EP4351272A1 - Dispositif de chauffage - Google Patents
Dispositif de chauffage Download PDFInfo
- Publication number
- EP4351272A1 EP4351272A1 EP22811068.0A EP22811068A EP4351272A1 EP 4351272 A1 EP4351272 A1 EP 4351272A1 EP 22811068 A EP22811068 A EP 22811068A EP 4351272 A1 EP4351272 A1 EP 4351272A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrode pad
- ceramic body
- heater
- lead terminal
- end surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 claims abstract description 77
- 238000010438 heat treatment Methods 0.000 claims abstract description 38
- 239000000463 material Substances 0.000 claims abstract description 38
- 230000005499 meniscus Effects 0.000 claims description 4
- 230000007774 longterm Effects 0.000 description 15
- 206010040844 Skin exfoliation Diseases 0.000 description 6
- 239000011162 core material Substances 0.000 description 6
- 239000007769 metal material Substances 0.000 description 5
- 230000002093 peripheral effect Effects 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 for example Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
- H05B3/42—Heating elements having the shape of rods or tubes non-flexible
- H05B3/48—Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
- H05B3/06—Heater elements structurally combined with coupling elements or holders
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/021—Heaters specially adapted for heating liquids
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/022—Heaters specially adapted for heating gaseous material
Definitions
- the present disclosure relates to a heater used for a liquid heating heater, a gas heating heater, an oxygen sensor heater, or the like.
- the ceramic heater described in Patent Document 1 includes a core member including a heat generation portion therein, a connection terminal portion provided at a side surface of the core material and connected to the heat generation portion, and a lead terminal including one end portion bonded to the connection terminal portion by a brazing material and the other end portion extending along a longitudinal direction of the ceramic heater.
- Patent Document 1 JP 2016-81608 A
- the heater includes a ceramic body having a cylindrical or a tubular shape and extending from a first end toward a second end, a heating resistor located inside the ceramic body, an electrode pad electrically connected to the heating resistor, a lead terminal electrically connected to the electrode pad, and a bonding material having electrical conductivity and bonding the electrode pad and the lead terminal, wherein the electrode pad is located from a side surface to an end surface of the ceramic body.
- a terminal connection portion is provided at one surface of a core member. This has resulted in a risk of failure to maintain the bonding strength of the terminal connection portion when vibration occurs in a direction in which the core member and the terminal connection portion are separated from each other. Thus, the terminal connection portion may be peeled off from the core member when used for a long period of time. As a result, it has been difficult to improve the long-term reliability of ceramic heaters.
- an electrode pad is located from a side surface to an end surface of a ceramic body.
- the electrode pad can be provided at a plurality of surfaces of the ceramic body.
- a heater 100 will be described in detail.
- FIG. 1A is a perspective view illustrating an example of the heater 100.
- FIG. 1B is a schematic perspective view in which part of the heater illustrated in FIG. 1A is seen through.
- the heater 100 includes a ceramic body 1 having a cylindrical or a tubular shape and extending from a first end 101 toward a second end 102, a heating resistor 2 located inside the ceramic body 1, an electrode pad 3 electrically connected to the heating resistor 2, a lead terminal electrically connected to the electrode pad 3, and a bonding material 5 having electrical conductivity and bonding the electrode pad 3 and the lead terminal 4, wherein the electrode pad 3 is located from a side surface to an end surface of the ceramic body 1.
- first end 101 and the second end 102 of the heater 100 are at the lower left side and the upper right side, respectively.
- first end 101 and the second end 102 are provided at the upper side and the lower side, respectively.
- first end 101 side and second end 102 side may be used. Based on the center in the longitudinal direction, which is the direction in which the ceramic body 1 extends, a portion closer to the first end 101 is the "first end 101 side” and a portion closer to the second end 102 is the "second end 102 side”.
- the "first end 101 side” can also be referred to as the vicinity of the first end 101
- the "second end 102 side” can also be referred to as the vicinity of the second end 102.
- the ceramic body 1 is a member provided to protect the heating resistor 2.
- the ceramic body 1 has a cylindrical or tubular shape having a longitudinal direction. In the heater 100 illustrated in FIG. 1 , the ceramic body 1 has a tubular shape.
- the ceramic body 1 includes an insulating ceramic material.
- the ceramic body 1 includes an insulating ceramic material such as, for example, alumina, silicon nitride, or aluminum nitride.
- the dimensions of the ceramic body 1 can be, for example, 10 mm to 400 mm in length and 5 mm to 60 mm in outer diameter.
- the dimensions of the ceramic body 1 may be, for example, 10 mm to 400 mm in length, 5 mm to 60 mm in outer diameter, and 3 mm to 50 mm in inner diameter.
- the ceramic body 1 may include a slit-like recess extending from the first end 101 toward the second end 102 in the outer peripheral surface as illustrated in FIGs. 1A and 1B .
- the heating resistor 2 is a member for generating heat when electrical current flows therethrough.
- the heating resistor 2 is provided inside the ceramic body 1 as illustrated in FIGs. 1B , 2A , and 2B .
- the heating resistor 2 may be disposed so as to generate the largest amount of heat at the second end 102 side of the ceramic body 1.
- the heating resistor 2 may extend from the first end 101 side toward the second end 102 side of the ceramic body 1 and may extend from the second end 102 side toward the other first end 101 side after reaching the second end 102 side. As illustrated in FIG.
- the heating resistor 2 may include a folded portion in which the heating resistor 2 is provided along a circumferential direction while being repeatedly folded in the longitudinal direction, at the second end 102 side of the ceramic body 1. Further, the heating resistor 2 may be a pair of linear portions at the second end 102 side of the folded portion. The heating resistor 2 may have a pattern in which the heating resistor 2 is repeatedly folded back and forth between the first end 101 side and the second end 102 side, instead of the pattern in which the folded portion with repeated folding is only at the second end 102 side.
- the heating resistor 2 includes a metal material.
- the metal material includes, for example, tungsten, molybdenum, or rhenium.
- the heating resistor 2 may include an insulating member. Thus, the resistance value of the heating resistor 2 can be adjusted.
- the dimensions of the heating resistor 2 can be set to, for example, 0.2 mm to 5 mm in width, 5 mm to 1000 mm in total length, and 0.05 mm to 0.5 mm in thickness.
- the electrode pad 3 is a member for connecting the lead terminal 4 and the heating resistor 2.
- the electrode pad 3 is provided from a side surface to an end surface of the ceramic body 1.
- the electrode pad 3 is electrically connected to the heating resistor 2.
- the electrode pad 3 includes a metal material.
- the metal material includes, for example, tungsten, molybdenum, or rhenium. Further, a layer of a metal such as nickel, chromium, or gold may be formed on the surface thereof.
- the dimensions of a portion of the electrode pad 3 provided at the side surface of the ceramic body 1 may be 0.5 mm to 15 mm in length, 0.5 mm to 5 mm in width, and 0.2 mm to 1.5 mm in thickness.
- the dimensions of a portion of the electrode pad 3 provided at the end surface of the ceramic body 1 may be 0.1 mm to 20 mm in length, 0.1 mm to 20 mm in width, and 0.2 mm to 1.5 mm in thickness. As illustrated in FIG. 1 , the electrode pad 3 and the lead terminal 4 may be provided at each of both ends of the heating resistor 2.
- the electrode pad 3 and the heating resistor 2 may be electrically connected to each other via a through-hole conductor, for example, as illustrated in FIG. 2B .
- the lead terminal 4 provided at the outer peripheral portion of the ceramic body 1 and the heating resistor 2 provided inside the ceramic body 1 can be electrically connected to each other.
- the lead terminal 4 is a member for supplying power to the heating resistor 2.
- the lead terminal 4 is electrically connected to an external power supply.
- the lead terminal 4 is electrically bonded to the electrode pad 3 and extends in the longitudinal direction of the ceramic body 1.
- the lead terminal 4 is, for example, a linear, rod-shaped, cylindrical, belt-shaped, or string-shaped member.
- the lead terminal 4 may have, for example, a circular, an elliptical, a polygonal such as a triangular or rectangular cross-sectional shape or may be hollow with these shapes. In the lead terminal 4 illustrated in FIG. 1 , the lead terminal 4 has a cylindrical shape.
- the dimensions of the lead terminal 4, for example, in the case of a cylindrical shape, may be 0.5 mm to 5 mm in diameter and 10 mm to 300 mm in length.
- a wire or a plate made of metal such as nickel or copper can be used as the lead terminal 4, a wire or a plate made of metal such as nickel or copper can be used as the lead terminal 4.
- the bonding material 5 is a member for firmly fixing the lead terminal 4 and the electrode pad 3.
- the bonding material 5 is located on the electrode pad 3.
- the bonding material 5 may be, for example, a metal material having electrical conductivity such as silver, copper, or tin.
- the heater 100 includes the ceramic body 1 having a cylindrical or a tubular shape and extending from the first end 101 toward the second end 102, the heating resistor 2 located inside the ceramic body 1, the electrode pad 3 electrically connected to the heating resistor 2, the lead terminal 4 electrically connected to the electrode pad 3, and the bonding material 5 having electrical conductivity and bonding the electrode pad 3 and the lead terminal 4, wherein the electrode pad 3 is located from a side surface to an end surface of the ceramic body 1.
- the electrode pad 3 can be provided at a plurality of surfaces of the ceramic body 1.
- the ceramic body 1 may include a first part 11 including the outer periphery of the ceramic body 1 and a second part 12 continuous with the first part 11 and located near the center axis.
- the first part 11 may include a first side surface 111 including the outer periphery and a first end surface 112 continuous with the first side surface 111.
- the second part 12 may include a second side surface 121 continuous with the first end surface 112 and extending toward the second end 102 and a second end surface 122 continuous with the second side surface 121.
- the "side surface” illustrated in FIG. 1 includes the first side surface 111 and the second side surface 121, and the "end surface” includes the first end surface 112 and the second end surface 122.
- the second part 12 since the second part 12 includes the second side surface 121 continuous from the first end surface 112 and extending toward the second end 102 and the second end surface 122 continuous with the second side surface 121, a step can be provided between the second part 12 and the first part 11.
- a space for storing the bonding material 5 can be provided between the lead terminal 4, the first end surface 112, and the second side surface 121. This makes it possible to add a larger amount of the bonding material 5.
- the bonding strength between the lead terminal 4 and the ceramic body 1 can be increased. As a result, the long-term reliability of the heater 100 can be improved.
- the electrode pad 3 may be located from the first side surface 111 to the first end surface 112.
- the second side surface 121 and the second end surface 122 may include a portion not provided with the electrode pad 3.
- the second side surface 121 and the second end surface 122 may include a portion not provided with the bonding material 5.
- the electrode pad 3 may be located from the first end surface 112 to the second side surface 121.
- the second end surface 122 may include a portion not provided with the electrode pad 3.
- the second end surface 122 may include a portion not provided with the bonding material 5.
- the electrode pad 3 may be located from the second side surface 121 to the second end surface 122.
- the first end surface 112 and the second side surface 121 may be provided with the electrode pad 3 and the bonding material 5.
- the electrode pad 3 With the electrode pad 3 located from the second side surface 121 to the second end 102 surface 122, the electrode pad 3 can be provided at a larger number of surfaces of the ceramic body 1. With this configuration, even when vibration occurs in a direction in which the ceramic body 1 and the electrode pad 3 are separated from each other, the bonding strength of the electrode pad 3 can be maintained. Thus, a risk of peeling of the electrode pad 3 from the ceramic body 1 can be reduced even when used for a long period of time. As a result, the long-term reliability of the heater 100 can be improved.
- the heating resistor 2 may be located between the first part 11 and the second part 12 and include an end portion protruding from the first end 101 surface 112, and the end portion and the electrode pad 3 may be bonded to each other.
- the number of paths through which electrical current flows from the lead terminal 4 to the heating resistor 2 can be increased.
- a risk of failure of electrical connection between the lead terminal 4 and the heating resistor 2 can be reduced.
- the long-term reliability of the heater 100 can be improved.
- the bonding material 5 may be provided in a meniscus form from the first end surface 112 to the second side surface 121.
- the bonding material 5 can cover the interface between the first end surface 112 and the second side surface 121, so that a risk of generation of cracks at the interface between the first end surface 112 and the second side surface 121 of the ceramic body 1 can be reduced.
- the long-term reliability of the heater 100 can be improved.
- the bonding material 5 may be provided in a meniscus form from the first end surface 112 to the lead terminal 4 and a space may be provided between the second side surface 121 and the lead terminal 4. Accordingly, while the lead terminal 4 and the ceramic body 1 are firmly fixed to each other by the bonding material, a region in which the bonding material 5 can thermally expand can be formed by the space provided between the second side surface 121 and the lead terminal 4. Accordingly, a risk of generation of thermal stress between the lead terminal 4 and the bonding material 5 due to thermal expansion of the bonding material 5 can be reduced. Thus, a risk of generation of cracks between the lead terminal 4 and the bonding material 5 can be reduced. As a result, the long-term reliability of the heater 100 can be improved.
- the bonding material 5 may be located filling the space between the second side surface 121 and the lead terminal 4.
- the lead terminal 4 and the ceramic body 1 can be firmly fixed by the bonding material 5.
- a risk of peeling between the lead terminal 4 and the ceramic body 1 can be reduced.
- the long-term reliability of the heater 100 can be improved.
- This space between the second side surface 121 and the lead terminal 4 refers to a portion surrounded by a virtual extension line of the first side surface 111 and a virtual extension line of the second end 102 surface 122.
- the lead terminal 4 may be curved.
- the expression "curved" as used herein means that, as illustrated in FIG. 9 , a portion connecting a portion electrically bonded to the electrode pad 3 and a portion extending toward the first end 101 is curved. With this configuration, vibration generated can be dispersed. Thus, the bonding strength between the lead terminal 4 and the bonding material 5 can be maintained. Thus, a risk of peeling between the lead terminal 4 and the bonding material 5 can be reduced. As a result, the long-term reliability of the heater 100 can be improved. The closer the angle between the portion electrically bonded to the electrode pad 3 and the portion extending toward the first end 101 is to 90 degrees, the larger the effect of the curve at the connecting portion.
- the bonding material 5 may be provided along the first side surface and extending to the second side surface, and a gap may be provided between the bonding material 5 and the first end 101 surface 121. Accordingly, the bonding material 5 can thermally expand to a portion where the first part 11 is exposed. Accordingly, a risk of generation of thermal stress between the lead terminal 4 and the bonding material 5 due to thermal expansion of the bonding material 5 can be reduced. Thus, a risk of generation of cracks between the lead terminal 4 and the bonding material 5 can be reduced. As a result, the long-term reliability of the heater 100 can be improved.
- the electrode pad 3 may be narrower at the first end 101 side than at the second end 102 side of the ceramic body 1.
- the term "narrow” used herein means that the length of the electrode pad 3 at the first end 101 side of the ceramic body 1 is shorter than that at the second end 102 side in the circumferential direction of the ceramic body 1.
- the electrode pad 3 may have a stepped shape in which the electrode pad 3 is narrower at the first end 101 side than at the second end 102 side of the ceramic body 1. Still, when the electrode pad 3 is tapered toward the first end 101 side of the ceramic body 1, the stress can be further reduced as compared with the stepped shape.
- the electrode pad 3 may be tapered toward the center of the second part 12 when viewed from the first end 101 side of the ceramic body 1.
- the two electrode pads 3 provided at the end surface of the ceramic body 1 can be separated from each other.
- a risk of occurrence of short circuiting at the end surface of the ceramic body 1 can be reduced.
- the long-term reliability of the heater 100 can be improved.
- the two electrode pads 3 may have different outer peripheral lengths as viewed from the first end 101 side of the ceramic body 1.
- the anode and the cathode can be distinguished from each other when bonding the heater 100 to another component.
- the heater 100 can be accurately connected with other members.
- the two electrode pads 3 may have different inner peripheral lengths as viewed from the first end 101 side of the ceramic body 1.
- the anode and the cathode can be distinguished from each other when bonding the heater 100 to another component.
- the heater 100 can be accurately connected with other members.
- making the outer periphery of the electrode pad 3 serving as the cathode longer than that of the anode or increasing the inner peripheral length can make the diameter or the number of lead terminals 4 attached to the electrode pad 3 serving as the cathode larger than that for the anode. This enables the heater 100 to be fixed, with the cathode lead terminal 4 grounded.
Landscapes
- Resistance Heating (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2021089387 | 2021-05-27 | ||
PCT/JP2022/018056 WO2022249794A1 (fr) | 2021-05-27 | 2022-04-18 | Dispositif de chauffage |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4351272A1 true EP4351272A1 (fr) | 2024-04-10 |
Family
ID=84229936
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP22811068.0A Pending EP4351272A1 (fr) | 2021-05-27 | 2022-04-18 | Dispositif de chauffage |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP4351272A1 (fr) |
JP (1) | JPWO2022249794A1 (fr) |
CN (1) | CN117356164A (fr) |
WO (1) | WO2022249794A1 (fr) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4048655B2 (ja) * | 1999-08-24 | 2008-02-20 | 株式会社デンソー | セラミックヒータ |
JP4514653B2 (ja) * | 2005-05-27 | 2010-07-28 | 京セラ株式会社 | セラミックヒーター及びこれを用いた加熱用こて |
JP2016081608A (ja) | 2014-10-10 | 2016-05-16 | イビデン株式会社 | セラミックヒーターの製造方法 |
JP6643093B2 (ja) * | 2016-01-15 | 2020-02-12 | 京セラ株式会社 | ヒータ |
JP6829022B2 (ja) * | 2016-07-27 | 2021-02-10 | 京セラ株式会社 | ヒータ |
-
2022
- 2022-04-18 WO PCT/JP2022/018056 patent/WO2022249794A1/fr active Application Filing
- 2022-04-18 EP EP22811068.0A patent/EP4351272A1/fr active Pending
- 2022-04-18 CN CN202280036791.6A patent/CN117356164A/zh active Pending
- 2022-04-18 JP JP2023523350A patent/JPWO2022249794A1/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPWO2022249794A1 (fr) | 2022-12-01 |
WO2022249794A1 (fr) | 2022-12-01 |
CN117356164A (zh) | 2024-01-05 |
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