EP3178888A1 - Matiere de remplissage pour une composition de traitement de surface - Google Patents

Matiere de remplissage pour une composition de traitement de surface Download PDF

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Publication number
EP3178888A1
EP3178888A1 EP15198350.9A EP15198350A EP3178888A1 EP 3178888 A1 EP3178888 A1 EP 3178888A1 EP 15198350 A EP15198350 A EP 15198350A EP 3178888 A1 EP3178888 A1 EP 3178888A1
Authority
EP
European Patent Office
Prior art keywords
particles
treatment composition
surface treatment
filler
wood
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP15198350.9A
Other languages
German (de)
English (en)
Other versions
EP3178888B1 (fr
Inventor
Susanne Eiberweiser
Daniel Von Laufenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gebrueder Dorfner GmbH and Co KG Kaolin und Kristallquarzsand Werke
Original Assignee
Gebrueder Dorfner GmbH and Co KG Kaolin und Kristallquarzsand Werke
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gebrueder Dorfner GmbH and Co KG Kaolin und Kristallquarzsand Werke filed Critical Gebrueder Dorfner GmbH and Co KG Kaolin und Kristallquarzsand Werke
Priority to ES15198350T priority Critical patent/ES2820762T3/es
Priority to PT151983509T priority patent/PT3178888T/pt
Priority to EP15198350.9A priority patent/EP3178888B1/fr
Priority to US15/136,483 priority patent/US10751908B2/en
Priority to JP2016237884A priority patent/JP6572197B2/ja
Publication of EP3178888A1 publication Critical patent/EP3178888A1/fr
Application granted granted Critical
Publication of EP3178888B1 publication Critical patent/EP3178888B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K1/00—Damping wood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N7/00—After-treatment, e.g. reducing swelling or shrinkage, surfacing; Protecting the edges of boards against access of humidity
    • B27N7/005—Coating boards, e.g. with a finishing or decorating layer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D15/00—Woodstains
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00—Other substrates
    • B05D2203/20—Wood or similar material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general

Definitions

  • the invention relates to a filler for a surface treatment composition, in particular a wood treatment composition. Furthermore, the invention relates to the use of particles with a surface coating, which give the respective particle a positive surface charge, for the treatment of wood.
  • Various surface treatment compositions are known in the art. These may include, for example, lacquers, glazes, impregnations, coatings, stains, anodizing, powder coatings, electrodeposition, oxidation (e.g., anodizing), and others.
  • the surface treatment can also have negative properties on the appearance and / or properties of the treated material.
  • An example of this is the application of paints on certain surfaces, since for example by the solvent contained in the paint depending on the material to be coated this can be damaged.
  • the present invention is therefore based on the object to provide a filler for a surface treatment composition, with which these disadvantages can be eliminated. Moreover, it is an object of the invention to provide substances with which the bleeding of wood after the surface treatment can be avoided or at least reduced. In addition, the invention is directed to the use of such substances for the treatment of wood.
  • An essential aspect of the invention is a filler for a surface treatment composition which is characterized in that the filler comprises particles which have a surface coating which gives a positive surface charge to the respective particle. Due to this positive surface charge, it is possible to locally bind anions emerging from the material to be treated, thereby drastically limiting their mobility.
  • a positive surface charge should be understood as meaning any surface charge. Thus, partial charges are included. However, it is preferred if the surface itself has an ionic-to be more precise cationic character-since this allows particularly efficient binding of the anions.
  • the surface treatment composition comprising the filler according to the invention offers the advantage that not the entire surface treatment composition has a cationic character but the positively charged centers are local and spatially separated, whereby the further diffusing of the anions from a positive charged center difficult to adjacent positively charged center or - depending on environmental conditions - even completely prevented.
  • the positively charged center is so close together and uniform that the energy barrier to an anion change from one charge center to the adjacent charge center is too small to effectively prevent or slow the diffusion of anions through the surface treatment composition.
  • Such a distribution having a plurality of closely spaced charge centers could be provided, for example, by a binder containing ionic groups.
  • the particles have a carrier particle size (d 50 ) in the range between 0.01 .mu.m and 5 mm, preferably in the range between 0.1 .mu.m and 1 mm, particularly preferably in the range between 1 ⁇ m and 100 ⁇ m.
  • the particularly preferred size in the range between 1 .mu.m and 100 .mu.m can be ensured on the one hand, that the particles and thus the charge centers are on the one hand sufficiently locally centered to prevent the above-described diffusion of the anions, on the other hand, however, also homogeneous are distributed over the entire surface coating that everywhere in the surface coating charge centers are so close to emerging from the material to be treated anions that can be effectively intercepted or bound.
  • This size of the carrier particle size also has an effect on other properties of the surface coating, such as haptics, hiding power, wet abrasion and others. Thus, not only bleeding can be prevented or reduced by these particles, they can also have other positive effects in their capacity as a filler.
  • the particle size stated above as well as the particle size mentioned below refer in each case to the carrier particle size unless explicitly stated otherwise. Unless stated otherwise, the particle size is given as the d 50 value. This value is measured by sedimentation unless otherwise stated (Sedigraph, eg Sedigraph 5120).
  • the (carrier) particles are selected from a group comprising talc, mica, glass beads, glass flour, alkaline earth carbonates, preferably CaCO 3 , kaolin (native and / or calcined), quartz, quartz flour and diatomaceous earth.
  • these substances have been found to be advantageous because, on the one hand, they are available in large quantities but, on the other, they do not adversely affect other properties of various known and commercially available surface treatment compositions.
  • these (non-surface modified) carrier particles are already added as a filler to known surface treatment compositions.
  • the materials from the above group a particularly good compatibility with known systems.
  • the surface charge retains its positive (partial) charge over a wide pH range. It is therefore preferred that the surface charge is cationic below a pH of 10, preferably below a pH of 11, more preferably below a pH of 12, and most preferably below a pH of 13.
  • the proportion of the surface coating in a particle is preferably 0.1-20% by weight (wt.%), Preferably 0.5-10 wt.%, Particularly preferably 1-7.5 wt.%, By weight the carrier particle.
  • a lower density of the charge centers of the surface coating could lead to certain areas of the particles can not effectively bind anions or these areas are saturated after binding of some anions and no more anions can be bound.
  • the surface coating preferably comprises a polymer. It is particularly easy to impart a variety of (partial) charges to polymers. These are sufficiently close to each other to bind anions possibly even through multiple charge centers. Thus, a chelation effect could be exploited. In this case, in addition - assuming the corresponding mobility of the polymer chains - it would also be possible for the charge centers to align with the anion and a largely nonpolar residue on the side of the polymer chain opposite to the anion, thereby rejecting water and redissolving the anion is prevented by water.
  • a polymer preferably has amino groups. However, other polymers may additionally be present which, if appropriate, impart further positive properties to the particles.
  • amino-modified alkylpolysiloxane is used as an example of an amino-containing polymer. Since it is irrelevant to the mode of action whether the amino groups are part (or by-product) of the monomers which form the polymer chain or whether they have been added to the polymer chain after polymerization, no distinction will be made hereinafter between these polymers. As amino-modified alkylpolysiloxane should therefore also be understood polymers in which the amino groups are part (or secondary product) of the monomers.
  • a filler in which the surface coating is suitable for binding and / or complexing anions is particularly preferred.
  • Binding should be understood to mean any type of interaction which at least temporarily restricts the mobility of the anions.
  • Complexation of an anion e.g., by a chelate thus represents a preferred variant of a bond.
  • the surface coating (of the (filler) particles) is colorless and more preferred that the surface coating (of the (filler) particles) remain colorless even upon complexing of the discoloring ingredients.
  • the surface coating itself does not cause any falsification of the desired color of the surface treatment composition or of the surface coating resulting therefrom (of the material treated therewith).
  • the compound of the surface coating (the (filler) particles) with anions is colorless. This can ensure that even when binding the anions no undesirable color effect occurs.
  • the surface treatment composition comprising the filler is preferably a wood-treatment composition.
  • the wood can be superficially charged with the filler comprising the particles with the surface coating which give the respective particle a positive surface charge. This positive surface charge can reduce bleeding and reduce the effect of the exiting anions on the appearance of the treated wood.
  • Another essential aspect of the invention is therefore the use of a particle comprising a carrier particle and a surface coating, wherein the particles which give the surface coating give a positive surface charge, for the treatment of wood.
  • the particles preferably have the properties already described above for the particles of the filler for a surface treatment composition.
  • Particularly preferred is the use of a particle in which the treatment serves to reduce the bleeding of wood.
  • a variant of the use is characterized in that the particles are part of a surface treatment composition.
  • the surface treatment composition is preferably present in liquid form. It is particularly preferred that the surface treatment composition is present as a suspension.
  • the application and in particular a uniform application of the particles to a surface is simplified.
  • a preferred variant is further characterized in that the surface treatment composition is applied with a wet layer thickness between 50 .mu.m and 1000 .mu.m.
  • a wet layer thickness ensures a simple and homogeneous application with devices known from the prior art (for example for lacquers, glazes or paints).
  • a sufficient material thickness and thus a sufficient amount of active particles is ensured by these wet layer thicknesses even after drying.
  • Wet layer thicknesses between 100 ⁇ m and 500 ⁇ m, particularly preferably between 200 ⁇ m and 300 ⁇ m, have proven to be particularly preferred.
  • the particles When the particles are used as part of a surface treatment composition, it has been found to be particularly advantageous to add them in a proportion of up to 50% by weight, preferably 1-30% by weight, more preferably 2-20% by weight become. These and all other proportions by weight given in this specification in each case relate to the weight of the surface treatment composition without the addition of the particles. More preferably, the particles are added in an amount of 3-15% by weight of the surface treatment composition.
  • the particles and in particular their surface coating are protonated in the surface treatment composition, preferably in multiply protonated form.
  • the surface treatment composition has a pH below 13, preferably between 1 and 12, more preferably between 3 and 11, particularly preferably between 5 and 10.
  • Table 1 shows exemplary embodiments of filler particles.
  • a native Kaolin serves on the one having a particle size (d 50) ⁇ 2 microns. This is identified as kaolin A.
  • the carrier material labeled kaolin B is also a native kaolin.
  • its average particle size (d 50 ) is slightly larger and is about 2.5 microns.
  • QM 2500 refers to a quartz flour whose particle size (d 50 ) is approximately 5 ⁇ m.
  • an amino-modified alkylpolysiloxane which is only abbreviated to "polysiloxane” in the table, was used. The order quantity used is between 0.1 and 20% by weight.
  • the pure carrier materials are anionic. At least, however, they have a negative surface charge. Due to the corresponding surface modification, the resulting composite particles receive a positive surface charge. Depending on the carrier particles and the amount of surface coating applied, the surface charge ranges between about 40 and almost 90 mV. It should be noted that the measured values given in Table 1 are subject to a comparatively large error, so that significant deviations from the stated values may also be present. However, taking into account this possible deviation from Table 1 It can be seen that with appropriate surface modification not only the charge is shifted into the positive range, but also that with an increasing amount of the applied surface coating, the surface charge also tends to increase.
  • FIG. 1 Figure 4 shows a comparison of various specimens obtained using kaolin A obtained with 5% of the amino-modified alkylpolysiloxane. This was used as an aqueous preparation and applied to the carrier particles. The resulting composite particle is added to a white wood primer. As a white pigment this contains titanium dioxide (TiO 2 ). The test substrate used is merbau wood.
  • various formulations were applied to the test specimens in which the ratio of coated kaolin to uncoated kaolin differed.
  • Examiner A (left) was treated with a formulation containing 15 wt% surface-coated filler and was free of untreated kaolin A.
  • Test specimens shown represent the results of an experiment obtained at an early stage of development. Further optimization of the composition used may result in further reduction of discoloration caused by bleeding.
  • One such example is in FIG. 2 shown.
  • the adaptation of the wetting properties and / or the viscosity of the surface treatment composition has a great influence on the occurrence of local discoloration. With a better wetting, which can not necessarily be achieved, for example, by a reduction in the viscosity, the bleeding or the number of individual pores that become visible can be further reduced.
  • FIG. 2 An example is shown in which a marketed product (market reference RM2), which is intended to prevent bleeding, has been treated with a surface-modified filler as described above.
  • Examiner A (left) represents a test specimen treated with RM2. Significant discoloration is seen. Already by the addition of untreated kaolin A this can be reduced.
  • B (second from the left) shows a test specimen obtained by coating with a composition of RM2 with an additional content of 15% by weight kaolin A.
  • C shows a test piece in which the market reference RM2 is added to 15% by weight of the above-described surface-modified filler. Both in comparison to A and B, a clear reduction of discoloration and thus blood circulation can be seen.
  • D a test specimen is shown in which a surface treatment is performed by a composition containing 15 wt .-% RM2 and calcium carbonate (CaCO 3).
  • FIG. 3 test specimens are shown in which glass particles have been used as the carrier material. These glass particles were surface-coated analogously to the kaolin particles described above by an amino-modified alkylpolysiloxane.
  • a pure binder intended to prevent bleeding of the wood constituents (A) was compared with a formulation in which 35% by weight of the surface-modified filler (B) was added to this binder. Again, there is a significant reduction in the discoloration encountered in the treatment with the composition containing the surface-coated particles by the amino-modified alkylpolysiloxane.
  • the carrier for the surface-modified filler is glass particles.
  • the positive property of the composition which significantly reduces bleeding, does not affect properties of the carrier particle, such as kaolin (cf. Fig. 2 ), but depends essentially on the surface coating of these particles.
  • test specimen was applied to a wet film thickness of 200 microns.
  • the results are thus directly comparable.
  • the layer thicknesses can deviate significantly from this value mentioned above and are not limited to this.
  • an analogous positive effect can be achieved by compositions containing fillers with the surface-modified particles as described above.
  • Analogous results could also be achieved with fillers comprising particles with different weight proportions of the surface coating relative to the carrier particles. Again, it could be shown that these at least reduced the blood circulation. The efficiency is dependent at least to a small extent on the proportion of surface coating on the carrier particle.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Forests & Forestry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
EP15198350.9A 2015-12-08 2015-12-08 Matiere de remplissage pour une composition de traitement de surface Active EP3178888B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES15198350T ES2820762T3 (es) 2015-12-08 2015-12-08 Relleno para una composición de tratamiento de superficies
PT151983509T PT3178888T (pt) 2015-12-08 2015-12-08 Material de enchimento para uma composição de tratamento de superfície
EP15198350.9A EP3178888B1 (fr) 2015-12-08 2015-12-08 Matiere de remplissage pour une composition de traitement de surface
US15/136,483 US10751908B2 (en) 2015-12-08 2016-04-22 Filler for a surface-treatment composition
JP2016237884A JP6572197B2 (ja) 2015-12-08 2016-12-07 表面処理組成物用の充填剤

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP15198350.9A EP3178888B1 (fr) 2015-12-08 2015-12-08 Matiere de remplissage pour une composition de traitement de surface

Publications (2)

Publication Number Publication Date
EP3178888A1 true EP3178888A1 (fr) 2017-06-14
EP3178888B1 EP3178888B1 (fr) 2020-08-26

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Family Applications (1)

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EP15198350.9A Active EP3178888B1 (fr) 2015-12-08 2015-12-08 Matiere de remplissage pour une composition de traitement de surface

Country Status (5)

Country Link
US (1) US10751908B2 (fr)
EP (1) EP3178888B1 (fr)
JP (1) JP6572197B2 (fr)
ES (1) ES2820762T3 (fr)
PT (1) PT3178888T (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3385046A1 (fr) * 2017-04-07 2018-10-10 Omya International AG Planches en bois décoratives revêtues en ligne

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0407085A2 (fr) * 1989-07-05 1991-01-09 Rohm And Haas Company Composition de peinture à base de latex cationique
WO1998036029A1 (fr) * 1997-02-14 1998-08-20 Ecc International Inc. Composition de revetement pour papier a impression par jet d'encre et son produit
WO2005071023A1 (fr) * 2004-01-22 2005-08-04 Nuplex Resins B.V. Composition de revetement aqueux antitache
WO2013147701A1 (fr) * 2012-03-29 2013-10-03 Pcts Specialty Chemicals Pte Ltd Dispersions de polyuréthane cationique aqueuse et leurs utilisations

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US5270103A (en) * 1990-11-21 1993-12-14 Xerox Corporation Coated receiver sheets
JP2001026666A (ja) * 1999-07-13 2001-01-30 Faimatekku:Kk 合成樹脂用有機添加剤を担持してなる無機フィラー及びその製造方法
JP5086556B2 (ja) * 2006-03-31 2012-11-28 エスケー化研株式会社 塗料組成物
US7691484B2 (en) * 2006-05-04 2010-04-06 Ppg Industries Ohio, Inc. Coating compositions suitable for use as a wood stain and/or toner
PT2044130E (pt) * 2006-07-17 2010-06-01 Basf Se Utilização de dispersões aquosas de partículas compostas como agentes de ligação em revestimentos para madeira
CN102341463B (zh) * 2009-03-13 2014-06-11 阿克佐诺贝尔化学国际公司 硅烷化二氧化硅水分散体
DE102010001135A1 (de) * 2010-01-22 2011-07-28 Evonik Degussa GmbH, 45128 Stabile wässrige Dispersionen aus gefällter Kieselsäure
JP5569422B2 (ja) * 2011-02-09 2014-08-13 東洋インキＳｃホールディングス株式会社 表面コート材用組成物
US9232939B2 (en) 2012-09-11 2016-01-12 Biomet Sports Medicine, Llc Flexible planar member for tissue fixation
US20140072815A1 (en) * 2012-09-12 2014-03-13 Ppg Industries Ohio, Inc. Curable film-forming compositions demonstrating burnish resistance and low gloss
WO2015116459A1 (fr) * 2014-01-29 2015-08-06 3M Innovative Properties Company Composition aqueuse de revêtement de surface et particules modifiées
CN103965846A (zh) * 2014-05-04 2014-08-06 陕西科技大学 一种双组份环氧树脂堵水剂及其使用方法
JP6622487B2 (ja) * 2015-05-28 2019-12-18 凸版印刷株式会社 化粧シートおよび化粧シートの製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0407085A2 (fr) * 1989-07-05 1991-01-09 Rohm And Haas Company Composition de peinture à base de latex cationique
WO1998036029A1 (fr) * 1997-02-14 1998-08-20 Ecc International Inc. Composition de revetement pour papier a impression par jet d'encre et son produit
WO2005071023A1 (fr) * 2004-01-22 2005-08-04 Nuplex Resins B.V. Composition de revetement aqueux antitache
WO2013147701A1 (fr) * 2012-03-29 2013-10-03 Pcts Specialty Chemicals Pte Ltd Dispersions de polyuréthane cationique aqueuse et leurs utilisations

Also Published As

Publication number Publication date
US20170157794A1 (en) 2017-06-08
ES2820762T3 (es) 2021-04-22
JP6572197B2 (ja) 2019-09-04
EP3178888B1 (fr) 2020-08-26
JP2017128797A (ja) 2017-07-27
PT3178888T (pt) 2020-10-08
US10751908B2 (en) 2020-08-25

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