ES2119172T5 - Procedimiento para la produccion de esteres plastificantes y esteres de poliol. - Google Patents
Procedimiento para la produccion de esteres plastificantes y esteres de poliol.Info
- Publication number
- ES2119172T5 ES2119172T5 ES94906704T ES94906704T ES2119172T5 ES 2119172 T5 ES2119172 T5 ES 2119172T5 ES 94906704 T ES94906704 T ES 94906704T ES 94906704 T ES94906704 T ES 94906704T ES 2119172 T5 ES2119172 T5 ES 2119172T5
- Authority
- ES
- Spain
- Prior art keywords
- esters
- plastifying
- procedure
- production
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
- B01J19/1875—Stationary reactors having moving elements inside resulting in a loop-type movement internally, i.e. the mixture circulating inside the vessel such that the upwards stream is separated physically from the downwards stream(s)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
UN PROCESO PARA LA ESTERIFICACION CATALITICA O NO CATALITICA DE ACIDOS O ANHIDRIDOS CON UN MONO-ALCOHOL O UN COMPUESTO POLIHIDROXI QUE COMNPRENDE LOS PASOS DE AÑADIR LOS REAGENTES AL VASO DE REACCION PARA FORMAR UNA MEZCLA DE REACCION, Y DE CALENTAR LA MEZCLA DE REACCION Y MANTENER UNA PRESION SUFICIENTE PARA OBTENER LA EBULLICION DE LA MEZCLA DE REACCION DE MANERA QUE SE PRODUZCA LA ESTERIFICACION Y SE ELIMINE AGUA COMO VAPOR MIENTRAS QUE LA MEZCLA DE REACCION SE SIGUE CONTINUAMENTE MEZCLANDO EN EL VASO REACTOR DE MODO QUE AL MENOS ALREDEDOR DE 2.5 A 20 VOLUMENES DE LA MEZCLA DE REACCION SEAN INTERNAMENTE RECIRCULADOS POR MINUTO, POR LO CUAL SE INTENSIFICA EL INDICE DE CONVERSION.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/006,228 US5324853A (en) | 1993-01-19 | 1993-01-19 | Process for the production of plasticizer and polyolesters |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2119172T3 ES2119172T3 (es) | 1998-10-01 |
ES2119172T5 true ES2119172T5 (es) | 2002-07-01 |
Family
ID=21719891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94906704T Expired - Lifetime ES2119172T5 (es) | 1993-01-19 | 1994-01-19 | Procedimiento para la produccion de esteres plastificantes y esteres de poliol. |
Country Status (14)
Country | Link |
---|---|
US (1) | US5324853A (es) |
EP (1) | EP0680463B2 (es) |
JP (1) | JPH08505879A (es) |
KR (1) | KR100284475B1 (es) |
CN (1) | CN1046265C (es) |
AU (1) | AU675294B2 (es) |
BR (1) | BR9405659A (es) |
CA (1) | CA2154153C (es) |
DE (1) | DE69410988T3 (es) |
ES (1) | ES2119172T5 (es) |
MY (1) | MY110495A (es) |
SG (1) | SG48306A1 (es) |
TW (1) | TW268940B (es) |
WO (1) | WO1994017028A1 (es) |
Families Citing this family (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5532405A (en) * | 1994-04-29 | 1996-07-02 | Exxon Chemical Patents Inc. | Preparation of plasticizer or polyol esters by the staged addition of the lower boiling point reactant |
US5534652A (en) * | 1994-10-18 | 1996-07-09 | Exxon Chemical Patents Inc. (Ecpi) | Preparation of plasticizer esters from phthalic anhydride residue |
JP3944251B2 (ja) * | 1995-03-22 | 2007-07-11 | 松本油脂製薬株式会社 | エステル精製方法 |
US6177387B1 (en) | 1996-08-30 | 2001-01-23 | Exxon Chemical Patents Inc | Reduced odor and high stability aircraft turbine oil base stock |
CN1249740A (zh) * | 1997-02-28 | 2000-04-05 | 新日本理化株式会社 | 对羟基苯甲酸酯,包含其的增塑剂、聚酰胺树脂组合物和模塑制品 |
US5898077A (en) * | 1997-10-07 | 1999-04-27 | Matsumoto Yushi-Seiyaku Co., Ltd. | Process for preparation of an ester |
EE04110B1 (et) * | 1997-11-24 | 2003-08-15 | Energea-Umwelttechnologie Gmbh | Rasvhappe metüülestri valmistamise meetod ja seadmestik meetodi realiseerimiseks |
DE10056179A1 (de) * | 2000-11-13 | 2002-05-29 | Basf Ag | Verfahren zur Herstellung von Estern mehrbasiger Säuren |
US6906164B2 (en) * | 2000-12-07 | 2005-06-14 | Eastman Chemical Company | Polyester process using a pipe reactor |
KR100426229B1 (ko) * | 2001-01-05 | 2004-04-08 | 주식회사 엘지화학 | 폴리염화비닐 수지용 트리메틸올프로판 에스테르 가소제조성물 |
AT504727A1 (de) * | 2002-04-12 | 2008-07-15 | Energea Umwelttechnologie Gmbh | Verfahren und anlage zur veresterung von fettsäuren |
GB0320206D0 (en) * | 2003-08-29 | 2003-10-01 | Exxonmobil Chem Patents Inc | Improvements in or relating to plasticiser |
JP2006154384A (ja) * | 2004-11-30 | 2006-06-15 | Konica Minolta Opto Inc | 位相差フィルム、及びそれを用いた偏光板、表示装置 |
JP2006182606A (ja) * | 2004-12-28 | 2006-07-13 | Miyoshi Oil & Fat Co Ltd | セメント混和剤及びセメント組成物 |
CN1300092C (zh) * | 2005-03-09 | 2007-02-14 | 贵州宏福实业开发有限总公司 | 多元醇脂肪酸酯的生产方法 |
US7919649B2 (en) * | 2005-05-27 | 2011-04-05 | Exxonmobile Chemical Patents Inc. | Plasticiser esters |
KR20080018961A (ko) * | 2005-06-24 | 2008-02-28 | 헥시온 스페셜티 케미컬스 리서치 벨기에 에스.에이. | 3차 알킬이 치환된 산을 이용한 폴리올의 에스테르화 방법 |
US7291748B2 (en) * | 2005-07-28 | 2007-11-06 | Basf Corporation | C10/C7 ester mixtures based on 2-propylheptanol |
JP2007031383A (ja) * | 2005-07-28 | 2007-02-08 | Mitsubishi Chemicals Corp | テレフタル酸ジエステルの製造方法 |
US7453008B2 (en) * | 2005-08-23 | 2008-11-18 | Lg Chem Ltd. | Synthetic method of glycol diesters from reaction of glycol monoesters and linear aliphatic carboxylic acids |
US20070087085A1 (en) * | 2005-10-17 | 2007-04-19 | Bunge Oils, Inc. | Protein-containing food product and coating for a food product and method of making same |
US20080113067A1 (en) * | 2005-10-17 | 2008-05-15 | Monoj Sarma | Protein-Containing Food Product and Coating for a Food Product and Method of Making Same |
US20070148311A1 (en) * | 2005-12-22 | 2007-06-28 | Bunge Oils, Inc. | Phytosterol esterification product and method of make same |
US20080044324A1 (en) * | 2006-08-16 | 2008-02-21 | Agency For Science, Technology And Research | Recirculating reactor |
US7649109B2 (en) * | 2006-12-07 | 2010-01-19 | Eastman Chemical Company | Polyester production system employing recirculation of hot alcohol to esterification zone |
US20080139780A1 (en) * | 2006-12-07 | 2008-06-12 | Debruin Bruce Roger | Polyester production system employing short residence time esterification |
US7943094B2 (en) | 2006-12-07 | 2011-05-17 | Grupo Petrotemex, S.A. De C.V. | Polyester production system employing horizontally elongated esterification vessel |
KR100919930B1 (ko) | 2007-01-10 | 2009-10-07 | 주식회사 엘지화학 | 내이행성이 우수한 고분자 가소제, 이의 제조방법 및 이를포함하는 고분자 수지 조성물 |
US7892498B2 (en) | 2007-03-08 | 2011-02-22 | Eastman Chemical Company | Polyester production system employing an unagitated esterification reactor |
US7863477B2 (en) | 2007-03-08 | 2011-01-04 | Eastman Chemical Company | Polyester production system employing hot paste to esterification zone |
KR101506046B1 (ko) * | 2007-03-13 | 2015-03-25 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 회분식 에스터화 |
ATE482921T1 (de) * | 2007-03-13 | 2010-10-15 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von estern |
US8729289B2 (en) * | 2007-03-13 | 2014-05-20 | Exxonmobil Chemical Patents Inc. | Ester production |
US7829653B2 (en) | 2007-07-12 | 2010-11-09 | Eastman Chemical Company | Horizontal trayed reactor |
US7842777B2 (en) | 2007-07-12 | 2010-11-30 | Eastman Chemical Company | Sloped tubular reactor with divided flow |
US7858730B2 (en) * | 2007-07-12 | 2010-12-28 | Eastman Chemical Company | Multi-level tubular reactor with dual headers |
US7868129B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Sloped tubular reactor with spaced sequential trays |
US7847053B2 (en) | 2007-07-12 | 2010-12-07 | Eastman Chemical Company | Multi-level tubular reactor with oppositely extending segments |
US7872090B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Reactor system with optimized heating and phase separation |
US7872089B2 (en) | 2007-07-12 | 2011-01-18 | Eastman Chemical Company | Multi-level tubular reactor with internal tray |
US7868130B2 (en) | 2007-07-12 | 2011-01-11 | Eastman Chemical Company | Multi-level tubular reactor with vertically spaced segments |
KR100943027B1 (ko) * | 2007-11-09 | 2010-02-18 | 주식회사 거영 | 디트리데실프탈산 제조방법 |
US7834109B2 (en) * | 2007-12-07 | 2010-11-16 | Eastman Chemical Company | System for producing low impurity polyester |
WO2009139005A1 (en) | 2008-05-14 | 2009-11-19 | Council Of Scientific & Industrial Research | Polyol esters of medium chain fatty acids and process for preparation thereof |
US7674931B1 (en) | 2008-12-15 | 2010-03-09 | Eastman Chemical Company | Method for producing 2,2,4-trimethyl-1,3-pentanediol di-2-ethylhexanoate |
MY157837A (en) | 2008-12-16 | 2016-07-29 | Basf Se | Production of carboxylic acid esters by stripping with alcohol vapor |
DE102009048771A1 (de) * | 2009-10-08 | 2011-04-21 | Oxea Deutschland Gmbh | Verfahren zur Herstellung von Polyolestern |
DE102009048774A1 (de) | 2009-10-08 | 2011-04-28 | Oxea Deutschland Gmbh | Verfahren zur Farbaufhellung von Polyolestern |
DE102009048772A1 (de) * | 2009-10-08 | 2011-04-21 | Oxea Deutschland Gmbh | Verfahren zur Herstellung von Polyolestern |
DE102009048773A1 (de) * | 2009-10-08 | 2011-04-21 | Oxea Deutschland Gmbh | Verfahren zur Farbaufhellung von Polyolestern |
DE102009048775A1 (de) * | 2009-10-08 | 2011-04-21 | Oxea Deutschland Gmbh | Verfahren zur Herstellung von Polyolestern |
WO2011054782A1 (de) | 2009-11-05 | 2011-05-12 | Basf Se | Kleb- und dichtstoffe enthaltend ester auf basis von 2-propylheptanol |
DE102010027458A1 (de) | 2010-07-17 | 2012-01-19 | Oxea Gmbh | Verfahren zur Nachbehandlung von Polyolestern |
CN102958898B (zh) | 2010-08-25 | 2015-05-20 | 埃克森美孚化学专利公司 | 酯的制备方法 |
US9365715B2 (en) | 2010-12-23 | 2016-06-14 | Styrolution Europe Gmbh | Thermoplastic elastomer composition and method for the production thereof |
CN102773048B (zh) * | 2011-05-09 | 2017-06-06 | 波利玛利欧洲股份公司 | 生产环己酮肟的氨肟化反应器 |
WO2013025277A1 (en) | 2011-08-15 | 2013-02-21 | Exxonmobil Chemical Patents Inc. | Esters and their preparation and use |
US9481628B2 (en) | 2012-03-30 | 2016-11-01 | Exxonmobil Chemical Patents Inc. | Esterification process |
WO2013143825A1 (en) | 2012-03-30 | 2013-10-03 | Exxonmobil Chemical Patents Inc. | Esterification process |
EP2883908B1 (en) * | 2012-08-09 | 2016-12-21 | NOK Corporation | Nbr composition |
DE102012018207A1 (de) | 2012-09-14 | 2014-03-20 | Oxea Gmbh | Verfahren zur Herstelluna von Polyolestern |
CN102863332B (zh) * | 2012-09-27 | 2014-08-06 | 昆明理工大学 | 一种有机琥珀及其制备方法 |
CN103130640B (zh) * | 2013-01-16 | 2015-06-10 | 宁波东来化工有限公司 | 一种制备1,2-环己烷二甲酸二癸酯的装置及其方法 |
DE102013015289A1 (de) | 2013-09-14 | 2015-03-19 | Oxea Gmbh | Verfahren zur Nachbehandlung von Polyolestern |
DE102013018456B4 (de) | 2013-11-02 | 2019-01-24 | Oxea Gmbh | Verfahren zur Gewinnung von mit Polyolestern angereicherten Produktströmen aus den Nebenströmen der Polyolesterherstellung |
CN105793341A (zh) | 2013-12-06 | 2016-07-20 | 巴斯夫欧洲公司 | 包含四氢呋喃衍生物和1,2-环己烷二甲酸酯的软化剂组合物 |
CN103739492A (zh) * | 2013-12-31 | 2014-04-23 | 河南庆安化工高科技股份有限公司 | 一种制备环己烷邻二甲酸二高碳醇酯的方法 |
PL3092266T3 (pl) | 2014-01-09 | 2018-12-31 | Basf Se | Kompozycja plastyfikatora zawierająca pochodną furanu i ester kwasu 1,2-cykloheksanodikarboksylowego |
DE102015207291A1 (de) | 2014-04-24 | 2016-03-10 | Basf Se | Weichmacher-Zusammensetzung, die Furanderivate und 1,2-Cyclohexandicarbonsäureester enthält |
TW201609628A (zh) | 2014-07-08 | 2016-03-16 | 巴斯夫歐洲公司 | 包含脂族二羧酸二酯及對苯二甲酸二烷基酯之塑化劑組成物 |
TW201605945A (zh) | 2014-07-08 | 2016-02-16 | 巴斯夫歐洲公司 | 包含二羧酸的酯及1,2-環己烷二羧酸的酯之模製化合物 |
WO2016027218A1 (en) | 2014-08-18 | 2016-02-25 | Basf Se | Process for preparing crystalline organic semiconductor material |
TWI706979B (zh) | 2014-08-19 | 2020-10-11 | 德商巴斯夫歐洲公司 | 包含聚合二羧酸酯的塑化劑組成物 |
TWI686444B (zh) | 2014-09-04 | 2020-03-01 | 德商巴斯夫歐洲公司 | 包含聚合二羧酸酯的塑化劑組成物 |
US10287417B2 (en) | 2015-01-30 | 2019-05-14 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and terephthalic acid dialkyl esters |
CN106045857A (zh) * | 2015-04-24 | 2016-10-26 | 中国科学院大连化学物理研究所 | 一种二环己基甲酸二元醇酯增塑剂的制备方法 |
EP3303315A1 (de) | 2015-05-29 | 2018-04-11 | Basf Se | Verfahren zur herstellung cyclischer ester |
US20180282511A1 (en) | 2015-09-30 | 2018-10-04 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and terephthalic acid dialkyl esters |
ES2743975T5 (es) | 2015-09-30 | 2023-05-10 | Basf Se | Composición de plastificante que contiene ésteres de ácido dicarboxílico poliméricos y ésteres de ácido 1,2-diclohexandicarboxílico |
US20180282510A1 (en) | 2015-09-30 | 2018-10-04 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters |
CN105254501A (zh) * | 2015-10-23 | 2016-01-20 | 淮阴师范学院 | 环己烷-1,2-二甲酸二异壬酯的制备方法 |
EP3178908A1 (en) | 2015-12-11 | 2017-06-14 | Basf Se | The use of 2,5-furandicarboxylic acid esters as lubricants |
PL3405518T3 (pl) | 2016-01-20 | 2020-05-18 | Basf Se | Kompozycja plastyfikatora, która zawiera estry alifatycznych kwasów dikarboksylowych i diestry wybrane spośród estrów kwasu 1,2-cykloheksanodikarboksylowego i estrów kwasu tereftalowego |
CA3018424A1 (en) | 2016-03-23 | 2017-09-28 | Basf Se | Polymer composition containing a cycloalkyl alkyl dicarboxylic acid diester as a plasticizer |
CN109563305A (zh) | 2016-08-01 | 2019-04-02 | 巴斯夫欧洲公司 | 增塑剂组合物 |
WO2018024597A1 (de) | 2016-08-01 | 2018-02-08 | Basf Se | Weichmacher-zusammensetzung |
WO2018024591A1 (de) | 2016-08-01 | 2018-02-08 | Basf Se | Weichmacher-zusammensetzung |
EP3491054A1 (de) | 2016-08-01 | 2019-06-05 | Basf Se | Weichmacher-zusammensetzung |
KR102641380B1 (ko) * | 2016-11-11 | 2024-02-28 | 오씨아이 주식회사 | 테레프탈산계 에스터 화합물을 정제하는 방법 |
WO2019185409A1 (de) | 2018-03-29 | 2019-10-03 | Basf Se | Pvc-zusammensetzung, enthaltend wenigstens einen weichmacher der wenigstens eine carbonsäureestergruppe aufweist und wenigstens eine carbodiimidverbindung |
EP3747860B1 (de) | 2019-06-04 | 2023-07-26 | Basf Se | Neue weichmacher auf cyclohexanon-basis |
KR102669652B1 (ko) | 2019-09-19 | 2024-05-28 | 주식회사 엘지화학 | 에스터화 생성물의 중화/수분리 장치 및 에스터화 생성물의 중화/수분리 방법 |
KR102528326B1 (ko) * | 2020-02-14 | 2023-05-02 | 한화솔루션 주식회사 | 에스테르계 화합물의 제조방법 |
KR20220067352A (ko) * | 2020-11-17 | 2022-05-24 | 주식회사 엘지화학 | 디에스터계 물질의 제조방법 |
WO2024133359A1 (de) | 2022-12-21 | 2024-06-27 | Basf Se | Weichmacher |
WO2024133358A1 (de) | 2022-12-21 | 2024-06-27 | Basf Se | Weichmacher-verbindung |
WO2024153687A1 (de) | 2023-01-19 | 2024-07-25 | Basf Se | Verfahren zur herstellung von 1,2-cyclohexandicarbonsäuredialkylestern |
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US2411136A (en) * | 1942-03-21 | 1946-11-12 | Monsanto Chemicals | Esterification reactions |
US2494133A (en) * | 1946-09-07 | 1950-01-10 | American Cyanamid Co | Method of neutralizing and completely removing salts before distilling crude high-boiling esters |
US2628249A (en) * | 1951-01-03 | 1953-02-10 | Pittsburgh Coke & Chemical Co | Esterification process |
US3056818A (en) * | 1955-10-13 | 1962-10-02 | Goodrich Co B F | Titanium and zirconium esterification catalysts |
IT778269A (es) * | 1964-01-25 | |||
GB1299078A (en) * | 1969-04-30 | 1972-12-06 | Ici Ltd | Distillation process |
US3519054A (en) * | 1969-01-06 | 1970-07-07 | Colgate Palmolive Co | Process for producing a particulate product |
GB1426057A (en) * | 1972-04-24 | 1976-02-25 | Ici Ltd | Production of esters |
GB1565663A (en) * | 1977-05-18 | 1980-04-23 | Bp Chemical Ltd | Production of esters in the presence of amphoteric catalysts and oxalic acid |
US4241216A (en) * | 1979-01-02 | 1980-12-23 | Basf Wyandotte Corporation | Phthalic acid diester preparation with waste stream purification and recycle |
JPS55130937A (en) * | 1979-03-29 | 1980-10-11 | Sekisui Chem Co Ltd | Preparation of ester |
EP0342357A3 (de) * | 1988-04-22 | 1990-03-28 | Henkel Kommanditgesellschaft auf Aktien | Vorrichtung, Anwendung und Verfahren zum diskontinuierlichen Führen einer Gleichgewichtsreaktion |
-
1993
- 1993-01-19 US US08/006,228 patent/US5324853A/en not_active Expired - Lifetime
-
1994
- 1994-01-19 SG SG1996008794A patent/SG48306A1/en unknown
- 1994-01-19 BR BR9405659A patent/BR9405659A/pt not_active IP Right Cessation
- 1994-01-19 KR KR1019950702934A patent/KR100284475B1/ko not_active IP Right Cessation
- 1994-01-19 MY MYPI94000144A patent/MY110495A/en unknown
- 1994-01-19 JP JP6517210A patent/JPH08505879A/ja not_active Ceased
- 1994-01-19 CN CN94191230A patent/CN1046265C/zh not_active Expired - Fee Related
- 1994-01-19 EP EP94906704A patent/EP0680463B2/en not_active Expired - Lifetime
- 1994-01-19 DE DE69410988T patent/DE69410988T3/de not_active Expired - Lifetime
- 1994-01-19 AU AU60322/94A patent/AU675294B2/en not_active Ceased
- 1994-01-19 ES ES94906704T patent/ES2119172T5/es not_active Expired - Lifetime
- 1994-01-19 WO PCT/US1994/000767 patent/WO1994017028A1/en active IP Right Grant
- 1994-01-19 CA CA002154153A patent/CA2154153C/en not_active Expired - Fee Related
- 1994-03-17 TW TW083102335A patent/TW268940B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU6032294A (en) | 1994-08-15 |
AU675294B2 (en) | 1997-01-30 |
EP0680463B1 (en) | 1998-06-10 |
JPH08505879A (ja) | 1996-06-25 |
BR9405659A (pt) | 1995-11-14 |
SG48306A1 (en) | 1998-04-17 |
CA2154153C (en) | 2004-08-10 |
DE69410988D1 (de) | 1998-07-16 |
DE69410988T3 (de) | 2002-06-27 |
ES2119172T3 (es) | 1998-10-01 |
US5324853A (en) | 1994-06-28 |
CA2154153A1 (en) | 1994-08-04 |
TW268940B (es) | 1996-01-21 |
CN1118158A (zh) | 1996-03-06 |
KR960700216A (ko) | 1996-01-19 |
EP0680463B2 (en) | 2001-12-19 |
DE69410988T2 (de) | 1998-12-10 |
EP0680463A1 (en) | 1995-11-08 |
CN1046265C (zh) | 1999-11-10 |
WO1994017028A1 (en) | 1994-08-04 |
MY110495A (en) | 1998-06-30 |
KR100284475B1 (ko) | 2001-04-02 |
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