |