AU576260B2 - Coproduction of carboxylic acids, anhydrides and optionally esters - Google Patents

Coproduction of carboxylic acids, anhydrides and optionally esters

Info

Publication number
AU576260B2
AU576260B2 AU45886/85A AU4588685A AU576260B2 AU 576260 B2 AU576260 B2 AU 576260B2 AU 45886/85 A AU45886/85 A AU 45886/85A AU 4588685 A AU4588685 A AU 4588685A AU 576260 B2 AU576260 B2 AU 576260B2
Authority
AU
Australia
Prior art keywords
iodide
general formula
carboxylic acids
alcohol
appropriate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU45886/85A
Other versions
AU4588685A (en
Inventor
Heinz Erpenbach
Klaus Gehrmann
Peter Horstermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of AU4588685A publication Critical patent/AU4588685A/en
Application granted granted Critical
Publication of AU576260B2 publication Critical patent/AU576260B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54—Preparation of carboxylic acid anhydrides
    • C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

1. A process for the common preparation of carboxylic acids and carboxylic anhydrides and, if appropriate, carboxylic acid esters of the general formulae RCOOH, RCOOCOR and RCOOR respectively, by reacting a dialkyl ether of the general formula ROR and an alcohol of the general formula ROH with carbon monoxide, optionally containing up to 10% by volume of hydrogen, in the presence of a catalyst system comprising carbonyl complexes of noble metals of group VIII of the Periodic Table ; an alkali metal iodide, organophosphonium iodide or organoammonium iodide ; an alkyl iodide of the general formula RI and, if appropriate, compounds of carbonyl forming non-noble metals of groups IV, V, VI, VII or VIII of the Periodic Table, where R in each case denotes the same alkyl radical having 1 to 4 carbon atoms, which comprises employing the dialkyl ether and the alcohol in the molar ratio 9 : 1 to 1 : 9 and carrying out the reaction under anhydrous conditions at temperatures of from 50 to 250 degrees C and pressures of from 0.1 to 120 bar.
AU45886/85A 1984-08-08 1985-08-07 Coproduction of carboxylic acids, anhydrides and optionally esters Ceased AU576260B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843429179 DE3429179A1 (en) 1984-08-08 1984-08-08 METHOD FOR THE SIMULTANEOUS PRODUCTION OF CARBONIC ACIDS AND CARBONIC ACID ANHYDRIDES AND IF ANY. CARBONIC ACID ESTERS
DE3429179 1984-08-08

Publications (2)

Publication Number Publication Date
AU4588685A AU4588685A (en) 1986-02-13
AU576260B2 true AU576260B2 (en) 1988-08-18

Family

ID=6242594

Family Applications (1)

Application Number Title Priority Date Filing Date
AU45886/85A Ceased AU576260B2 (en) 1984-08-08 1985-08-07 Coproduction of carboxylic acids, anhydrides and optionally esters

Country Status (9)

Country Link
EP (1) EP0170965B1 (en)
JP (1) JPS6147428A (en)
AT (1) ATE45722T1 (en)
AU (1) AU576260B2 (en)
BR (1) BR8503725A (en)
CA (1) CA1258469A (en)
DE (2) DE3429179A1 (en)
MX (1) MX163194B (en)
ZA (1) ZA855954B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3429180A1 (en) * 1984-08-08 1986-02-20 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING ACETIC ACID ANHYDRIDE AND GGF. ACETIC ACID
CA1299195C (en) * 1986-06-16 1992-04-21 G. Paull Torrence Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol
DE3823645C1 (en) * 1988-07-13 1989-11-30 Hoechst Ag
GB9021454D0 (en) * 1990-10-03 1990-11-14 Bp Chem Int Ltd Process
DE4034501A1 (en) * 1990-10-30 1992-05-07 Hoechst Ag METHOD FOR REMOVING METAL CORROSION PRODUCTS FROM WATER-FREE CARBONYLATION REACTIONS
DE4034867A1 (en) * 1990-11-02 1992-05-07 Hoechst Ag CONTINUOUS PROCESS FOR THE SIMULTANEOUS PRODUCTION OF ACETIC ACID AND ACETIC ACID ANHYDRIDE
CA2093752C (en) * 1992-04-15 1999-06-15 David W. Studer Integrated process for oxygenated acetyl compounds from synthesis gas via dimethyl ether
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5760279A (en) * 1995-06-19 1998-06-02 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU531718B2 (en) * 1978-08-17 1983-09-01 Hoechst A.G. Production of acetic anhydride
AU2369184A (en) * 1983-01-25 1984-07-26 Shell Internationale Research Maatschappij B.V. Preparation of carboxylic acids and esters
AU552612B2 (en) * 1981-09-22 1986-06-12 Shell Internationale Research Maatschappij B.V. Preparation of acids and esters

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2939839A1 (en) * 1979-10-02 1981-04-23 Hoechst Ag, 6000 Frankfurt METHOD FOR PRODUCING ACETIC ACID ANHYDRIDE
JPS5930687B2 (en) * 1980-04-22 1984-07-28 三菱瓦斯化学株式会社 Method for producing ethylidene diacetate and/or acetic anhydride
DE3144772A1 (en) * 1981-11-11 1983-05-19 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING ACETIC ACID ANHYDRIDE AND ACETIC ACID

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU531718B2 (en) * 1978-08-17 1983-09-01 Hoechst A.G. Production of acetic anhydride
AU552612B2 (en) * 1981-09-22 1986-06-12 Shell Internationale Research Maatschappij B.V. Preparation of acids and esters
AU2369184A (en) * 1983-01-25 1984-07-26 Shell Internationale Research Maatschappij B.V. Preparation of carboxylic acids and esters

Also Published As

Publication number Publication date
BR8503725A (en) 1986-05-13
EP0170965A3 (en) 1987-05-20
ATE45722T1 (en) 1989-09-15
AU4588685A (en) 1986-02-13
ZA855954B (en) 1986-04-30
JPH0371418B2 (en) 1991-11-13
EP0170965A2 (en) 1986-02-12
CA1258469A (en) 1989-08-15
DE3429179A1 (en) 1986-02-20
DE3572473D1 (en) 1989-09-28
JPS6147428A (en) 1986-03-07
MX163194B (en) 1991-10-15
EP0170965B1 (en) 1989-08-23

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Legal Events

Date Code Title Description
MK14 Patent ceased section 143(a) (annual fees not paid) or expired