EP4065482B1 - Wiederverschliessbares ausgiesselement für karton-kunststoff-verbundpackungen mit einem originalitätssiegel zur indikation der erstöffnung - Google Patents
Wiederverschliessbares ausgiesselement für karton-kunststoff-verbundpackungen mit einem originalitätssiegel zur indikation der erstöffnung Download PDFInfo
- Publication number
- EP4065482B1 EP4065482B1 EP20797394.2A EP20797394A EP4065482B1 EP 4065482 B1 EP4065482 B1 EP 4065482B1 EP 20797394 A EP20797394 A EP 20797394A EP 4065482 B1 EP4065482 B1 EP 4065482B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- screw cap
- pouring
- anchor ring
- element according
- predetermined breaking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
- B65D5/42—Details of containers or of foldable or erectable container blanks
- B65D5/72—Contents-dispensing means
- B65D5/74—Spouts
- B65D5/746—Spouts formed separately from the container
- B65D5/747—Spouts formed separately from the container with means for piercing or cutting the container wall or a membrane connected to said wall
- B65D5/748—Spouts formed separately from the container with means for piercing or cutting the container wall or a membrane connected to said wall a major part of the container wall or membrane being left inside the container after the opening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
- B65D5/42—Details of containers or of foldable or erectable container blanks
- B65D5/72—Contents-dispensing means
- B65D5/74—Spouts
- B65D5/746—Spouts formed separately from the container
- B65D5/747—Spouts formed separately from the container with means for piercing or cutting the container wall or a membrane connected to said wall
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
- B65D41/32—Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
- B65D41/34—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
- B65D41/3404—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with ratchet-and-pawl mechanism between the container and the closure skirt or the tamper element
- B65D41/3409—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with ratchet-and-pawl mechanism between the container and the closure skirt or the tamper element the tamper element being integrally connected to the closure by means of bridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D55/00—Accessories for container closures not otherwise provided for
- B65D55/02—Locking devices; Means for discouraging or indicating unauthorised opening or removal of closure
- B65D55/024—Closures in which a part has to be ruptured to gain access to the contents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D55/00—Accessories for container closures not otherwise provided for
- B65D55/16—Devices preventing loss of removable closure members
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2401/00—Tamper-indicating means
- B65D2401/15—Tearable part of the closure
Definitions
- the invention relates to a resealable pouring element for cardboard/plastic composite packs, in particular beverage packs, with a base element having a circumferential fastening flange and an external thread, with opening means arranged inside the base element at least in the unopened state of the pouring element and a screw cap with an internal thread, the opening means being so are designed that when the composite pack is first opened when the screw cap is unscrewed, a pouring opening is created within the pouring element by breaking open the composite material of the pack or a barrier layer located in the base element and at least one tamper-evident seal is arranged between the base element and the screw cap.
- a generic pouring element is from the applicant DE 10 2006 016 113 B3 known.
- the screw cap is moved over the cutting element protruding from the pouring element and, together with it, pressed (bounced) onto the base element.
- a plate is integrally molded onto the screw cap and is connected to the screw cap via connecting bridges.
- the plate has pins on its underside, which engage in corresponding recesses in the flange of the base element and are caulked from below after assembly.
- this well-known pouring element therefore requires, on the one hand, a relatively large amount of space to accommodate the plate on the fastening flange and, on the other hand, the caulking step in order to do so to be able to create a positive or material connection between the plate and the mounting flange.
- Pouring elements are also known which have a plate or flap inside the base element, which act as a barrier layer and, when the composite pack is first opened, driven by the screw lid, reveal a pouring opening into the inside of the pack by removing it or folding it away ( DE 600 24 772 T2 ).
- Pouring elements are also known ( WO 2008/002249 A1 ), in which display elements for signaling that an initial opening has already taken place are arranged directly in the lower area of the screw cap.
- This is also from the US 5,482,176 A known, in which a ring made in one piece with the screw cap is used as a tamper-evident seal, which shears off when the screw cap is first opened and remains as an indicator element on the base of the base element.
- the present invention is based on the task of designing and developing a resealable pouring element of the type mentioned in such a way that the assembly effort is reduced.
- the object is achieved in that an anchor ring which is connected to it in a rotationally fixed manner via a hinge is arranged underneath the screw cap and in that the tamper-evident seal consists of a display element, one end of which is firmly connected to the anchor ring and the other end of which using a predetermined breaking point with the anchor ring or Screw cap is connected in such a way that the predetermined breaking point is broken by at least one mandrel element arranged on the fastening flange when the screw cap is unscrewed and thus informs the consumer that the initial opening has already taken place.
- the invention has recognized that a firm connection between the tamper-evident seal and the fastening flange is not absolutely necessary, since the arrangement according to the invention of the elements required for the tamper-evident seal reliably fulfills the function of the tamper-evident seal, even without the display element being in shape with the fastening flange or the mandrel element arranged thereon. or is materially connected.
- a further teaching of the invention provides that the anchor ring is radially freely rotatable around the base element and is connected to the base element in a tension-resistant manner in the axial direction.
- Such an embodiment of the invention ensures that even after the screw cap has been opened for the first time, in the screwed-on state, it still remains connected via a suitable element, such as a hinge, to the anchor ring arranged in a tension-resistant manner on the base element. Loose plastic parts are therefore reliably avoided even when the package is opened.
- the pouring element according to the invention can be freely rotated when the screw lid is open and unfolded. However, a certain frictional resistance acting in the circumferential direction is desirable in order to be able to rotate the opened screw cap when pouring in a direction that does not hinder the pouring jet.
- the anchor ring has at least one cam on its upper side, which is arranged in the area of the display element, has an inclined surface and engages in a corresponding recess in the lower edge of the screw cap. Due to the surface of the cam, which runs obliquely in the circumferential direction, the anchor ring is pressed towards the fastening flange when it is opened for the first time, so that the Predetermined breaking points existing between the anchor ring and screw cover can be reliably broken up.
- a further teaching of the invention provides that the predetermined breaking point of the display element is arranged in the screwing-on direction of the screw cap before the fixed connection to the anchor ring. This is useful if the dimension and arrangement of the display element are coordinated with the mandrel element in such a way that the predetermined breaking point is reliably destroyed when screwing it on.
- the predetermined breaking point of the display element in the screwing-on direction of the screw cap behind the fixed connection with the anchor ring.
- a further alternative can also be designed in such a way that the display element is designed as a radially projecting loop and that the predetermined breaking point of the display element is arranged on the fixed connection to the anchor ring.
- the loop of the display element expediently encloses the mandrel element on the fastening flange before the initial opening of the pouring element.
- a membrane is provided as the predetermined breaking point of the display element.
- the membrane is completely or largely destroyed, so that the display element immediately shows the consumer the first opening of such a pouring element.
- the mandrel element is arranged radially outside the anchor ring on the fastening flange.
- an internal bead can also be formed all around the anchor ring.
- the cutting element cuts very steeply into the packaging material during the initial opening, it is particularly expedient if, in a further embodiment of the invention, the display element and the mandrel element are aligned with one another in the unopened position in such a way that the predetermined breaking point from the mandrel element when screwing on the screw cap breaks open at a rotation angle of 3° to 10°, preferably at a rotation angle of 5° to 7°.
- Another embodiment of the invention provides that the predetermined breaking point breaks open when the screw cap is screwed on at a torque of >0.2 Nm.
- the predetermined breaking point is broken when the screw cap is screwed on before the actual first opening of the composite pack or before the barrier layer breaks inside the base element. This means that even the smallest manipulations on the screw cap can be reliably displayed.
- a further teaching of the invention provides that the lower cut between the anchor ring and the screw cap is higher than the upper end of the display element. This cut marks the gap between the anchor ring and the screw cap below the hinge between both elements.
- a further preferred embodiment of the invention provides that the display element is arranged opposite the hinge with respect to the circumference of the screw cap. This design reliably ensures that the functions of the display element and the hinge do not interfere with each other.
- pouring element according to the invention with its special design of the tamper-evident seal can also be used as a transport security.
- FIG. 1 clearly shows the circumferential fastening flange 1 of the (hidden) base element and a screw cap 2, which is used for the first opening and for re-closing the pack (not shown) after it has been opened for the first time.
- screw cap 2 and anchor ring 3 are connected to one another in an articulated manner.
- a display element 4 serves as a seal of originality, one end of which is firmly connected to the anchor ring 3 and in which the other end is connected to the anchor ring 3 by means of a predetermined breaking point 5 in such a way that the predetermined breaking point 5 is protected by a mandrel element 6 arranged on the fastening flange 1 Unscrewing the screw cap 2 is broken. In the unopened assembly position according to Fig. 1 you can see a certain distance between the predetermined breaking point 5 and the mandrel element 6.
- Fig. 2 now shows the pouring element Fig. 1 after a slight rotation during the screwing process.
- the predetermined breaking point 5 (which can no longer be seen in the figure) already abuts the mandrel element 6. It is clear that further screwing on the screw cap 2 results in the mandrel element 6 shearing off the predetermined breaking point 5 and thus releasing the leading end of the display element 4 from the anchor ring 3.
- the screw cap 2 When the screw cap 2 is screwed on further, the screw cap 2, together with the anchor ring 3, slowly lifts up in accordance with the pitch of the external thread (not shown) on the base element 8 or the corresponding internal thread of the screw cap 2, as in Fig. 3 shown.
- the band-like display element 4 is only connected in one piece to the anchor ring 3 at its fixed connection.
- the type of articulated connection between the screw cap 2 and the anchor ring 3 which is designed as a hinge 9 in the illustrated and therefore preferred exemplary embodiment.
- the hinge 9 has a reinforcing element 9A or 9B on each side. This design ensures a firm connection between the screw cap 2 and the anchor ring 3, so that the screw cap 2 is reliably prevented from tearing off from the anchor ring 3.
- Fig. 3 It can also be seen that the display element 4 is arranged opposite the hinge 9 with respect to the circumference of the screw cap 2.
- the design according to the invention allows easier assembly of the resealable pouring element without the display element 4 serving as a tamper-evident seal having to be positively or materially connected to the fastening flange 1.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
- Cartons (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102019132538.2A DE102019132538B4 (de) | 2019-11-29 | 2019-11-29 | Wiederverschließbares Ausgießelement für Karton/Kunststoff-Verbundpackungen mit einem Originalitätssiegel zur Indikation der Erstöffnung |
| PCT/EP2020/078735 WO2021104736A1 (de) | 2019-11-29 | 2020-10-13 | WIEDERVERSCHLIEßBARES AUSGIEßELEMENT FÜR KARTON/KUNSTSTOFF-VERBUNDPACKUNGEN MIT EINEM ORIGINALITÄTSSIEGEL ZUR INDIKATION DER ERSTÖFFNUNG |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP4065482A1 EP4065482A1 (de) | 2022-10-05 |
| EP4065482C0 EP4065482C0 (de) | 2023-11-29 |
| EP4065482B1 true EP4065482B1 (de) | 2023-11-29 |
Family
ID=73020162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20797394.2A Active EP4065482B1 (de) | 2019-11-29 | 2020-10-13 | Wiederverschliessbares ausgiesselement für karton-kunststoff-verbundpackungen mit einem originalitätssiegel zur indikation der erstöffnung |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11840380B2 (pl) |
| EP (1) | EP4065482B1 (pl) |
| JP (1) | JP7775191B2 (pl) |
| CN (1) | CN114746342B (pl) |
| DE (1) | DE102019132538B4 (pl) |
| ES (1) | ES2971698T3 (pl) |
| MX (1) | MX2022003123A (pl) |
| PL (1) | PL4065482T3 (pl) |
| WO (1) | WO2021104736A1 (pl) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3947180A1 (en) * | 2019-04-05 | 2022-02-09 | Nypro Inc. | Tethered cap and spout |
| EP4025514A4 (en) | 2019-09-06 | 2023-10-11 | Silgan White Cap LLC | Tethered, hinged closure |
| CN114746343A (zh) * | 2019-11-29 | 2022-07-12 | Sig技术股份公司 | 纸板/塑料复合包装件的带有用于牢固地紧固螺旋盖的锚环的可重新密封的倾倒元件 |
| MX2022011385A (es) * | 2020-04-09 | 2022-10-10 | Tetra Laval Holdings & Finance | Ensamblaje de tapa para recipiente, recipiente que tiene un ensamblaje de tapa y metodo de acoplamiento de un ensamblaje de tapa a un pico. |
| DE102020121536A1 (de) * | 2020-08-17 | 2022-02-17 | Fritz Schäfer Gesellschaft Mit Beschränkter Haftung | Vorrichtung zum gezielten Auftrennen einer die Verbindung zwischen einem Deckel und einem Behälter absichernden Plombe |
| EP4429966A4 (en) | 2021-11-08 | 2026-01-14 | Silgan White Cap LLC | PROJECTION ON THE NECK OF A CONTAINER |
| AU2023219700A1 (en) | 2022-02-11 | 2024-07-18 | Silgan White Cap LLC | Tethered, hinged closure with modified primary slit |
| USD1025722S1 (en) * | 2023-08-16 | 2024-05-07 | Shenzhen Fanpuguizhen E-Commerce Co., Ltd. | Coffee tamper |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3168544B2 (ja) * | 1991-12-25 | 2001-05-21 | 日本クラウンコルク株式会社 | ピルフアープルーフ特性を有する合成樹脂製キャップ |
| US5482176A (en) | 1994-03-16 | 1996-01-09 | The West Company, Incorporated | Membrane piercing closure and spout assembly |
| JP3447409B2 (ja) * | 1995-01-18 | 2003-09-16 | 株式会社アルコア・クロージャー・システムズ | 閉止装置及び容器 |
| JP2907064B2 (ja) * | 1995-06-22 | 1999-06-21 | 東洋製罐株式会社 | ピルファープルーフ特性を備えたキャップ及び該キャップと容器との係合構造 |
| JPH11511102A (ja) * | 1995-08-30 | 1999-09-28 | ジー.ヴィ.エンジニアリング.ピー.ティ.ワイ.リミテッド | 不正操作が一見してわかるクロージャー |
| JPH09142502A (ja) * | 1995-11-15 | 1997-06-03 | Toppan Printing Co Ltd | チャイルドプルーフ注出口栓 |
| KR100528251B1 (ko) * | 1996-05-14 | 2006-05-09 | 가부시키가이샤 알코아. 클로져. 시스템즈 | 밀폐장치및용기 |
| JP4063394B2 (ja) * | 1998-03-26 | 2008-03-19 | 日本クラウンコルク株式会社 | 樹脂キャップ |
| JP4160163B2 (ja) * | 1998-06-11 | 2008-10-01 | 日本テトラパック株式会社 | キャップ付き容器 |
| FR2785264B1 (fr) * | 1998-10-29 | 2001-01-05 | Crown Cork & Seal Tech Corp | Dispositif de bouchage |
| JP2000191001A (ja) * | 1998-12-28 | 2000-07-11 | Nippon Paper Industries Co Ltd | 容器の口栓 |
| EP1127798B1 (en) | 2000-02-25 | 2005-12-14 | SIG Combibloc International AG | Pouring spout attachment with automatic opening feature |
| JP2003191980A (ja) * | 2001-12-28 | 2003-07-09 | Satoru Ichikawa | キャップとボトルとこれらによる密封構造 |
| JP2007514612A (ja) * | 2003-07-22 | 2007-06-07 | バラングア、ソシエダ リミタダ | 容器用ねじキャップ |
| JP2005053542A (ja) * | 2003-08-05 | 2005-03-03 | Toppan Printing Co Ltd | 不正開封防止機能付キャップ |
| JP2005059876A (ja) * | 2003-08-11 | 2005-03-10 | Toppan Printing Co Ltd | 不正開封防止機能付キャップ |
| JP3682973B1 (ja) * | 2004-04-24 | 2005-08-17 | 利寛 牧野 | ペットボトル |
| JP4646620B2 (ja) * | 2004-12-24 | 2011-03-09 | 株式会社吉野工業所 | ヒンジキャップ |
| DE102006016113B3 (de) | 2006-04-04 | 2007-08-23 | Sig Technology Ag | Wiederverschließbares Ausgießelement für Karton/Kunststoff-Verbundpackungen |
| SE530031C2 (sv) | 2006-06-30 | 2008-02-12 | Tetra Laval Holdings & Finance | Öppningsanordning, skruvkork för användning i en sådan öppningsanordning och förfarande för att bilda en sådan öppningsanordning |
| GB0620483D0 (en) * | 2006-10-17 | 2006-11-22 | Martin Peter J | The re:tie |
| DE102007057863A1 (de) | 2007-11-29 | 2009-06-04 | Sig Technology Ag | Selbstöffnendes und wiederverschließbares Ausgießelement aus Kunststoff zur Applikation auf einer Packung für Flüssigkeiten |
| JP5579421B2 (ja) * | 2009-11-30 | 2014-08-27 | 株式会社吉野工業所 | 不正開封防止機構付きヒンジキャップ |
| BRMU9100630U2 (pt) * | 2011-03-02 | 2013-05-28 | Da Costa Ivan Ferreira | tampa dotada de rosca de avanÇo variÁvel que efetua rompimento simultÂneo, entre selo de vedaÇço interno e lacre externo |
| CN106573707B (zh) * | 2014-08-07 | 2019-07-23 | 万通集团公司 | 用于容器的闭合件及用于容器的用具 |
| US11001409B2 (en) * | 2015-06-30 | 2021-05-11 | Sig Technology Ag | Pouring element for a package and composite package having such a pouring element |
| DE102015110526B4 (de) * | 2015-06-30 | 2018-08-23 | Sig Technology Ag | Ausgiesselement für eine Verpackung sowie Verbundverpackung mit einem solchen Ausgiesselement |
| JP6598655B2 (ja) * | 2015-09-30 | 2019-10-30 | 株式会社吉野工業所 | ヒンジキャップ |
| CN109661353B (zh) * | 2016-06-22 | 2020-12-29 | 科莱恩保健品包装简易股份有限公司 | 显窃启封闭件、具有这种封闭件的容器及其用途 |
| JP2018030651A (ja) * | 2017-11-29 | 2018-03-01 | 大日本印刷株式会社 | 注出口付飲料用紙容器 |
| JP2019137462A (ja) * | 2018-02-09 | 2019-08-22 | 凸版印刷株式会社 | 注出口栓 |
-
2019
- 2019-11-29 DE DE102019132538.2A patent/DE102019132538B4/de active Active
-
2020
- 2020-10-13 ES ES20797394T patent/ES2971698T3/es active Active
- 2020-10-13 US US17/772,922 patent/US11840380B2/en active Active
- 2020-10-13 JP JP2022529933A patent/JP7775191B2/ja active Active
- 2020-10-13 EP EP20797394.2A patent/EP4065482B1/de active Active
- 2020-10-13 WO PCT/EP2020/078735 patent/WO2021104736A1/de not_active Ceased
- 2020-10-13 CN CN202080083020.3A patent/CN114746342B/zh active Active
- 2020-10-13 PL PL20797394.2T patent/PL4065482T3/pl unknown
- 2020-10-13 MX MX2022003123A patent/MX2022003123A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20220371772A1 (en) | 2022-11-24 |
| JP2023503321A (ja) | 2023-01-27 |
| JP7775191B2 (ja) | 2025-11-25 |
| PL4065482T3 (pl) | 2024-03-18 |
| MX2022003123A (es) | 2022-04-06 |
| EP4065482C0 (de) | 2023-11-29 |
| WO2021104736A1 (de) | 2021-06-03 |
| EP4065482A1 (de) | 2022-10-05 |
| DE102019132538A1 (de) | 2021-06-02 |
| BR112022005102A2 (pt) | 2022-06-14 |
| DE102019132538B4 (de) | 2022-08-11 |
| US11840380B2 (en) | 2023-12-12 |
| ES2971698T3 (es) | 2024-06-06 |
| CN114746342A (zh) | 2022-07-12 |
| CN114746342B (zh) | 2026-01-27 |
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