ES2088899T3 - Microesferas huecas, polimericas de acrilato. - Google Patents

Microesferas huecas, polimericas de acrilato.

Info

Publication number
ES2088899T3
ES2088899T3 ES89311538T ES89311538T ES2088899T3 ES 2088899 T3 ES2088899 T3 ES 2088899T3 ES 89311538 T ES89311538 T ES 89311538T ES 89311538 T ES89311538 T ES 89311538T ES 2088899 T3 ES2088899 T3 ES 2088899T3
Authority
ES
Spain
Prior art keywords
microspheres
pressure sensitive
hollow microspheres
diameter
hollow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89311538T
Other languages
English (en)
Inventor
Joaquin Delgado
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Application granted granted Critical
Publication of ES2088899T3 publication Critical patent/ES2088899T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • C08J3/16Powdering or granulating by coagulating dispersions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
    • C08L2205/20Hollow spheres
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

SE PRESENTAN MICROESFERAS HUECAS DE ADHESIVO ELASTOMERICO SENSIBLE A LA PRESION, DISPERSIBLES EN SOLVENTE, INSOLUBLES EN SOLVENTE, INFUNDIBLES, DE ACRILATO POLIMERICO QUE TIENEN UN DIAMETRO MEDIO DE MENOS DE UN MICROMETRO. LAS MICROESFERAS MAS ADECUADAS SON AQUELLAS EN LAS QUE LA MAYORIA DE LAS MICROESFERAS HUECAS CONTIENEN AL MENOS UN HUECO VACIO INTERIOR QUE TENGA UN DIAMETRO DE AL MENOS EL 10% DEL DIAMETRO DE LA MICROESFERA. ESTAS MICROESFERAS HUECAS SON UTILES COMO ADHESIVOS REPOSICIONABLES SENSIBLES A LA PRESION. EL INVENTO TAMBIEN SUMINISTRA ADHESIVOS SENSIBLES A LA PRESION QUE CONSTAN ESENCIALMENTE DE DICHAS MICROESFERAS HUECAS. TAMBIEN SE SUMINISTRAN SUSPENSIONES ACUOSAS DE ESTAS MICROESFERAS, PROCESOS PARA SU PREPARACION, COMPUESTOS DE ADHESIVO REPOSICIONABLE SENSIBLE A LA PRESION EN "SPRAY", Y MATERIALES LAMINADOS REVESTIDOS DE MICROESFERAS. SORPRENDENTEMENTE, LAS MICROESFERAS HUECAS DEL INVENTO MUESTRAN UNA TRANSFERENCIA DE ADHESIVO REDUCIDA O NULA, EN COMPARACION CON LOS ADHESIVOS REPOSICIONABLES SENSIBLES A LA PRESION ANTERIORES QUE SE BASAN EN MICROESFERAS SOLIDAS.
ES89311538T 1988-11-30 1989-11-08 Microesferas huecas, polimericas de acrilato. Expired - Lifetime ES2088899T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/276,767 US5045569A (en) 1988-11-30 1988-11-30 Hollow acrylate polymer microspheres

Publications (1)

Publication Number Publication Date
ES2088899T3 true ES2088899T3 (es) 1996-10-01

Family

ID=23057992

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89311538T Expired - Lifetime ES2088899T3 (es) 1988-11-30 1989-11-08 Microesferas huecas, polimericas de acrilato.

Country Status (14)

Country Link
US (1) US5045569A (es)
EP (1) EP0371635B1 (es)
JP (1) JP2940875B2 (es)
KR (1) KR0155353B1 (es)
AR (1) AR246283A1 (es)
AU (1) AU619350B2 (es)
BR (1) BR8906061A (es)
CA (1) CA1328331C (es)
DE (1) DE68926846T2 (es)
DK (1) DK599989A (es)
ES (1) ES2088899T3 (es)
MX (1) MX169793B (es)
NO (1) NO175154C (es)
ZA (1) ZA897828B (es)

Families Citing this family (206)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE115149T1 (de) * 1989-07-13 1994-12-15 Vernis Valentine Comp D Partikel von hydrophoben polymeren, die hohlräume enthalten.
US5284881A (en) * 1989-09-06 1994-02-08 Nippon Paint Co., Ltd. Composite hollow particles
US4994322A (en) * 1989-09-18 1991-02-19 Minnesota Mining And Manufacturing Pressure-sensitive adhesive comprising hollow tacky microspheres and macromonomer-containing binder copolymer
DE4015753A1 (de) * 1990-05-16 1991-11-21 Basf Ag Farbbildner enthaltende mikrokapseln
DE69212154T2 (de) * 1991-05-17 1997-01-09 Minnesota Mining & Mfg Flexible, anpassungsfähige folien auf basis ionomerischen harzes
US5198301A (en) * 1991-05-17 1993-03-30 Minnesota Mining And Manufacturing Company Flexible and conformable ionomeric resin based films
US5196246A (en) * 1991-05-17 1993-03-23 Minnesota Mining And Manufacturing Company Wall decorating system
EP1475423B9 (en) * 1991-08-09 2006-09-06 3M Company Repositionable glue stick
US5719247A (en) * 1991-12-17 1998-02-17 Minnesota Mining And Manufacturing Company Tack-free elastomeric acrylate microspheres
CA2124342C (en) * 1991-12-17 2003-03-25 Joaquin Delgado Tack-free elastomeric acrylate microspheres
TW221061B (es) * 1991-12-31 1994-02-11 Minnesota Mining & Mfg
US5334094A (en) * 1992-09-21 1994-08-02 Minnesota Mining And Manufacturing Company Carbonless pad assembly
TW338043B (en) * 1992-12-11 1998-08-11 Minnesota Mining & Mfg Tacky microspheres having pendant hydrophilic polymeric or oligomeric moieties
CA2156164A1 (en) * 1993-02-16 1994-09-01 Lori A. Bilski System comprising release agent and high peel adhesion repositionable adhesive
DE4305081C2 (de) * 1993-02-19 1996-08-01 Minnesota Mining & Mfg Verfahren und Vorrichtung zum Auftragen von Haftkleber auf Bogen aus Papier oder dergleichen Material
US5468523A (en) * 1993-03-15 1995-11-21 Minnesota Mining And Manufacturing Company Method and apparatus for forming prefabricated self-forming self-adhering pull bow and pull bow formed thereby
US5607763A (en) * 1993-04-07 1997-03-04 Minnesota Mining And Manufacturing Company Decorative film with PSA for easy application
US5571617A (en) * 1993-04-23 1996-11-05 Minnesota Mining And Manufacturing Company Pressure sensitive adhesive comprising tacky surface active microspheres
US5378405A (en) * 1993-07-28 1995-01-03 Minnesota Mining And Manufacturing Company Conductive microparticles and pressure-sensitive adhesive tapes made therefrom
CA2174739A1 (en) * 1993-11-16 1995-05-26 Charles P. Huss Preformed self-adhering bow
US5885722A (en) * 1994-02-15 1999-03-23 Minnesota Mining And Manufacturing Method for applying coating materials to overlapped individuals sheets
WO1995030720A1 (en) * 1994-05-06 1995-11-16 Minnesota Mining And Manufacturing Company High temperature resistant antistatic pressure-sensitive adhesive tape
US5914186A (en) * 1994-05-06 1999-06-22 Minnesota Mining And Manufacturing Company High temperature resistant antistatic pressure-sensitive adhesive tape
US5514122A (en) * 1994-05-16 1996-05-07 Minnesota Mining And Manufacturing Company Feminine hygiene pad
US5851592A (en) * 1994-08-17 1998-12-22 Minnesota Mining And Manufacturing Company Apparatus and method for applying coating materials to individual sheet members
EP1234682B1 (en) 1994-08-17 2006-02-22 Minnesota Mining And Manufacturing Company Method and apparatus for applying a coating material to sheets
US5614310A (en) * 1994-11-04 1997-03-25 Minnesota Mining And Manufacturing Company Low trauma wound dressing with improved moisture vapor permeability
US5663241A (en) * 1994-12-13 1997-09-02 Minnesota Mining And Manufacturing Company Removable pressure sensitive adhesive and article
DE69626018D1 (de) 1995-06-26 2003-03-06 Minnesota Mining & Mfg Lichtstreuender klebstoff
AU6487996A (en) 1995-07-10 1997-02-10 Minnesota Mining And Manufacturing Company Screen printable adhesive compositions
US20010028953A1 (en) * 1998-11-16 2001-10-11 3M Innovative Properties Company Adhesive compositions and methods of use
US5942461A (en) * 1995-11-06 1999-08-24 Minnesota Mining And Manufacturing Company Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor
US5578650A (en) * 1995-12-01 1996-11-26 Minnesota Mining And Manufacturing Company Methods of preparing hollow acrylate polymer microspheres
US5696199A (en) * 1995-12-07 1997-12-09 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive polyacrylate polymer and method of making
EP0888412B1 (en) * 1996-03-21 2002-09-11 Minnesota Mining And Manufacturing Company Pressure sensitive adhesive film comprising tacky microspheres
US6004308A (en) * 1996-04-19 1999-12-21 Mcneil-Ppc, Inc. Adhesive attachment system with a non-tacky surface for sanitary napkins
US5948427A (en) * 1996-04-25 1999-09-07 Point Medical Corporation Microparticulate surgical adhesive
US5889118A (en) * 1996-06-03 1999-03-30 Minnesota Mining And Manufacturing Company Thermomorphic "smart" pressure sensitive adhesives
US5888650A (en) * 1996-06-03 1999-03-30 Minnesota Mining And Manufacturing Company Temperature-responsive adhesive article
US5824748A (en) * 1996-06-03 1998-10-20 Minnesota Mining And Manufacturing Company Composite pressure sensitive adhesive microspheres
US6368708B1 (en) 1996-06-20 2002-04-09 3M Innovative Properties Company Polyolefin microspheres
AU3290797A (en) * 1996-06-20 1998-01-07 Minnesota Mining And Manufacturing Company Polyolefin microspheres
US6383591B1 (en) 1996-06-21 2002-05-07 3M Innovative Properties Company Method and apparatus for adhering linerless repositionable sheets onto articles
US5716685A (en) * 1996-10-23 1998-02-10 Minnesota Mining And Manufacturing Company Silicone-containing copolymer and bleed through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom
US5874144A (en) * 1996-10-23 1999-02-23 Minnesota Mining And Manufacturing Company Silicon-free copolymer and bleed-through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom
US6080418A (en) * 1997-04-07 2000-06-27 3M Innovative Properties Company Suspensions of microcapsules containing biologically active ingredients and adhesive microspheres
US6406244B1 (en) 1998-07-09 2002-06-18 Frederic P. A. Le Riche Stack of sheets with repositionable adhesive alternating between opposite edges and containing one or more sheets different from other sheets
US6444305B2 (en) 1997-08-29 2002-09-03 3M Innovative Properties Company Contact printable adhesive composition and methods of making thereof
US6268032B1 (en) 1997-10-03 2001-07-31 3M Innovative Properties Company Repositionable note sheets and method of formation thereof
US6063229A (en) * 1998-02-03 2000-05-16 3M Innovative Properties Company Method of article assembly formation
US7354596B1 (en) 1998-05-01 2008-04-08 3M Innovative Properties Company Anti-microbial agent delivery system
US6471975B1 (en) 1998-05-01 2002-10-29 3M Innovative Properties Company Microspheres as a delivery vehicle for bio-active agents useful in agricultural applications
US6312715B1 (en) 1998-05-01 2001-11-06 3M Innovative Properties Company Adhesive microsphere drug delivery composition
US6139961A (en) * 1998-05-18 2000-10-31 Rohm And Haas Company Hollow sphere organic pigment for paper or paper coatings
US20010044477A1 (en) * 1998-12-10 2001-11-22 Soane David S. Expandable polymeric microspheres, their method of production, and uses and products thereof
US6296932B1 (en) * 1998-12-14 2001-10-02 3M Innovative Properties Company Microsphere adhesive coated article for use with coated papers
US6235344B1 (en) * 1999-02-05 2001-05-22 Rohm And Haas Company Method of improving an adhesive article
US6548164B1 (en) 1999-06-30 2003-04-15 3M Innovative Properties Company Removable sheeting
US6375968B1 (en) 1999-10-22 2002-04-23 3M Innovative Properties Company Encapsulated active material immobilized in hydrogel microbeads
US6793937B2 (en) 1999-10-22 2004-09-21 3M Innovative Properties Company Method of delivering active material within hydrogel microbeads
US6365189B1 (en) 1999-10-22 2002-04-02 3M Innovative Properties Company Method of delivering and releasing a pheromone
AU2001252601A1 (en) * 2000-05-15 2001-11-26 Toagosei Co., Ltd. Tackifier and adhesive composition
US6360466B1 (en) 2000-05-19 2002-03-26 Iomega Corporation Data storage cartridge with multiple labels
DE60109780T2 (de) * 2000-06-23 2005-09-01 Solutia Inc. Verfahren zur herstellung von festen druckempfindlichen klebenden polymere-mikrokugeln
KR100369845B1 (ko) * 2000-10-20 2003-01-30 한솔제지주식회사 포어 마이크로스피어 구조의 리포지션어블 점착제 및 그제조방법
KR100411188B1 (ko) * 2000-10-20 2003-12-18 한솔제지주식회사 포어 마이크로스피어 점착제용 씨드고분자 입자의 제조방법
US6883908B2 (en) 2001-01-08 2005-04-26 3M Innovative Properties Company Methods and compositions for ink jet printing of pressure sensitive adhesive patterns or films on a wide range of substrates
US6660352B2 (en) 2001-01-09 2003-12-09 3M Innovative Properties Company Adhesive electrostatic sheets
US20030049415A1 (en) 2001-03-12 2003-03-13 Pedginski James J. Film constructions and methods
US6540991B2 (en) 2001-04-06 2003-04-01 3M Innovative Properties Company Stabilized active materials
US6562361B2 (en) 2001-05-02 2003-05-13 3M Innovative Properties Company Pheromone immobilized in stable hydrogel microbeads
US7316832B2 (en) 2001-12-20 2008-01-08 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
KR100484125B1 (ko) * 2002-01-11 2005-04-20 티오켐 주식회사 방사선 또는 일렉트론-빔을 이용한 단분산상 고분자미립자의 제조방법
FR2835811B1 (fr) * 2002-02-12 2004-05-21 Pechiney Capsules Insert fonctionnel pour goulot de recipient, typiquement une bouteille, et capsule de bouchage comprenant ledit insert
US6715633B2 (en) 2002-03-06 2004-04-06 Kimberly-Clark Worldwide, Inc. Interfolded sheet dispenser having a starter sheet pull-out system
KR100642621B1 (ko) 2003-02-14 2006-11-13 아베리 데니슨 코포레이션 변색 방지 차단층을 갖는 다층 건조 도막 장식성라미네이트
US20040161564A1 (en) 2003-02-14 2004-08-19 Truog Keith L. Dry paint transfer laminate
US7097727B2 (en) * 2003-05-06 2006-08-29 3M Innovative Properties Company Inline accumulating die padder
US20040229193A1 (en) * 2003-05-14 2004-11-18 Larry Wittmeyer Coloring paper having adhesive
US20050196607A1 (en) 2003-06-09 2005-09-08 Shih Frank Y. Multi-layer dry paint decorative laminate having discoloration prevention barrier
US20050233101A1 (en) * 2003-11-04 2005-10-20 Wittmeyer Larry E Jr Multi-functional stack of repositionable sheets
US7718241B2 (en) * 2003-11-04 2010-05-18 Larry E. Wittmeyer, Jr. Multi-functional stack of repositionable sheets
US6908240B1 (en) * 2003-12-16 2005-06-21 International Imaging Materials, Inc Thermal printing and cleaning assembly
US7356884B2 (en) * 2003-12-18 2008-04-15 3M Innovative Properties Company Fastener for a display page
JP4681248B2 (ja) * 2004-04-09 2011-05-11 パナソニック株式会社 スクリーン印刷用インク
US20050271849A1 (en) 2004-06-02 2005-12-08 3M Innovative Properties Company Shingled assembly of repositionable devices
US8517329B2 (en) * 2004-07-26 2013-08-27 3M Innovative Properties Company Easel stand mountable display board
US20060024463A1 (en) * 2004-07-27 2006-02-02 3M Innovative Properties Company Dry erase substrate
US20060024461A1 (en) * 2004-07-27 2006-02-02 3M Innovative Properties Company Dry erase substrate
US20060131197A1 (en) * 2004-12-16 2006-06-22 Kimberly-Clark Worldwide, Inc. Disposable package with a repositioning attachment feature
US20060147636A1 (en) * 2004-12-30 2006-07-06 Cooprider Terrence E Method and apparatus of forming a coating fluid pattern
US7625605B2 (en) * 2004-12-30 2009-12-01 3M Innovative Properties Company Method for coating a surface with a pattern of coating fluid
MY146405A (en) * 2005-03-01 2012-08-15 Basf Ag Fast-release microcapsule products
US7749247B2 (en) * 2005-08-04 2010-07-06 St. Jude Medical Puerto Rico, Llc Tissue puncture closure device with coiled automatic tamping system
US8186541B2 (en) * 2005-08-31 2012-05-29 Kimberly-Clark Worldwide, Inc. Tissue sheet dispenser and process for making same
US20080003383A1 (en) * 2005-09-15 2008-01-03 3M Innovative Properties Company Repositionable photo paper
US20070059631A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable glossy photo media
US20070089832A1 (en) * 2005-09-15 2007-04-26 Kitchin Jonathan P Repositionable matte photo media
US20070059472A1 (en) * 2005-09-15 2007-03-15 3M Innovative Properties Company Repositionable photo media and photographs
US20070059613A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable photo card
US20070059652A1 (en) * 2005-09-15 2007-03-15 Kitchin Jonathan P Repositionable glossy photo media
US7467873B2 (en) * 2005-10-14 2008-12-23 3M Innovative Properties Company Privacy film
US7326504B2 (en) * 2005-10-14 2008-02-05 3M Innovative Properties Company Imaged anti-copy film
GB2432338A (en) * 2005-11-21 2007-05-23 3M Innovative Properties Co Personalised adhesive memoboard
US7661554B2 (en) * 2005-12-13 2010-02-16 Kimberly-Clark Worldwide, Inc. Tissue sheet dispenser and process for making same
US20070147712A1 (en) * 2005-12-19 2007-06-28 3M Innovative Properties Company Method of making articles for storing and organizing materials
US20070140597A1 (en) * 2005-12-19 2007-06-21 Eser Ozdeger Donovan Method of making articles for storing and organizing materials
US20070138044A1 (en) * 2005-12-19 2007-06-21 Trotter Byron E Article for storing and organizing materials
US7442439B2 (en) 2005-12-28 2008-10-28 Kimberly-Clark Worldwide, Inc. Microencapsulated heat delivery vehicles
US7914891B2 (en) 2005-12-28 2011-03-29 Kimberly-Clark Worldwide, Inc. Wipes including microencapsulated delivery vehicles and phase change materials
US20070148459A1 (en) * 2005-12-28 2007-06-28 Kimberly-Clark Worldwide, Inc. Microencapsulated delivery vehicles
US20070155859A1 (en) * 2006-01-04 2007-07-05 Zhengzhe Song Reactive polyurethane hot melt adhesive
US7531595B2 (en) 2006-03-08 2009-05-12 3M Innovative Properties Company Pressure-sensitive adhesive containing silica nanoparticles
US7645827B2 (en) * 2006-03-08 2010-01-12 3M Innovative Properties Company High shear pressure-sensitive adhesive
WO2007112294A1 (en) * 2006-03-24 2007-10-04 Henkel Corporation Sprayable water-based adhesive
TWI422597B (zh) * 2006-03-29 2014-01-11 Kawamura Inst Chem Res 中空聚合物粒子、著色中空聚合物粒子及彼等之製法
US20080092457A1 (en) * 2006-03-31 2008-04-24 Marilyn Malone Articles for Selecting Colors for Surfaces
US7654412B2 (en) 2006-05-30 2010-02-02 Kimberly-Clark Worldwide, Inc. Wet wipe dispensing system for dispensing warm wet wipes
US7497351B2 (en) 2006-05-30 2009-03-03 Kimberly-Clark Worldwide, Inc. Wet wipe dispensing system
US7713375B2 (en) * 2006-08-31 2010-05-11 Avery Dennison Corporation Dry erase writing board and method
US20080063842A1 (en) * 2006-09-12 2008-03-13 3M Innovative Properties Company Repositionable privacy note
US7547155B2 (en) * 2006-09-15 2009-06-16 3M Innovative Properties Company Marking device
US20080087376A1 (en) * 2006-10-11 2008-04-17 3M Innovative Properties Company Method of making a photographic print with an adhesive composite
US20080087379A1 (en) * 2006-10-11 2008-04-17 3M Innovative Properties Company Repositionable adhesive-backed photographs and photo media and methods of making
US20080096150A1 (en) 2006-10-23 2008-04-24 3M Innovative Properties Company Dental articles, methods, and kits including a compressible material
US9539065B2 (en) 2006-10-23 2017-01-10 3M Innovative Properties Company Assemblies, methods, and kits including a compressible material
CN101529957B (zh) * 2006-11-01 2012-07-04 富士通株式会社 无线通信装置和无线通信方法
US7645355B2 (en) 2006-11-17 2010-01-12 3M Innovative Properties Company Method of making a microsphere transfer adhesive
US7674345B2 (en) * 2006-12-08 2010-03-09 3M Innovative Properties Company Adhesive articles with discontinuities and methods of making the same
US8192841B2 (en) 2006-12-14 2012-06-05 Kimberly-Clark Worldwide, Inc. Microencapsulated delivery vehicle having an aqueous core
US7517582B2 (en) * 2006-12-14 2009-04-14 Kimberly-Clark Worldwide, Inc. Supersaturated solutions using crystallization enthalpy to impart temperature change to wet wipes
US8647426B2 (en) 2006-12-28 2014-02-11 3M Innovative Properties Company Dental filler and methods
US20080156444A1 (en) * 2006-12-28 2008-07-03 3M Innovative Properties Company Tape and Masking Material Composite
US20080200587A1 (en) * 2007-02-16 2008-08-21 3M Innovative Properties Company Pressure-sensitive adhesive containing acicular silica particles crosslinked with polyfunctional aziridines
US7393901B1 (en) 2007-02-16 2008-07-01 3M Innovative Properties Company Acrylate adhesives containing silica nanoparticles crosslinked with polyfunctional aziridines
BRPI0812559B1 (pt) * 2007-06-13 2018-09-04 3M Innovative Properties Co material de montagem reposicionável, dispositivo de controle de poluição e métodos para fabricação dos mesmos
US7652095B2 (en) * 2007-06-20 2010-01-26 3M Innovative Properties Company Pressure-sensitive adhesive containing aziridinyl silanes
US20090052973A1 (en) * 2007-08-22 2009-02-26 3M Innovative Properties Company Writing instrument with compact sheet dispenser
US20090050646A1 (en) * 2007-08-22 2009-02-26 3M Innovative Properties Company Compact sheet dispenser
US20090075007A1 (en) * 2007-09-13 2009-03-19 3M Innovative Properties Company Adhesive composite
US20090075070A1 (en) * 2007-09-13 2009-03-19 3M Innovative Properties Company Photographic print with an adhesive composite
US8378046B2 (en) 2007-10-19 2013-02-19 3M Innovative Properties Company High refractive index pressure-sensitive adhesives
US20090105437A1 (en) * 2007-10-19 2009-04-23 3M Innovative Properties Company High refractive index pressure-sensitive adhesives
KR101545365B1 (ko) * 2007-10-30 2015-08-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 고 굴절률 접착제
EP2231810A1 (en) * 2007-12-18 2010-09-29 3M Innovative Properties Company Microsphere pressure sensitive adhesive composition
US7652103B2 (en) * 2008-02-14 2010-01-26 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridine crosslinking agents
US7714076B2 (en) * 2008-03-27 2010-05-11 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridine crosslinking agents
EP2291478B1 (en) * 2008-06-09 2012-08-01 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridine crosslinking agents
US7924142B2 (en) 2008-06-30 2011-04-12 Kimberly-Clark Worldwide, Inc. Patterned self-warming wipe substrates
CN102317396A (zh) * 2008-12-24 2012-01-11 3M创新有限公司 微球压敏粘合剂组合物
CN102405267A (zh) 2009-03-09 2012-04-04 3M创新有限公司 用于丙烯酸系粘合剂的氮丙啶交联剂
US8067504B2 (en) 2009-08-25 2011-11-29 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with acylaziridine crosslinking agents
JP5439102B2 (ja) * 2009-09-25 2014-03-12 積水化成品工業株式会社 中空粒子、その製造法及びその用途
US8148471B2 (en) 2009-11-23 2012-04-03 3M Innovative Properties Company Acrylic pressure-sensitive adhesives with aziridinyl-epoxy crosslinking system
US20170238576A9 (en) * 2009-11-23 2017-08-24 Xiaohu Xia Gum bases containing non-uniform crosslinked polymer microparticles
US20110123672A1 (en) * 2009-11-23 2011-05-26 Xiaohu Xia Gum bases, chewing gums based thereupon, and methods for making the same
RU2533035C2 (ru) * 2009-11-23 2014-11-20 Вм. Ригли Дж. Компани Основа жевательной резинки (варианты) и способ ее изготовления
CN102108133B (zh) 2009-12-23 2014-12-10 3M创新有限公司 (甲基)丙烯酰基-氮丙啶交联剂和粘合剂聚合物
CN102127183B (zh) * 2010-01-20 2014-08-20 3M创新有限公司 可交联的丙烯酸酯粘合剂聚合物组合物
CA137792S (en) 2010-02-08 2011-06-13 Avery Dennison Corp Note sheet pad
US8778474B2 (en) 2010-02-08 2014-07-15 Ccl Label, Inc. Repositionable medium and stack thereof
USD679753S1 (en) 2010-02-08 2013-04-09 Avery Dennison Corporation Note sheets and related pads of note sheets
US20110195217A1 (en) * 2010-02-08 2011-08-11 Sato Jay K Note sheet and pads thereof and related method
US8137807B2 (en) 2010-03-26 2012-03-20 3M Innovative Properties Company Pressure-sensitive adhesives derived from 2-alkyl alkanols
US8222340B2 (en) 2010-04-05 2012-07-17 3M Innovative Properties Company Crosslinkable syrup copolymers with aminoalkyl (meth)acryloyl solvent monomers
SG186758A1 (en) 2010-06-30 2013-02-28 3M Innovative Properties Co (meth)acryloyl pressure-sensitive foam adhesives
CN103237824B (zh) 2010-12-21 2015-07-22 3M创新有限公司 衍生自仲烷基(甲基)丙烯酸酯的聚合物
JP5897037B2 (ja) 2010-12-29 2016-03-30 スリーエム イノベイティブ プロパティズ カンパニー トリアジン−エポキシ架橋系を有する感圧性接着剤
EP3649980B1 (en) 2010-12-30 2021-08-11 3M Innovative Properties Co. Bondable dental assemblies including a compressible material
EP2694952B1 (en) 2011-03-28 2017-11-01 3M Innovative Properties Company Sensor comprising a masking layer adhesive
DE102011007124B8 (de) 2011-04-11 2019-05-16 Gerd Jürgen Dürhager Innenauskleidung für Boxen
US8785517B2 (en) 2011-05-25 2014-07-22 3M Innovative Properties Company Pressure-sensitive adhesives with onium-epdxy crosslinking system
KR20140047666A (ko) 2011-06-23 2014-04-22 쓰리엠 이노베이티브 프로퍼티즈 컴파니 오늄-에폭시 수지 가교결합 시스템을 갖는 감압 접착제
EP2573150A1 (en) 2011-09-26 2013-03-27 3M Innovative Properties Company Multilayer pressure-sensitive adhesive films with pressure-sensitive adhesives comprising (meth)acrylate esters of 2-alkyl alkanols
WO2013074446A1 (en) 2011-11-18 2013-05-23 3M Innovative Properties Company Pressure - sensitive adhesive composition
EP2782941B1 (en) 2011-11-21 2017-02-22 3M Innovative Properties Company Polymeric particles for storage and delivery of active agents
CN104995020B (zh) 2012-02-03 2017-12-08 3M创新有限公司 用于保护性膜中的压敏粘合剂共混物
US9222254B2 (en) 2012-03-13 2015-12-29 Schabel Polymer Technology, Llc Structural assembly insulation
US20150307753A1 (en) * 2012-11-16 2015-10-29 3M Innovation Properties Company Conductive Resilient Hollow Microsphere, Adhesive Composition, and Adhesive Articles
BR112015015510A2 (pt) 2012-12-28 2017-07-11 3M Innovative Properties Co artigo e método de fabricar um artigo
US9434866B2 (en) 2013-03-13 2016-09-06 3M Innovative Properties Company Adhesives comprising epoxy-acid crosslinked groups and methods
EP2970093B1 (en) 2013-03-15 2018-12-12 3M Innovative Properties Company Method for preparing (meth)acrylates of biobased alcohols and polymers thereof
WO2014143690A1 (en) 2013-03-15 2014-09-18 3M Innovative Properties Company Method for preparing (meth)acrylates of biobased alcohols and polymers thereof
KR20160010493A (ko) 2013-05-14 2016-01-27 쓰리엠 이노베이티브 프로퍼티즈 컴파니 접착제 조성물
CN105228820B (zh) 2013-05-17 2017-08-29 3M创新有限公司 反应混合物、多孔粒子以及制备方法
JP6316944B2 (ja) 2013-05-17 2018-04-25 スリーエム イノベイティブ プロパティズ カンパニー 重合体複合粒子からの生物活性剤の放出
EP2803712A1 (en) 2013-05-17 2014-11-19 3M Innovative Properties Company Multilayer Pressure Sensitive Adhesive Assembly
US20170283669A1 (en) 2014-09-04 2017-10-05 3M Innovative Properties Company Pressure-sensitive adhesive containing nanocrystalline cellulose
WO2016167924A1 (en) 2015-04-13 2016-10-20 3M Innovative Properties Company Method of preparing crosslinked pressure-sensitive adhesives using a light-emitting diode for crosslinking
EP3310867B1 (en) 2015-06-22 2021-04-21 3M Innovative Properties Company Pressure sensitive adhesive comprising (meth)acrylic polymer and amino acid crosslinker
EP3156465A1 (en) 2015-10-15 2017-04-19 3M Innovative Properties Company Multilayer pressure sensitive adhesive foam tape for outdooor applications
EP3156466B1 (en) 2015-10-15 2020-11-25 3M Innovative Properties Company Multilayer pressure sensitive adhesive foam tape for outdooor applications
US20180304592A1 (en) * 2015-12-29 2018-10-25 3M Innovative Properties Company Mounting tab, dispenser for same, and method of use
CN106893534A (zh) * 2017-03-02 2017-06-27 浙江龙游道明光学有限公司 用于道路标志牌反光膜的热剥离压敏胶及其制备方法
JP6926725B2 (ja) * 2017-06-28 2021-08-25 東洋インキScホールディングス株式会社 水性分散液、接着剤、および水性分散液の製造方法
WO2019082023A1 (en) 2017-10-26 2019-05-02 3M Innovative Properties Company COMPOSITION CONTAINING SILICONE ADHESIVE AND CELLULOSE NANOCRYSTALS, METHODS AND ARTICLES
KR102470448B1 (ko) * 2017-12-15 2022-11-24 주식회사 엘지화학 의류용 수성 아크릴계 점착제 및 이의 제조 방법
US11661536B2 (en) 2018-02-28 2023-05-30 3M Innovative Properties Company Adhesives comprising polymerized units of secondary hexyl (meth)acrylates
EP3775086B1 (en) 2018-04-05 2022-09-14 3M Innovative Properties Company Gel adhesive comprising crosslinked blend of polydiorganosiloxane and acrylic polymer
EP3569622B1 (en) 2018-05-14 2021-01-06 3M Innovative Properties Company Multilayer pressure-sensitive adhesive assembly
EP3569669A1 (en) 2018-05-14 2019-11-20 3M Innovative Properties Company Method of manufacturing an electronic control device
EP3613820A1 (en) 2018-08-24 2020-02-26 3M Innovative Properties Company Multilayer pressure-sensitive adhesive assembly
WO2020093313A1 (en) 2018-11-08 2020-05-14 Avery Dennison Corporation Yellowing resistant psa
CN113165412B (zh) 2018-11-21 2022-10-25 3M创新有限公司 螺旋形粘合剂便笺本以及用于制备其的方法和装置
EP3715432A1 (en) 2019-03-27 2020-09-30 3M Innovative Properties Company Pressure-sensitive adhesive composition with transparency characteristics

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3615972A (en) * 1967-04-28 1971-10-26 Dow Chemical Co Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same
US3620988A (en) * 1968-10-31 1971-11-16 Goodrich Co B F Method of preparing bead-type polymers
US3691140A (en) * 1970-03-09 1972-09-12 Spencer Ferguson Silver Acrylate copolymer microspheres
US3857731A (en) * 1973-04-06 1974-12-31 Minnesota Mining & Mfg Acrylate microsphere-surfaced sheet material
DE2722751C2 (de) * 1977-05-20 1990-06-21 Röhm GmbH, 6100 Darmstadt Perlpolymerisat mit einem Teilchendurchmesser von 5 bis 1000 μm und innerem Hohlraum
US4166152B1 (en) * 1977-08-17 1999-05-18 Minnesota Mining & Mfg Tacky polymeric microspheres
GR78476B (es) * 1980-01-30 1984-09-27 Calgon Corp
US4495318A (en) * 1984-03-21 1985-01-22 International Cube Corporation Low tack microsphere glue
US4598112A (en) * 1984-09-14 1986-07-01 International Cube Corp. Low tack cationic microsphere glue
JPS6187734A (ja) * 1984-10-03 1986-05-06 Japan Synthetic Rubber Co Ltd 中空ポリマ−粒子の製造方法
US4645783A (en) * 1985-02-08 1987-02-24 Sanyo Kokusaku Pulp Co. Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same
US4656218A (en) * 1985-02-08 1987-04-07 Sanyo Kokusaku Pulp Co., Ltd. Adhesive copolymer microspheres-containing aqueous suspension and method for producing the same
JPH0414434Y2 (es) * 1985-04-08 1992-03-31
JPS61258854A (ja) * 1985-05-13 1986-11-17 Nichiban Co Ltd アクリル酸エステル系架橋重合体微小球及びその製法
DE3677843D1 (de) * 1985-07-13 1991-04-11 Smith & Mclaurin Klebstoffe.
US4742086A (en) * 1985-11-02 1988-05-03 Lion Corporation Process for manufacturing porous polymer
JPS6328901A (ja) * 1986-07-17 1988-02-06 ライオン株式会社 吸収性物品
JPS62106902A (ja) * 1985-11-02 1987-05-18 Lion Corp 多孔性ポリマ−の製造方法
JPH0788410B2 (ja) * 1986-09-01 1995-09-27 ライオン株式会社 表面架橋した多孔性ポリマ−の製造方法
US4839416A (en) * 1987-06-09 1989-06-13 Ampad Corporation Low tack microsphere adhesive
US4810763A (en) * 1987-12-23 1989-03-07 Avery International Corporation Suspension polymerization in an organic medium
US4944888A (en) * 1987-12-23 1990-07-31 Avery International Corporation Suspension polymerization in an organic medium
US4839393A (en) * 1988-07-08 1989-06-13 Wm. T. Burnett & Co., Inc. Polyurethane foams containing organofunctional silanes

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MX169793B (es) 1993-07-26
NO175154B (no) 1994-05-30
NO894064D0 (no) 1989-10-11
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AU4295189A (en) 1990-06-07
DK599989D0 (da) 1989-11-28
US5045569A (en) 1991-09-03
AU619350B2 (en) 1992-01-23
BR8906061A (pt) 1990-06-26
JP2940875B2 (ja) 1999-08-25
EP0371635B1 (en) 1996-07-17
DE68926846T2 (de) 1997-02-27
KR0155353B1 (ko) 1999-02-18
EP0371635A2 (en) 1990-06-06
ZA897828B (en) 1990-08-29
EP0371635A3 (en) 1991-05-29
DE68926846D1 (de) 1996-08-22
DK599989A (da) 1990-05-31
AR246283A1 (es) 1994-07-29
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KR900007990A (ko) 1990-06-02
NO894064L (no) 1990-05-31

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