ES2087961T3 - Preparacion de esteres alquilicos superiores de acidos carboxilicos. - Google Patents

Preparacion de esteres alquilicos superiores de acidos carboxilicos.

Info

Publication number
ES2087961T3
ES2087961T3 ES91200275T ES91200275T ES2087961T3 ES 2087961 T3 ES2087961 T3 ES 2087961T3 ES 91200275 T ES91200275 T ES 91200275T ES 91200275 T ES91200275 T ES 91200275T ES 2087961 T3 ES2087961 T3 ES 2087961T3
Authority
ES
Spain
Prior art keywords
superior
preparation
alkyl esters
methyl
carboxyl acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91200275T
Other languages
English (en)
Inventor
Ian R King
Karl L Krumel
Simon C Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corteva Agriscience LLC
Original Assignee
DowElanco LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DowElanco LLC filed Critical DowElanco LLC
Application granted granted Critical
Publication of ES2087961T3 publication Critical patent/ES2087961T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72Nitrogen atoms
    • C07D213/73Unsubstituted amino or imino radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Steroid Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

LOS ESTERES DE CADENA MAS LARGA (C SUB 6-C SUB 12) DE LOS ACIDOS DE SUSTITUCION 2-PIRIDINILOXIALCANOS, COMO EL ACETATO DE 1-METILHEPTIL (4-AMINO-3, 5-DICLORO-6-FLUOR-2-PIRIDINILOXI), SE PREPARAN CON GRAN RENDIMIENTO Y PUREZA PREPARANDO EN PRIMER LUGAR EL GRUPO METILO O ESTER METILO Y LUEGO TRANSESTERIFICANDOLOS CON UN ALCOHOL C SUB 6-C SUB 12. EL METILO O EL ESTER METILO SE PUEDE PREPARAR MEDIANTE ALKILACION DE UNA SAL METALICA ALCALINA DE 4-AMINO-3,5-DICLORO-6-FLUORO-2-PIRIDINOL CON CLOROACETATO DE METILO O ETILO Y ENTONCES SE PUEDE LLEVAR A CABO LA TRANSESTERIFICACION EN PRESENCIA DE UN CATALIZADOR DE TITANATO DE TETRAALKILO.
ES91200275T 1990-02-09 1991-02-08 Preparacion de esteres alquilicos superiores de acidos carboxilicos. Expired - Lifetime ES2087961T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US47770290A 1990-02-09 1990-02-09

Publications (1)

Publication Number Publication Date
ES2087961T3 true ES2087961T3 (es) 1996-08-01

Family

ID=23897004

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91200275T Expired - Lifetime ES2087961T3 (es) 1990-02-09 1991-02-08 Preparacion de esteres alquilicos superiores de acidos carboxilicos.

Country Status (15)

Country Link
EP (1) EP0441457B1 (es)
JP (1) JP3045320B2 (es)
CN (1) CN1031566C (es)
AT (1) ATE138912T1 (es)
AU (1) AU635608B2 (es)
BR (1) BR9100532A (es)
CA (1) CA2036017C (es)
DE (1) DE69119921T2 (es)
DK (1) DK0441457T3 (es)
ES (1) ES2087961T3 (es)
FI (1) FI101535B (es)
HU (1) HU208957B (es)
IL (1) IL97146A (es)
NZ (1) NZ237039A (es)
RU (1) RU1836348C (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374603A (en) * 1993-04-23 1994-12-20 Dowelanco Agricultural formulations comprising fluroxypyr esters which are liquid at 25° C.
CN103172561B (zh) * 2013-03-18 2015-03-18 永农生物科学有限公司 一锅法合成氟草烟仲辛酯的方法
CN103755629B (zh) * 2014-02-10 2016-03-30 济南科赛基农化工有限公司 一种制备氯氟吡氧乙酸盐的方法及应用
CN103787962A (zh) * 2014-03-07 2014-05-14 江苏省激素研究所股份有限公司 一种氟草烟仲辛酯合成方法
CN106749397B (zh) * 2016-12-09 2019-01-18 西安元创化工科技股份有限公司 一种甲基膦酸二甲庚酯的制备方法
CN113999169B (zh) * 2021-11-26 2023-04-07 江苏中旗科技股份有限公司 一种氯氟吡氧乙酸异辛酯的制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4542221A (en) * 1981-05-18 1985-09-17 The Dow Chemical Company Exchanging fluorine for chlorine in a chlorinated pyridine with an alkali metal fluoride
US4487933A (en) * 1981-12-14 1984-12-11 The Dow Chemical Company Titanium catalyzed transesterification

Also Published As

Publication number Publication date
HU208957B (en) 1994-02-28
EP0441457A3 (en) 1992-01-02
CN1054420A (zh) 1991-09-11
FI101535B1 (fi) 1998-07-15
IL97146A (en) 1994-12-29
ATE138912T1 (de) 1996-06-15
DE69119921D1 (de) 1996-07-11
CA2036017C (en) 2001-07-24
NZ237039A (en) 1992-11-25
FI910632A (fi) 1991-08-10
BR9100532A (pt) 1991-10-29
HUT56346A (en) 1991-08-28
AU635608B2 (en) 1993-03-25
DK0441457T3 (da) 1996-10-14
JP3045320B2 (ja) 2000-05-29
JPH054967A (ja) 1993-01-14
FI101535B (fi) 1998-07-15
IL97146A0 (en) 1992-05-25
CN1031566C (zh) 1996-04-17
RU1836348C (ru) 1993-08-23
AU7085791A (en) 1991-08-15
HU910421D0 (en) 1991-08-28
DE69119921T2 (de) 1996-10-24
FI910632A0 (fi) 1991-02-08
CA2036017A1 (en) 1991-08-10
EP0441457B1 (en) 1996-06-05
EP0441457A2 (en) 1991-08-14

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