EP3476382B1 - Mittel zur behandlung eines pulvers für ein kosmetikum, pulver für kosmetikum und kosmetikum mit diesem pulver - Google Patents

Mittel zur behandlung eines pulvers für ein kosmetikum, pulver für kosmetikum und kosmetikum mit diesem pulver Download PDF

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Publication number
EP3476382B1
EP3476382B1 EP17815408.4A EP17815408A EP3476382B1 EP 3476382 B1 EP3476382 B1 EP 3476382B1 EP 17815408 A EP17815408 A EP 17815408A EP 3476382 B1 EP3476382 B1 EP 3476382B1
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EP
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Prior art keywords
powder
cosmetic
acid
oil
treatment agent
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EP17815408.4A
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English (en)
French (fr)
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EP3476382A4 (de
EP3476382A1 (de
Inventor
Norihisa Kishimoto
Yasue Kanzaki
Sayuri Kikunaga
Seiji Hori
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Dow Toray Co Ltd
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Dow Toray Co Ltd
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/022—Powders; Compacted Powders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/02—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings containing insect repellants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/614—By macromolecular compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/61—Surface treated
    • A61K2800/62—Coated
    • A61K2800/623—Coating mediated by organosilicone compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions

Definitions

  • the present invention relates to a novel treatment agent for cosmetic powder, a cosmetic powder surface-treated with the treatment agent, and a cosmetic containing the powder.
  • a treatment agent for a cosmetic powder capable of imparting excellent lipophilicity.
  • a cosmetic powder, a cosmetic raw material, or a cosmetic using the same which has a cosmetic effect and has an excellent feeling of use by including the treatment agent or being treated by the treatment agent.
  • a treatment agent for a cosmetic powder of the present invention is characterized in that it contains a reactive organosiloxane represented by the following general formula (1) as a main ingredient: wherein each R 1 is independently an alkyl group having 1 to 30 carbon atoms; each R 2 is independently an alkyl group having 1 to 20 carbon atoms; R 3 is a divalent alkylene group having 3 to 18 carbon atoms; n is an integer of 1 to 200; and p is an integer of 1 to 3.
  • a reactive organosiloxane represented by the following general formula (1) as a main ingredient: wherein each R 1 is independently an alkyl group having 1 to 30 carbon atoms; each R 2 is independently an alkyl group having 1 to 20 carbon atoms; R 3 is a divalent alkylene group having 3 to 18 carbon atoms; n is an integer of 1 to 200; and p is an integer of 1 to 3.
  • One of the cosmetic powders of the present invention is characterized by comprising the cosmetic powder surface-treated with the above-mentioned treatment agent.
  • One of the cosmetic raw materials of the present invention is characterized by comprising a cosmetic powder. Further, one of the cosmetics of the present invention is characterized by comprising the above-mentioned cosmetic powder.
  • the treatment agent for the cosmetic powder of the present invention can impart lipophilicity, compatibility, and dispersibility to the powder relatively easily without leaving SiH bonds in the powder. Therefore, the cosmetic powder of the present invention has not only high lipophilicity, compatibility, and dispersibility, but also high storage stability and easy handling. In addition, the cosmetic powder of the present invention has good dispersibility in cosmetics, is excellent in stability over time, and can give smooth feeling of use to the skin. The cosmetics of the present invention has the above-mentioned effects.
  • One aspect of the present invention is a treatment agent for a cosmetic powder containing a reactive organosiloxane represented by the following general formula (1) as a main ingredient: wherein each R 1 is independently an alkyl group having 1 to 30 carbon atoms; each R 2 is independently an alkyl group having 1 to 20 carbon atoms; R 3 is a divalent alkylene group having 3 to 18 carbon atoms; n is an integer of 1 to 200; and p is an integer of 1 to 3.
  • a reactive organosiloxane represented by the following general formula (1) as a main ingredient: wherein each R 1 is independently an alkyl group having 1 to 30 carbon atoms; each R 2 is independently an alkyl group having 1 to 20 carbon atoms; R 3 is a divalent alkylene group having 3 to 18 carbon atoms; n is an integer of 1 to 200; and p is an integer of 1 to 3.
  • R 1 in the formula (1) examples include alkyl groups such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, a lauryl group, a cetyl group, a stearyl group, and a behenyl group; and cycloalkyl groups such as a cyclopentyl group and a cyclohexyl group.
  • R 1 is a methyl group or an octyl group, or a methyl group or an octyl group for the R 1 at the terminal and a methyl group for the R 1 other than at the terminal.
  • R 2 in Formula (1) is an alkyl group having 1 to 20 carbons.
  • R 2 is an alkyl group having 1 to 12 carbon atoms, an alkyl group having 1 to 8 carbon atoms, an alkyl group having 1 to 4 carbon atoms, or a methyl group, or an ethyl group.
  • R 3 in the formula (1) is a divalent alkylene group having 3 to 18 carbon atoms, an alkylene group having 4 to 15 carbon atoms, or an alkylene group having 6 to 13 carbon atoms, from the viewpoint of compatibility with oil agents used in cosmetics of the cosmetic powders.
  • R 3 may be linear, or may be partially branched or cyclic.
  • n is an integer of 1 to 200.
  • n is 5 or more, 10 or more, and n is 160 or less, 120 or less, 100 or less, or 80 or less, from the viewpoint of compatibility with silicone oil agents used in cosmetics of the cosmetic powders.
  • the number average molecular weight of the reactive organosiloxane represented by the formula (1) is suitably selected to be 300 to 100,000, or 1,000 to 10,000, although it differs depending on the powder to be treated.
  • the treatment agent of the cosmetic powder of the present invention contains a reactive organosiloxane represented by the general formula (1) as a main ingredient, and the content ratio thereof may be any amount capable of exhibiting an effect as a treatment agent.
  • the content of the organosiloxane in the treatment agent is 1 mass% or more, 5 mass% or more, 10 mass% or more, 15 mass% or more, 20 mass% or more, or 25 mass% or more.
  • the treatment agent may be used when a reactive organosiloxane represented by the general formula (1) is used alone or also in combination with one or more other components.
  • the powder treatment using the treatment agent of the cosmetic powder of the present invention can be performed by a known method such as a wet method or a dry method.
  • a known method such as a wet method or a dry method.
  • the following methods can be cited.
  • a method is such that after surface treating the powder, the powder is passed through a jet mill.
  • a method of surface treating the powder, and then passing the powder through the jet mill for example, the following two methods can be cited. (1) A method in which a surface treatment agent and powder are mixed and dispersed by a dry process or a wet process, and then heated and dried by passing through a jet mill; and (2) a method in which the surface treatment agent and the powder are mixed and dispersed by a dry process or a wet process, followed by being heated and dried, and then passed through a jet mill.
  • a pulverizer such as a pin mill or a hammer mill can be used instead of the jet mill.
  • Examples of the mixing and dispersing machine used for mixing and contacting the above powder include a Henschel mixer, a ribbon blender, a Q mill, a kneader, a planetary mixer, a pony mixer, a Banbury mixer, a ball mill, a dry sand mill, a wet sand mill, an attritor, a disper mixer, a homomixer, an extruder, and the like. Further, at the time of this surface treatment, the surface may be treated while giving energy such as mechanochemical mechanical force, ultrasonic wave, plasma, flame, ultraviolet, electron beam, superheated steam, or the like.
  • the amount of the treatment agent used for the untreated cosmetic powder is preferably 0.1 to 30 parts by mass of the treatment agent with respect to 100 parts by mass of the untreated cosmetic powder.
  • This amount ratio is preferably 1 to 20 parts by mass of the treatment agent with respect to 100 parts by mass of the cosmetic powder.
  • the powder which was surface-treated by the mixing and dispersing machine is dried, for example, at a temperature of 100°C to 170°C for 3 hours to 20 hours in order to complete the reaction between the treating agent and the surface of the powder particles.
  • ease of dispersibility is further improved by grinding the surface-treated powder using a jet mill pulverizer after mixing and bringing the powder into contact with each other.
  • the jet mill is roughly classified into a fluidized bed type, a spiral type, a jet-o-mizer type, and the like, and any type of jet mill can be used, but a fluidized bed type capable of uniformly and efficiently processing is most preferable.
  • the particle diameter of the cosmetic powder of the present invention is represented by a median diameter, and the value thereof is preferably 0.50 ⁇ m or less, preferably 0.40 ⁇ m or less, or 0.30 ⁇ m or less.
  • the particle diameter corresponding to 50% of the cumulative distribution is represented by D50
  • D84 represents the particle diameter at the point where the cumulative curve is 84%
  • D16 represents the particle diameter at the point where the cumulative curve is 16%.
  • any powder can be used as long as it is used in a usual cosmetic, regardless of its shape (spherical, acicular, plate-like, or the like), particle diameter (aerosol, fine particle, pigment class, or the like), particle structure (porous, non-porous, or the like).
  • Such cosmetic powders include inorganic powders, organic powders, surfactant metal salt powders, colored pigments, pearl pigments, metal powder pigments, extender pigments, natural pigments, and the like.
  • the inorganic powder examples include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, white mica, synthetic mica, magnesia mica, lepidolite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, Higilite, bentonite, montmorillonite, hectorite, zeolite, ceramics powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, silica and the like.
  • organic powder examples include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethylmethacrylate powder, cellulose, silk powder, nylon powder, nylon 12, nylon 6, crosslinked silicone fine powder in which dimethylsilicone is crosslinked, fine powder of polymethylsilsesquioxane, styrene-acrylic acid copolymer, divinylbenzene-styrene copolymer, vinyl resin, urea resin, phenol resin, fluorine resin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, starch powder, lauroyl lysine, and the like.
  • surfactant metal salt powder examples include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, sodium zinc cetyl phosphate, and the like.
  • the color pigment include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate; inorganic brown pigments such as ⁇ -iron oxide; inorganic yellow pigments such as yellow iron oxide and yellow ocher; inorganic black pigments such as black iron oxide and carbon black; inorganic violet pigments such as manganese violet and cobalt violet; inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate; inorganic blue pigments such as prussian blue and ultramarine blue; laked tar-based pigment, laked natural pigment, and synthetic resin powder obtained by combining these powder, and the like.
  • inorganic red pigments such as iron oxide, iron hydroxide and iron titanate
  • inorganic brown pigments such as ⁇ -iron oxide
  • inorganic yellow pigments such as yellow iron oxide and yellow ocher
  • inorganic black pigments such as black iron oxide and carbon black
  • inorganic violet pigments such as manganese violet and co
  • pearl pigments examples include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, titanium oxide-coated colored mica, and the like;
  • examples of the metal powder pigments include aluminum powder, copper powder, stainless powder, and the like;
  • examples of the tar pigments include Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5, Yellow No.
  • examples of the natural pigments include powders selected from carminic acid, laccaic acid, carthamin, brazillin, crocin and the like.
  • the cosmetic powder surface-treated with the treatment agent of the present invention is suitable as a cosmetic raw material.
  • the blending amount is preferably adjusted according to the type and dosage form of the cosmetic and the properties of the powder.
  • the cosmetic powder of 0.1 to 70 mass%, typically 1 to 50 mass%, more typically 1 to 40 mass% with respect to the total mass of the cosmetic is blended.
  • the treatment amount of the untreated cosmetic powder and the treatment agent is preferably 0.1 to 30 parts by mass of the treatment agent with respect to 100 parts by mass of the cosmetic powder.
  • the blending ratio is preferably 1 to 20 parts by mass of the treatment agent with respect to 100 parts by mass of the cosmetic powder.
  • the cosmetic raw material of the present invention may be in the form of a liquid dispersion (slurry).
  • the liquid dispersion includes a liquid dispersion obtained by dispersing the cosmetic powder after treatment with a cosmetic powder treatment agent in an oil agent, or a liquid dispersion obtained by dissolving or dispersing organosiloxane in an oil agent, adding powders thereto and mixing and dispersing the same.
  • the content of the cosmetic powder and the oil agent in the cosmetic raw material is preferably 10 to 5,000 parts by mass with respect to 100 parts by mass of the cosmetic powder after treatment.
  • the content of the oil agent is preferably 30 parts by mass or more, 50 parts by mass or more, 100 parts by mass or more, 200 parts by mass or more, 5,000 parts by mass or less, 3,000 parts by mass or less, 2,000 parts by mass or less, or 1,000 parts by mass or less with respect to 100 parts by mass of the cosmetic powder.
  • the above-mentioned oil agent is not particularly limited as long as it can prepare a liquid dispersion, and is generally used as a component of a cosmetic, and is usually liquid at room temperature, but may be a solid such as wax, or may be a gum or paste having a high viscosity and viscous, which will be described later.
  • Such an oil agent is suitably one or more oil agents selected from silicone oils, non-polar organic compounds or low polarity organic compounds which are liquid at 5 to 100°C.
  • oil agents in the cosmetic of the present invention, one or more of "(B) oil agents” can be used depending on the purpose. Any oil agent, in the form of solid, semisolid or liquid, can be used as long as it is used in ordinary cosmetics.
  • natural animal and vegetable oils and fats and semi-synthetic oils and fats include avocado oil, linseed oil, almond oil, insects wax, perilla oil, olive oil, cocoa butter, kapok wax, kaya oil, carnauba wax, liver oil, candelilla wax, beef tallow, beef foot oil, beef bone fat, hardened beef tallow, apricot kernel oil, whale wax, hydrogenated oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugar cane wax, camellia kissi seed oil, safflower oil, shea butter, Chinese tung oil, cinnamon oil, jojoba wax, shellac wax, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese tung oil, bran wax, germ oil, horse fat, persic oil, palm oil, palm kernel oil, castor oil, hydrogenated castor oil, castor oil fatty acid methyl ester, sunflower oil,
  • Hydrocarbon oils include ozokerite, squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, vaseline, and the like; and higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), isostearic acid, 12-hydroxystearic acid, and the like.
  • higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (
  • Higher alcohols include lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldodecanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol, cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerine ether (batyl alcohol), monooleyl glyceryl ether (ceralkyl alcohol), and the like.
  • Ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl-2-ethylhexanoate, tri-2-ethylhexanoate trimethylolpropane, tetra-2-ethylhexanoate pentaerythritol, cetyl octanoate, octyl dodecyl gum ester, oleyl oleate, octyl dodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amy
  • silicone oils include low viscosity to high viscosity organopolysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, dimethylsiloxane/methylphenylsiloxane copolymer; cyclic siloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethyltetrahydrogen cyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane; silicone rubber such as gum-like dimethylpolysiloxane having a high degree of polymerization, gum-like dimethylsiloxane-methylphenylsiloxane copolymer; and higher alkoxy-modified silicones such as cyclic siloxane solution of silicone rubber, tri
  • the blending amount of these oil agents (B) is 1 to 98 mass%, preferably 2 to 50 mass% of the total cosmetic, although it differs depending on the agent system.
  • (C) water can be blended depending on the purpose.
  • the blending amount is 1 to 95 mass%, preferably 5 to 80 mass% of the total cosmetic, although it differs depending on the agent system.
  • (D) surfactants can be used depending on the purpose.
  • Such surfactants include anionic, cationic, nonionic and amphoteric surfactants.
  • anionic surfactants include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, condensate salts of amino acids and fatty acids, alkane sulfonates, alkene sulfonates, sulfonates of fatty acid esters, sulfonates of fatty acid amides, formalin condensate sulfonates, alkyl sulfates, secondary higher alcohol sulfates, alkyl and allyl ether sulfates, sulfates of fatty acid ester, sulfates of fatty acid alkylolamides, sulfates such as turkey red oil, alkyl phosphates, ether phosphates, alkyl allyl ether phosphates, amide phosphates, N-acyl amino acid-based active agents; examples of the cationic surfactants include amine salts such as alkylamine, al
  • Non-ionic surfactants include sorbitan fatty acid esters, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, poly oxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid esters, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, linear or branched polyoxyalkylene modified organopolysiloxane, linear or branched polyoxyalky
  • amphoteric surfactant examples include betaine, an aminocarboxylate, an imidazoline derivative, an amidoamine type, and the like.
  • anionic surfactants such as fatty acid soaps such as sodium stearate or triethanolamine palmitate, alkyl sulfates, alkyl phosphates, alkyl quaternary ammonium salts, and the like; and nonionic surfactants such as sorbitan fatty acid esters, glycerin fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene hydrogenated castor oils, linear or branched polyoxyalkylene-modified organopolysiloxanes, linear or branched polyoxyalkylene-alkyl co-modified organopolysiloxanes, and particularly nonionic surfactants having HLB of 2 to 8 are preferable.
  • linear or branched silicones having a polyoxyalkylene chain and a polyglycerin chain is generally preferable for a W/O type cosmetic.
  • the blending amount of the surfactant is in the range of 0.1 to 20 mass%, particularly preferably 0.2 to 10 mass% of the total cosmetic.
  • one or more of "(E) a compound having an alcoholic hydroxyl group” can be used depending on the purpose.
  • Compounds having an alcoholic hydroxyl group which can be added in the present invention include lower alcohols such as ethanol and isopropanol, sugar alcohols such as sorbitol and maltose, and sterols such as cholesterol, sitosterol, phytosterol and lanosterol, polyhydric alcohols such as butylene glycol, propylene glycol and dibutylene glycol, and the like.
  • the blending amount is preferably in the range of 0.1 to 98 mass% of the total cosmetic.
  • one or more of "(F) water-soluble or water-swellable polymer” can be used depending on the purpose.
  • vegetable-based polymers such as gum arabic, tragacanth, galactan, carob gum, guar gum, karaya gum, carrageenan, pectin, agar, quince seed (marmelo), starch (rice, corn, potato, wheat), algae colloid, trant gum, and locust bean gum; microorganism-based polymers such as xanthan gum, dextran, succinoglucan, and pullulan; animal-based polymers such as collagen, casein, albumin, and gelatin; starch-based polymers such as carboxymethyl starch and methylhydroxypropyl starch; cellulose-based polymers of cellulose powder such as methyl cellulose, ethyl cellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitrocellulose, sodium cellulose sulfate, sodium carboxymethylcellulose, crystalline cellulose; alginic acid-based polymers such as sodium alginate and alginic acid
  • At least one silicone resin selected from acrylic silicone resin and network silicone resin can be used according to the purpose.
  • the acrylic silicone resin may be either an acrylic/silicone graft polymer or an acrylic/silicone block copolymer.
  • these network silicone resins do not have SiH bonds.
  • the acrylic silicone resin and the network silicone resin have at least one selected from a pyrrolidone moiety, a long chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety, a carboxylic acid, and an amino group.
  • the acrylic silicone resin and the network silicone resin are preferably 0.1 to 20 mass %, more preferably 1 to 10 mass % with respect to the total amount of the cosmetic.
  • components commonly used in cosmetics such as oil-soluble gelling agents, organic modified clay minerals, resins, antiperspirants, ultraviolet absorbing agents, ultraviolet absorbing/scattering agents, moisturizing agents, antiseptic agents, antibacterial agents, perfumes, salts, antioxidants, pH adjusting agents, chelating agents, refreshing agents, anti-inflammatory agents, ingredients for a beautiful skin (such as skin-whitening agents, cell activators, skin roughening ameliorating agents, blood circulation promotors, skin astringents, antiseborrheic agents), vitamins, amino acids, nucleic acids, hormones, clathrate compounds, hair fixing agents, and the like, can be added within a range that does not prevent the effect of the present invention.
  • Oil-soluble gelling agents include gelling agents selected from metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid, and ⁇ , ⁇ -di-n-butylamine; dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; benzylidene derivatives of sorbitol such as monobenzylidenesorbitol and dibenzylidenesorbitol; organically modified clay minerals such as dimethylbenzyldodecylammonium montmorillonite clay, and dimethyldioctadecylammonium montmorillonite clay; and the like.
  • metal soaps such as aluminum stearate, magnesium stearate, and zinc myr
  • antiperspirants examples include antiperspirants selected from aluminum chlorohydrate, aluminum chloride, aluminum sesquichlorohydrate, zirconyl hydroxychloride, aluminum zirconium hydroxychloride, aluminum zirconium glycine complex, and the like.
  • Ultraviolet absorbing agents include benzoic acid-based ultraviolet absorbing agents such as paraaminobenzoic acid, anthranilic acid-based ultraviolet absorbing agents such as methyl anthranilate, salicylic acid-based ultraviolet absorbing agents such as methyl salicylate, silicic acid-based ultraviolet absorbing agents such as paramethoxysilicic acid octyl, benzophenone-based ultraviolet absorbing agents such as 2,4-dihydroxybenzophenone, urocanic acid-based ultraviolet absorbing agents such as ethyl urocaninate, and dibenzoylmethane-based ultraviolet absorbing agents such as 4-t-butyl-4'-methoxy-dibenzoylmethane, and the like.
  • Ultraviolet absorbing/scattering agents include powder that absorbs and scatters ultraviolet such as fine particulate titanium oxide, fine particulate iron oxide-containing titanium oxide, fine particulate zinc oxide, fine particulate cerium oxide, and complexes thereof.
  • Moisturizing agents include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside, and the like.
  • Antimicrobial-antiseptic agents include paraoxybenzoic acid alkyl esters, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol and the like, and antibacterial agents include benzoic acid, salicylic acid, carbolic acid, sorbic acid, paraoxybenzoic acid alkyl esters, parachlormetacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, phenoxyethanol and the like.
  • Antioxidants include tocopherol, butyl hydroxyanisole, dibutyl hydroxytoluene, phytic acid, and the like; pH adjusting agents include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium hydrogen carbonate, ammonium hydrogen carbonate, and the like; chelating agents include alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like; refreshing agents include L-menthol, camphor, and the like; and anti-inflammatory agents include alantoin, glycyrrhizinic acid and salts thereof, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, azulene, and the like.
  • Ingredients for a beautiful skin include skin-whitening agents such as placental extracts, albutin, glutathione, and euquinosita extracts; cell activators such as royal jellies, photosensitive agents, cholesterol derivatives, and juvenile blood extracts; skin roughening ameliorating agents; blood circulation promotors such as nonylic acid vanillylamide, benzyl nicotinate, ⁇ -butoxyethyl nicotinate, capsaicin, gingeron, cantharides tincture, ichthammol, caffeine, tannic acid, ⁇ -borneol, tocopherol nicotinates, inositol hexanicotinate, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cepharanthin, and ⁇ -oryzanol; skin astringents such as zinc oxide and tannic acid; antiseborrheic agents such as sulfur and thianthol
  • Vitamins include vitamin A such as vitamin A oil, retinol, retinol acetate, and retinol palmitate; vitamin B2 such as riboflavin, riboflavin butyrate, and flavin adenine nucleotide; Vitamin B6 such as pyridoxine hydrochloride, pyridoxine dioctanoate, and pyridoxine tripalmitate; vitamin B such as vitamin B12 and derivatives thereof, and vitamin B15 and derivatives thereof; vitamin C such as L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, and L-ascorbic acid phosphate diester dipotassium; vitamin D such as ergocalciferol, and cholecalciferol; Vitamin E such as ⁇ -tocopherol, ⁇ -tocopherol, ⁇ -tocopherol, dl- ⁇ -tocopherol acetate, dl
  • Amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, tryptophan, and the like; nucleic acids include deoxyribonucleic acid and the like; hormones include estradiol, ethenylestradiol, and the like.
  • Hair fixing polymeric compounds include amphoteric, anionic, cationic, and nonionic polymer compounds, and examples thereof include polyvinyl pyrrolidone polymer compounds such as polyvinyl pyrrolidone and vinyl pyrrolidone/vinyl acetate copolymer; acidic vinyl ether based polymers such as methyl vinyl ether/maleic anhydride alkyl half ester copolymer; acidic polyvinyl acetate based polymers such as vinyl acetate/crotonic acid copolymer; acidic acrylic polymer compounds such as (meth)acrylic acid/alkyl (meth)acrylate copolymer, (meth)acrylic acid/alkyl (meth)acrylate/alkylacrylamide copolymer; amphoteric acrylic polymer compounds such as N-methacryloylethyl-N, N-dimethylammonium ⁇ -N-methylcarboxybetaine/alkyl (meth)acrylate copolymer, hydroxy
  • the cosmetics of the present invention include skin care cosmetics such as lotions, milky lotions, creams, cleansing agents, packs, oil liquids, massage agents, detergents, deodorants, hand creams, and lip creams; makeup cosmetics such as makeup bases, face powder, liquid foundations, oily foundations, blushers, eye shadows, mascara, eyeliners, eyebrows, and lipsticks; hair cosmetics such as shampoos, rinses, treatments, and setting agents; antiperspirants; ultraviolet protective cosmetics such as sunscreen milk lotions, and sunscreen creams.
  • skin care cosmetics such as lotions, milky lotions, creams, cleansing agents, packs, oil liquids, massage agents, detergents, deodorants, hand creams, and lip creams
  • makeup cosmetics such as makeup bases, face powder, liquid foundations, oily foundations, blushers, eye shadows, mascara, eyeliners, eyebrows, and lipsticks
  • hair cosmetics such as shampoos, rinses, treatments, and setting agents
  • antiperspirants ultraviolet protective cosmetics such as sunscreen milk lotions, and sunscreen cream
  • These cosmetics may be in various forms such as liquid, emulsion, cream, solid, paste, gel, powder, press, mousse, spray, stick, pencil, and the like.
  • an organohydrogensiloxane represented by the following formula (2): and 21.0 g of 5-hexenyltrimethoxysilane were charged and heated to 50 to 60°C while stirring under an inert gas.
  • a solution of platinum-1,3-divinyltetradimethyldisiloxane complex in isopropyl alcohol platinum concentration 0.38% was added, the reaction solution was stirred while maintaining the temperature at 85 to 95°C.
  • reaction solution 0.5 g was taken and it was confirmed that the reaction was completed by an alkali decomposition gas generation method (the remaining Si-H group was decomposed by KOH in an ethanol/aqueous solution, and the reaction rate was calculated from the volume of hydrogen gas generated).
  • the reaction solution was warmed to 150 to 160°C under reduced pressure to remove low-boiling components such as isopropyl alcohol, 192 g of a treatment agent for a cosmetic powder containing 80% or more of reactive organosiloxane represented by the following formula (3): was obtained.
  • the above Formula was confirmed by 1 H-NMR and 29 Si-NMR.
  • the viscosity of the obtained reactive organosiloxanes was measured according to JIS-Z-8803 using an Ubbelohde-type viscosity tube and found to be 31 mm 2 /s.
  • the above Formula was confirmed by 1 H-NMR and 29 Si-NMR.
  • the viscosity of the resulting reactive organosiloxanes was measured according to JIS-Z-8803 using an Ubbelohde-type viscosity tube and found to be 51 mm 2 /s.
  • Example 1 a cosmetic raw material in the form of a slurry containing titanium oxide treated in the same manner was obtained using the treatment agent of Synthesis Example 2.
  • a slurry-like cosmetic raw material containing titanium oxide with the same composition was produced using a powder treated similarly with 100 parts of the same untreated titanium oxide with 5 parts of methylhydrogen polysiloxane.
  • MICROTRAC UPA model 9340-UPA manufactured by Nikkiso Co., Ltd.
  • Example 4 a cosmetic raw material in the form of a slurry containing titanium oxide treated in the same manner was obtained using the treatment agent of Synthesis Example 2.
  • a slurry-like cosmetic raw material containing titanium oxide with the same composition was produced using fine particle titanium oxide treated with methylhydrogen polysiloxane (MTY-02, manufactured by Tayca Corporation).
  • sunscreen (W/O) creams were produced according to the following formulation, and SPF values (ultraviolet protection index) and PA values (UV-A protection index) were measured.
  • UV-1000S manufactured by Labsphere, Inc.
  • Three samples were prepared in which 2.00 mg/cm 2 of the sample was applied to a Transpore surgical tape (manufactured by 3M Japan Limited), 10 points were measured per sample, the average value was calculated by deleting the highest value and the lowest value, and using 8 measured values. The mean value of the three samples was used as the SPF value.
  • the PA value was also measured under the same conditions using the same measuring instrument.
  • Evaluation of feeling of use was also carried out by the following method. Based on ten professional evaluation panels, evaluation of spreadability at the time of application to the skin and smoothness after drying were evaluated in 5 grades according to the following criteria, and further judged from the average score.
  • the lipophilicity of the cosmetic powder can be effectively enhanced.
  • the cosmetic powder treated with this treatment agent is characterized by high lipophilicity.
  • the cosmetic having the cosmetic powder has a feature of having a good tactile impression.
  • the treatment agent obtained in this manner can be used not only as a cosmetic but also as a treatment agent widely used in various fields such as plastic additives, inks, paints, toners (magnetic powders), chemical fibers, packaging materials, and the like.

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Claims (6)

  1. Ein Behandlungsmittel für ein kosmetisches Pulver, das als Hauptbestandteil ein reaktives Organosiloxan enthält, das durch die folgende allgemeine Formel (1) dargestellt ist:
    Figure imgb0008
     wobei jedes R1 unabhängig eine Alkylgruppe mit 1 bis 30 Kohlenstoffatomen ist; jedes R2 unabhängig eine Alkylgruppe mit 1 bis 20 Kohlenstoffatomen ist; R3 eine zweiwertige Alkylengruppe mit 3 bis 18 Kohlenstoffen ist; n eine ganze Zahl von 1 bis 200 ist; und p eine ganze Zahl von 1 bis 3 ist.
  2. Ein kosmetisches Pulver, das mit dem Behandlungsmittel gemäß Anspruch 1 oberflächenbehandelt ist.
  3. Kosmetisches Pulver gemäß Anspruch 2, wobei der Teilchendurchmesser 0,50 µm oder weniger beträgt.
  4. Kosmetisches Pulver gemäß Anspruch 2 oder 3, wobei die Standardabweichung des Teilchendurchmessers 0,25 µm oder weniger beträgt.
  5. Ein kosmetischer Rohstoff, beinhaltend, bezogen auf 100 Massenteile des kosmetischen Pulvers, zu 10 bis 10 000 Massenteile das kosmetische Pulver gemäß einem der Ansprüche 2 bis 4 und ein Ölmittel.
  6. Ein Kosmetikum, das mit dem kosmetischen Pulver gemäß einem der Ansprüche 2 bis 4 gemischt ist.
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