ES2046375T3 - Procedimiento para la preparacion de acido acetico y anhidrido de acido acetico. - Google Patents

Procedimiento para la preparacion de acido acetico y anhidrido de acido acetico.

Info

Publication number
ES2046375T3
ES2046375T3 ES198989110743T ES89110743T ES2046375T3 ES 2046375 T3 ES2046375 T3 ES 2046375T3 ES 198989110743 T ES198989110743 T ES 198989110743T ES 89110743 T ES89110743 T ES 89110743T ES 2046375 T3 ES2046375 T3 ES 2046375T3
Authority
ES
Spain
Prior art keywords
acetic acid
distillation zone
preparation
iodide
components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198989110743T
Other languages
English (en)
Other versions
ES2046375T5 (es
Inventor
Heinz Dr. Erpenbach
Klaus Dr. Gehrmann
Erhard Dr. Jagers
Georg Kohl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6358531&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2046375(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of ES2046375T3 publication Critical patent/ES2046375T3/es
Application granted granted Critical
Publication of ES2046375T5 publication Critical patent/ES2046375T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54—Preparation of carboxylic acid anhydrides
    • C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/12—Acetic anhydride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PARA LA FABRICACION DE ACIDO ACETICO Y ANHIDRIDO DE ACIDO ACETICO SE TRANSFORMAN MATANOL Y METILACETATO A CONDICIONES DE ANHIDRIDO CON MONOXIDO DE CARBONO EN PRESENCIA DE UN COMPLEJO CARBONYL DEL GRUPO VIII DE METALES PRECIOSOS METILIODID, ASI COMO ACETATO DE AMONIO ORGANICO O ACETATO FOSFONIO ORGANICO ALCALI CUATERNARIO O IODO CONTENIDO EN UN SISTEMA CATALIZADOR. LA MEZCLA CALIENTE DE CARBONIZACION ES TENSADA, SE AÑADEN LOS COMPONENTES VAPORIZADOS DE LA PRIMERA ZONA DE DESTILACION, SE RETIRAN LAS SOLUCIONES DE CATALIZADOR QUE QUEDAN DE LA ZONA DE REACCION. EN LA PRIMERA ZONA DE DESTILACION SE DESTILAN LOS PRODUCTOS FLOTANTES DE CARBONIZACION FRACCIONADOS; LA LEVE EBULLICION DEL IODO METALICO Y ACETATO METILICO RETROCEDE A LA ZONA DE REACCION COMO PRODUCTO EN FORMA DE LODO SE FORMA UNA MEZCLA ENTRE ACIDO ACETICO Y ANHIDRIDO DE ACIDO ACETICO QUE SE DESTILA EN UNA SEGUNDA Y TERCERA ZONA DE DESTILACION EXTRAYENDO LOS COMPONENTES PUROS.
ES89110743T 1988-07-13 1989-06-14 Procedimiento para la preparacion de acido acetico y anhidrido de acido acetico. Expired - Lifetime ES2046375T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3823645A DE3823645C1 (es) 1988-07-13 1988-07-13

Publications (2)

Publication Number Publication Date
ES2046375T3 true ES2046375T3 (es) 1994-02-01
ES2046375T5 ES2046375T5 (es) 2002-12-16

Family

ID=6358531

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89110743T Expired - Lifetime ES2046375T5 (es) 1988-07-13 1989-06-14 Procedimiento para la preparacion de acido acetico y anhidrido de acido acetico.

Country Status (15)

Country Link
US (1) US5380929A (es)
EP (1) EP0350635B2 (es)
JP (1) JPH072672B2 (es)
KR (1) KR0144154B1 (es)
CN (1) CN1025184C (es)
AT (1) ATE95158T1 (es)
AU (1) AU617833B2 (es)
BR (1) BR8903416A (es)
CA (1) CA1339278C (es)
DE (2) DE3823645C1 (es)
ES (1) ES2046375T5 (es)
NO (1) NO170539C (es)
NZ (1) NZ229904A (es)
SU (1) SU1766249A3 (es)
ZA (1) ZA895285B (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1313676C (en) * 1987-12-23 1993-02-16 Mark Owen Scates Purification of acetic acid with ozone
DE4029917A1 (de) * 1990-09-21 1992-03-26 Hoechst Ag Verfahren zur gleichzeitigen herstellung von essigsaeure und essigsaeureanhydrid
GB9120902D0 (en) * 1991-10-02 1991-11-13 Bp Chem Int Ltd Purification process
US5488143A (en) * 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
KR960007736B1 (ko) * 1993-07-27 1996-06-11 한국과학기술연구원 원료 가스 중에 함유된 철 카르보닐 화합물의 제거 방법
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5648531A (en) * 1993-08-18 1997-07-15 Daicel Chemical Industries, Ltd. Process for producing acetic anhydride alone or acetic anhydride and acetic acid
US5554790A (en) * 1994-04-04 1996-09-10 Daicel Chemical Industries, Ltd. Process for producing acetic anhydride and acetic acid
JP3308392B2 (ja) * 1994-06-02 2002-07-29 ダイセル化学工業株式会社 カルボニル化反応方法
US5510524A (en) * 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
GB9625335D0 (en) * 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
SG65716A1 (en) * 1996-12-30 1999-06-22 Chiyoda Chem Eng Construct Co Process for the production of carbonyl compound
GB9802027D0 (en) * 1998-01-31 1998-03-25 Bp Chem Int Ltd Chemical process
US7737298B2 (en) * 2006-06-09 2010-06-15 Eastman Chemical Company Production of acetic acid and mixtures of acetic acid and acetic anhydride
US7582792B2 (en) * 2006-06-15 2009-09-01 Eastman Chemical Company Carbonylation process
US7253304B1 (en) 2006-06-20 2007-08-07 Eastman Chemical Company Carbonylation process
US7629491B2 (en) * 2006-06-26 2009-12-08 Eastman Chemical Company Hydrocarboxylation process
US20090247783A1 (en) * 2008-04-01 2009-10-01 Eastman Chemical Company Carbonylation process
US8168822B2 (en) * 2009-07-07 2012-05-01 Celanese International Corporation Acetic acid production by way of carbonylation with enhanced reaction and flashing
US8394988B2 (en) 2010-09-28 2013-03-12 Celanese International Corporation Production of acetic acid with high conversion rate
US8877963B2 (en) * 2010-09-28 2014-11-04 Celanese International Corporation Production of acetic acid with high conversion rate
US9012683B2 (en) 2010-11-12 2015-04-21 Eastman Chemical Company Coproduction of acetic acid and acetic anhydride
US9416086B2 (en) 2010-11-12 2016-08-16 Eastman Chemical Company Processes for purification of acid solutions
CN103189125A (zh) * 2010-11-12 2013-07-03 伊士曼化工公司 羰基化过程产生的气流的处理
US9663437B2 (en) 2011-09-13 2017-05-30 Celanese International Corporation Production of acetic acid with high conversion rate
MX362499B (es) * 2011-12-16 2019-01-21 Celanese Int Corp Produccion de acido acetico con estabilidad mejorada del catalizador.
CN103402965A (zh) * 2012-02-08 2013-11-20 国际人造丝公司 以高的转化率生产乙酸
US8759576B2 (en) 2012-09-06 2014-06-24 Celanese International Corporation Processes for purifying acetic anhydride
CN104276939B (zh) * 2013-07-09 2016-09-07 上海华谊工程有限公司 一种醋酐的生产工艺
JP6034478B2 (ja) * 2015-01-30 2016-11-30 セラニーズ・インターナショナル・コーポレーション 酢酸の製造方法
JP6034477B2 (ja) * 2015-01-30 2016-11-30 セラニーズ・インターナショナル・コーポレーション 酢酸の製造方法
CN112441901B (zh) * 2020-12-15 2023-08-29 山东泰和科技股份有限公司 一种乙酸酐的合成方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR976166A (fr) * 1952-12-05 1951-03-14 Ct D Etudes Et De Rech S Tech Procédé pour la préparation d'éthylène et d'éthane à côté d'hydrocarbures aromatiques à partir d'hydrocarbures aliphatiques
DE1115234B (de) † 1960-01-23 1961-10-19 Basf Ag Verfahren zur Herstellung von Essigsaeure oder deren Gemisch mit Methylacetat
US3772380A (en) * 1970-03-12 1973-11-13 Monsanto Co Production of carboxylic acids and esters
US4559183A (en) * 1973-09-04 1985-12-17 The Halcon Sd Group, Inc. Preparation of carboxylic acid anhydrides
DE2450965C2 (de) † 1974-10-26 1983-06-09 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Essigsäureanhydrid
US4110359A (en) * 1976-12-10 1978-08-29 Texaco Development Corporation Production of cleaned and purified synthesis gas and carbon monoxide
DE2836084A1 (de) * 1978-08-17 1980-03-06 Hoechst Ag Verfahren zur herstellung von essigsaeureanhydrid
DE2939839A1 (de) † 1979-10-02 1981-04-23 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von essigsaeureanhydrid
DE3137782A1 (de) † 1981-09-23 1983-03-31 Hoechst Ag, 6230 Frankfurt Verfahren zur rueckgewinnung von jodverbindungen aus dem abgas von carbonylierungsreaktionen
DE3149092A1 (de) * 1981-12-11 1983-06-16 Hoechst Ag, 6230 Frankfurt Verfahren zur abtrennung des katalysatorsystems aus reaktionsgemischen von carbonylierungsreaktionen
NZ203225A (en) * 1982-02-13 1985-01-31 Bp Chem Int Ltd Coproduction of monocarboxylic acids and anhydrides
DE3329781A1 (de) * 1983-08-18 1985-02-28 Hoechst Ag, 6230 Frankfurt Verfahren zur abtrennung von jod und dessen verbindungen aus den bei der carbonylierung von dimethylether, methylacetat oder methanol erhaltenen carbonylierungsprodukten
CA1231965A (en) * 1983-12-02 1988-01-26 David J. Schreck Synergistic production of carboxylic acids from alcohols
DE3429180A1 (de) * 1984-08-08 1986-02-20 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von essigsaeureanhydrid und ggf. essigsaeure
DE3429179A1 (de) * 1984-08-08 1986-02-20 Hoechst Ag, 6230 Frankfurt Verfahren zur gemeinsamen herstellung von carbonsaeuren und carbonsaeureanhydriden sowie ggf. carbonsaeureestern
CA1248549A (en) * 1984-08-16 1989-01-10 Richard W. Wegman Production of anhydrous carboxylic acids from alcohols using rhodium complex catalysts and organic ester source
JPS6158803A (ja) † 1984-08-27 1986-03-26 Daicel Chem Ind Ltd カルボニル化反応廃ガスからの沃素化合物の回収法
US4615806B1 (en) † 1985-03-07 1994-05-03 Hoechst Co American Removal of iodide compounds from non-aqueous organic media
DE3534070A1 (de) * 1985-09-25 1987-04-02 Hoechst Ag Verfahren zur abtrennung von jod und dessen verbindungen aus den bei der carbonylierung von dimethylether, methylacetat oder methanol erhaltenen carbonylierungsprodukten
JPS6399027A (ja) * 1985-09-30 1988-04-30 ヘキスト・アクチエンゲゼルシヤフト ジメチルエ−テル、酢酸メチル又はメタノ−ルのカルボニル化に際して得られるカルボニル化生成物から沃素及びその化合物を分離する方法
DE3612504A1 (de) * 1985-09-30 1987-04-09 Hoechst Ag Verfahren zur abtrennung von jod und dessen verbindungen aus den bei der carbbonylierung von dimethylether, methylacetat oder methanol erhaltenden carbonylierungsprodukten
US4894477A (en) * 1986-10-14 1990-01-16 Hoechst Celanese Corporation Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid

Also Published As

Publication number Publication date
NO170539C (no) 1992-10-28
KR0144154B1 (ko) 1998-07-15
JPH072672B2 (ja) 1995-01-18
EP0350635B2 (de) 2002-07-17
NO892882D0 (no) 1989-07-12
SU1766249A3 (ru) 1992-09-30
JPH02104551A (ja) 1990-04-17
CA1339278C (en) 1997-08-12
NO170539B (no) 1992-07-20
ES2046375T5 (es) 2002-12-16
KR900001637A (ko) 1990-02-27
NO892882L (no) 1990-01-15
ATE95158T1 (de) 1993-10-15
CN1025184C (zh) 1994-06-29
DE58905741D1 (de) 1993-11-04
DE3823645C1 (es) 1989-11-30
BR8903416A (pt) 1990-02-13
ZA895285B (en) 1990-04-25
US5380929A (en) 1995-01-10
CN1039410A (zh) 1990-02-07
EP0350635A1 (de) 1990-01-17
AU3803789A (en) 1990-01-18
EP0350635B1 (de) 1993-09-29
AU617833B2 (en) 1991-12-05
NZ229904A (en) 1991-07-26

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