ES2127957T3 - Copolimeros de bloques de monomeros monovinilaromaticos y de dienos conjugados. - Google Patents

Copolimeros de bloques de monomeros monovinilaromaticos y de dienos conjugados.

Info

Publication number
ES2127957T3
ES2127957T3 ES95104209T ES95104209T ES2127957T3 ES 2127957 T3 ES2127957 T3 ES 2127957T3 ES 95104209 T ES95104209 T ES 95104209T ES 95104209 T ES95104209 T ES 95104209T ES 2127957 T3 ES2127957 T3 ES 2127957T3
Authority
ES
Spain
Prior art keywords
load
conjugated
monovinilaromatic
monomer
initiator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95104209T
Other languages
English (en)
Inventor
Craig D Deporter
Ralph C Farrar
Nathan A Stacy
George A Moczygemba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of ES2127957T3 publication Critical patent/ES2127957T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

UN METODO PARA PREPARAR BLOQUES DE COPOLIMEROS A PARTIR DE LOS CUALES PUEDAN SER HECHOS ARTICULOS AZULES TRANSPARENTES CARGANDO SECUENCIALMENTE BAJO CONDICIONES DE POLIMERIZACION AL MENOS UN MONOMERO MONOVINILAROMATICO Y AL MENOS UN MONOMERO DIENO CONJUGADO, EN EL QUE AL MENOS LA PRIMERA CARGA MONOMERA ES UNA CARGA MONOMERA MONOVINILAROMATICA POLIMERIZADA EN PRESENCIA DE UN INICIADOR, EN EL QUE AL MENOS UNA OTRA CARGA POLIMERIZADA EN PRESENCIA DE UN INICIADOR ES UN MONOMERO SELECCIONADO DEL GRUPO DE MONOMEROS DE DIENO CONJUGADOS Y MEZCLAS DE MONOVINILAROMATICOS Y MONOMEROS DE DIENO CONJUGADOS; EN EL QUE LA CARGA MONOMERA FINAL ES UNA CARGA DIENO CONJUGADO; CARGANDO DESPUES LA REACCION MEZCLA CON AL MENOS UN AGENTE DE ENGANCHE. LOS COPOLIMEROS INVENTADOS SON ESPECIALMENTE UTILES PARA APLICACIONES TALES COMO EMPAQUETADORAS, EXPOSITORES, JUGUETES Y OTROS USOS DECORATIVOS EN LOS QUE LA APARIENCIA AZUL DESEADA SIN UN COMPROMISO SIGNIFICANTE DE OTRAS PROPIEDADES FISICAS O MECANICAS.
ES95104209T 1994-03-23 1995-03-22 Copolimeros de bloques de monomeros monovinilaromaticos y de dienos conjugados. Expired - Lifetime ES2127957T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/216,725 US5438103A (en) 1994-03-23 1994-03-23 Block copolymers of monovinylaromatic and conjugated diene monomers

Publications (1)

Publication Number Publication Date
ES2127957T3 true ES2127957T3 (es) 1999-05-01

Family

ID=22808262

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95104209T Expired - Lifetime ES2127957T3 (es) 1994-03-23 1995-03-22 Copolimeros de bloques de monomeros monovinilaromaticos y de dienos conjugados.

Country Status (9)

Country Link
US (1) US5438103A (es)
EP (1) EP0673953B1 (es)
JP (1) JPH08143636A (es)
KR (1) KR100373544B1 (es)
AT (1) ATE176251T1 (es)
CA (1) CA2143598C (es)
DE (1) DE69507522T2 (es)
ES (1) ES2127957T3 (es)
TW (1) TW382633B (es)

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KR100458169B1 (ko) * 2002-07-26 2004-11-20 금호석유화학 주식회사 비대칭 다중블록 ｓｂｓ 중합체 및 이의 제조 방법
US20040115381A1 (en) * 2002-12-12 2004-06-17 Chevron Phillips Chemical Company, Lp Method for manufacturing articles with materials containing tapered polymers
JP4683928B2 (ja) 2002-12-18 2011-05-18 株式会社ブリヂストン クレイの剥離方法、該方法から得られた組成物、及び該組成物を含む変性ゴム
US6875818B2 (en) 2003-01-16 2005-04-05 Bridgestone Corporation Polymer nano-strings
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US7205370B2 (en) 2004-01-12 2007-04-17 Bridgestone Corporation Polymeric nano-particles of flower-like structure and applications
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US20050166551A1 (en) * 2004-02-02 2005-08-04 Keane J. A. Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer
US7112369B2 (en) * 2004-03-02 2006-09-26 Bridgestone Corporation Nano-sized polymer-metal composites
US8063142B2 (en) 2004-03-02 2011-11-22 Bridgestone Corporation Method of making nano-particles of selected size distribution
US7718737B2 (en) 2004-03-02 2010-05-18 Bridgestone Corporation Rubber composition containing functionalized polymer nanoparticles
US20050282956A1 (en) 2004-06-21 2005-12-22 Xiaorong Wang Reversible polymer/metal nano-composites and method for manufacturing same
US7998554B2 (en) 2004-07-06 2011-08-16 Bridgestone Corporation Hydrophobic surfaces with nanoparticles
US7572855B2 (en) 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US7659342B2 (en) 2005-02-03 2010-02-09 Bridgestone Corporation Polymer nano-particle with polar core and method for manufacturing same
US9061900B2 (en) 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US7538159B2 (en) 2005-12-16 2009-05-26 Bridgestone Corporation Nanoparticles with controlled architecture and method thereof
US7884160B2 (en) 2005-12-19 2011-02-08 Bridgestone Corporation Non-spherical nanoparticles made from living triblock polymer chains
US8288473B2 (en) 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US7601772B2 (en) 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
US8877250B2 (en) 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
US7560510B2 (en) 2005-12-20 2009-07-14 Bridgestone Corporation Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
US8697775B2 (en) 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US7935184B2 (en) 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
JP6096398B2 (ja) 2006-07-28 2017-03-15 株式会社ブリヂストン 重合体ナノ粒子、ゴム組成物及び使用
US7597959B2 (en) 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
US7649049B2 (en) 2006-12-20 2010-01-19 Bridgestone Corporation Rubber composition containing a polymer nanoparticle
US7829624B2 (en) 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
KR101116750B1 (ko) * 2008-10-31 2012-02-22 금호석유화학 주식회사 비대칭 스타 폴리머의 제조 방법
US8846819B2 (en) 2008-12-31 2014-09-30 Bridgestone Corporation Core-first nanoparticle formation process, nanoparticle, and composition
US9062144B2 (en) 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
US20100272975A1 (en) * 2009-04-23 2010-10-28 Chevron Phillips Chemical Company Lp System and method for the production and use of lamination films
US9115222B2 (en) 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers
MX362954B (es) 2012-05-08 2019-02-27 Denka Company Ltd Composicion de copolimero de bloque y lamina.
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US9598524B1 (en) 2015-09-18 2017-03-21 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications
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IT1196517B (it) * 1986-07-17 1988-11-16 Montedipe Spa Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione
CA2028410C (en) * 1990-01-02 1996-09-17 William J. Trepka Tapered block styrene/butadiene copolymers
US5319033A (en) * 1990-01-02 1994-06-07 Phillips Petroleum Company Tapered block monovinyl aromatic/conjugated diene copolymer
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Also Published As

Publication number Publication date
EP0673953A1 (en) 1995-09-27
CA2143598A1 (en) 1995-09-24
KR100373544B1 (ko) 2003-04-26
TW382633B (en) 2000-02-21
KR950032340A (ko) 1995-12-20
US5438103A (en) 1995-08-01
DE69507522D1 (de) 1999-03-11
EP0673953B1 (en) 1999-01-27
DE69507522T2 (de) 1999-06-24
JPH08143636A (ja) 1996-06-04
ATE176251T1 (de) 1999-02-15
CA2143598C (en) 2000-01-11

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