EP3178952B9 - Alliage d'aluminium à haute ductilité, semi-rigide destiné à la fabrication de demi-produits ou de pièces pour véhicules automobiles - Google Patents
Alliage d'aluminium à haute ductilité, semi-rigide destiné à la fabrication de demi-produits ou de pièces pour véhicules automobiles Download PDFInfo
- Publication number
- EP3178952B9 EP3178952B9 EP17151174.4A EP17151174A EP3178952B9 EP 3178952 B9 EP3178952 B9 EP 3178952B9 EP 17151174 A EP17151174 A EP 17151174A EP 3178952 B9 EP3178952 B9 EP 3178952B9
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- aluminium alloy
- components
- aluminum alloy
- rolling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000838 Al alloy Inorganic materials 0.000 title claims description 61
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 239000011265 semifinished product Substances 0.000 title claims description 12
- 238000005096 rolling process Methods 0.000 claims description 25
- 238000000137 annealing Methods 0.000 claims description 24
- 239000000956 alloy Substances 0.000 claims description 21
- 229910045601 alloy Inorganic materials 0.000 claims description 20
- 238000000265 homogenisation Methods 0.000 claims description 19
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 229910052748 manganese Inorganic materials 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000005097 cold rolling Methods 0.000 claims description 7
- 238000005266 casting Methods 0.000 claims description 6
- 238000005098 hot rolling Methods 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 238000005260 corrosion Methods 0.000 description 25
- 230000007797 corrosion Effects 0.000 description 25
- 239000011651 chromium Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910021365 Al-Mg-Si alloy Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
Definitions
- the reduction of the Cu content to a maximum of 0.05% by weight, preferably a maximum of 0.01% by weight, has a similar effect, while at the same time the tendency to filiform corrosion or intergranular corrosion due to the reduction in the Cu content generally declining.
- the homogenization at a temperature of 500 ° C. to 600 ° C. for at least 0.5 h, preferably at least 2 h ensures that a homogeneous structure is achieved the further processing of the billet is provided.
- the hot rolling temperatures enable good recrystallization during hot rolling so that the structure is as fine-grained as possible after hot rolling. This fine-grain structure is only stretched by cold rolling and recrystallized again in the final soft annealing.
- the cold rolling produces a particularly high number of dislocations in the structure, which in the final soft annealing produces a very fine-grain, fully recrystallized structure.
- the degree of rolling of the final thickness before the final soft annealing must be at least 50%, preferably at least 70% of the desired final thickness.
- the homogenization takes place in two stages, whereby the rolling billet is first heated to 550 ° C to 600 ° C for at least 0.5 h and then the rolling billet at 450 ° C to 550 ° for at least 0.5 h, preferably at least 2 h. The billet is then hot rolled.
- An aluminum alloy strip or sheet can be produced from an aluminum alloy according to the invention, the strip having a thickness of 0.2 mm to 5 mm and, in the soft-annealed state, a yield point R p0.2 of at least 45 MPa and a uniform elongation A g of at least 23% and an elongation at break A 80mm of at least 35%.
- the prerequisites are given that the aluminum alloy strip or sheet can be used for components in motor vehicles which, in addition to very good forming properties, also have very good Have resistance to intergranular corrosion or filiform corrosion. This also applies in particular to painted or coated components.
- the stated object is achieved by a structural part of a motor vehicle, in particular an inner door part of a motor vehicle, comprising at least one formed sheet metal from a Aluminum alloy according to the invention solved.
- the aluminum alloy according to the invention not only provides the required forming properties in the soft-annealed state, but also ensures the necessary corrosion resistance and strength of the structural parts at the same time.
- the structural part according to the invention is produced from a strip which has been produced using the method described. It has been shown that the forming properties as well as the strength properties of the structural part can be achieved in a process-reliable manner with the method, so that an economical production of the structural parts that meet the stated requirements is possible.
- the degree of rolling must be at least 50%, preferably at least 70%, in order to produce a sufficiently fine-grain structure during the final soft annealing.
- the final soft annealing in which the strip recrystallizes again, takes place in the chamber furnace at 300 ° C. to 400 ° C., preferably at 330 ° C. to 370 ° C. in step 10.
- inventive alloy components of Mg, Si, Fe and Mn it is used a continuous furnace for the production of the aluminum alloy strip is not possible, since other structures would be provided due to the different heating and cooling speeds.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metal Rolling (AREA)
- Continuous Casting (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Claims (7)
- Alliage d'aluminium pour la fabrication de produits semi-finis ou de pièces pour véhicules automobiles présantant des composants d'alliage en % en poids ci-dessous :0,6 % ≤ Si ≤ 0,9 %,0,6 % ≤ Fe ≤ 1,0 %,Cu ≤ 0,1 %,0,6 % ≤ Mn ≤ 0,9 %,0,5 % ≤ Mg ≤ 0,8 %,Cr ≤ 0,05 %,le reste Al et impuretés, au maximum individuellement 0,05 % en poids, au maximum au total 0,15 % en poids.
- Alliage d'aluminium selon la revendication 1,
caractérisé en ce que
les composants de l'alliage Si, Fe, Mn et Mg ont les teneurs en % en poids ci-dessous:0,7 % ≤ Si ≤ 0,9 %,0,7 % ≤ Fe ≤ 1,0 %,0,7 % ≤ Mn ≤ 0,9 % et0,6 % ≤ Mg ≤ 0,8 %. - Alliage d'aluminium selon la revendication 2,
caractérisé en ce que
les composants de l'alliage Si, Fe, Mn et Mg ont les teneurs en % en poids ci-dessous :0,7 % ≤ Si ≤ 0,8 %,0,7 % ≤ Fe ≤ 0,8 %,0,7 % ≤ Mn ≤ 0,8 % et0,6% ≤ Mg ≤ 0,7 %. - Alliage d'aluminium selon l'une des revendications 1 à 3,
caractérisé en ce que
l'alliage d'aluminium a la teneur en Cr en % en poids ci-dessous :
Cr ≤ 0,01 %. - Alliage d'aluminium selon l'une des revendications 1 à 4,
caractérisé en ce que
l'alliage d'aluminium a la teneur en Cu en % en poids ci-dessous :
Cu ≤ 0,05 %. - Élément structurel, particulièrement parte intérieure de la porte (30), d'un véhicule automobile présentant
au moins une tôle déformée fabriquée à partir d'un alliage d'aluminium selon la revendication 1 à 5. - Élément structurel selon la revendication 6,
caractérisé en ce que
la tôle est découpée dans une bande, laquelle est fabriquée avec un procédé d'une bande d'alliage d'aluminium selon les revendications 1 à 5 comprenant les étapes suivantes :- Moulage (2) d'une plaque de laminage,- Homogénéisation (4,16) à une température entre 500 °C et 600 °C pendant 0,5 h minimum,- Laminage à chaud (6) de la plaque de laminage à une température de 280 °C à 500 °C á une épaisseur de 3 mm à 12 mm,- Laminage à froid (8) avec ou sans recuit intermédiaire avec un niveau de laminage d'au moins 50 %, de préférence au moins 70 % á une épaisseur finale de 0,2 mm à 5 mm et- Recuit doux final (10) à 300 °C jusqu'à 400 °C pendant au moins 0,5 h dans un four à chambre.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP17151174.4A EP3178952B9 (fr) | 2014-03-28 | 2014-03-28 | Alliage d'aluminium à haute ductilité, semi-rigide destiné à la fabrication de demi-produits ou de pièces pour véhicules automobiles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP17151174.4A EP3178952B9 (fr) | 2014-03-28 | 2014-03-28 | Alliage d'aluminium à haute ductilité, semi-rigide destiné à la fabrication de demi-produits ou de pièces pour véhicules automobiles |
EP14162348.8A EP2924135B1 (fr) | 2014-03-28 | 2014-03-28 | Procédé pour la fabrication d'une bande d'un alliage d'aluminium à fermeté moyenne hautement déformable pour la fabrication de produits semi-finis ou de composants de véhicules automobiles |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14162348.8A Division EP2924135B1 (fr) | 2014-03-28 | 2014-03-28 | Procédé pour la fabrication d'une bande d'un alliage d'aluminium à fermeté moyenne hautement déformable pour la fabrication de produits semi-finis ou de composants de véhicules automobiles |
EP14162348.8A Division-Into EP2924135B1 (fr) | 2014-03-28 | 2014-03-28 | Procédé pour la fabrication d'une bande d'un alliage d'aluminium à fermeté moyenne hautement déformable pour la fabrication de produits semi-finis ou de composants de véhicules automobiles |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3178952A1 EP3178952A1 (fr) | 2017-06-14 |
EP3178952B1 EP3178952B1 (fr) | 2020-07-29 |
EP3178952B9 true EP3178952B9 (fr) | 2021-07-14 |
Family
ID=50478703
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14162348.8A Active EP2924135B1 (fr) | 2014-03-28 | 2014-03-28 | Procédé pour la fabrication d'une bande d'un alliage d'aluminium à fermeté moyenne hautement déformable pour la fabrication de produits semi-finis ou de composants de véhicules automobiles |
EP17151174.4A Active EP3178952B9 (fr) | 2014-03-28 | 2014-03-28 | Alliage d'aluminium à haute ductilité, semi-rigide destiné à la fabrication de demi-produits ou de pièces pour véhicules automobiles |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14162348.8A Active EP2924135B1 (fr) | 2014-03-28 | 2014-03-28 | Procédé pour la fabrication d'une bande d'un alliage d'aluminium à fermeté moyenne hautement déformable pour la fabrication de produits semi-finis ou de composants de véhicules automobiles |
Country Status (10)
Country | Link |
---|---|
US (1) | US10047424B2 (fr) |
EP (2) | EP2924135B1 (fr) |
JP (1) | JP6279761B2 (fr) |
KR (2) | KR101808812B1 (fr) |
CN (1) | CN106164311A (fr) |
CA (1) | CA2944061C (fr) |
ES (1) | ES2655434T3 (fr) |
PT (1) | PT2924135T (fr) |
RU (1) | RU2655510C2 (fr) |
WO (1) | WO2015144888A2 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116145057A (zh) * | 2023-03-20 | 2023-05-23 | 山东南山铝业股份有限公司 | 一种6系铝合金板材均匀化工艺方法及该工艺方法在铝合金板材生产中的应用 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07252611A (ja) * | 1994-03-17 | 1995-10-03 | Kobe Steel Ltd | 成形加工用Al−Mn−Mg系合金板 |
JP2002275566A (ja) * | 2001-03-21 | 2002-09-25 | Kobe Steel Ltd | プレス成形性に優れたAl−Mn系合金板 |
JP4703033B2 (ja) * | 2001-05-21 | 2011-06-15 | 三菱樹脂株式会社 | ダイカスト用アルミニウム合金材 |
DE60203801T2 (de) * | 2001-07-09 | 2006-05-18 | Corus Aluminium Walzprodukte Gmbh | Schweißbare hochfeste Al-Mg-Si-Legierung |
RU2221891C1 (ru) * | 2002-04-23 | 2004-01-20 | Региональный общественный фонд содействия защите интеллектуальной собственности | Сплав на основе алюминия, изделие из этого сплава и способ изготовления изделия |
US20060032560A1 (en) * | 2003-10-29 | 2006-02-16 | Corus Aluminium Walzprodukte Gmbh | Method for producing a high damage tolerant aluminium alloy |
JP2006152359A (ja) * | 2004-11-29 | 2006-06-15 | Furukawa Sky Kk | ボトル缶用アルミニウム合金板およびその製造方法 |
JP4916333B2 (ja) * | 2006-03-13 | 2012-04-11 | 住友軽金属工業株式会社 | 強度とろう付け性に優れた熱交換器用アルミニウム合金クラッド材 |
JP2008231475A (ja) * | 2007-03-19 | 2008-10-02 | Furukawa Sky Kk | 成形加工用アルミニウム合金板およびその製造方法 |
JP4312819B2 (ja) * | 2008-01-22 | 2009-08-12 | 株式会社神戸製鋼所 | 成形時のリジングマーク性に優れたアルミニウム合金板 |
DK2527479T3 (da) * | 2011-05-27 | 2014-05-05 | Hydro Aluminium Rolled Prod | Højtledende aluminiumlegering til elektrisk ledende produkter |
JP6227222B2 (ja) * | 2012-02-16 | 2017-11-08 | 株式会社神戸製鋼所 | 焼付け塗装硬化性に優れたアルミニウム合金板 |
JP5379883B2 (ja) * | 2012-05-11 | 2013-12-25 | 株式会社神戸製鋼所 | アルミニウム合金板およびその製造方法 |
EP2770071B9 (fr) | 2013-02-21 | 2020-08-12 | Hydro Aluminium Rolled Products GmbH | Alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles, procédé de fabrication d'une bande d'alliage en aluminium à partir de cet alliage en aluminium ainsi que la bande d'alliage en aluminium et utilisations de celui-ci |
CA2912021C (fr) | 2013-06-19 | 2020-05-05 | Rio Tinto Alcan International Limited | Composition d'alliage d'aluminium presentant des proprietes mecaniques ameliorees, a temperature elevee |
-
2014
- 2014-03-28 EP EP14162348.8A patent/EP2924135B1/fr active Active
- 2014-03-28 EP EP17151174.4A patent/EP3178952B9/fr active Active
- 2014-03-28 PT PT141623488T patent/PT2924135T/pt unknown
- 2014-03-28 ES ES14162348.8T patent/ES2655434T3/es active Active
-
2015
- 2015-03-27 KR KR1020167030120A patent/KR101808812B1/ko active IP Right Grant
- 2015-03-27 RU RU2016142403A patent/RU2655510C2/ru active
- 2015-03-27 KR KR1020177030782A patent/KR20170121336A/ko not_active Application Discontinuation
- 2015-03-27 CN CN201580017129.6A patent/CN106164311A/zh active Pending
- 2015-03-27 WO PCT/EP2015/056733 patent/WO2015144888A2/fr active Application Filing
- 2015-03-27 CA CA2944061A patent/CA2944061C/fr active Active
- 2015-03-27 JP JP2016559550A patent/JP6279761B2/ja active Active
-
2016
- 2016-09-20 US US15/270,601 patent/US10047424B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
RU2016142403A (ru) | 2018-04-28 |
US20170009323A1 (en) | 2017-01-12 |
EP2924135A1 (fr) | 2015-09-30 |
ES2655434T3 (es) | 2018-02-20 |
CN106164311A (zh) | 2016-11-23 |
JP6279761B2 (ja) | 2018-02-14 |
KR20160132119A (ko) | 2016-11-16 |
EP3178952B1 (fr) | 2020-07-29 |
EP3178952A1 (fr) | 2017-06-14 |
WO2015144888A3 (fr) | 2016-01-07 |
EP2924135B1 (fr) | 2017-12-13 |
US10047424B2 (en) | 2018-08-14 |
PT2924135T (pt) | 2018-02-09 |
CA2944061C (fr) | 2019-10-22 |
WO2015144888A2 (fr) | 2015-10-01 |
RU2655510C2 (ru) | 2018-05-28 |
KR20170121336A (ko) | 2017-11-01 |
JP2017514014A (ja) | 2017-06-01 |
CA2944061A1 (fr) | 2015-10-01 |
KR101808812B1 (ko) | 2017-12-13 |
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