ES2004935A6 - Un metodo para minimizar o evitar la precipitacion del rodio de un catalizador complejo de rodio-fosfito - Google Patents

Un metodo para minimizar o evitar la precipitacion del rodio de un catalizador complejo de rodio-fosfito

Info

Publication number
ES2004935A6
ES2004935A6 ES8701486A ES8701486A ES2004935A6 ES 2004935 A6 ES2004935 A6 ES 2004935A6 ES 8701486 A ES8701486 A ES 8701486A ES 8701486 A ES8701486 A ES 8701486A ES 2004935 A6 ES2004935 A6 ES 2004935A6
Authority
ES
Spain
Prior art keywords
aldehyde
prod
transition metal
metal complex
catalyzed hydroformylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8701486A
Other languages
English (en)
Spanish (es)
Inventor
John Michael Maher
David Robert Bryant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/865,061 external-priority patent/US4717775A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES2004935A6 publication Critical patent/ES2004935A6/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
ES8701486A 1986-05-20 1987-05-20 Un metodo para minimizar o evitar la precipitacion del rodio de un catalizador complejo de rodio-fosfito Expired ES2004935A6 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/865,061 US4717775A (en) 1984-12-28 1986-05-20 Transition metal complex catalyzed reactions
US07/046,821 US4774361A (en) 1986-05-20 1987-05-11 Transition metal complex catalyzed reactions
PCT/US1987/001124 WO1987007261A2 (en) 1986-05-20 1987-05-19 Transition metal complex catalyzed hydroformulation

Publications (1)

Publication Number Publication Date
ES2004935A6 true ES2004935A6 (es) 1989-02-16

Family

ID=26724327

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8701486A Expired ES2004935A6 (es) 1986-05-20 1987-05-20 Un metodo para minimizar o evitar la precipitacion del rodio de un catalizador complejo de rodio-fosfito

Country Status (12)

Country Link
US (1) US4774361A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0276231B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPS63503385A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN1010011B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU613312B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA1312094C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE3773890D1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2004935A6 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IN (1) IN169727B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (1) MX166107B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NO (1) NO166583C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO1987007261A2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

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US5169981A (en) * 1991-12-06 1992-12-08 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5243099A (en) * 1991-12-06 1993-09-07 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
US5739352A (en) * 1995-10-19 1998-04-14 United Carbide Chemicals & Plastics Technology Corporation Process for preparing carboxylic acids
DE19605435A1 (de) * 1996-02-14 1997-08-21 Basf Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion
US6090987A (en) * 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
DE69923801T2 (de) 1998-12-10 2006-03-23 Mitsubishi Chemical Corp. Verfahren zur Herstellung von Aldehyden
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DE19954510A1 (de) 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
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KR100988732B1 (ko) * 2002-08-31 2010-10-20 에보니크 옥세노 게엠베하 사이클릭 탄산 에스테르의 존재하에 개질되지 않은 금속 착물에 의해 촉매된 올레핀계 불포화 화합물의 하이드로포밀화에 의해 알데하이드를 제조하는 방법
ATE470736T1 (de) * 2003-01-16 2010-06-15 Teijin Fibers Ltd Differential-shrinkage-filamentgarn in kombination mit polyester
BRPI0411948B1 (pt) * 2003-07-03 2014-03-25 Dow Technology Investments Llc Método para minimizar a produção de um ou mais produtos de degradação de ligantes de íons fosfônio e processo para minimizar a formação de um ou mais produtos de degradação de ligantes de íons fosfônio
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
PL209549B1 (pl) 2004-08-02 2011-09-30 Dow Technology Investments Llc Sposób hydroformylowania
WO2008115740A1 (en) * 2007-03-20 2008-09-25 Union Carbide Chemicals & Plastics Technology Llc Hydroformylation process with improved control over product isomers
JP5298119B2 (ja) * 2007-04-09 2013-09-25 エルジー・ケム・リミテッド ホスファイト配位子を含む触媒組成物およびこれを用いたヒドロホルミル化方法
MX2010014570A (es) 2008-07-03 2011-08-15 Dow Technology Investments Llc Proceso para controlar pesados en una corriente de catalizador de reciclado.
EP2349560B1 (en) 2008-11-14 2025-01-22 University Of Kansas Polymer-supported transition metal catalyst complexes and methods of use
WO2010117391A1 (en) 2009-03-31 2010-10-14 Dow Technology Investment Llc Hydroformylation process with a doubly open-ended bisphosphite ligand
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
US8586800B2 (en) 2009-10-16 2013-11-19 Dow Technology Investments Llc Gas phase hydroformylation process
EP2581362B1 (en) 2009-12-22 2018-01-31 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process
EP2516373B2 (en) 2009-12-22 2020-08-12 Dow Technology Investments LLC Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process
CN102753511B (zh) 2009-12-22 2014-11-19 陶氏技术投资有限责任公司 在混合配体加氢甲酰化工艺中通过控制合成气分压来控制正构:异构醛的比率
JP2014502254A (ja) 2010-10-05 2014-01-30 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化の方法
MX346922B (es) 2010-11-12 2017-04-05 Dow Technology Investments Llc Moderación de suciedad en procesos de hidroformilación mediante adición de agua.
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PL2822921T3 (pl) 2012-03-07 2018-11-30 Basf Se SPOSÓB INTEGRACJI CIEPŁA PRZY UWODORNIANIU I DESTYLACJI C<sub>3</sub>-C<sub>20</sub>- ALDEHYDÓW
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
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WO2013184350A1 (en) 2012-06-04 2013-12-12 Dow Technology Investments Llc Hydroformylation process
WO2014035673A1 (en) * 2012-08-29 2014-03-06 Dow Technology Investments Llc Catalyst preparation process
RU2639156C2 (ru) 2012-09-25 2017-12-20 Дау Текнолоджи Инвестментс Ллс Способ стабилизации фосфитного лиганда против деградации
EP2740535A1 (en) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentate ligands for hydroformylation of ethylene
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CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
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TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
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TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
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JP7356419B2 (ja) 2017-10-25 2023-10-04 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス中に形成されるアルデヒド化合物を含む溶液中の重質形成を低減する方法
CN111278560B (zh) 2017-11-13 2023-07-21 陶氏技术投资有限责任公司 从氢甲酰化方法回收铑的方法
TWI793216B (zh) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
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KR20210013702A (ko) 2018-05-30 2021-02-05 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포밀화 공정에서 촉매의 탈활성화를 느리게 하고/하거나 테트라포스핀 리간드 사용을 느리게 하는 방법
CN112055614A (zh) 2018-05-30 2020-12-08 陶氏技术投资有限责任公司 包括单膦、四膦配位体的组合的催化剂组合物和使用其的加氢甲酰化过程
MY203235A (en) * 2018-11-29 2024-06-19 Dow Technology Investments Llc Hydroformylation process
MY208581A (en) * 2019-06-27 2025-05-16 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
WO2021126421A1 (en) 2019-12-19 2021-06-24 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
CN114478214B (zh) * 2020-10-23 2024-05-17 中国石油化工股份有限公司 一种氢甲酰化方法和一种氢甲酰化产物的分离方法
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WO2025029369A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity
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Also Published As

Publication number Publication date
JPH0548215B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-07-20
EP0276231B1 (en) 1991-10-16
NO880207L (no) 1988-01-19
AU613312B2 (en) 1991-08-01
CN87104311A (zh) 1988-06-08
NO166583C (no) 1991-08-14
JPS63503385A (ja) 1988-12-08
DE3773890D1 (de) 1991-11-21
CN1010011B (zh) 1990-10-17
AU7489887A (en) 1987-12-22
NO166583B (no) 1991-05-06
US4774361A (en) 1988-09-27
NO880207D0 (no) 1988-01-19
IN169727B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1991-12-14
MX166107B (es) 1992-12-21
CA1312094C (en) 1992-12-29
WO1987007261A3 (en) 1988-04-07
EP0276231A1 (en) 1988-08-03
WO1987007261A2 (en) 1987-12-03

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