EP3314031B1 - Bande almg facilement déformable et très résistante et son procédé de fabrication - Google Patents
Bande almg facilement déformable et très résistante et son procédé de fabrication Download PDFInfo
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- EP3314031B1 EP3314031B1 EP16732581.0A EP16732581A EP3314031B1 EP 3314031 B1 EP3314031 B1 EP 3314031B1 EP 16732581 A EP16732581 A EP 16732581A EP 3314031 B1 EP3314031 B1 EP 3314031B1
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- aluminium alloy
- alloy strip
- rolling
- aluminum alloy
- strip
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- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 229910000838 Al alloy Inorganic materials 0.000 claims description 136
- 238000000137 annealing Methods 0.000 claims description 58
- 230000007797 corrosion Effects 0.000 claims description 42
- 238000005260 corrosion Methods 0.000 claims description 42
- 238000005096 rolling process Methods 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 26
- 238000005097 cold rolling Methods 0.000 claims description 23
- 238000012360 testing method Methods 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 238000005098 hot rolling Methods 0.000 claims description 8
- 206010070834 Sensitisation Diseases 0.000 claims description 7
- 238000005275 alloying Methods 0.000 claims description 7
- 230000008313 sensitization Effects 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 5
- 238000005266 casting Methods 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 1
- 239000011572 manganese Substances 0.000 description 18
- 239000011651 chromium Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- 230000006399 behavior Effects 0.000 description 9
- 229910052804 chromium Inorganic materials 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- 241001295925 Gegenes Species 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 229910021365 Al-Mg-Si alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 208000016261 weight loss Diseases 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
Definitions
- the invention relates to a method for producing an aluminum strip or sheet from an aluminum alloy and an aluminum alloy strip or sheet and its use.
- the highly stressed vehicle components were preferably made of aluminum sheets consisting of a curable Al-Mg-Si alloy of class AA6XXX.
- Aluminum alloy sheets of this class are used in the solution-treated state T4 and then subjected to a heat aging to achieve a higher ultimate strength in the state T6.
- This complicated manufacturing path leads to higher production costs, in particular due to the logistical effort for processing the plates in the state T4 and the hot aging of the plates to reach the state T6.
- components of non-hardenable aluminum alloys of the type AA5XXX have been produced by forming soft annealed aluminum alloy sheets.
- AlMg alloys of the type AA 5xxx with Mg contents of more than 3% by weight, in particular more than 4% by weight, are increasingly prone to intercrystalline corrosion, for example when exposed to elevated temperatures.
- ⁇ -Al 5 Mg 3 phases separate out along the grain boundaries, which are called ⁇ -particles and can be selectively dissolved in the presence of a corrosive medium.
- This also applies to the components of a motor vehicle, in particular the components of the so-called "body-in-white" of the motor vehicle, which are usually subjected to a cathodic dip coating (KTL) and then dried in a baking process. Sensitization to intergranular corrosion can already be caused by this baking process in conventional aluminum alloy strips.
- KTL cathodic dip coating
- the susceptibility to intergranular corrosion is usually tested in a standard test according to ASTM G67, in which the samples are exposed to nitric acid and the mass loss of the aluminum sheet is measured.
- ASTM G67 a standard test according to ASTM G67
- a corresponding heat load of the components in the application is simulated by a prior sensitization annealing at temperatures of 130 ° C. for 17 hours.
- ASTM G67 the mass loss for materials which are not resistant to intergranular corrosion is more than 15 mg / cm 2 .
- the magnesium content of the aluminum alloy to be used according to the invention is from 3.6% by weight to 6% by weight, preferably from 4.2% by weight to 6% by weight, particularly preferably from 4.2% by weight to 5 , 2 wt .-% contributes to the fact that the aluminum alloy with good forming properties simultaneously high strength values , in particular yield strength R p0,2 and tensile strength R m . Unwanted hardening and precipitation effects of Si are reduced by limiting the Si content to a maximum of 0.4% by weight. In order not to adversely affect the properties of the aluminum alloy, the Fe content should be limited to a maximum of 0.5 wt .-%.
- the copper content which should be limited to a maximum of 0.15 wt .-%.
- Manganese leads to an increase in strength and also to an improvement in the resistance to intergranular corrosion.
- the manganese content must be limited, since otherwise the forming properties of the re-annealed aluminum alloy strips are adversely affected.
- too high Mn contents at the last intermediate annealing lead to mean grain diameters of less than 20 ⁇ m.
- the Mn content should be 0.1% by weight to 0.4% by weight. Chromium, even in the smallest amounts, already causes the forming properties, for example the uniform elongation A g or the fracture contraction Z, to decrease, so that the forming properties are impaired.
- the chromium content is to be limited to values of less than 0.05 wt .-%, preferably less than 0.01 wt .-%.
- Zr which, since it usually has to be added, is not listed here in detail.
- Zinc could have a negative effect on the corrosion resistance of the aluminum alloy strip and should therefore be limited to a maximum of 0.2% by weight.
- Titanium is commonly added in continuous casting of the aluminum alloy as a grain refining agent, for example in the form of Ti-boride wire or rods.
- too high Ti contents in turn have a negative effect on the forming properties, so that a limitation of the Ti content to a maximum of 0.20 wt .-% is desired.
- a roll bar for hot rolling By casting and homogenizing the rolling ingot at 480 ° C to 550 ° C for at least 0.5 hours, a roll bar for hot rolling can be provided which has a very homogeneous distribution of the alloy components.
- a homogeneous recrystallized hot strip is provided by hot rolling in a temperature range of 280 ° C to 500 ° C.
- the degree of rolling during cold rolling of the aluminum alloy strip is according to the invention only 10% to 45%, since the degree of rolling before the last intermediate annealing decisively influences the formation of the grain structure during recrystallization during the intermediate annealing.
- the intermediate annealing makes it possible to provide a recrystallized microstructure for the last cold rolling step, which is carried out with a rolling degree of 30% to 60% of final thickness.
- the final rolling degree makes it possible, unlike soft annealed variants, to continuously increase the yield strength of the aluminum alloy strip to be produced by work hardening to the desired application, for example to a yield strength of more than 190 MPa after the subsequent final annealing.
- the final annealing of the aluminum alloy strip in the coil at metal temperatures of 190 ° C to 250 ° C for at least 0.5 hours results in that the forming properties, in particular the uniform elongation A g and the Brucheinschnürung Z are improved by the recovery process in the structure of the aluminum alloy strip.
- the production method can thus be used to provide an aluminum alloy strip which, on the one hand, can be shaped well, for example into a vehicle component, and on the other hand also provides high yield strengths in the unformed regions.
- the produced aluminum alloy strip is at the same time also resistant to intergranular corrosion and, due to the simple production route, less expensive than previously used AA6XXX alloy strips.
- the degree of rolling is limited to 20% to 30% in the case of cold rolling before the last intermediate annealing, larger grain diameters are provided in the aluminum alloy strip after the last intermediate annealing, thus improving the resistance to intergranular corrosion in the re-annealed aluminum alloy strip.
- the yield strength R p0,2 can be set to values above 200 MPa, without the forming properties, for example, the uniform elongation A g or ., the fracture constriction Z are adversely affected.
- the method according to the invention makes it possible to provide aluminum alloy strips and sheets for conversion to vehicle components, for example body-in-white (BIW) components.
- the temperature during the annealing of the aluminum alloy strip is 220 ° C to 240 ° C.
- the forming capability of the aluminum alloy strip is increased by recovery processes with an increase in the uniform elongation A g and the Brucheinschnürung Z process reliable.
- the high annealing temperatures of 220 ° C. to 240 ° C.
- the above object is achieved by a cold-rolled and re-annealed aluminum alloy strip or sheet produced by the method of the invention consisting of an aluminum alloy having the following alloying components: 3.6 % ⁇ mg ⁇ 6 % . Si ⁇ 0.4 % . Fe ⁇ 0.5 % . Cu ⁇ 0.15 0.1 % ⁇ Mn ⁇ 0.4%, Cr ⁇ 0.05 % . Zn ⁇ 0.20 % . Ti ⁇ 0.20 % . Residual Al and unavoidable impurities, individually max.0,05%, in total max.
- the aluminum alloy ribbon a yield strength R p0.2 of more than 190 MPa, a uniform elongation A g of at least 14%, a fracture constriction Z of more than 50% and in the corrosion test according to ASTM G67 after a previous sensitization annealing for 17 h at 130 ° C has a mass loss of less than 15 mg / cm 2 .
- an aluminum alloy strip or sheet having the above-mentioned aluminum alloy composition having a yield strength of more than 190 MPa, a uniform elongation A g of at least 14%, and a fracture waist Z of more than 50% while resisting the corrosion test according to ASTM G67 with a mass loss of less than 15 mg / cm 2 after a previous sensitization annealing for 17 h at 130 ° C for non-hardenable aluminum alloy tapes open up further applications previously reserved for aluminum alloy tapes of hardenable materials, in particular AA6xxx aluminum alloys.
- Yield strengths Rp0.2 of greater than 190 MPa to 300 MPa with a uniform elongation of 14% to 18% and a breakage entanglement Z of more than 50% to 70% for given aluminum oxide composition are expected Corrosion resistance can be achieved.
- the embodiments set forth below show inventive aluminum alloy strips or sheets with yield strengths R p0.2 of more than 190 MPa and up to 270 MPa while maintaining a good forming behavior due to a uniform expansion of A g up to 16.6% and a Brucheinschnürung Z from to to 62% with existing resistance to intergranular corrosion.
- the yield strength values are opposite to the values obtained for the uniform elongation A g and the fracture constriction Z.
- the Mg content of the aluminum alloy strip or sheet is 4.2% by weight to 6% by weight, preferably 4.2% by weight to 5.2% by weight Aluminum alloy strip or sheet with maximum yield strengths after the last cold rolling.
- the manganese content is limited to 0.1 wt% to 0.3 wt% according to another aspect of the aluminum alloy strip or sheet, good and good strength can be attained despite the positive influence of manganese on the strength and corrosion resistance of the aluminum alloy strip or sheet Forming properties, ie high values for uniform expansion A g and the Brucheinschnürung Z can be achieved with high process reliability.
- mean grain diameters of more than 20 ⁇ m can be set reliably, which positively influence the corrosion resistance of the aluminum alloy strip or sheet.
- the chromium content negatively affects the properties of the aluminum alloy even at very low concentrations with respect to the forming behavior and limits the grain size after the last intermediate annealing, so that according to another embodiment of the aluminum alloy strip or sheet the chromium content is reduced to less is limited as 0.01 wt .-%. This also applies analogously to zirconium and scandium which, if at all, are only present in traces in the aluminum alloy.
- the aluminum alloy strip or sheet has one or more of the following limitations on the proportions of alloying ingredients: Si ⁇ 0.2 weight , - % . Fe ⁇ 0.35 weight , - % or Zn ⁇ 0.01 weight , - % . Negative effects of said alloying components on the properties of the aluminum alloy strip or sheet can be excluded.
- the aluminum alloy strip or sheet according to the present embodiment allows a significantly increased field of application due to the greatly improved yield strengths compared to the previously annealed, soft annealed variants.
- the above object is also achieved by the use of an aluminum alloy strip or sheet according to the invention for the production of structural parts or vehicle components, in particular BIW components of a motor vehicle, since the aluminum alloy strips according to the invention allow the production of molded parts for the corresponding use, which undergo very high degrees of deformation At the same time, however, they can provide high yield strengths for reducing the material thickness of the aluminum alloy strip or sheet and nevertheless have a very good corrosion behavior in the corrosion test according to ASTM G67.
- FIG. 1 shows first in a schematic representation of the method steps of an embodiment for producing an aluminum strip on an aluminum alloy according to the present invention.
- step 1 a billet of aluminum alloy having the following alloy contents is cast: 3.6 weight , - % ⁇ mg ⁇ 6 weight , - % . Si ⁇ 0.4 weight , - % . Fe ⁇ 0.5 weight , - % . Cu ⁇ 0.15 weight , - % . 0.1 weight , - % ⁇ Mn ⁇ 0.4 weight , - % . Cr ⁇ 0.05 weight , - % . Zn ⁇ 0.20 weight , - % . Ti ⁇ 0.20 weight , - % .
- Residual Al and unavoidable impurities individually max.0.05 wt .-%, in total max. 0.15% by weight.
- the ingot is homogenized for a period of at least 0.5 h according to step 2.
- This is followed by the Hot rolling the rolling ingot in step 3 at a temperature of 280 ° C to 500 ° C to a hot strip.
- the limitation of Abwalzgrads to 10% to 45% causes in the subsequent intermediate annealing according to step 5 by recrystallization a mean grain size of more than 20 microns can be achieved.
- Carrying out the last intermediate annealing of the cold-rolled aluminum alloy strip at 300 ° C. to 500 ° C.
- step 6 provides for the final cold rolling step 6 a recrystallized structure with particle sizes of more than 20 ⁇ m. If necessary, steps 4 and 5 can be repeated to obtain thinner sheet thicknesses of final thickness if required.
- step 6 work hardening is introduced into the recrystallized structure at a rolling degree of 30% to 60% of the final thickness, which leads to an increase in the yield strength R p0.2 .
- step 7 the cold-rolled structure is subjected to a recovery, so that in particular the uniform dimension A g and the Brucheinschnürung Z again assume higher values and a good forming behavior is set.
- the increase in yield strength R p0.2 achieved during the last cold rolling remains at least partly due to the temperature selection after the annealing, so that an aluminum alloy strip with a yield strength of more than 190 MPa can be made available.
- the produced aluminum alloy strip and sheets produced therefrom may also be subjected to complex forming processes.
- additional step 8 are cut from the aluminum alloy strip sheets, which are then converted into forming processes to form parts, for example, to vehicle components of the "body-in-white" of a motor vehicle, so-called BIW components.
- BIW components often have complex geometries and therefore require high forming capacity of the strips or sheets from which they are made.
- BIW components made from an aluminum alloy also require correspondingly low sheet thicknesses, which requires high strengths and yield strengths of the aluminum alloy strips or sheets used.
- the aluminum alloy strips according to the invention and the sheets produced therefrom fulfill this requirement as well as the necessary corrosion resistance, as experiments show. If vehicle components, in particular BIW components, are therefore produced from an aluminum alloy strip according to the invention, they can be made available at lower cost than previous components made of AA6XXX materials.
- FIGS. 2a) and 2b schematically show areas of application of the aluminum alloy strip produced according to the invention in the form of a wide variety of metal sheets according to a vehicle structure FIG. 2a ) or, for example, a schematically illustrated inner part of a vehicle door according to FIG. 2b ). Due to the good corrosion behavior of the aluminum alloy strips according to the present invention, further application possibilities for the non-curable, ie naturally hard, aluminum alloy strips and sheets according to the invention open up in the motor vehicle.
- Roll bars were cast from various aluminum alloy compositions, subjected to homogenization at 480 ° C to 550 ° C for at least 0.5 hour, hot rolled at 280 ° C to 500 ° C into hot strip, and then subjected to varying conditions in cold rolling before and after a final intermediate annealing.
- Table 1 shows a total of seven different alloy compositions. In the twelve experiments, in addition to the seven different alloys, different parameters were used for cold rolling before and after the last intermediate annealing. Until the completion of the hot strip, the test strips produced did not differ, apart from different hot strip thicknesses and different aluminum alloys. Table 1 Alloy components [% by weight] Experiment No.
- the hot strips made of various aluminum alloys were then cold rolled according to the specifications in Table 2 in the cold rolling before the last intermediate annealing and after the intermediate annealing.
- the annealing temperature was 240 ° C in all experiments.
- the annealing was carried out in the coil, wherein the metal temperature of the annealing temperature was maintained for a period of at least 0.5 h.
- Table 2 also indicates the final thicknesses ao, which are approximately between 0.7 mm and 1.7 mm.
- Comparative Examples Nos. 1 and 6 have excessive degrees of finish before intermediate annealing, whereas Comparative Example No. 3 has too low a final rolling degree after intermediate annealing.
- the mean grain size ie the average grain diameter
- samples were taken from the tapes and anodized longitudinal blanks according to the Barker method. Under the microscope, the samples were measured according to ASTM E1382 and the mean grain size determined by the mean grain diameter.
- Comparative Examples 1 and 2 clearly show the influence of the alloy composition on the results with regard to formability.
- Comparative Example No. 1 which has a markedly increased Mn content, for example, the uniform elongation A g decreases to 10.6%. Also, the too low Mg content of Comparative Example No. 1 counteracts large elongation values.
- Comparative Example No. 2 having an increased Cr content at a slightly excessive Mn content shows fracture necking values Z which are less than 50%, indicating a deteriorated forming performance.
- the Brucheinschnürung Z represents namely the property of the material, in large transformations over a cross-sectional reduction material for forming to provide without tearing. Due to the higher Mn contents or Cr contents, the average particle size of 10 or 15 ⁇ m has no negative influence on the corrosion properties of these samples.
- the yield point R p0.2 can be set via the adjustment of the degree of rolling during final rolling after the intermediate annealing .
- Embodiments Nos. 4, 5 and 8 show that over final rolling degrees after intermediate annealing of 31% to 60%, the yield strength R p0.2 can be increased to values up to 211 MPa without significant sacrifice in the range of characteristics important for forming how to draw the uniform strain A g or Z.
- Comparative Example No. 6 which has an identical aluminum alloy as Examples 3, 4, 5 and 8, the effect of adjusting the average grain diameter by limiting the degree of rolling in cold rolling before the last intermediate annealing can be very clearly recognized.
- the intermediate annealing produces a relatively fine grain having an average diameter or a mean grain size of 13 ⁇ m, which adversely affects the corrosion properties. Comparative Example No. 6 is classified as not resistant to intergranular corrosion.
- the embodiments according to the invention show that the yield strength R p0.2 can be increased to values of up to 270 MPa by using degrees of rolling in final cold rolling of 40% to 60%.
- the higher Mg content of up to 5.2 wt .-% in the embodiment no. 12 contributes to the significant increase in the yield strength R p0.2 .
- a comparison of the embodiments of the invention No. 9, 10 and 11 shows that the corrosion resistance depends strongly on the choice of Abwalzgrades before the last intermediate annealing and thus from the mean grain diameter or the average grain size.
- the Mg content is increased over Embodiment No. 9, which in principle may lead to inferior corrosion resistance to intergranular corrosion.
- the corrosion resistance of these embodiments is significantly better than the smaller grain diameter and lower Mg content embodiment No. 9.
- the preferred process route over the inventive limitations of the cold rolling degrees before the last intermediate annealing has a significant influence on the end product of the annealed strip.
- the embodiments of the present invention show that an aluminum alloy ribbon having yield strengths, elongation values and corrosion resistance against intergranular corrosion, which is particularly well suited for use in high-stress vehicle components, can be manufactured inexpensively due to the use of a non-hardenable aluminum alloy can be.
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Claims (13)
- Procédé de fabrication d'une bande ou d'une tôle en aluminium à partir d'un alliage d'aluminium, avec les constituants d'alliage suivants en pourcentage en poids :
où le procédé comprend les étapes suivantes consistant à :- Coulage d'un lingot de laminage constitué dudit alliage d'aluminium,- Homogénéisation du lingot de laminage à une température allant de 480 °C à 550 °C pendant au moins 0,5 h,- Laminage à chaud du lingot de laminage à une température allant de 280 °C à 500 °C pour former une bande à chaud,- Laminage à froid de la bande d'alliage d'aluminium après le laminage à chaud avec un degré de laminage de 10 % à 45 % avant un dernier recuit intermédiaire,- Exécution d'au moins un dernier recuit intermédiaire de la bande en alliage d'aluminium laminée à froid à une température allant de 300 °C à 500 °C de sorte que la bande en alliage d'aluminium laminée à froid présente une structure recristallisée après le recuit intermédiaire,- Laminage à froid de la bande en alliage d'aluminium recuite avec un degré de laminage de 30 % à 60 % à une épaisseur finale, et- Recuit d'adoucissement partiel la bande en alliage d'aluminium dans l'enroulement à l'épaisseur finale, où la température du métal est de 190 - 250 °C pendant au moins 0,5 h. - Procédé selon la revendication 1,
caractérisé en ce que
le degré de laminage lors du laminage à froid avant le dernier recuit intermédiaire est de 20 % à 30 %. - Procédé selon la revendication 1 ou 2,
caractérisé en ce que
le degré de laminage lors du laminage à froid à l'épaisseur finale après le dernier recuit intermédiaire est de 40 % à 60 %. - Procédé selon l'une des revendications 1 à 3,
caractérisé en ce que
la bande en alliage d'aluminium est laminée à froid sur une épaisseur finale de 0,5 mm à 5,0 mm, de préférence de 1,0 à 3,0 mm. - Procédé selon l'une des revendications 1 à 4,
caractérisé en ce que
la température lors du recuit d'adoucissement partiel est de 220 à 240 °C. - Bande ou tôle en alliage d'aluminium laminée à froid et recuite par adoucissement partiel, fabriquée avec un procédé selon l'une des revendications 1 à 5, se composant d'un alliage d'aluminium avec les constituants d'alliage suivants :
où la bande en alliage d'aluminium présente
une limite d'élasticité Rp0,2 supérieure à 190 MPa,
un allongement uniforme Ag d'au moins 14 %,
une striction Z supérieure à 50 % ainsi
qu'une perte de masse inférieure à 15 mg/cm2 dans un test de corrosion selon ASTM G67 après un précédent recuit de sensibilisation pendant 17 h à 130 °C. - Bande ou tôle en alliage d'aluminium selon la revendication 6,
caractérisée en ce que
la teneur en Mg de la bande en alliage d'aluminium est de 4,2 à 6 % en pourcentage en poids, de préférence 4,2 à 5,2 % en pourcentage en poids. - Bande ou tôle en alliage d'aluminium selon la revendication 6 ou 7,
caractérisée en ce que
la teneur en Mn de la bande en alliage d'aluminium est de 0,1 à 0,3 % en pourcentage en poids. - Bande ou tôle en alliage d'aluminium selon l'une de revendications 6 à 8,
caractérisée en ce que
la teneur en Cr de la bande en alliage d'aluminium est inférieure à 0,01 % en pourcentage en poids. - Bande ou tôle en alliage d'aluminium selon la revendication 6 à 10,
caractérisée en ce que
la bande en alliage d'aluminium présente une ou plusieurs des propriétés suivantes :une limite d'élasticité Rp0,2 supérieure à 200 MPa,un allongement uniforme Ag d'au moins 15 %,une striction Z d'au moins 55 % ouune perte de masse inférieure à 10 mg/cm2 dans un test de corrosion selon ASTM G67 après un précédent recuit de sensibilisation pendant 17 h à 130 °C. - Bande ou tôle en alliage d'aluminium selon l'une des revendications 6 à 11,
caractérisée en ce que
la bande en alliage d'aluminium présente une épaisseur de 0,5 à 5,0 mm, de préférence jusqu'à 3,0 mm. - Utilisation d'une bande ou tôle en alliage d'aluminium selon l'une des revendications 6 à 12 pour la fabrication d'éléments structurels ou composants du train de roulement d'un véhicule automobile.
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EP15173888 | 2015-06-25 | ||
PCT/EP2016/064530 WO2016207274A1 (fr) | 2015-06-25 | 2016-06-23 | Bande almg à haute résistance aisément façonnable et procédé de production de celle-ci |
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EP3314031A1 EP3314031A1 (fr) | 2018-05-02 |
EP3314031B1 true EP3314031B1 (fr) | 2018-11-07 |
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ID=53498817
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EP16732581.0A Active EP3314031B1 (fr) | 2015-06-25 | 2016-06-23 | Bande almg facilement déformable et très résistante et son procédé de fabrication |
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Country | Link |
---|---|
US (1) | US11352686B2 (fr) |
EP (1) | EP3314031B1 (fr) |
JP (1) | JP6481052B2 (fr) |
KR (1) | KR101911037B1 (fr) |
CN (1) | CN107787376A (fr) |
CA (1) | CA2990303C (fr) |
ES (1) | ES2700140T3 (fr) |
RU (1) | RU2685295C1 (fr) |
WO (1) | WO2016207274A1 (fr) |
Families Citing this family (19)
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KR20230098356A (ko) * | 2018-06-11 | 2023-07-03 | 노벨리스 코블렌츠 게엠베하 | 내식성이 개선된 Al-Mg-Mn 합금 판 제품의 제조 방법 |
FR3085968B1 (fr) * | 2018-09-13 | 2022-08-12 | Constellium Issoire | PRODUIT EN ALLIAGE AlMgMn A TENUE A LA CORROSION AMELIOREE |
CN109321790B (zh) * | 2018-12-06 | 2020-10-02 | 中铝瑞闽股份有限公司 | 一种土司盒用铝基材及其制备方法 |
EP3690076A1 (fr) * | 2019-01-30 | 2020-08-05 | Amag Rolling GmbH | Procédé de fabrication d'une tôle ou d'une bande d'un alliage d'aluminium ainsi que tôle, bande ou pièce moulée fabriqués selon ledit procédé |
EP3741875A1 (fr) * | 2019-05-24 | 2020-11-25 | Constellium Rolled Products Singen GmbH & Co.KG | Produit de feuille en alliage d'aluminium ayant un aspect de surface amélioré |
CN110343919A (zh) * | 2019-07-18 | 2019-10-18 | 哈尔滨理工大学 | 一种质量轻硬度大强度高的铝合金及其制备方法 |
CN111647774A (zh) * | 2020-02-17 | 2020-09-11 | 海德鲁挤压解决方案股份有限公司 | 生产耐腐蚀和耐高温材料的方法 |
RU2749101C1 (ru) * | 2020-08-07 | 2021-06-04 | Федеральное государственное бюджетное учреждение науки Самарский федеральный исследовательский центр Российской академии наук (СамНЦ РАН) | СПОСОБ ХОЛОДНОЙ МНОГОПРОХОДНОЙ ПРОКАТКИ ТОНКИХ ЛЕНТ ИЗ АЛЮМИНИЕВЫХ СПЛАВОВ Al-Mg |
CN112442617B (zh) * | 2020-11-11 | 2022-04-19 | 宁波吉顺汽车配件有限公司 | 一种汽车气门嘴变形铝合金、制备方法及应用 |
CN113403506A (zh) * | 2021-06-21 | 2021-09-17 | 安徽标兵实业有限公司 | 一种8系铝合金带材制备电池盖板用防爆片、翻转片方法 |
JP2024534911A (ja) * | 2021-09-03 | 2024-09-26 | スペイラ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 成形のために最適化されたアルミニウム合金ストリップおよび製造のための方法 |
CN113862533B (zh) * | 2021-09-30 | 2022-06-28 | 中国航发北京航空材料研究院 | 一种铝合金及其制备方法 |
CN113981282A (zh) * | 2021-10-28 | 2022-01-28 | 中铝西南铝板带有限公司 | 一种液晶背光模组背板用铝合金带材及其制备方法和应用 |
CN114438381B (zh) * | 2022-01-13 | 2023-03-24 | 河南泰鸿新材料有限公司 | 一种高强、高韧、耐腐蚀的铝合金板及其制备方法 |
CN114480928A (zh) * | 2022-01-28 | 2022-05-13 | 全良金属(苏州)有限公司 | 一种电子产品用高强铝板及其制造方法 |
CN114457265B (zh) * | 2022-01-28 | 2023-06-02 | 河南明晟新材料科技有限公司 | 一种高强度高疲劳性能6系铝合金、气瓶及其制备方法 |
CN115369293B (zh) * | 2022-04-08 | 2023-08-18 | 中铝瑞闽股份有限公司 | 一种高强度阳极氧化用Al-Mg系铝板带及其制备方法 |
CN115652152B (zh) * | 2022-11-30 | 2023-03-17 | 中铝材料应用研究院有限公司 | 可细化mig焊缝晶粒的5xxx铝合金、其制备方法及应用 |
CN116904785B (zh) * | 2023-09-13 | 2023-12-01 | 湖南卓创精材科技股份有限公司 | 一种铝镁合金镜面材料、制备方法和应用 |
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JP3103122B2 (ja) * | 1991-01-28 | 2000-10-23 | 住友軽金属工業株式会社 | 高成形性の得られる成形加工用アルミニウム合金板及びその製造方法 |
JP3241064B2 (ja) * | 1991-07-05 | 2001-12-25 | 住友軽金属工業株式会社 | 耐軟化性に優れた飲料缶蓋用アルミニウム合金硬質板の製造方法 |
JP2818721B2 (ja) * | 1992-11-12 | 1998-10-30 | 川崎製鉄株式会社 | ボディーシート用アルミニウム合金板の製造方法とこれにより得られるアルミニウム合金板 |
JP3155678B2 (ja) * | 1994-06-09 | 2001-04-16 | 古河電気工業株式会社 | 自動車ボディーシート用アルミニウム合金板の製造方法 |
FR2740144B1 (fr) * | 1995-10-18 | 1997-11-21 | Pechiney Rhenalu | Alliage almg pour constructions soudees a caracteristiques mecaniques ameliorees |
EP0799900A1 (fr) * | 1996-04-04 | 1997-10-08 | Hoogovens Aluminium Walzprodukte GmbH | Alliage d'aluminium-magnesium à haute résistance mécanique pour structures soudées de grandes dimensions |
JP4101749B2 (ja) | 2001-07-23 | 2008-06-18 | コラス・アルミニウム・バルツプロドウクテ・ゲーエムベーハー | 溶接可能な高強度Al−Mg−Si合金 |
US20070286763A1 (en) | 2004-03-31 | 2007-12-13 | Hydro Aluminium | Heat Resistant Aluminum Alloy for Heat Exchangers |
AU2008214846B2 (en) * | 2007-02-12 | 2012-05-24 | Novelis Koblenz Gmbh | Al-Mg alloy product suitable for armour plate applications |
DE102009008282A1 (de) | 2009-02-10 | 2010-08-19 | Benteler Automobiltechnik Gmbh | Verfahren zur Herstellung eines Blechformteils aus einer walzharten, nicht aushärtbaren Aluminiumlegierung |
ES2459307T3 (es) | 2011-09-15 | 2014-05-08 | Hydro Aluminium Rolled Products Gmbh | Procedimiento de producción para banda de aluminio de AlMgSi |
CN102586707B (zh) * | 2012-03-13 | 2013-10-23 | 北京工业大学 | 一种耐晶间腐蚀的高Mg含Er 铝合金冷轧板材的热处理工艺 |
JP5870791B2 (ja) * | 2012-03-21 | 2016-03-01 | 日本軽金属株式会社 | プレス成形性と形状凍結性に優れたアルミニウム合金板およびその製造方法 |
ES2613857T3 (es) | 2012-08-22 | 2017-05-26 | Hydro Aluminium Rolled Products Gmbh | Cinta de aleación de aluminio resistente a la corrosión intercristalina y procedimiento para su fabricación |
WO2014029856A1 (fr) * | 2012-08-22 | 2014-02-27 | Hydro Aluminium Rolled Products Gmbh | Bande d'almg à fort pouvoir de déformation, résistante à la corrosion intercristalline |
CN103924175B (zh) * | 2014-04-12 | 2017-01-25 | 北京工业大学 | 一种提高含Zn、Er铝镁合金耐蚀性能的稳定化热处理工艺 |
JP6689291B2 (ja) * | 2015-06-05 | 2020-04-28 | ノベリス・インコーポレイテッドNovelis Inc. | 高強度5xxxアルミニウム合金及びそれを作製する方法 |
-
2016
- 2016-06-23 JP JP2017566413A patent/JP6481052B2/ja active Active
- 2016-06-23 CN CN201680037164.9A patent/CN107787376A/zh active Pending
- 2016-06-23 CA CA2990303A patent/CA2990303C/fr not_active Expired - Fee Related
- 2016-06-23 EP EP16732581.0A patent/EP3314031B1/fr active Active
- 2016-06-23 RU RU2018102706A patent/RU2685295C1/ru not_active IP Right Cessation
- 2016-06-23 WO PCT/EP2016/064530 patent/WO2016207274A1/fr active Application Filing
- 2016-06-23 KR KR1020187002189A patent/KR101911037B1/ko active IP Right Grant
- 2016-06-23 ES ES16732581T patent/ES2700140T3/es active Active
-
2017
- 2017-12-20 US US15/849,387 patent/US11352686B2/en active Active
Non-Patent Citations (1)
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Also Published As
Publication number | Publication date |
---|---|
KR20180016608A (ko) | 2018-02-14 |
CN107787376A (zh) | 2018-03-09 |
ES2700140T3 (es) | 2019-02-14 |
CA2990303C (fr) | 2019-12-17 |
RU2685295C1 (ru) | 2019-04-17 |
KR101911037B1 (ko) | 2018-10-23 |
JP2018524468A (ja) | 2018-08-30 |
CA2990303A1 (fr) | 2016-12-29 |
WO2016207274A1 (fr) | 2016-12-29 |
JP6481052B2 (ja) | 2019-03-13 |
US20180112297A1 (en) | 2018-04-26 |
US11352686B2 (en) | 2022-06-07 |
EP3314031A1 (fr) | 2018-05-02 |
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