Classifications

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  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
  • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
  • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
  • B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
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  • B32B15/00—Layered products comprising a layer of metal
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  • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
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  • B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
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  • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
  • B32B15/095—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyurethanes
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  • B32B7/04—Interconnection of layers
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• • C—CHEMISTRY; METALLURGY
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  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/226—Mixtures of di-epoxy compounds
• • C—CHEMISTRY; METALLURGY
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  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/32—Epoxy compounds containing three or more epoxy groups
  • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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• • C—CHEMISTRY; METALLURGY
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• • C—CHEMISTRY; METALLURGY
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• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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• • B—PERFORMING OPERATIONS; TRANSPORTING
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Definitions

• the present invention relates to the technical field of metal surface treatment. Specifically, a two-component curing composition for metal surface treatment, a method for mounting a film on a metal surface, and a surface structure are provided in the present invention, and are especially suitable for surface treatment of a vehicle body and mounting of a film on the surface of the vehicle body.
• graphic films are often mounted on the metal surface for purposes such as marking, warning, and advertising.
• the metal surface for mounting the graphic film must be flat without obvious defects, such as holes, bumps, and recesses.
• the graphic film can be mounted only after confirming that the metal surface is flat. The above existing method is time-consuming and complicated in the process.
• an objective of the present invention is to provide a two-component curing composition for metal surface treatment, a method for mounting a film on the surface of a vehicle body, and a surface structure.
• the two-component curing composition has good open time and surface drying time when applied, and has a very high bonding strength to the metal surface to be treated and aging resistance.
• convenient, simple, and quick mounting of a film on the metal surface can be realized.
• the inventors have conducted intensive and detailed research to achieve the present invention.
• a two-component curing composition for metal surface treatment comprising, based on 100 wt% of the two-component curing composition:
• liquid epoxy resin having a viscosity ranging from 200-35000 centipoises at 25°C;
• the two-component curing composition comprises a part A and a part B, the part A comprising the liquid epoxy resin, the part B comprising the curing agent for epoxy resin, and the diluent, the weight reducing agent and the flame retardant are present in one or both of the part A and the part B.
• a method for mounting a film on a metal surface comprising: mixing the part A with the part B of the two-component curing composition for metal surface treatment described above and applying the resulting mixture to the metal surface to form a coating; drying the coating; and attaching the film to the dried coating.
• a surface structure comprising: a metal surface; a coating formed by applying the two-component curing composition for metal surface treatment described above on the metal surface; and a film attached on the coating.
• the two-component curing composition for metal surface treatment has good open time and surface drying time when applied, and has a very high bonding strength to the metal surface to be treated and aging resistance.
• multiple treatments such as sandblasting, priming, polishing, puttying, drying, and sanding in sequence are performed on a cleaned metal surface, and then a graphic film is applied thereto in the prior art, by means of the use of the two-component curing composition, convenient, simple, and quick mounting of a film on the metal surface can be realized.
• FIG. 1 shows a schematic cross-sectional view of a surface structure obtained by mounting a graphic film on a metal surface according to the method of the present invention.
• the inventors of the present invention have conducted intensive research. Specifically, the inventors have found that when the compositions of the surface treatment composition and contents thereof are specifically selected, it is possible to provide a surface treatment composition capable of firmly mounting a graphic film on a metal surface without complicated operations such as priming and puttying on the substrate surface in advance.
• a two-component curing composition for metal surface treatment comprising, based on 100 wt% of the two-component curing composition:
• liquid epoxy resin having a viscosity ranging from 200-35000 centipoises at 25°C;
• the two-component curing composition comprises a part A and a part B, the part A comprising the liquid epoxy resin, the part B comprising the curing agent for epoxy resin, and the diluent, the weight reducing agent and the flame retardant are present in one or both of the part A and the part B.
• a two-component curing composition comprising a liquid epoxy resin and a curing agent for epoxy resin is used as a surface treatment agent for a metal surface so as to subsequently mount a graphic film on the surface conveniently and firmly.
• the two-component curing composition forms a cured coating on the metal surface by means of a curing reaction between the liquid epoxy resin comprised in the part A and the curing agent for epoxy resin comprised in the part B, and the cured coating has good adhesion to the metal surface and firmly adheres to the graphic film mounted subsequently.
• the two-component curing composition in order to improve the reactivity between the epoxy resin and the epoxy resin accelerator and the operability of the resulting two-component curing composition, comprises 15-35 wt%, and preferably 25-30 wt% of the liquid epoxy resin, based on 100 wt% of the two-component curing composition.
• the viscosity of the liquid epoxy resin at 25°C is in the range of 200-35000 centipoises, and preferably 5000-15000 centipoises.
• epoxy resin has the general meaning generally recognized about epoxy resins in the art, and epoxy resin refers to an organic epoxy compound containing two or more epoxy groups in the molecule. Any organic compound having an oxirane ring polymerizable by ring-opening reaction can be used as the epoxy resin employed in the technical solution according to the present invention, as long as the epoxy resin is in a liquid state at room temperature and has a viscosity ranging from 200-35000 centipoises at 25°C.
• the liquid epoxy resin is an aliphatic epoxy resin, an alicyclic epoxy resin, an aromatic epoxy resin, a heterocyclic epoxy resin or a combination thereof.
• an organic epoxy compound comprising 2-4 epoxy groups in the molecule is preferably used.
• the epoxy equivalent of the liquid epoxy resin is in the range of 100-500, and preferably 150-300.
• the liquid epoxy resin is one or more selected from the group consisting of: alkylene oxide, alkenyl oxide, glycidyl ester, glycidyl ether, epoxy novolac, glycidyl acrylate, and polyurethane polyepoxide and the like.
• More preferred epoxy resins include epoxy resins containing glycidyl ether or polyglycidyl ethers of monohydric, dihydric or polyhydric phenol, or epoxy resins composed of glycidyl ether or polyglycidyl ethers of monohydric, dihydric or polyhydric phenol.
• the monohydric, dihydric or polyhydric phenol is, for example, but not limited to bisphenol A, bisphenol F, and polymers including repeating units comprising these phenols.
• the liquid epoxy resin is bisphenol A diglycidyl ether or bisphenol F diglycidyl ether.
• Examples of commercially available epoxy resins useful in the present invention include: bisphenol A diglycidyl ether, e.g., EPON828 (liquid; epoxy equivalent: 185-192; viscosity at 25°C: 11000-15000 centipoises), EPON830 (liquid; epoxy equivalent: 190-198; viscosity at 25°C: 17000-22500 centipoises), and EPONlOOlF (liquid; epoxy equivalent: 525-550; viscosity at 25°C: 7000-9600 centipoises) available from Hexion Speciality Chemicals GmbH, Rosbach, Germany, and D.E.R-331 (liquid; epoxy equivalent 182-192; viscosity at 25°C: 11000-14000 centipoises) and D.E.R-332 (liquid; epoxy equivalent: 171-175; viscosity at 25°C: 4000-6000 centipoises) available from Dow Chemical Co.; bisphenol F diglycidyl ether, e.g
• the two-component curing composition according to the present invention further comprises one or more epoxy curing agents, i.e., compounds that react with the alkylene oxide ring of the epoxy resin (i.e., epoxide) to crosslink.
• the liquid epoxy resin and the curing agent for epoxy resin must be placed separately.
• the two-component curing composition comprises a part A and a part B, the part A comprises the liquid epoxy resin, and the part B comprises the curing agent for epoxy resin.
• the specific type of the curing agent for epoxy resin that is present in part B for curing the liquid epoxy resin during mixing of part A with part B can be appropriately selected from the curing agents generally used for curing epoxy resin in the prior art.
• a single type of the curing agent for epoxy resin can be used.
• a mixed system of curing agent for epoxy resins i.e., a combination of multiple curing agents, or a combination of one or more curing agents and a curing catalyst, can be used, instead of a single curing agent.
• the ratio of the curing agent for epoxy resin to the epoxy resin is selected such that they have approximately the same equivalent, i.e., the molar ratio of the reactive amino groups (or reactive anhydride groups) in the curing agent for epoxy resin to the reactive epoxy groups in the epoxy resin is about 1:1 or 0.9:1 to about 1:0.9.
• the two-component curing composition Based on 100 wt% of the two-component curing composition, the two-component curing composition comprises 20-35 wt%, and preferably 20-25 wt% of the curing agent for epoxy resin.
• the curing agent for epoxy resin is selected from an amine curing agent, an anhydride curing agent or a combination thereof.
• the amine curing agent comprises at least one primary amino (-ME) group
• a preferred amine curing agent comprises at least one modified polyamine, such as aliphatic linear polyamine or polyamide polyamine.
• modified polyamine such as aliphatic linear polyamine or polyamide polyamine.
• amine curing agents useful in the present invention include, but are not limited to, ethylenediamine, diethylenediamine, diethylenetriamine, triethylenetetramine, propylenediamine, tetraethylenepentamine, hexaethyleneheptamine, hexamethylenediamine, 2-methyl-l,5-pentylenediamine, etc.
• amine curing agents having a group selected from heteroalkylene groups, such as heteroalkylene groups with an oxygen as a heteroatom, may also be used in the present invention.
• the amine curing agent may be: aminoethylpiperazine; 4,7, 10-trioxatridecane-l, 13-diamine (TTD) available from TCI America (Portland, OR), USA; or poly(alkyleneoxy)diamine (also known as polyether diamine) such as poly(ethyleneoxy)diamine, poly(propyleneoxy)diamine or a copolymer thereof.
• polyether diamines are commercially available from Huntsman Corporation (The Woodlands, TX, USA) under the trade name JEFF AMINE.
• the anhydride curing agent useful in the present invention includes but is not limited to phthalic anhydride, among which tetrahydroxy phthalic anhydride, hexahydroxy phthalic anhydride or norbomene phthalic anhydride is preferred. Particularly preferred are methyl norbomene phthalic anhydride and methyl-tetrahydrophthalic anhydride. Particularly preferably, the amine curing agent for epoxy resin Ancamide 910 produced by Evonik Industries AG can be used.
• the two-component curing composition for metal surface treatment further comprises at least one diluent.
• the diluent is used to adjust the fluidity of the two-component curing composition during the mixed use, to facilitate the application operation on the metal surface.
• the two-component curing composition Based on 100 wt% of the two-component curing composition, the two-component curing composition comprises 5-15 wt%, and preferably 7-10 wt% of the diluent.
• the diluent is a non-reactive or reactive diluent.
• the non-reactive diluent is selected from benzyl alcohol, butylene orthophthalate, dioctyl phthalate, diallyl phthalate, or the like, or a combination thereof.
• the reactive diluent is selected from resorcinol diglycidyl ether, cyclohexane dimethanol diglycidyl ether, neopentyl glycol diglycidyl ether, 1,6-hexanediol diglycidyl ether, trimethylolpropane triglycidyl ether or a combination thereof.
• Suitable commercially available reactive epoxy diluents are compounds of the Heloxy series of Hexion, such as Heloxy 107 (i.e., l,4-bis[(glycidyloxy)methyl]cyclohexane).
• the two-component curing composition for metal surface treatment according to the present invention further comprises at least one weight reducing agent.
• the weight reducing agent is used to adjust the weight of the two-component curing composition, for the purpose of reducing the mass of the cured coating applied to the metal surface without substantially affecting the mechanical properties (e.g., bonding strength) of the cured composition.
• the density of the weight reducing agent is less than 0.5 g/cm 3 .
• the weight reducing agent is a low-density inorganic filler having a density between 0.1- 0.5 g/cm 3 .
• the weight reducing agent is hollow glass microspheres, hollow ceramic microspheres, hollow zirconia microspheres, or the like.
• the average particle size of the hollow glass microspheres, hollow ceramic microspheres or hollow zirconia microspheres ranges from 1-300 pm, and preferably 10-100 pm.
• Particularly preferred hollow inorganic microspheres are glass microspheres, for example, available from 3M China Limited under the trade names Scotchlite K37 (density: 0.37 g/cm 3 ; average particle size: 45 pm) and Scotchlite S38 (density: 0.38 g/cm 3 ; average particle size: 40 pm).
• the two-component curing composition for metal surface treatment according to the present invention further comprises at least one flame retardant to impart the flame retardant performance.
• the flame retardant is preferably a flame retardant substantially free of halogen.
• the two- component curing composition comprises 5-20 wt%, and preferably 10-15 wt% of the flame retardant.
• the flame retardant is a phosphorus flame retardant or expanded graphite.
• the phosphorus flame retardant is selected from, for example, elemental red phosphorus, melamine phosphate, dimelamine phosphate, melamine pyrophosphate and inorganic phosphite such as aluminum phosphite, and preferably elemental red phosphorus and inorganic phosphite.
• the flame retardant system may also include optional boron-containing materials, such as barium metaborate, calcium metaborate, zinc metaborate, and a mixture thereof.
• the expanded graphite has a graphite intercalation structure, i.e., expandable graphite.
• expanded graphite useful in the present invention examples include ES 100 CIO, ES 250 B5, and ES 350 F5 available from Germany Kropfmuehl Graphite Co., Ltd./AMG Mining Group, and expanded graphite ADT 1002 provided by Shijiazhuang Kepeng Flame Retardant Material Co.
• commercially available examples of phosphorus flame retardants useful in the present invention include: EXOLIT AP 750 and EXOLIT RP 6500 produced by Clariant Chemical Co., Ltd.
• the two-component curing composition for metal surface treatment preferably comprises at least one epoxy resin curing accelerator.
• the epoxy resin curing accelerator is present in the part B.
• the two- component curing composition Based on 100 wt% of the two-component curing composition, the two- component curing composition comprises 2-10 wt%, and preferably 3-7 wt% of an epoxy resin curing accelerator.
• the epoxy resin curing accelerator is a tertiary amine accelerator.
• the tertiary amine accelerator is selected from triethylamine, triethanolamine, benzyldimethylamine, dimethylaminomethylphenol, tri(dimethylaminomethyl)phenol or a combination thereof.
• a specific example of a commercially available epoxy resin curing accelerator useful in the present invention is Ancamine K54 produced by Evonik Industries AG.
• the two-component curing composition comprises at least one antioxidant.
• the antioxidant may optionally exist in one or both of the part A and the part B.
• the antioxidant is a hindered phenolic antioxidant. Based on 100 wt% of the two-component curing composition, the antioxidant is present in an amount of 0.5-5 wt%, and preferably 1-2 wt% in the two- component curing composition.
• Commercially available products of the antioxidant useful in the two-component curing composition of the present invention include: Irganox 1135, Irganox 1726, and Irganox 1520L produced by BASF Co.
• the two-component curing composition further comprises at least one wetting agent to improve the wettability when the composition is applied to the substrate.
• the wetting agent may optionally exist in one or both of the part A and the part B.
• the wetting agent is present in an amount of 0.5-5 wt%, and preferably 0.5-1 wt% in the two-component curing composition.
• Specific examples of the wetting agent that can be used are selected from a titanate salt, silane, a zirconate salt, a zirconium aluminate salt, a phosphate ester, or a combination thereof.
• Commercially available examples of the wetting agent useful in the present invention include W995 produced by BYK Co.
• the method of preparing the two-component curing composition for metal surface treatment is not particularly limited, and the composition may be prepared by simple mixing.
• the two-component curing composition obtained by mixing comprises separate part A and part B, wherein the part A comprises a liquid epoxy resin, the part B comprises a curing agent for epoxy resin, and a diluent, a weight reducing agent, and a flame retardant are present in one or both of the part A and the part B.
• the epoxy resin curing accelerator In the presence of an epoxy resin curing accelerator, the epoxy resin curing accelerator must coexist with the curing agent for epoxy resin in the part B.
• an antioxidant and/or a wetting agent the antioxidant and/or the wetting agent may be present in one or both of the part A and the part B.
• a method for mounting a film on a metal surface comprising: mixing the part A with the part B of the two-component curing composition for metal surface treatment described above and applying the resulting mixture to the metal surface to form a coating; drying the coating; and attaching the film to the dried coating.
• the method for applying the composition onto the metal surface is not limited particularly, and methods such as roller coating, brush coating, and spraying commonly used in the art may be employed.
• the thickness of the applied coating is in the range of 0.2-1.0 mm, and preferably 0.3-0.5 mm.
• the method further comprises, before applying the two-component curing composition to the metal surface: cleaning the metal surface. This step includes: wiping the metal surface with a clean cloth. If there is grease or wax on the surface, it is better to wipe with a solvent such as ethanol, isopropanol or ethyl acetate, to obtain a clean and dry surface after the solvent evaporates.
• the method further includes, after drying the coating and before attaching the film: sanding the surface of the dried coating.
• the sanding step can planarize the surface of the dried coating so that the graphic film can be attached uniformly and firmly thereon. Then, the sanded surface is cleaned with a solvent such as ethanol or isopropanol, and after the solvent completely evaporates, the film is attached on the surface.
• the film includes a film layer and an adhesive layer adhered to each other.
• the film layer has a pattern for purposes of marking, warning and advertising, and the adhesive layer is used to adhere the film layer to the treated metal surface.
• the specific material constituting the film layer is not particularly limited, and can be selected from conventional materials commonly used in the art to form a graphic film.
• the film layer comprises one or more of polyvinyl chloride, polyurethane and polyethylene terephthalate.
• the film layer optionally has a pattern for purposes of marking, warning and advertising, on the side away from the adhesive layer.
• the thickness of the film layer is in the range of 50-500 pm.
• the specific material constituting the adhesive layer is not limited particularly.
• the adhesive layer is a pressure-sensitive adhesive layer.
• the pressure-sensitive adhesive layer preferably comprises an acrylic pressure-sensitive adhesive, a rubber-based pressure- sensitive adhesive, or a silicone-based pressure-sensitive adhesive.
• the thickness of the adhesive layer is in the range of 30-200 pm.
• a surface structure including: a metal surface; a coating formed by applying the two-component curing composition for metal surface treatment described above on the metal surface; and the film attached to the coating.
• FIG. 1 shows a schematic cross-sectional view of the surface structure 1 obtained by mounting a graphic film 4 on a metal surface 2 according to the method of the present invention.
• the surface structure 1 includes in sequence: a metal surface 2; a coating 3 formed of the two-component curing composition for metal surface treatment described above applied on the metal surface 2; and a film 4 (i.e., a graphic film) attached on the coating 3.
• the metal surface for mounting the graphic film In the currently commonly used process operation for mounting a graphic film on a metal surface, the metal surface for mounting the graphic film must be flat without obvious defects, such as holes, bumps, and recesses. Therefore, in order to achieve firm mounting of the graphic film on the metal surface, it is usually needed to perform multiple surface treatment steps on the metal surface. For example, it is needed to clean the metal surface first to remove impurities and grease. Then, multiple treatments such as sandblasting, priming, polishing, puttying, drying, and sanding in sequence are performed on the cleaned metal surface. The graphic film can be mounted only after confirming that the metal surface is flat. The above mounting method is time-consuming and complicated in process.
• the film can be attached after only one coating operation on the clean metal surface, and the obtained graphic film has very high bonding strength to the metal surface. Therefore, the technical solution according to the present invention can realize convenient, simple and quick mounting of the film on the metal surface.
• Particular embodiment l is a two-component curing composition for metal surface treatment, comprising, based on 100 wt% of the two-component curing composition:
• liquid epoxy resin having a viscosity ranging from 200-35000 centipoises at 25°C;
• the two-component curing composition comprises a part A and a part B, the part A comprising the liquid epoxy resin, the part B comprising the curing agent for epoxy resin, and the diluent, the weight reducing agent and the flame retardant are present in one or both of the part A and the part B.
• Particular embodiment 2 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the liquid epoxy resin has a viscosity ranging from 5000-15000 centipoises at 25°C.
• Particular embodiment 3 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the liquid epoxy resin has an epoxy equivalent ranging from 100-500.
• Particular embodiment 4 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the liquid epoxy resin is one or more selected from the group consisting of: alkylene oxide, alkenyl oxide, glycidyl ester, glycidyl ether, epoxy novolac, glycidyl acrylate, and polyurethane polyepoxide, and preferably, the liquid epoxy resin is bisphenol A diglycidyl ether or bisphenol F diglycidyl ether.
• Particular embodiment 5 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the curing agent for epoxy resin is selected from an amine curing agent, an anhydride curing agent or a combination thereof.
• Particular embodiment 6 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the diluent is a non reactive or reactive diluent, and preferably, the non-reactive diluent is selected from benzyl alcohol, butylene orthophthalate, dioctyl phthalate, diallyl phthalate or a combination thereof, and the reactive diluent is selected from resorcinol diglycidyl ether, cyclohexane dimethanol diglycidyl ether, neopentyl glycol diglycidyl ether, 1,6- hexanediol diglycidyl ether, trimethylolpropane triglycidyl ether or a combination thereof.
• the diluent is a non reactive or reactive diluent
• the non-reactive diluent is selected from benzyl alcohol, butylene orthophthalate, dioctyl phthalate, dial
• Particular embodiment 7 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the weight reducing agent is a low-density inorganic filler having a density ranging from 0.1-0.5 g/cm 3 .
• Particular embodiment 8 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the weight reducing agent is hollow glass microspheres, hollow ceramic microspheres or hollow zirconia microspheres, and preferably, the average particle size of the hollow glass microspheres, hollow ceramic microspheres or hollow zirconia microspheres ranges from 1-300 pm.
• the weight reducing agent is hollow glass microspheres, hollow ceramic microspheres or hollow zirconia microspheres, and preferably, the average particle size of the hollow glass microspheres, hollow ceramic microspheres or hollow zirconia microspheres ranges from 1-300 pm.
• Particular embodiment 9 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the flame retardant is phosphorus flame retardant or expanded graphite.
• Particular embodiment 10 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the two-component curing composition further comprises an epoxy resin curing accelerator in the part B.
• Particular embodiment 11 is the two-component curing composition for metal surface treatment according to particular embodiment 10, wherein the two-component curing composition comprises 2-10 wt% of the epoxy resin curing accelerator, based on 100 wt% of the two-component curing composition.
• Particular embodiment 12 is the two-component curing composition for metal surface treatment according to particular embodiment 11, wherein the epoxy resin curing accelerator is a tertiary amine accelerator, and preferably, the tertiary amine accelerator is selected from triethylamine, triethanolamine, benzyldimethylamine, dimethylaminomethylphenol, tri(dimethylaminomethyl)phenol or a combination thereof.
• Particular embodiment 13 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the two-component curing composition further comprises 0.5-5 wt% of a hindered phenolic antioxidant.
• Particular embodiment 14 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the two-component curing composition further comprises 0.5-5 wt% of a wetting agent, and the wetting agent is selected from a titanate salt, silane, a zirconate salt, a zirconium aluminate salt, a phosphate ester or a combination thereof.
• a wetting agent is selected from a titanate salt, silane, a zirconate salt, a zirconium aluminate salt, a phosphate ester or a combination thereof.
• Particular embodiment 15 is the two-component curing composition for metal surface treatment according to particular embodiment 1, wherein the metal surface is a surface of a vehicle body.
• Particular embodiment 16 is a method for mounting a film on a metal surface, the method comprising: mixing the part A with the part B of the two-component curing composition for metal surface treatment according to any of particular embodiments 1-15 and applying the resulting mixture onto the metal surface to form a coating; drying the coating; and attaching the film to the dried coating.
• Particular embodiment 17 is the method for mounting a film on a metal surface according to particular embodiment 16, wherein the thickness of the coating is in the range of 0.2-1.0 mm.
• Particular embodiment 18 is the method for mounting a film on a metal surface according to particular embodiment 16, wherein the method further comprises, before applying the two-component curing composition to the metal surface: cleaning the metal surface.
• Particular embodiment 19 is the method for mounting a film on a metal surface according to particular embodiment 16, wherein the method further comprises, after drying the coating and before attaching the film: sanding the surface of the dried coating.
• Particular embodiment 20 is the two-component curing composition for metal surface treatment according to particular embodiment 16, wherein the film comprises a film layer and an adhesive layer adhered to each other.
• Particular embodiment 21 is the method for mounting a film on a surface of a vehicle body according to particular embodiment 20, wherein the film layer comprises one or more of polyvinyl chloride, polyurethane, and polyethylene terephthalate.
• Particular embodiment 22 is the method for mounting a film on a metal surface according to particular embodiment 20, wherein the thickness of the film layer is in the range of 50-500 pm.
• Particular embodiment 23 is the method for mounting a film on a metal surface according to particular embodiment 20, wherein the adhesive layer is a pressure-sensitive adhesive layer.
• Particular embodiment 24 is the method for mounting a film on a metal surface according to particular embodiment 20, wherein the thickness of the adhesive layer is in the range of 30-200 pm.
• Particular embodiment 25 is a surface structure, comprising: a metal surface; a coating formed by applying the two-component curing composition for metal surface treatment according to any of particular embodiments 1 to 15 on the metal surface; and a film attached on the coating.
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied. Then, the viscosity of the mixture (in MPa s) was measured by a viscosity tester (model HB DV2T) produced by Brookfiled Co., with a No. 64 rotor, set at a rotation speed of 2 revolutions per minute.
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 200 g of the mixture stood still for half hour, and sampling were performed every 5 minutes to observe whether the mixture could be uniformly coated on a stainless steel plate (dimension: 12 cm x 5 cm), until the viscosity was found to increase significantly so that the mixture could not be smoothly coated on the steel plate.
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 200 g of the mixture was poured onto a glass plate, in a length of about 100 mm, and then the poured mixture was wiped with a scraper into a thickness of 1-2 mm, to obtain a glass plate specimen applied with the mixture.
• the glass plate specimen was stood still at 23 ⁇ 2°C for 50 minutes, and then a smooth glass rod was used to gently touch three different positions of the mixture coating on the glass plate specimen. The above operation was repeated every 5 minutes, until the mixture could be pulled up when the glass rod was lifted from the mixture coating, but the mixture no longer stained the glass rod.
• the time from application of the mixture to the time when the mixture could be lifted by the glass rod without adhering to the glass plate was recorded as the surface drying time (unit: minute). Density
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 15 g of the mixture was cast into a mold having a cavity with a dimension of 1.25 cm x 1.25 cm x 10 cm.
• curing was performed in the mold in a forced air oven at 80°C for 2 hours to prepare a test specimen.
• the cured specimen was removed from the mold and the precise volume thereof was recorded (unit: cm 3 ).
• the weight (g) of each specimen was measured, and the density thereof was calculated and recorded in g/cm 3 .
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 5 g of the mixture was poured on a cleaned stainless steel plate (dimension: 12 cm x 5 cm), wiped with a scraper into a thin layer of about 1 mm, and placed at room temperature for 24 hours.
• the polishing is performed with an 80 grit sandpaper, the surface thereof is cleaned, and then a structural adhesive was used to bond a 1 inch wide anodized aluminum plate with the polished surface, in a bonding area of 1 square inch.
• the resulting sample was stretched by a tensile machine (model 5965) produced by Instron at a tensile speed of 5 mm/min until the structure of the sample was damaged.
• the bonding strength of the cured product of the mixture to the stainless steel plate was recorded in MPa. At least 3 samples were measured each time and an average value was taken.
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 5 g of the mixture was poured on a cleaned stainless steel plate (dimension: 12 cm x 5 cm), wiped with a scraper into a thin layer having a thickness of about 1-2 mm, and placed at room temperature for 24 hours.
• the obtained sample was subjected to aging treatment including the following test steps in sequence: at 80°C for 4 hours; at room temperature for 0.5 hours; at -40°C for 4 hours; at room temperature for 0.5 hours; at 70°C and 95% relative humidity for 4 hours, and the above aging treatment was repeated for 10 cycles.
• the aged sample was taken out and placed at room temperature for 24 hours, to observe whether there are bubbles, embrittlement and cracks appearing on the surface.
• the samples without bubbles, embrittlement or cracks were indicated as “PASS.”
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 5 g of the mixture was poured on a cleaned stainless steel plate (dimension: 12 cm x 5 cm), wiped with a scraper into a thin layer of about 1 mm, and placed at room temperature for 24 hours.
• the polishing is performed with an 80 grit sandpaper, and the surface thereof is cleaned.
• a 3M180MC adhesive film produced by 3M China Limited was cut to have a width of 25 mm, and adhered to the cleaned surface of the cured product after the release paper was removed, and a 2.5-kg rubber roller was rolled back and forth once thereon.
• a tensile machine (model 5965) produced by Instron was used to measure the peeling force of the adhesive film on the surface of the cured product at a tensile speed of 300 mm/min, and results were recorded in N/mm. At least 3 samples were measured each time and an average value was taken.
• parts A and B of the two-component curing composition prepared in the following embodiments and comparative examples were uniformly mixed to obtain mixtures to be applied.
• 5 g of the mixture was poured on a cleaned stainless steel plate (dimension: 12 cm x 5 cm), wiped with a scraper into a thin layer of about 1 mm, and placed at room temperature for 24 hours.
• the polishing is performed with an 80 grit sandpaper, and the surface thereof is cleaned.
• a 3M180MC adhesive film produced by 3M China Limited was cut to have a width of 40 mm, and adhered to the cleaned surface of the cured product after the release paper was removed, and a 2.5-kg rubber roller was rolled back and forth once thereon.
• the sample obtained through the above steps was placed in a cooling and heating cycle aging box for a weather resistance test.
• the aging box was set as follows: at 80°C, 95% RH for 4 hours; changing to -40°C at a rate of temperature change of l°C/min and keeping at the condition for 4 hours; and changing to 80°C and 95% RH at a rate of temperature change of l°C/min and keeping at the condition for 4 hours.
• the above 12 hours is included in a cycle, and ten cycles were repeated in total. After that, the sample was taken out and visually observed whether there are bubbles on the surface.
• a tensile machine (model 5965) produced by Instron was used to measure the bonding strength of the adhesive film on the surface of the cured product at a tensile speed of 300 mm/min, and the results were recorded in N/mm. At least 3 samples were measured each time and an average value was taken.
• a two-component curing composition 1 was prepared, and the two-component curing composition 1 included a part A and a part B that were independent of each other.
• the preparation of the part A included uniformly mixing 28 g of bisphenol A diglycidyl ether (D.E.R-331), 9 g of l,4-bis[(glycidyloxy)methyl]cyclohexane (Heloxy 107), 0.5 g of a phosphoric polyester copolymer (W995), 13 g of glass microspheres (Scotchlite S38), 10 g of expanded graphite (ADT 1002) and 5 g of a phosphorus flame retardant (EXOLIT RP 6500) according to the ratio in Table 2 shown below.
• the preparation of the part B included uniformly mixing 1.5 g of isooctyl 3,5-di-tert-butyl-4- hydroxyphenylpropionate (Irganox 1135), 30 g of a polyamide curing agent (Ancamide 910) and 3 g of 2,4,6-tris(dimethylaminomethyl)phenol (Ancamine K54) according to the ratio in Table 2 shown below.
• the two-component thermally conductive adhesive composition 1 obtained according to the above steps was tested.
• the test results obtained are shown in Table 3.
• Two-component curing compositions 2-4 and comparative two-component curing compositions 1-3 were prepared respectively in a manner similar to embodiment 1, in accordance with the ratio in Table 2 shown below.
• Comparative Example 4 a film was attached to a stainless steel plate by a conventional method in the art.
• a 3M PN1089 body filler produced by 3M China Limited was applied in a thickness of about 1 mm to a stainless steel plate (dimension: 12 cm x 5 cm), dried at 80°C for 2 hours, and placed at room temperature for 24 hours.
• the coating was polished with an 80 grit sandpaper, and the surface thereof is cleaned.
• a 3M180MC adhesive film produced by 3M China Limited was cut to have a width of 25 mm, and adhered to the cleaned surface of the cured product after the release paper was removed, and a 2.5-kg rubber roller was rolled back and forth once thereon.
• the sample obtained through the above steps was placed in a cooling and heating cycle aging box for a weather resistance test.
• the aging box was set as follows: at 80°C, 95% RH for 4 hours; changing to -40°C at a rate of temperature change of l°C/min and keeping at the condition for 4 hours; and changing to 80°C and 95% RH at a rate of temperature change of l°C/min and keeping at the condition for 4 hours.
• the above 12 hours is included in a cycle, and ten cycles were repeated in total. After that, the sample was taken out and visually observed whether there are bubbles on the surface.
• a tensile machine (model 5965) produced by Instron was used to measure the bonding strength of the adhesive film on the surface of the cured product at a tensile speed of 300 mm/min, and the results were recorded in N/mm. At least 3 samples were measured each time and an average value was taken.
• the compositions of the surface treatment composition and contents thereof are specifically selected within the scope of the present invention, it is possible to provide a surface treatment composition capable of firmly mounting a graphic film on a metal surface without complicated operations such as priming and puttying on the substrate surface in advance.
• the two-component curing composition has good open time and surface drying time when applied, and has very high bonding strength to the surface of the stainless steel plate to be treated and aging resistance.
• the two-component curing composition for metal surface treatment prepared according to the method of the present invention provides bonding strength of the film mounted to the substrate, aging performance of the film and the like comparable to or even better than the bonding strength and the aging performance of the film obtained according to the complicated process in the art.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
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• Engineering & Computer Science (AREA)
• Wood Science & Technology (AREA)
• Materials Engineering (AREA)
• Medicinal Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Health & Medical Sciences (AREA)
• Polymers & Plastics (AREA)
• Inorganic Chemistry (AREA)
• Paints Or Removers (AREA)
• Adhesive Tapes (AREA)
• Other Surface Treatments For Metallic Materials (AREA)
• Laminated Bodies (AREA)
• Adhesives Or Adhesive Processes (AREA)

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• 2020
  • 2020-06-10 CN CN202010526058.5A patent/CN113773726B/zh active Active
• 2021
  • 2021-06-09 JP JP2022575884A patent/JP2023531598A/ja active Pending
  • 2021-06-09 EP EP21821892.3A patent/EP4165138A1/en not_active Withdrawn
  • 2021-06-09 WO PCT/IB2021/055078 patent/WO2021250595A1/en unknown

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