EP3443147A1 - Unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung - Google Patents
Unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierungInfo
- Publication number
- EP3443147A1 EP3443147A1 EP17719525.2A EP17719525A EP3443147A1 EP 3443147 A1 EP3443147 A1 EP 3443147A1 EP 17719525 A EP17719525 A EP 17719525A EP 3443147 A1 EP3443147 A1 EP 3443147A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- conveyor frame
- dip coating
- component
- process sequence
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/20—Pretreatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4488—Cathodic paints
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/02—Electrophoretic coating characterised by the process with inorganic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/04—Electrophoretic coating characterised by the process with organic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/22—Servicing or operating apparatus or multistep processes
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium
Definitions
- the present invention relates to a method for corrosion-protective pretreatment of a plurality of metallic components, in which the Uberschleppung water-soluble phosphates from an acidic passivation, the water having dissolved phosphates as active component and in particular may be a phosphating, is effectively avoided in the treatment stage of dip coating.
- a component is guided by means of conveyor frame through all treatment stages of the pretreatment line and the transport pair consisting of component and conveyor frame separated only after the dip coating and for the transfer of the pretreated component to the baking stage, and thus released the conveyor frame for the re-admission of a pretreated component
- the inventive method now provides that the transport pair consisting of component and conveyor frame before the dip coating and immediately after the acid passivation led by an intermediate treatment stage and thereby at least the part of the conveyor racks, previously in the acidic passivation with the aqueous treatment solution containing water-soluble phosphates Now brought into contact with an acidic aqueous agent containing water-soluble compounds of the elements Zr, Ti, Cr (III) and / or AI in a total amount of at least 0.1 g / kg based on the agent in contact.
- the corrosion-protective pretreatment of metallic components in particular consisting of the materials zinc, iron, steel, galvanized steel and / or aluminum, in a process sequence comprising an acidic passivation based on water-soluble phosphates followed by dip coating has been established in the art for decades.
- the acidic passivation can bring about the formation of a crystalline phosphate layer according to EP 2503025 or merely the formation of an amorphous phosphate-containing coating, for example in the context of a zirconium phosphating according to EP 2215285.
- the thus passivated metallic components are usually immediately after a sink in the treatment stage of Dipcoating transferred.
- the purpose of the passivation and the subsequent dip coating interposed sink serves only the purpose of removing the adhering to the component wet film containing active components of the passivation for setting a reproducible surface, possibly to recycle in the previous treatment stage and the transfer of the same in the dip coating - so-called
- the transfer of active components from process stages of priority to the immersion coating often involves problems because the stability and reproducibility of the dip coating as well as the processing during firing are directly related to the stability of the dip bath and its composition
- An entrainment of dissolved phosphates can be the cause of increased stoving temperatures of the dip. Increased stoving temperatures when dissolved phosphors are carried over can be observed, in particular, for immersion paints which, in addition to the dispersed resin, contain water-soluble salts of yttrium and / or bismuth.
- the metallic components are pretreated against corrosion, while the transfer of dissolved phosphate from the acidic passivation is effectively suppressed in the dip coating on the conveyor racks. Since the dip painting ever Conveyor frame is repeatedly traversed in the process according to the invention, builds on the areas of the conveyor frame, which repeatedly come into contact with the dip paint, without being baked, a Lackkoagulat in considerable layer thickness. In the method according to the invention, however, the absorption capacity of the adhering lacquer coagulum for dissolved phosphate is minimized by guiding the conveyor frames together with the component through the wet-chemical treatment stage for conditioning.
- a pre-treatment in series according to the present invention is when a plurality of metallic components undergo the wet-chemical treatment stages of the anti-corrosive pretreatment process sequence, each component passing through the individual treatment stages of the process sequence with a time lag.
- a metallic component according to the present invention is when the component is at least partially composed of at least one metallic material, preferably of zinc, iron, aluminum and of the respective alloys, inasmuch as the aforementioned elements in each case the main alloy component with more than 50 at. -% form, as well as of galvanized steel.
- Acid passivation in the sense of the present invention characterizes a wet-chemical treatment stage, in the course of which a passivating coating containing phosphate is formed.
- the acidic passivation is based on an aqueous medium with a pH below of 7 containing dissolved phosphate, wherein dissolved phosphate is present in water in the form of hydrated compounds which are a source of phosphate ions.
- An immersion coating in the context of the present invention characterizes a wet-chemical treatment stage, in the course of which a curable coating coagulate is deposited on the metallic component, which is filmed and cured in a subsequent treatment stage by baking.
- the dip-coating is based on an aqueous agent containing at least one dispersed organic resin in an amount of at least 1% by weight, based on the aqueous agent.
- the dip paint is electrophoretically depositable, in a particularly preferred embodiment by applying a current in which the metallic component is connected as a cathode.
- cathodic dip coating in which an alkaline pH shift at the interface to the metallic component causes the coagulation of the dispersed resin particles and thus the film formation on the component.
- lacquer coagulum of cathodic dip coatings favors the absorption of dissolved phosphate.
- the positive zeta potential of the resin particles or the positive charge density in the polymer responsible for the relatively high absorption capacity and the increased tendency to overturn dissolved phosphate in the dip coating on the paint coagulum adhering to the conveyor frame.
- the preferred dip coating is a cathodic dip coating, wherein in addition to the dispersed resin is preferably at least one water-soluble compound of the element bismuth and / or yttrium. Especially these elements tend to form sparingly soluble salts in the presence of dissolved phosphate, so that the result of such a dip coating is particularly dependent on the transfer of dissolved phosphates.
- a sequence of processes for anticorrosive pretreatment comprises a predetermined sequence of wet-chemical treatment stages from the admission of the component to be pretreated by the conveyor frame to the removal of the pretreated product Component for the purpose of transfer to the baking stage, wherein each individual wet chemical treatment stage provides an in contact bringing the component and at least parts of the conveyor frame with an aqueous agent.
- a conveyor frame in the sense of the present invention identifies a frame for transporting the components through all spatially separate wet-chemical treatment stages in accordance with the process sequence according to the invention.
- the frame can take any spatial configuration that allows the component to be received and transported.
- the conveyor frame and component to be pretreated form a transport pair for the duration of the process sequence.
- the pretreated component is removed and provided for the burn-in stage, and once the pre-treated component has been removed, the conveyor frame is released again and can receive another component to be pretreated, usually for procedural economy if a multiplicity of conveyor racks are also used for the quasi-continuous treatment of a large number of components in series, the number of conveyor racks preferably corresponds at least to the number of wet-chemical treatment stages.
- the acidic aqueous conditioning agent contains water-soluble compounds of the element aluminum, preferably in an amount of at least 0.2 g / kg calculated as Al based on the agent.
- the acidic aqueous conditioning agent contains water-soluble compounds of the elements Zr, Ti and / or Cr (III) in a total amount of at least 0.2 g / kg, preferably of at least 0.4 g / kg calculated as weight fraction of these elements in relation to the mean.
- the acidic aqueous conditioning agent is substantially free of dissolved phosphates. This is intended to mean that less than 100 mg / kg, preferably less than 50 ppm, of dissolved phosphates calculated as PO4 are contained in the composition.
- compounds are "water-soluble" if their solubility in deionized water having a conductivity of not more than 1 ⁇ at a temperature of 20 ° C is at least 1 g / l.
- the pH of the acidic aqueous agent is greater than 3.0 and preferably less than 5.0.
- the acid passivation treatment stage be preceded by such cleaning / degreasing as a wet chemical treatment stage within the process sequence for the corrosion-protective pretreatment of components in series, in which the cleaning and degreasing takes place on the basis of aqueous cleaning solutions whose pH is above 6, preferably above 8, more preferably above 10. It is then ensured that the lacquer coagulum adhering to the conveyor frame and active components contained therein remain from the treatment of the conveyor frame in the lacquer coagulate and are not released into the cleaning / degreasing.
- the process sequence for corrosion-protective pretreatment of a plurality of components in series is followed by baking of the dip paint to form a cured coating, wherein preferably again conveyor frames, which are not such conveyor frames, the process sequence belong to the corrosion-protective pretreatment, take the pre-treated components and transferred to the baking stage and possibly subsequent stages for further coating.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016206418.5A DE102016206418A1 (de) | 2016-04-15 | 2016-04-15 | Unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung |
PCT/EP2017/058995 WO2017178619A1 (de) | 2016-04-15 | 2017-04-13 | Unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3443147A1 true EP3443147A1 (de) | 2019-02-20 |
Family
ID=58632953
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17719525.2A Withdrawn EP3443147A1 (de) | 2016-04-15 | 2017-04-13 | Unterdrückung anlagenbedingter phosphatüberschleppung in einer prozessfolge zur tauchlackierung |
Country Status (6)
Country | Link |
---|---|
US (1) | US20190032224A1 (de) |
EP (1) | EP3443147A1 (de) |
CN (1) | CN108779572A (de) |
DE (1) | DE102016206418A1 (de) |
MX (1) | MX2018010249A (de) |
WO (1) | WO2017178619A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3569743A1 (de) * | 2018-05-16 | 2019-11-20 | Henkel AG & Co. KGaA | Fördergestellreinigung in einer prozessfolge zur elektrotauchlackierung |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT202931B (de) * | 1957-02-15 | 1959-04-10 | Otto Dipl Kfm Schenker | Vorrichtung zum Transport chemisch oder elektrochemisch zu behandelnder Ware durch Behandlungsstationen, z. B. Behandlungsbäder |
US3695942A (en) * | 1970-12-02 | 1972-10-03 | Amchem Prod | Zirconium rinse for phosphate coated metal surfaces |
US4165242A (en) * | 1977-11-21 | 1979-08-21 | R. O. Hull & Company, Inc. | Treatment of metal parts to provide rust-inhibiting coatings by phosphating and electrophoretically depositing a siccative organic coating |
DE4017187A1 (de) * | 1990-05-29 | 1991-12-05 | Metallgesellschaft Ag | Verfahren zur nachspuelung von konversionsschichten |
DE3924984A1 (de) * | 1989-07-28 | 1991-01-31 | Metallgesellschaft Ag | Verfahren zur passivierenden nachspuelung von phosphatschichten |
US5128211A (en) * | 1991-02-28 | 1992-07-07 | Diversey Corporation | Aluminum based phosphate final rinse |
US5397390A (en) * | 1993-08-13 | 1995-03-14 | Ardrox, Inc. | Composition and method for treatment of phosphated metal surfaces |
DE19616502A1 (de) * | 1995-05-05 | 1996-11-07 | Volkswagen Ag | Verbesserte Oberflächenbehandlung |
US5885373A (en) * | 1997-06-11 | 1999-03-23 | Henkel Corporation | Chromium free, low organic content post-rinse for conversion coatings |
DE19834796A1 (de) * | 1998-08-01 | 2000-02-03 | Henkel Kgaa | Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung |
DE102005043031A1 (de) * | 2005-09-10 | 2007-03-15 | Mauer, Dieter, Dr. | Verfahren zum Entfernen von Phosphaten aus Acetat-gepufferten Lösungen |
DE102007057185A1 (de) | 2007-11-26 | 2009-05-28 | Henkel Ag & Co. Kgaa | Zirconiumphosphatierung von metallischen Bauteilen, insbesondere Eisen |
DE102008023444A1 (de) * | 2008-05-14 | 2009-11-19 | Basf Coatings Ag | Elektrotauchlackzusammensetzung |
DE102008038653A1 (de) * | 2008-08-12 | 2010-03-25 | Henkel Ag & Co. Kgaa | Sukzessive korrosionsschützende Vorbehandlung von Metalloberflächen in einem Mehrstufenprozess |
PL2503025T3 (pl) | 2011-03-22 | 2013-12-31 | Henkel Ag & Co Kgaa | Chroniąca przed korozją, wielostopniowa obróbka metalowych elementów konstrukcyjnych o powierzchniach cynkowych |
JP5657157B1 (ja) * | 2013-08-01 | 2015-01-21 | 関西ペイント株式会社 | 複層皮膜形成方法 |
-
2016
- 2016-04-15 DE DE102016206418.5A patent/DE102016206418A1/de not_active Withdrawn
-
2017
- 2017-04-13 WO PCT/EP2017/058995 patent/WO2017178619A1/de active Application Filing
- 2017-04-13 MX MX2018010249A patent/MX2018010249A/es unknown
- 2017-04-13 CN CN201780016614.0A patent/CN108779572A/zh active Pending
- 2017-04-13 EP EP17719525.2A patent/EP3443147A1/de not_active Withdrawn
-
2018
- 2018-10-02 US US16/149,502 patent/US20190032224A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
MX2018010249A (es) | 2018-09-27 |
CN108779572A (zh) | 2018-11-09 |
WO2017178619A1 (de) | 2017-10-19 |
US20190032224A1 (en) | 2019-01-31 |
DE102016206418A1 (de) | 2017-10-19 |
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