EP2770071B2 - Alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles, procédé de fabrication d'une bande d'alliage en aluminium à partir de cet alliage en aluminium ainsi que la bande d'alliage en aluminium et utilisations de celui-ci - Google Patents
Alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles, procédé de fabrication d'une bande d'alliage en aluminium à partir de cet alliage en aluminium ainsi que la bande d'alliage en aluminium et utilisations de celui-ci Download PDFInfo
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- EP2770071B2 EP2770071B2 EP13156100.3A EP13156100A EP2770071B2 EP 2770071 B2 EP2770071 B2 EP 2770071B2 EP 13156100 A EP13156100 A EP 13156100A EP 2770071 B2 EP2770071 B2 EP 2770071B2
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- aluminium alloy
- weight
- aluminum alloy
- alloy strip
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- 229910000838 Al alloy Inorganic materials 0.000 title claims description 153
- 239000011265 semifinished product Substances 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 25
- 229910052802 copper Inorganic materials 0.000 claims description 23
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000005275 alloying Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 description 40
- 230000007797 corrosion Effects 0.000 description 40
- 229910045601 alloy Inorganic materials 0.000 description 39
- 239000000956 alloy Substances 0.000 description 39
- 238000000137 annealing Methods 0.000 description 29
- 239000011777 magnesium Substances 0.000 description 29
- 239000010949 copper Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 27
- 238000000265 homogenisation Methods 0.000 description 25
- 238000005097 cold rolling Methods 0.000 description 18
- 238000005096 rolling process Methods 0.000 description 17
- 239000000463 material Substances 0.000 description 15
- 239000010936 titanium Substances 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- 238000005266 casting Methods 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 238000005098 hot rolling Methods 0.000 description 6
- 238000009864 tensile test Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 238000009749 continuous casting Methods 0.000 description 4
- 238000009533 lab test Methods 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D7/00—Casting ingots, e.g. from ferrous metals
- B22D7/005—Casting ingots, e.g. from ferrous metals from non-ferrous metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
Definitions
- the invention relates to an aluminum alloy strip and uses therefor.
- Semi-finished products and components for motor vehicles have to meet different requirements depending on their location and intended use in the motor vehicle, in particular with regard to their mechanical properties and their corrosion properties.
- the mechanical properties are predominantly determined, for example, by the rigidity, which depends in particular on the shape of these parts.
- the strength has a minor influence, although the materials used must not be too soft.
- Good formability is very important, since the components and semi-finished products generally go through complex forming processes, for example in the manufacture of door interior parts. This applies in particular to components that are manufactured in a one-piece sheet metal shell construction, e.g. a sheet metal inner door with integrated window frame area. By saving joining operations, such components have cost advantages compared to an attached profile solution for the window frame.
- corrosion resistance also plays a major role in motor vehicles, since motor vehicle components such as door interior parts are exposed to splash water, condensation water or condensation water. It is therefore desirable that the motor vehicle components have good resistance to various corrosion attacks, in particular to intergranular corrosion and to filiform corrosion.
- Filiform corrosion means a type of corrosion that occurs in coated components and shows a thread-like course. Filiform corrosion occurs in high humidity in the presence of chloride ions.
- Hardenable AA 6xxx alloys have high strengths as well as good resistance to intergranular corrosion and filiform corrosion, but are much more difficult to form than AA 8006 and are therefore not particularly suitable for the production of complex components such as door parts.
- the production of semi-finished products and components from an AA 6xxx alloy is quite complex and expensive, since it requires continuous annealing as a special process step.
- AA 5xxx alloys with a high magnesium content combine high strength with quite good formability.
- the formability is not as good as that of steel solutions, which leads to restrictions in the design of the components.
- these alloys tend to intergranular corrosion.
- Steel materials are very easy to form, but have the same rigidity and a weight disadvantage and are also prone to corrosion.
- the present invention is based on the object of providing an aluminum alloy strip which is highly malleable, medium-strength and corrosion-resistant. Should continue advantageous uses for the tape are provided. This object is achieved with an aluminum alloy strip and a use of the strip with the features of claims 1 or 8 and 9.
- the aforementioned object is achieved according to the invention in that the alloy components of the aluminum alloy have the following proportions in percent by weight: Fe ⁇ 0.80%, Si ⁇ 0.50%, 0.90% ⁇ Mn ⁇ 1.50%, Mg ⁇ 0.25%, Cu ⁇ 0.20%, Cr ⁇ 0.05%, Ti ⁇ 0.05%, V ⁇ 0.05%, Zr ⁇ 0.05%,
- the aluminum alloy of the aluminum alloy strip according to the invention is based on the alloy type AA 3xxx, in particular AA 3103 (AlMn1). Such alloys have a very good formability, but are usually too soft for many applications such as components of motor vehicles.
- the addition of certain alloying elements, in particular Mg and Cu, can increase the strength of the aluminum alloy, but this also leads to a significant reduction in ductility and thus in turn to poorer formability.
- the combined proportion of copper and magnesium in the aluminum alloy of the aluminum alloy strip according to the invention must be precisely controlled in order to achieve the desired mechanical properties, namely an elastic limit R p0.2 of at least 45 MPa with a uniform expansion A g of at least 23% and an elongation at break A 80mm of at least 30%, with good corrosion resistance.
- an elastic limit R p0.2 of at least 45 MPa with a uniform expansion A g of at least 23% and an elongation at break A 80mm of at least 30%
- a combination of Mg and Cu between 0.15 and 0.25% by weight achieves a combination of strength and formability of the aluminum alloy that is advantageous for the applications mentioned.
- the combined proportion of magnesium and copper must be at least 0.17% by weight so that the aluminum alloy of the aluminum alloy strip according to the invention achieves sufficient strength, in particular with an elastic limit R p0.2 of at least 45 MPa.
- the combined proportion of Mg and Cu must be limited to at most 0.25% by weight, preferably at most 0.23% by weight, in particular at most 0.20% by weight, since otherwise uniform expansion A g and elongation at break A 80 mm fall too much, namely below 23% for A g or below 30% for A 80mm .
- the combined proportion of magnesium and copper is generally understood to mean the sum of the two individual proportions for Mg and Cu in% by weight.
- the aluminum alloy of the aluminum alloy strip according to the invention has a Cu content of at most 0.20% by weight, preferably at most 0.10% by weight, in particular at most 0.05% by weight, and a magnesium Proportion of at most 0.25% by weight, preferably at most 0.2% by weight. Furthermore, the aluminum alloy preferably has a Mg content of at least 0.06% by weight, more preferably of at least 0.10% by weight, in particular of at least 0.15% by weight.
- the previously described aluminum alloy of the aluminum alloy strip according to the invention has proven to be highly malleable and medium-strength in tests.
- the aluminum alloy can be used particularly well for semi-finished products and components of motor vehicles, the production of which comprises complex forming processes.
- With the aluminum alloy it is sometimes even possible to achieve such a good formability that semi-finished products and components made from the alloy can be formed on forming tools for steel components.
- the aluminum alloy of the aluminum alloy strip according to the invention has good corrosion resistance. In particular, no intercrystalline corrosion occurs with AA 3xxx alloys, to which the above-mentioned alloy belongs. Furthermore, the aluminum alloy of the aluminum alloy strip according to the invention showed in laboratory tests a considerably better resistance to filiform corrosion than, for example, AA 8006 alloys.
- the elements titanium, chromium, vanadium and in particular zircon can hinder the recrystallization during the final annealing and thus impair the formability of the aluminum alloy of the aluminum alloy strip according to the invention.
- the aluminum alloy of the aluminum alloy strip according to the invention therefore has Ti, Cr, V and Zr portions of at most 0.05% by weight and preferably in particular a Zr portion of at most 0.02% by weight. -% on.
- the proportions of all other inevitable accompanying elements are individually less than 0.05% by weight and together less than 0.15% by weight, so that they do not cause any undesirable phase formation and / or negative influences on the material properties.
- the Mg content of the aluminum alloy of the aluminum alloy strip according to the invention is greater than the Cu content of the aluminum alloy. In this way, the corrosion behavior of the aluminum alloy of the aluminum alloy strip according to the invention, in particular with regard to filiform corrosion, can be further improved.
- the formability of the aluminum alloy of the aluminum alloy strip according to the invention is further improved in a further embodiment in that the aluminum alloy has a Cr content ⁇ 0.02% by weight, preferably ⁇ 0.01% by weight, and / or a V content ⁇ 0.02 wt .-%, preferably ⁇ 0.01 wt .-%, and / or a Zr content ⁇ 0.01 wt .-%.
- Titanium can be added during the continuous casting of the aluminum alloy of the aluminum alloy strip according to the invention as a grain refining agent, for example in the form of Ti boride wire or rods.
- the aluminum alloy therefore has a Ti content of at least 0.01% by weight, preferably of at least 0.015% by weight, in particular of at least 0.02% by weight.
- the material properties of the aluminum alloy of the aluminum alloy strip according to the invention can be improved in that the aluminum alloy has an Fe content of ⁇ 0.7% by weight, preferably ⁇ 0.6% by weight, in particular ⁇ 0.5% by weight. %, having.
- the further limitation of the Fe content prevents the susceptibility of the aluminum alloy of the aluminum alloy strip according to the invention to filiform corrosion.
- the aluminum alloy of the aluminum alloy strip according to the invention preferably has a Si content of 0,4 0.4% by weight, preferably ⁇ 0.3% by weight, in particular ⁇ 0.25% by weight.
- the further restriction of the Si content can prevent the formability from being reduced too much.
- the aluminum alloy of the aluminum alloy strip according to the invention further preferably has an Fe content of at least 0.10% by weight, preferably at least 0.25% by weight, in particular at least 0.40% by weight, and / or Si content of at least 0.06% by weight, preferably at least 0.10% by weight, in particular at least 0.15% by weight.
- the alloy components of the aluminum alloy have the following proportions in percent by weight: 0.40% ⁇ Fe ⁇ 0.70%, 0.10% ⁇ Si ⁇ 0.25%, 1.00% ⁇ Mn ⁇ 1.20%, Mg ⁇ 0.25%, Cu ⁇ 0.10%, Cr ⁇ 0.02%, Ti ⁇ 0.05%, V ⁇ 0.05%, Zr ⁇ 0.05%,
- the formability of this alloy can be improved in that the alloy has a V content 0,0 0.02% by weight and / or a Zr content ⁇ 0.01% by weight. Grain refinement can also be improved by a Ti content of at least 0.01% by weight.
- the alloy components of the aluminum alloy have the following proportions in percent by weight: 0.40% ⁇ Fe ⁇ 0.70%, 0.10% ⁇ Si ⁇ 0.25%, 1.00% ⁇ Mn ⁇ 1.20%, Mg ⁇ 0.20%, Cu ⁇ 0.05%, Cr ⁇ 0.02%, Ti ⁇ 0.05%, V ⁇ 0.05%, Zr ⁇ 0.05%,
- the formability of this alloy can be improved in that the alloy has a V content 0,0 0.02% by weight and / or a Zr content ⁇ 0.01% by weight. Grain refinement can also be improved by a Ti content of at least 0.01% by weight.
- this process can be used to produce an aluminum alloy strip that is highly malleable, medium-strength and corrosion-resistant, especially against intergranular corrosion and filiform corrosion. Furthermore, this process allows the aluminum alloy strip to be produced economically, since the process comprises standard process steps (i.e. continuous casting, homogenizing, hot rolling, cold rolling, soft annealing) and does not necessarily require special, complex process steps such as continuous strip annealing.
- the rolling ingot is preferably cast in DC continuous casting. Alternatively, however, a strip casting process can also be used, for example.
- the billet By homogenizing the billet at 480 ° C to 600 ° C, preferably at 500 ° C to 600 ° C, in particular at 530 ° C to 580 ° C, for at least 0.5 h, it is achieved that the aluminum alloy strip after the final annealing has fine-grained structure with good strength and formability. These properties can be further improved by homogenizing the billet for at least 2 hours.
- the hot rolling of the rolled ingot takes place at a temperature between 280 ° C. and 500 ° C., preferably between 300 ° C. and 400 ° C., in particular between 320 ° C. and 380 ° C.
- the billet is preferably rolled down to a thickness between 3 and 12 mm. This ensures that a sufficiently high degree of rolling, preferably at least 70%, in particular at least 80%, is achieved in the subsequent cold rolling, by means of which the strength, formability and elongation values of the aluminum alloy strip are also determined.
- the cold rolling of the aluminum alloy strip can be done in one or more passes.
- the aluminum alloy strip is preferably rolled to a final thickness in the range from 0.2 to 5 mm, preferably from 0.25 to 4 mm, in particular from 0.5 to 3.6 mm.
- the desired material properties of the aluminum alloy strip can be achieved particularly well in these thickness ranges.
- the final annealing of the aluminum strip enables a fine-grained, crystallized structure with good strength and formability to be achieved.
- the final annealing is therefore a recrystallizing soft annealing.
- the final annealing can take place in particular in a chamber furnace at 300 ° C. to 400 ° C., preferably at 320 ° C. to 360 ° C. or in a continuous furnace at 450 ° C. to 550 ° C., preferably at 470 ° C. to 530 ° C.
- the chamber furnace is less expensive to operate and purchase than the continuous furnace.
- the final annealing time in the chamber furnace is typically 1 hour or more.
- This process step can improve the corrosion properties of the aluminum alloy strip produced or of an end product produced from this aluminum alloy strip.
- the milling of the top and / or bottom of the roll ingot can be carried out, for example, after casting and before homogenizing the roll ingot.
- the at least two-stage homogenization enables a fine-grained structure with good strength and formability to be achieved after the final annealing. It has been shown that in this way, after the final annealing, in particular grain sizes, determined according to ASTM E1382, of less than 45 ⁇ m, in particular even less than 35 ⁇ m, can be achieved.
- the second homogenization is preferably carried out at the hot rolling temperature which the rolling bar has at the beginning of the subsequent hot rolling step.
- the upper and / or lower side of the roll ingot can be milled between the first homogenization and the second homogenization, particularly preferably after the roll ingot has cooled to room temperature.
- the degree of rolling during cold rolling is at least 70%, preferably at least 80%. Due to this minimum degree of rolling, a fine-grained structure with good strength and formability can be achieved with the aluminum alloy strip after the final annealing.
- the degree of rolling during cold rolling is a maximum of 90%, preferably a maximum of 85%. This maximum degree of rolling can prevent an excessive decrease in the elongation values of the aluminum alloy strip.
- the method can be carried out particularly economically in that the cold rolling is carried out without intermediate annealing. It has been found that the desired properties of the aluminum alloy strip can also be achieved without intermediate annealing. In the production of the aluminum alloy strip, there is preferably also no complex and expensive continuous strip annealing.
- the aluminum alloy strip is annealed between two cold rolling passes, in particular between the penultimate and the last cold rolling pass, in particular at one temperature from 300 ° C to 400 ° C, preferably at a temperature of 330 ° C to 370 ° C.
- the intermediate annealing can take place, for example, in a chamber furnace.
- the intermediate annealing is in particular an intermediate soft annealing of the strip.
- the intermediate annealing is preferably carried out when the degree of rolling during cold rolling is more than 85%, in particular more than 90%.
- the cold rolling and the intermediate annealing are then preferably carried out such that the degree of rolling after the intermediate annealing is less than 90%, in particular less than 85%.
- the degree of rolling after the intermediate annealing is particularly preferably between 70% and 90%, in particular between 80% and 85%.
- the object described above is achieved according to the invention in the case of an aluminum alloy strip, which is preferably produced using one of the methods described above , in that the aluminum alloy strip consists of the alloy described above and an elastic limit R p0.2 of at least 45 MPa, a uniform expansion A g of has at least 23% and an elongation at break A 80mm of at least 30%.
- an aluminum alloy strip according to the invention can be produced with the alloy described and in particular also by the method described above, which has the material properties mentioned above and also has good corrosion resistance to intergranular corrosion and filiform corrosion.
- the aluminum alloy strip according to the invention is therefore particularly well suited for components and semi-finished products for motor vehicles, in particular for coated components such as interior door components.
- the proof stress R p0.2 is determined according to DIN EN ISO 6892-1: 2009.
- the uniform elongation A g and the elongation A 80mm are also determined according to DIN EN ISO 6892-1: 2009 with a flat tensile test according to DIN EN ISO 6892-1: 2009, Appendix B, Form 2.
- the aluminum alloy strip has a thickness in the range from 0.2 to 5 mm, preferably from 0.25 to 4 mm, in particular from 0.5 to 3.6 mm.
- the desired material properties of the aluminum alloy strip can be achieved particularly well in these thickness ranges.
- the object described above is further achieved by the use of the aluminum alloy strip according to the invention described above for semi-finished products or components for motor vehicles, in particular for coated components for motor vehicles. It has been found that material properties which are particularly advantageous for these uses can be achieved with the aluminum alloy strip according to the invention. According to one embodiment, the aluminum alloy strip can be used particularly advantageously for interior door components of a motor vehicle.
- the object described above is further achieved by the use of a sheet made from an aluminum alloy strip according to the invention as a component in the motor vehicle.
- a sheet made from an aluminum alloy strip according to the invention as a component in the motor vehicle.
- the material properties of the aluminum alloy strip and thus also the material properties of a sheet made from it are particularly suitable for use in a motor vehicle, especially as an inner door sheet.
- the sheet metal produced from the aluminum alloy strip according to the invention is particularly preferably used for coated, in particular painted, components of a motor vehicle.
- Fig. 1 shows a flow chart for a first embodiment of the method for producing an aluminum alloy strip according to the invention.
- a billet is first cast from an aluminum alloy.
- the casting can take place, for example, in DC continuous casting or in strip casting.
- the billet is homogenized in step 4 at a temperature in the range from 480 ° C to 600 ° C for at least 0.5 h.
- the billet is then hot-rolled to a final thickness between 3 and 12 mm at a temperature in the range from 280 ° C to 500 ° C.
- the hot strip hot-rolled from the rolled bar is then cold-rolled in step 8 to a final thickness of preferably 0.2 mm to 5 mm.
- the aluminum alloy strip is finally annealed, for example in a chamber furnace at a temperature between 300 ° C and 400 ° C or in a continuous furnace between 450 ° C and 550 ° C.
- the top and / or bottom of the billet can optionally be milled in a step 12.
- the aluminum alloy strip can optionally be annealed in a step 14, preferably in a chamber furnace at a temperature between 300 ° C. and 400 ° C.
- the intermediate annealing is particularly suitable for improving the material properties of the aluminum alloy strip if the hot strip is relatively thick and therefore the degree of rolling in cold rolling is more than 85% overall, in particular more than 90%.
- the intermediate annealing is preferably carried out before the last cold rolling pass.
- the degree of rolling during cold rolling is, for example, a total of approximately 96.7%.
- the hot strip can first be rolled to 2 mm in a first cold rolling pass, then annealed and finally rolled to 0.4 mm in a second cold rolling pass.
- the degree of rolling after the intermediate annealing is then only 80% and is therefore in a preferred range.
- Figure 2 shows a part of a flow chart for further exemplary embodiments of the method.
- the process sequence of these exemplary embodiments essentially agrees with the process sequence with reference to Figure 1 described method.
- the homogenization of the billet takes place in the exemplary embodiments Figure 2 however, not in step 4, but in a step 16, which is divided into several individual steps.
- Figure 2 shows possible sequences of the individual steps of step 16.
- a first homogenization at a temperature between 550 and 600 ° C. for at least 0.5 h, preferably for at least 2 h.
- the billet is cooled to the temperature of the second homogenization in the range from 450 ° C. and 550 ° C., before the second homogenization at this temperature in turn in the subsequent step 22 for at least 0.5 h, preferably for at least 2 h, is done.
- the billet can also be cooled to room temperature in a step 24 and warmed to the temperature for the second homogenization in a subsequent step 26.
- the top and / or bottom of the roll bar can optionally be milled.
- aluminum alloys of the AA 3xxx type in particular based on AA 3103, with different Mg and Cu contents were produced.
- the alloy compositions of these aluminum alloys are compiled in Table 1 below, the individual alloy proportions each being given in% by weight. Table 1 No.
- Alloys Nos. 5-7 are exemplary embodiments of the strips according to the invention made of alloy (E), while alloys Nos. 1-4 and 8-11 are comparative examples (V).
- Aluminum alloy strips were then made from these aluminum alloys Nos. 1-11 using the previously described process. Specifically, each of these alloys 1 to 11 was cast in a DC ingot with a thickness of 600 mm, which was then homogenized in two stages, first for several hours at approx. 580 ° C and then for several hours approx. 500 ° C. After homogenization, the rolled bars were hot-rolled at about 500 ° C. to form aluminum alloy hot strips with a thickness of 4 to 8 mm. These aluminum alloy hot strips were then cold rolled to a final thickness of 1.2 mm and finally subjected to a recrystallizing final annealing at 350 ° C. for 1 h.
- the aluminum alloy strips were then examined for their mechanical properties, in particular for their strength and formability.
- Table 2 also shows in the last line the corresponding material properties of an alloy of the type AA 8006, as is known from the prior art.
- the good formability is particularly evident from the measured cupping value, which in the aluminum alloy strips according to the invention preferably has a value SZ 32 15 15.8 mm, in particular hearing 15.9 mm.
- the aluminum alloy tapes No. 5 - 7 have the same strength only a slightly poorer formability than the comparison alloy AA 8006.
- the aluminum alloy tapes No. 5 - 7 have the advantage over the alloy AA 8006 that they are considerably better Have corrosion resistance. In principle, intergranular corrosion does not occur with AA 3xxx alloys.
- Table 2 show that the exemplary embodiments for the aluminum alloy strips according to the invention also achieve good values for the tensile strength R m and for the n and r values, which are in particular within the scope of conventional AA 3xxx alloys or are even better.
- Figure 4 shows a schematic representation of a typical component of a motor vehicle in the form of an inner door part.
- Such inner door parts 40 are usually made of steel. However, steel components are heavy and prone to corrosion with the same rigidity.
- aluminum alloys described above such as aluminum alloys No. 5-7, can be used to produce aluminum alloy strips which are highly formable, medium-strength and very corrosion-resistant, in particular against intergranular corrosion and also against filiform corrosion.
- the material properties of these aluminum alloy strips or the sheets produced from them are therefore particularly favorable for the production of motor vehicle components, such as the door inner part 40.
- the good resistance to filiform corrosion is particularly evident when using the aluminum alloys for coated, in particular painted, components such as the inner door part 40, advantageous.
- the components made from these aluminum alloy strips have better corrosion resistance than corresponding components made from steel or from an alloy of type AA 8006. At the same time, they have a significantly lower weight than components made from steel.
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Claims (9)
- Bande en alliage d'aluminium caractérisé en ce que la bande en alliage d'aluminium est constitué d'un alliage d'aluminium, où les éléments de l'alliage d'aluminium présentent les parts suivantes en % en poids:
Fe ≤ 0,80 %, Si ≤ 0,50 %, 0,90 % ≤ Mn ≤ 1,50 %, Mg ≤ 0,25 %, Cu ≤ 0,20 %, Cr ≤ 0,05 %, Ti ≤ 0,05 %, V ≤ 0,05 %, Zr ≤ 0,05 %,
et la part combinée de Mg et de Cu satisfait à l'équation suivante: - Bande en alliage d'aluminium selon la revendication 1, caractérisé en ce que la bande en alliage d'aluminium présente une épaisseur de l'ordre de 0,2 mm à 5 mm.
- Bande en alliage d'aluminium selon la revendication 1 ou 2, caractérisé en ce que l'alliage d'aluminium comporte une part en Cu d'un maximum de 0,10 % en poids et/ou une part en Mg de 0,06 % en poids à 0,20 % en poids.
- Bande en alliage d'aluminium selon l'une quelconque des revendications 1 à 3, caractérisé en ce que la part en Mg de l'alliage d'aluminium est supérieure à la part en Cu de l'alliage d'aluminium.
- Bande en alliage d'aluminium selon l'une quelconque des revendications 1 à 4, caractérisé en ce que l'alliage d'aluminium comporte une part en Cr ≤ 0,02 % en poids et/ou une part en V ≤ 0,02 % en poids et/ou une part en Zr ≤ 0,02 % en poids, notamment ≤ 0,01 % en poids.
- Bande en alliage d'aluminium selon l'une quelconque des revendications 1 à 5, caractérisé en ce que l'alliage d'aluminium comporte une part en Fe de 0,4 à 0,7 % en poids et/ou une part en Si de 0,1 à 0,25 % en poids et/ou une part en Mn de 1,0 à 1,2 % en poids.
- Bande en alliage d'aluminium selon l'une quelconque des revendications 1 à 6, caractérisé en ce que l'alliage d'aluminium comporte une part en Ti d'au moins 0,01 % en poids.
- Utilisation d'une bande en alliage d'aluminium selon l'une quelconque des revendications 1 à 7 pour des produits semi-finis ou d'éléments constitutifs de véhicules, notamment pour des éléments d'intérieur de portière.
- Utilisation d'une tôle, fabriquée en une bande en alliage d'aluminium selon l'une quelconque des revendications 1 à 7 en tant qu'élément dans le véhicule automobile, notamment en tant que tôle d'intérieur de portière.
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES13156100.3T ES2621871T3 (es) | 2013-02-21 | 2013-02-21 | Aleación de aluminio para la fabricación de productos semiacabados o componentes para automóviles, procedimiento para la fabricación de una cinta de aleación de aluminio de esta aleación de aluminio así como cinta de aleación de aluminio y usos de la misma |
EP13156100.3A EP2770071B9 (fr) | 2013-02-21 | 2013-02-21 | Alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles, procédé de fabrication d'une bande d'alliage en aluminium à partir de cet alliage en aluminium ainsi que la bande d'alliage en aluminium et utilisations de celui-ci |
PT131561003T PT2770071T (pt) | 2013-02-21 | 2013-02-21 | Liga de alumínio para a produção de produtos semiacabados ou componentes para automóveis, procedimento para a produção de uma tira de alumínio a partir dessa liga de alumínio bem como tira de liga de alumínio e utilizações da mesma |
CA2899991A CA2899991C (fr) | 2013-02-21 | 2014-02-20 | Alliage d'aluminium servant a fabriquer des demi-produits ou des composants de vehicules a moteur, procede de fabrication d'un feuillard a partir de cet alliage d'aluminium, ainsique feuillard d'alliage d'aluminium et son utilisation |
RU2015139899A RU2637458C2 (ru) | 2013-02-21 | 2014-02-20 | Алюминиевый сплав для изготовления полуфабрикатов или деталей автомобилей, способ изготовления полосы алюминиевого сплава из указанного алюминиевого сплава, полоса алюминиевого сплава и ее применение |
ES14705528T ES2590779T5 (es) | 2013-02-21 | 2014-02-20 | Uso de una aleación de aluminio para la fabricación de productos semiacabados o componentes para automóviles |
PCT/EP2014/053323 WO2014128212A1 (fr) | 2013-02-21 | 2014-02-20 | Alliage d'aluminium servant à fabriquer des demi-produits ou des composants de véhicules à moteur, procédé de fabrication d'un feuillard à partir de cet alliage d'aluminium, ainsi que feuillard d'alliage d'aluminium et son utilisation |
KR1020157025451A KR101656419B1 (ko) | 2013-02-21 | 2014-02-20 | 차량용 반제품 또는 부품을 제조하기 위한 알루미늄 합금, 알루미늄 합금으로 구성된 알루미늄 합금 스트립 제조 방법, 알루미늄 합금 스트립 및 그 용도 |
JP2015558448A JP6143892B2 (ja) | 2013-02-21 | 2014-02-20 | 自動車用半製品又は部品を製造するためのアルミニウム合金、アルミニウム合金薄板を前記アルミニウム合金から製造する方法、並びにアルミニウム合金薄板及びそのための使用 |
CN201480009934.XA CN105008563B (zh) | 2013-02-21 | 2014-02-20 | 用于制造汽车半成品或构件的铝合金、由其制造铝合金带的方法以及铝合金带及其应用 |
EP14705528.9A EP2959028B2 (fr) | 2013-02-21 | 2014-02-20 | Utilisation d'un alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles |
PT147055289T PT2959028T (pt) | 2013-02-21 | 2014-02-20 | Liga de alumínio para a produção de produtos semiacabados ou componentes para automóveis, procedimento para a produção de uma tira de alumínio a partir desta liga de alumínio bem como tira de liga de alumínio e utilização da mesma |
US14/826,244 US10501833B2 (en) | 2013-02-21 | 2015-08-14 | Aluminum alloy for producing semi-finished products or components for motor vehicles, method for producing an aluminium alloy strip from said aluminium alloy, and aluminium alloy strip and uses therefore |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13156100.3A EP2770071B9 (fr) | 2013-02-21 | 2013-02-21 | Alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles, procédé de fabrication d'une bande d'alliage en aluminium à partir de cet alliage en aluminium ainsi que la bande d'alliage en aluminium et utilisations de celui-ci |
Publications (4)
Publication Number | Publication Date |
---|---|
EP2770071A1 EP2770071A1 (fr) | 2014-08-27 |
EP2770071B1 EP2770071B1 (fr) | 2017-02-01 |
EP2770071B2 true EP2770071B2 (fr) | 2020-04-01 |
EP2770071B9 EP2770071B9 (fr) | 2020-08-12 |
Family
ID=47739152
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EP13156100.3A Active EP2770071B9 (fr) | 2013-02-21 | 2013-02-21 | Alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles, procédé de fabrication d'une bande d'alliage en aluminium à partir de cet alliage en aluminium ainsi que la bande d'alliage en aluminium et utilisations de celui-ci |
EP14705528.9A Active EP2959028B2 (fr) | 2013-02-21 | 2014-02-20 | Utilisation d'un alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles |
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Application Number | Title | Priority Date | Filing Date |
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EP14705528.9A Active EP2959028B2 (fr) | 2013-02-21 | 2014-02-20 | Utilisation d'un alliage en aluminium pour la fabrication de demi-produits ou de composants pour véhicules automobiles |
Country Status (10)
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---|---|
US (1) | US10501833B2 (fr) |
EP (2) | EP2770071B9 (fr) |
JP (1) | JP6143892B2 (fr) |
KR (1) | KR101656419B1 (fr) |
CN (1) | CN105008563B (fr) |
CA (1) | CA2899991C (fr) |
ES (2) | ES2621871T3 (fr) |
PT (2) | PT2770071T (fr) |
RU (1) | RU2637458C2 (fr) |
WO (1) | WO2014128212A1 (fr) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3008427B1 (fr) * | 2013-07-11 | 2015-08-21 | Constellium France | Tole en alliage d'aluminium pour structure de caisse automobile |
ES2655434T3 (es) | 2014-03-28 | 2018-02-20 | Hydro Aluminium Rolled Products Gmbh | Procedimiento para la fabricación de una cinta de una aleación de aluminio altamente conformable y de resistencia media para productos semiacabados o componentes de automóviles |
CN105593392B (zh) * | 2014-04-09 | 2017-08-29 | 日本轻金属株式会社 | 弯曲加工性与形状冻结性优良的高强度铝合金板及其制造方法 |
CA2959416C (fr) | 2014-09-12 | 2020-07-07 | Novelis Inc. | Alliages pour des produits en aluminium tres faconnes et leurs procedes de fabrication |
CN104264009B (zh) * | 2014-09-30 | 2016-11-23 | 国网河南省电力公司周口供电公司 | 一种高铁铝合金导体材料及其退火工艺 |
EP3026134B2 (fr) | 2014-11-27 | 2022-01-12 | Speira GmbH | Échangeur thermique, utilisation d'un alliage d'aluminium et d'une bande d'aluminium et procédé de production d'une bande d'aluminium |
BR112018008641B1 (pt) | 2016-05-27 | 2022-12-06 | Novelis Inc | Liga de alumínio, método para produção de uma liga de alumínio, e, artigo |
JP7116046B2 (ja) * | 2016-09-14 | 2022-08-09 | エフピーイノベイションズ | 少ない叩解エネルギーを用いたセルロースフィラメントの製造方法 |
CN107447133B (zh) * | 2017-07-26 | 2019-07-12 | 江苏亚太轻合金科技股份有限公司 | 一种耐腐蚀铝合金管及其制备方法 |
DE102018215243A1 (de) * | 2018-09-07 | 2020-03-12 | Neumann Aluminium Austria Gmbh | Aluminiumlegierung, Halbzeug, Dose, Verfahren zur Herstellung eines Butzen, Verfahren zur Herstellung einer Dose sowie Verwendung einer Aluminiumlegierung |
DE102018215254A1 (de) * | 2018-09-07 | 2020-03-12 | Neuman Aluminium Austria Gmbh | Aluminiumlegierung, Halbzeug, Dose, Verfahren zur Herstellung eines Butzen, Verfahren zur Herstellung einer Dose sowie Verwendung einer Aluminiumlegierung |
CN109097637B (zh) * | 2018-09-10 | 2021-01-26 | 招商局铝业(重庆)有限公司 | 一种球釜型锅胆用铝合金材料的制备方法 |
RU2731634C2 (ru) * | 2018-11-01 | 2020-09-07 | АО "Завод алюминиевых сплавов" | Способ получения деформированных полуфабрикатов из вторичного алюминиевого сплава |
CN109128728A (zh) * | 2018-11-17 | 2019-01-04 | 景德镇兴航科技开发有限公司 | 一种消耗油箱薄壁加工工艺 |
EP3741875A1 (fr) | 2019-05-24 | 2020-11-25 | Constellium Rolled Products Singen GmbH & Co.KG | Produit de feuille en alliage d'aluminium ayant un aspect de surface amélioré |
CN111471901B (zh) * | 2020-05-22 | 2021-03-23 | 永杰新材料股份有限公司 | 铝锰合金及其生产方法 |
CN112267053A (zh) * | 2020-09-27 | 2021-01-26 | 绵阳市优泰精工科技有限公司 | 一种含有稀土成份的铝合金材料 |
CN112195373A (zh) * | 2020-11-09 | 2021-01-08 | 江苏常铝铝业集团股份有限公司 | 一种电池壳体用铝合金带材及其制造方法 |
FR3123922B1 (fr) | 2021-06-11 | 2023-12-22 | Constellium Rolled Products Singen | Tôle forte en alliage d’aluminium pour boîtier de batterie parallélépipédique |
CN113802033B (zh) * | 2021-09-15 | 2022-03-08 | 山东宏桥新型材料有限公司 | 一种耐腐蚀船舶装饰用铝合金带材及其制备工艺和应用 |
US12031199B2 (en) | 2022-03-30 | 2024-07-09 | Relativity Space, Inc. | Aluminum alloy compositions, articles therefrom, and methods of producing articles therefrom |
CN115094276B (zh) * | 2022-06-30 | 2023-04-11 | 广东和胜工业铝材股份有限公司 | 一种铝合金及其制备方法和应用 |
CN116590554B (zh) * | 2023-05-19 | 2024-01-12 | 盐城永鑫机械有限公司 | 一种高性能车用转向节 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5985837A (ja) † | 1982-11-08 | 1984-05-17 | Mitsubishi Alum Co Ltd | 耐垂下性にすぐれた熱交換器フイン材 |
US5028276A (en) † | 1990-02-16 | 1991-07-02 | Aluminum Company Of America | Method for making lithoplate having improved grainability |
EP0823305A2 (fr) † | 1996-08-08 | 1998-02-11 | Denso Corporation | Feuille de brasage à haute résistance à la corrosion pour usage dans un échangeur de chaleur et échangeur de chaleur obtenu |
WO2005118899A1 (fr) † | 2004-05-26 | 2005-12-15 | Corus Aluminium Walzprodukte Gmbh | Procede de production d'une feuille de brasage d'alliage d'aluminium, et feuille de brasage d'alliage d'aluminium obtenue par ce procede |
EP2123386A1 (fr) † | 2003-10-20 | 2009-11-25 | Furukawa-Sky Aluminum Corporation | Un tube plat multi cavités en aluminium et revétu de résine avec une rugosité controllée ; Procédé de fabrication d'un tel tube plat |
US20100279143A1 (en) † | 2009-04-30 | 2010-11-04 | Kamat Rajeev G | Multi-alloy composite sheet for automotive panels |
JP2012149354A (ja) † | 2012-05-11 | 2012-08-09 | Kobe Steel Ltd | アルミニウム合金板およびその製造方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60248859A (ja) * | 1984-05-25 | 1985-12-09 | Sumitomo Light Metal Ind Ltd | 超高圧用プレ−トフイン型熱交換器のフイン材 |
JPH03215645A (ja) * | 1989-12-20 | 1991-09-20 | Furukawa Alum Co Ltd | フッ素樹脂塗装容器用アルミニウム合金およびその製造方法 |
JPH03222796A (ja) * | 1990-01-30 | 1991-10-01 | Nippon Light Metal Co Ltd | 平版印刷版用アルミニウム支持体 |
JPH0755373B2 (ja) * | 1990-09-18 | 1995-06-14 | 住友軽金属工業株式会社 | アルミニウム合金クラッド材および熱交換器 |
FR2707092B1 (fr) | 1993-06-28 | 1995-08-25 | Pechiney Rhenalu | Produit métallurgique en alliage d'Al à durcissement structural présentant une variation continue des propriétés d'emploi suivant une direction donnée et un procédé et dispositif d'obtention de celui-ci. |
KR0165927B1 (ko) * | 1995-05-18 | 1999-01-15 | 우사미 카즈오 | 강도 및 성형성이 우수한 핀 형성용 알루미늄 합금 및 그 제조방법 |
RU2142187C1 (ru) * | 1997-07-18 | 1999-11-27 | Общество с ограниченной ответственностью "Таврида Электрик Р" | Реклоузер (автоматический выключатель воздушных линий) серии tel |
DE29924474U1 (de) * | 1999-07-02 | 2003-08-28 | Hydro Aluminium Deutschland GmbH, 53117 Bonn | Lithoband |
FR2797454B1 (fr) * | 1999-08-12 | 2001-08-31 | Pechiney Rhenalu | Bande ou tube en alliage d'aluminium pour la fabrication d'echangeurs de chaleur brases |
AUPQ485399A0 (en) | 1999-12-23 | 2000-02-03 | Commonwealth Scientific And Industrial Research Organisation | Heat treatment of age-hardenable aluminium alloys |
RU2221891C1 (ru) * | 2002-04-23 | 2004-01-20 | Региональный общественный фонд содействия защите интеллектуальной собственности | Сплав на основе алюминия, изделие из этого сплава и способ изготовления изделия |
BRPI0408432B1 (pt) | 2003-03-17 | 2015-07-21 | Corus Aluminium Walzprod Gmbh | Método para produção de uma estrutura integrada de alumínio monolítico e produto de alumínio usinado daquela estrutura |
US20050217770A1 (en) | 2004-03-23 | 2005-10-06 | Philippe Lequeu | Structural member for aeronautical construction with a variation of usage properties |
US7407714B2 (en) * | 2004-05-26 | 2008-08-05 | Aleris Aluminum Koblenz Gmbh | Process by producing an aluminium alloy brazing sheet, aluminium alloy brazing sheet |
FR2897319B1 (fr) * | 2006-02-15 | 2009-01-23 | Pechiney Softal Soc Par Action | Composants de structure de caisse automobile pour absorption d'energie de choc en alliage d'aluminium de la famille 3000 |
JP5054364B2 (ja) * | 2006-12-08 | 2012-10-24 | 株式会社神戸製鋼所 | アルミニウム合金板の製造方法 |
CN101815804B (zh) | 2007-10-04 | 2013-07-24 | 阿勒里斯铝业科布伦茨有限公司 | 制造在工程性质上具有梯度的锻造金属板产品的方法 |
JP4444354B2 (ja) * | 2008-08-04 | 2010-03-31 | 株式会社東芝 | 画像処理装置、および画像処理方法 |
JP5750237B2 (ja) * | 2010-05-25 | 2015-07-15 | 株式会社Uacj | アルミニウム合金製熱交換器の製造方法 |
CN101956102B (zh) * | 2010-10-27 | 2012-05-23 | 江苏格林威尔金属材料科技有限公司 | 热交换器用平行流管及其制造方法 |
JP5746528B2 (ja) * | 2011-03-15 | 2015-07-08 | 株式会社神戸製鋼所 | 焼付け塗装硬化性に優れたアルミニウム合金板 |
JPWO2013176038A1 (ja) * | 2012-05-25 | 2016-01-12 | 株式会社Uacj | 電極集電体用アルミニウム合金箔、その製造方法及び電極材 |
CA2959416C (fr) * | 2014-09-12 | 2020-07-07 | Novelis Inc. | Alliages pour des produits en aluminium tres faconnes et leurs procedes de fabrication |
-
2013
- 2013-02-21 ES ES13156100.3T patent/ES2621871T3/es active Active
- 2013-02-21 PT PT131561003T patent/PT2770071T/pt unknown
- 2013-02-21 EP EP13156100.3A patent/EP2770071B9/fr active Active
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2014
- 2014-02-20 EP EP14705528.9A patent/EP2959028B2/fr active Active
- 2014-02-20 KR KR1020157025451A patent/KR101656419B1/ko active IP Right Grant
- 2014-02-20 CN CN201480009934.XA patent/CN105008563B/zh not_active Expired - Fee Related
- 2014-02-20 RU RU2015139899A patent/RU2637458C2/ru not_active IP Right Cessation
- 2014-02-20 WO PCT/EP2014/053323 patent/WO2014128212A1/fr active Application Filing
- 2014-02-20 ES ES14705528T patent/ES2590779T5/es active Active
- 2014-02-20 JP JP2015558448A patent/JP6143892B2/ja active Active
- 2014-02-20 CA CA2899991A patent/CA2899991C/fr not_active Expired - Fee Related
- 2014-02-20 PT PT147055289T patent/PT2959028T/pt unknown
-
2015
- 2015-08-14 US US14/826,244 patent/US10501833B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5985837A (ja) † | 1982-11-08 | 1984-05-17 | Mitsubishi Alum Co Ltd | 耐垂下性にすぐれた熱交換器フイン材 |
US5028276A (en) † | 1990-02-16 | 1991-07-02 | Aluminum Company Of America | Method for making lithoplate having improved grainability |
EP0823305A2 (fr) † | 1996-08-08 | 1998-02-11 | Denso Corporation | Feuille de brasage à haute résistance à la corrosion pour usage dans un échangeur de chaleur et échangeur de chaleur obtenu |
EP2123386A1 (fr) † | 2003-10-20 | 2009-11-25 | Furukawa-Sky Aluminum Corporation | Un tube plat multi cavités en aluminium et revétu de résine avec une rugosité controllée ; Procédé de fabrication d'un tel tube plat |
WO2005118899A1 (fr) † | 2004-05-26 | 2005-12-15 | Corus Aluminium Walzprodukte Gmbh | Procede de production d'une feuille de brasage d'alliage d'aluminium, et feuille de brasage d'alliage d'aluminium obtenue par ce procede |
US20100279143A1 (en) † | 2009-04-30 | 2010-11-04 | Kamat Rajeev G | Multi-alloy composite sheet for automotive panels |
JP2012149354A (ja) † | 2012-05-11 | 2012-08-09 | Kobe Steel Ltd | アルミニウム合金板およびその製造方法 |
Non-Patent Citations (25)
Title |
---|
"ASM Specialty Handbook", 1993, article J.R. DAVIS ET AL.,: "Aluminum and Aluminum Alloys", pages: 221 - 222 † |
"Design - Design Methodology", THE ALUMINIUM AUTOMOTIVE MANUAL, 2011, pages 1 - 20 † |
"Products - rolled products", THE ALUMINIUM AUTOMOTIVE MANUAL, 2002, pages 1 - 42 † |
A. HAKONSEN ET AL.: "Modelling the metallurgical reactions during homogenisation of an AA3103 alloy", LIGHT METALS, 2002, pages 1028 - 1035 † |
Aluminium - Properties and Physical Metallurgy, 1984, pages 356-361 † |
Aluminium und Aluminiumlegierungen, Springer-Verlag 1965, Seiten 700, 701 † |
Aluminium-Verlag 1999, Handbook, Vol.1: Fudamentals and Materials, pages 118-121 † |
J. LANGERWEGER: "Influence of homogenizing on the properties of cast aluminium products", LIGHT METALS, 1982, pages 1036 - 1042 † |
J.R. Davis, "Aluminium and Aluminium Alloys, 1993, pages 665-668 † |
JOHN E HATCH: "Aluminium. Properties and Physical Metallurgy", 1 January 1984, article "Effects of alloying elements and impurities on properties", pages: 237 - 238 † |
Kontoinformationen, Tagesauszug eines Kontos von E1 bei der Deutschen Bank, Tages beleg vom 01.06.2011 † |
Maschinenübersetzung zu JP 2012-149354 A † |
Maschinenübersetzung zu JP S5985837 A † |
Mit Datum vom 16.04.2019 reichte E2 das folgende weitere Dokument ein: † |
Mit Online-Einreichung vom 17.06.2019 reichte E2 die folgenden weiteren Dokumente ein † |
Mit schreiben vom 10.12.2018 reichte E1 die folgenden weiteren Dokumente ein: † |
Mit schreiben vom 16.01.2019 reichte E1 weiterhin das Dokument † |
N.V. GOVINDARAJ ET AL.: "Threshold deformation for exhibiting the hard- ening on annealing behaviour in AA3103 alloy", ICAA13: 13TH INTERNATIONAL CONFERENCE ON ALUMINUM ALLOYS, 2012, pages 1873 - 1878 † |
Ofen kundige Vorbenutzung mit Lieferschein (E2A) und Prüfprotokoll (E2B), Verkauf von Coils AA3103 von Aleris Koblenz GmbH an Nissen A.s. Dänemark, 03/2011 † |
T. Itagaki, K. Tohma: "Development of Aluminium Alloys for Heat Exchangers Manufactured by Brazing", P. 629-634, Oct. 1991, The Japan Institute of light Metals † |
THE ALUMINIUM ASSOCIATION: "Chemical Composition Limits", REGISTRATION RECORD SERIES TEAL SHEETS, February 2009 (2009-02-01), pages 4 † |
W HUFNAGEL: "Aluminium-Taschenbuch", 1983, article "Aluminium-Halbzeug", pages: 249 † |
Z.J. ZOK: "Microchemistry in aluminium sheet production (PhD thesis)", April 2005 (2005-04-01), pages 1 - 164 † |
Zusammenfassung von JP S5985837 A † |
Zwischenentscheidung im Einspruchsverfahren für EP 2959028 † |
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WO2014128212A9 (fr) | 2014-11-27 |
KR101656419B1 (ko) | 2016-09-09 |
JP6143892B2 (ja) | 2017-06-07 |
RU2637458C2 (ru) | 2017-12-04 |
EP2770071A1 (fr) | 2014-08-27 |
CN105008563B (zh) | 2018-05-25 |
CN105008563A (zh) | 2015-10-28 |
EP2959028B2 (fr) | 2019-07-10 |
ES2590779T5 (es) | 2020-03-11 |
US10501833B2 (en) | 2019-12-10 |
PT2770071T (pt) | 2017-04-19 |
KR20150119369A (ko) | 2015-10-23 |
CA2899991C (fr) | 2017-05-02 |
RU2015139899A (ru) | 2017-03-24 |
WO2014128212A1 (fr) | 2014-08-28 |
ES2590779T3 (es) | 2016-11-23 |
EP2959028A1 (fr) | 2015-12-30 |
CA2899991A1 (fr) | 2014-08-28 |
EP2959028B1 (fr) | 2016-07-27 |
US20150368771A1 (en) | 2015-12-24 |
EP2770071B1 (fr) | 2017-02-01 |
ES2621871T3 (es) | 2017-07-05 |
PT2959028T (pt) | 2016-09-19 |
JP2016514206A (ja) | 2016-05-19 |
EP2770071B9 (fr) | 2020-08-12 |
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