EP3140344A1 - Primaire pour améliorer l'adhérence de bandes adhésives à surfaces hydrophiles - Google Patents

Primaire pour améliorer l'adhérence de bandes adhésives à surfaces hydrophiles

Info

Publication number
EP3140344A1
EP3140344A1 EP15718199.1A EP15718199A EP3140344A1 EP 3140344 A1 EP3140344 A1 EP 3140344A1 EP 15718199 A EP15718199 A EP 15718199A EP 3140344 A1 EP3140344 A1 EP 3140344A1
Authority
EP
European Patent Office
Prior art keywords
primer
radical
primer according
weight
monomer mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15718199.1A
Other languages
German (de)
English (en)
Inventor
Sebastian Dietze
Kai Ellringmann
Marco Kupsky
Uwe Schümann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tesa SE
Original Assignee
Tesa SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tesa SE filed Critical Tesa SE
Publication of EP3140344A1 publication Critical patent/EP3140344A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J139/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
    • C09J139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/057—Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J139/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
    • C09J139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C09J139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer
    • C09J2433/003—Presence of (meth)acrylic polymer in the primer coating

Definitions

  • the present invention relates to the technical field of primers for improving the adhesion of adhesive tapes on hydrophilic surfaces, for example on glass surfaces.
  • a primer composition for improving the adhesion of polyacrylate-based adhesive tapes is proposed, which may contain pigments or other functional, filler-like substances in high concentration, without the adhesion-promoting effect is thereby significantly impaired.
  • Primers often referred to as adhesion promoters or adhesion promoters, are widely known in the form of commercial products or from the technical literature. An overview of the substances or substance classes that can be used in primer formulations can be found in J. Bielemann, Lackadditive (1998), Chap. 4.3., P.1 14-129.
  • Primer compositions are disclosed in a variety of patents, but primers are described in only a few writings with which an adhesion improvement of adhesive tapes to be achieved.
  • WO 2008/094721 A1 in connection with adhesive tape applications, a primer composition based on a maleic anhydride-modified polyolefin and an organic diamine is proposed with which an improvement in adhesion to polyolefin-based materials is to be achieved.
  • JP 2008-156566 A discloses a primer composition based on an acidic acrylate polymer and a fluorine-containing copolymer for adhesive tape applications.
  • WO 02/100961 A1 proposes a primer composition containing an acrylate copolymer grafted with an aminoalkyl group containing terminal primary amino groups, furthermore an acrylate copolymer having carboxyl groups in the molecular chain and a solvent.
  • WO 03/052021 A1 describes a primer composition which contains a polydiorganosiloxane-polyurea copolymer with electron-rich groups and may have the form of a primer, an adhesive, a pressure-sensitive adhesive or another coating material. This primer composition is also mentioned in connection with adhesive tape applications.
  • EP 833 865 B1, EP 833 866 B1, EP 739 383 B1 and US Pat. No. 5,602,202 describe primer compositions based on mixtures of styrene / diene block copolymers or styrene / hydrogenated diene block copolymers and selected polyacrylates which inhibit adhesion on both sides of the adhesive to improve foamed adhesive tapes on both low energy and higher energy surfaces.
  • a primer suitable for improving the adhesion of adhesive tapes to hard-to-bond substrates, particularly to galvanized steel, as well as to olefin-based thermoplastic elastomers, e.g. PP / EPDM is suitable, is disclosed in DE 10 201 1 077 510 A1.
  • silane primers or silane coupling agents are often used for adhesion on hydrophilic substrates such as glass. Such are described for example in DE 10 2009 007 930 A1 or DE 10 2007 030 196 A1, furthermore in EP 577 014 A1, EP 1 693 350 A1, EP 1 730 247 A1, US 2008 0245 271 A, US 2008 023 425 A or WO 2008/025846 A2.
  • the systems disclosed in the cited documents are not designed to improve the adhesion of adhesive tapes to glass. Accordingly, they contain no suitable components to improve the adhesion to a pressure-sensitive adhesive, in particular the adhesion to a pressure-sensitive adhesive based on a copolymer of acrylic acid esters and optionally acrylic acid.
  • US 6,646,048 B2 discloses a primer composition of a reactive acrylic resin consisting of two different methacrylates, a silane compound, a bisphenol A type epoxy resin and carbon black. Although this primer composition of a reactive acrylic resin and a silane is suitable for the adhesion improvement of a urethane-based sealant or a reactive adhesive on glass, but for the adhesion improvement of a pressure-sensitive adhesive tape on glass, it is considered to be unsuitable. Unlike a urethane-based sealant and a reactive adhesive, which can crosslink even after the application and thus enter into a chemical compound with the primer, the polymer base of the pressure-sensitive adhesives is no longer reactive during the application of the adhesive tape.
  • the primer composition of US Pat. No. 6,646,048 B2 therefore does not achieve adhesion improvement between an adhesive tape and a glass substrate.
  • the object of the invention is generally to provide a primer for improving the adhesion of adhesive tapes on hydrophilic surfaces such as in particular glass or ceramic.
  • the primer should preferably allow the incorporation of pigments or other functional fillers in high concentration, without thereby the adhesion-promoting effect of the primer is significantly reduced. It should be possible to incorporate pigments in such a high concentration in the primer that in a thin-layer application of this primer on glass opacity is achieved.
  • thin layer is meant here a layer thickness on the order of between approximately 5 ⁇ m and 20 ⁇ m. Opaque means that one does not pass through the primer layer It should be possible to see through it that the visible light should not shine through the primer layer.
  • the adhesion-promoting effect of the primer should be established quickly.
  • An adhesive tape adhered to the primer layer should no longer be removable from the primer layer applied to a glass or ceramic surface, especially after 24 hours.
  • the primer should be designed so that an adhesive tape can be adhered to the primer layer already a short time after application of the primer to the substrate surface, in particular to glass.
  • the primer should therefore already be "dry” shortly after application, that is, the solvent should already have evaporated after a short time, a short time being understood here to be a period of 60 seconds, preferably 40 seconds.
  • the primer should be free of halogen-containing, in particular chlorine-containing substances.
  • the subject of the invention is a primer which comprises a mixture G dissolved or dispersed in one or more solvents
  • acrylic acid esters of a linear, primary alcohol having 2 to 10 carbon atoms in the alkyl radical of the alcohol b) acrylic esters of a branched, non-cyclic
  • Alcohol having 3 to 12 carbon atoms in the alkyl radical of the alcohol having 3 to 12 carbon atoms in the alkyl radical of the alcohol
  • R 2 is an aminoalkyl, vinyl, methacryloxyalkyl, isocyanatoalkyl, O-methylcarbamatoalkyl, glycidoxyalkyl or phenyl;
  • At least one metal compound selected from the group consisting of metal acetylacetonates, metal alkoxides and alkoxy
  • Vinylcaprolactam refers to N-vinylcaprolactam (CAS # 2235-00-9) and "vinylpyrrolidone” N-vinyl-2-pyrrolidone (CAS # 88-12-0).
  • a metal acetylacetonate is understood according to the invention to mean a coordination compound of acetylacetonate anions and metal cations.
  • the general formula is: M (acac) m .
  • M stands for a metal cation, acac for the acetylacetonate anion.
  • the lUPAC name for acetylacetone is: pentane-2,4-dione, CAS no. is 123-54-6.
  • m is the number of acetylacetonate anions required to charge balance, m depends on the oxidation state of the metal cation.
  • metal alkoxide is synonymous with "metal alcoholate.”
  • M (OR) n M stands for a metal cation
  • OR stands for an alcoholate anion
  • R stands for an alkyl radical
  • n stands for the number of alcoholate anions
  • alkoxy metal acetylacetonates refers to mixed coordination compounds of both acetylacetonate and alkoxide anions and metal cations
  • M (acac) m (OR) n M stands for a metal cation, acac for the acetylacetonate anion
  • OR for an alcoholate anion R stands for an alkyl radical
  • m and n stand for the number of acetylacetonate anions or Alcoholatanionen required for charge compensation
  • m and n depend on the oxidation state of the metal cation.
  • Primers of the invention have a strong adhesion to hydrophilic substrates such as in particular glass or ceramic on the one hand and to adhesive tapes, in particular those with polar pressure-sensitive adhesives, for example with pressure-sensitive adhesives based on polyacrylic acid ester, on the other hand.
  • primers according to the invention are excellent adhesion promoters for bonding tapes to glass and ceramic.
  • the adhesion-promoting effect of a primer according to the invention starts very quickly. It was found that an adhesive tape adhered to the primer layer could no longer be removed without destruction from the primer layer applied to a glass or ceramic surface for a short time after adhering, for example after approximately 30 minutes.
  • a primer according to the invention it is possible to fill a primer according to the invention with pigments or other functional fillers, without its adhesion-promoting effect is thereby reduced to an extent relevant to application technology.
  • the speed at which the adhesion-promoting effect sets in and builds up is hardly impaired by the addition of pigments or other functional fillers.
  • the pigments or other functional fillers are contained in the primer layer in such a high concentration that the primer layer is opaque to glass at opacity of about 5 to 20 ⁇ m, ie is opaque.
  • the necessary concentration of the pigments is between 50 and 200% by weight, based on the total weight of the copolymers.
  • a coating material for producing a basecoat is understood in accordance with DIN EN ISO 4618 a coating material for producing a basecoat.
  • a primer or coating material is applied to the surface of a substrate, followed by film formation by evaporation of the solvent and / or by another chemical or physical curing or film-forming process, and then another, other substance, on the thus produced layer,
  • a paint, a paint, an adhesive or an adhesive tape can be applied.
  • requirement for an adhesion-promoting effect of a primer on the one hand a good adhesion of the primer layer to the substrate, the surface of which is also referred to as the substrate, is achieved, and on the other hand also adheres well to the produced primer layer of the other further material to be applied thereto.
  • a primer has an optimum adhesion-promoting effect when it comes to cohesive failure within the fabric, the adhesive product or the adhesive tape or when it comes to destroying the substrate in an attempt to peel off the applied to the primer substance or applied to the primer adhesive product comes on which the primer was previously applied. If the forces required to peel off the primer, adhesive, or tape applied to the primer are higher than they are when no primer is used, adhesion enhancement or adhesion force enhancement is provided. The higher these forces are, the stronger the adhesion improvement or the improvement of the adhesion force.
  • a solvent in the context of the invention is any known liquid which is suitable for dissolving or at least finely distributing the mixture disclosed in the main claim, without entering into an unwanted chemical reaction with the substances according to the invention of this mixture.
  • Preferred solvents according to the invention are organic solvents, for example esters, ketones, aliphatic and aromatic hydrocarbons. Particularly preferred are solvents having a boiling point of less than or equal to 100 ° C. Very particular preference is given to solvents whose boiling point is less than 80 ° C., in particular ethyl acetate with CAS no. 141 -78-6 and acetone (CAS No. 67-64-1).
  • a dispersed mixture is understood according to the invention to mean a finely divided, homogeneous mixture.
  • the degree of fine distribution and homogeneity is not strictly defined, but it must be sufficient that after coating to form a closed layer and the size of the non-molecular dissolved agglomerates or aggregates is sufficiently low that the function of the primer layer as For example, adhesion-promoting layer is guaranteed.
  • the mixture G contained in the primer according to the invention preferably comprises at least one copolymer which is obtained by free-radical copolymerization of the following monomers:
  • the at least one copolymer of mixture G of the primer according to the invention is preferably a pressure-sensitive adhesive. Particularly preferred are all copolymers contained in the mixture G pressure-sensitive adhesives.
  • a pressure-sensitive adhesive As common in common usage, a substance understood that - especially at room temperature - permanently sticky and sticky. It is characteristic of a pressure-sensitive adhesive that it can be applied by pressure to a substrate and adhere there, whereby the pressure to be applied and the duration of this pressure are not further defined. In some cases, depending on the exact nature of the pressure-sensitive adhesive, the temperature and humidity, and the substrate, the application of short-term, minimum pressure, which does not go beyond a light touch for a brief moment to achieve the adhesion effect, is sufficient in others Cases may also require a longer-term exposure time of high pressure.
  • Pressure-sensitive adhesives have special, characteristic viscoelastic properties which lead to permanent tackiness and adhesiveness. Characteristic of them is that when they are mechanically deformed, it comes both to viscous flow processes as well as to build elastic restoring forces. Both processes are in a certain ratio with regard to their respective proportions, depending on the exact composition, the structure and the degree of crosslinking of the pressure-sensitive adhesive as well as on the speed and duration of the deformation and on the temperature. The proportional viscous flow is necessary to achieve adhesion. Only the viscous portions, caused by macromolecules with relatively high mobility, allow a good wetting and a good flow onto the substrate to be bonded.
  • a high proportion of viscous flow leads to a high pressure tack (also referred to as tack or surface tackiness) and thus often also to a high bond strength.
  • Strongly crosslinked systems, crystalline or glassy solidified polymers are usually not or at least only slightly tacky due to the lack of flowable components.
  • the proportional elastic restoring forces are necessary to achieve cohesion. They are caused for example by very long-chained and strongly entangled as well as by physically or chemically crosslinked macromolecules and allow the transmission of forces acting on an adhesive bond forces. They result in an adhesive bond being able to withstand a sustained load acting on it, for example in the form of a permanent shearing load, to a sufficient extent over a relatively long period of time.
  • the variables storage modulus (G ') and loss modulus (G ") which can be determined by means of dynamic mechanical analysis (DMA) can be used elastic proportion, G "is a measure of the viscous portion of a substance. Both quantities depend on the deformation frequency and the temperature. The sizes can be determined with the help of a rheometer.
  • the material to be examined is exposed to a sinusoidal oscillating shear stress in a plate-and-plate arrangement, for example.
  • shear stress controlled devices the deformation as a function of time and the time lag of this deformation are compared with the introduction of the shear stress measured. This time offset is referred to as the phase angle ⁇ .
  • a substance is generally considered to be pressure-sensitive and is defined as tacky, if at room temperature, here by definition at 23 ° C, in the deformation frequency range of 10 ° to 10 1 rad / sec G 'at least partially in the range of 10 3 to 10 7 Pa and when G "is also at least in part within this range.” means “in part, that at least a portion of the G 'curve is within the window formed by the deformation of the frequency range including 10 ° up to and including 10 1 rad / sec (abscissa) and the range of G 'values of 10 3 to and including 10 7 Pa (ordinate) is spanned, and if at least a portion of the G "curve is also within this window.
  • Pressure-sensitive adhesives containing vinylcaprolactam and / or vinylpyrrolidone in the copolymer usually have only average adhesive properties. It was all the more surprising that it was found within the scope of the present invention that a primer containing a copolymer of the invention with vinylcaprolactam and / or vinylpyrrolidone as monomer components has outstanding adhesion-promoting properties and very strong bonding of adhesive tapes to hydrophilic substrates, in particular Glass, manufactures.
  • the copolymer is particularly preferably a pressure-sensitive adhesive, and the monomer mixture of the copolymer comprises only vinylcaprolactam and / or vinylpyrrolidone and one or more of the monomers a) and / or b), i.
  • the copolymer is composed only of these monomers without further copolymerizable monomers are contained.
  • a primer based on such a copolymer has particularly good adhesion-promoting properties.
  • the presence of other - especially softening - comonomers and components can be dispensed with. For example, it is possible to dispense completely with comonomers with cyclic hydrocarbon building blocks.
  • Linear alkyl esters having 2 to 10 C atoms in the alkyl radical are ethyl acrylate, n-propyl acrylate, n-butyl acrylate, n-pentyl acrylate, n-hexyl acrylate, n-heptyl acrylate, n-octyl acrylate, n-nonyl acrylate, n-decyl acrylate.
  • the monomer mixture preferably contains n-butyl acrylate.
  • Branched noncyclic acrylic esters having 3 to 12 carbon atoms, inclusive, in the alkyl radical of the alcohol are preferably selected from the group consisting of 2-ethylhexyl acrylate (EHA), 2-propylheptyl acrylate, isooctyl acrylate, isobutyl acrylate, isoamyl acrylate and isodecyl acrylate.
  • EHA 2-ethylhexyl acrylate
  • 2-propylheptyl acrylate isooctyl acrylate
  • isobutyl acrylate isoamyl acrylate
  • isodecyl acrylate isodecyl acrylate.
  • the monomers b) selected from the group consisting of 2-ethylhexyl acrylate (EHA), 2-propylheptyl acrylate and isooctyl acrylate (to be more precise: the acrylic esters in which the alcohol component is attributable to a mixture of primary isooctanols, ie to those alcohols which consist of an isohepten mixture can be obtained by hydroformylation and subsequent hydrogenation).
  • EHA 2-ethylhexyl acrylate
  • 2-propylheptyl acrylate 2-propylheptyl acrylate
  • isooctyl acrylate to be more precise: the acrylic esters in which the alcohol component is attributable to a mixture of primary isooctanols, ie to those alcohols which consist of an isohepten mixture can be obtained by hydroformylation and subsequent hydrogenation).
  • the weight ratio (monomers a) and b)): (vinylcaprolactam + vinylpyrrolidone) is preferably from 95: 5 to 40:60, more preferably from 85:15 to 50:50, especially from 80:20 to 60:40, for example from 75: 25 to 65: 35.
  • the monomer mixture consists of vinylcaprolactam and / or vinylpyrrolidone and exactly one monomer of the grade a), particular preference being given to choosing n-butyl acrylate as monomer a).
  • vinylcaprolactam is particularly preferred.
  • the monomer mixture consists of vinylcaprolactam and n-butyl acrylate.
  • the weight ratio of n-butyl acrylate: vinyl caprolactam is preferably from 95: 5 to 50:50, more preferably from 80:20 to 60:40.
  • the monomer mixture can contain up to 10% by weight, based on the total weight of the monomer mixture, of further copolymerizable monomers in addition to the monomers already included in the subject of the invention.
  • the other monomers may be selected from the group consisting of: methyl acrylate, methyl methacrylate, ethyl methacrylate, benzyl acrylate, benzyl methacrylate, phenyl acrylate, phenyl methacrylate, isobornyl acrylate, isobornyl methacrylate, t-butylphenyl acrylate, t-butylaphenyl methacrylate, dodecyl methacrylate, lauryl acrylate, n-undecyl acrylate, stearyl acrylate, tridecyl acrylate , Behenyl acrylate, cyclohexyl methacrylate,
  • Macromonomers such as 2-polystyrene ethyl methacrylate (molecular weight MW from 4000 to 13000 g / mol), poly (methyl methacrylate) ethyl methacrylate (MW from 2000 to 8000 g / mol).
  • the monomer mixture of the copolymer of the primer according to the invention preferably contains not more than 50% by weight, more preferably not more than 40% by weight, of vinylcaprolactam and vinylpyrrolidone, based on the total weight of the monomer mixture. Also preferably, the monomer mixture preferably contains at least 10 wt .-%, particularly preferably at least 20 wt .-%, in particular at least 30 wt .-% vinylcaprolactam and / or vinylpyrrolidone, based on the total weight of the monomer mixture.
  • the monomer mixture preferably contains not more than 1% by weight, more preferably not more than 0.1% by weight, based on the total weight of the monomer mixture, of acrylic acid.
  • the monomer mixture is free of acrylic acid.
  • the concentration of the copolymer or the totality of all copolymers of the mixture G, based on the total weight of the primer, is preferably from 1% by weight to 30% by weight, particularly preferably from 2% by weight to 20% by weight, in particular from 3% by weight to 10% by weight.
  • the radicals R 1 independently of one another preferably represent a methyl, ethyl, 2-methoxyethyl or an acetyl radical.
  • the radicals R 3 independently of one another preferably represent a methyl, isooctyl, hexadecyl or cyclohexyl radical.
  • the radical R 2 preferably represents an aminoalkyl, glycidoxyalkyl, vinyl, methacryloxymethyl, 3-methacryloxypropyl or a phenyl radical, in particular a 3-glycidoxy- (n-) propyl or an aminoalkyl radical or a vinyl group.
  • the organofunctional silane of the general structure (1) contains an aminoalkyl radical or a vinyl group.
  • alkoxy-metal acetylacetonate are metal alkoxide acetylacetonate or metal acetylacetonate alkoxide. According to the invention, the metal compound may carry further ligands without departing from the spirit of the invention.
  • the metal is preferably selected from the group consisting of titanium, aluminum, zirconium, zinc and iron; In particular, the metal is titanium or zirconium.
  • the metal compound is particularly preferably selected from titanium or zirconium alkoxides. Most preferably, the metal compound is titanium tetraisopropoxide Ti (/ ' Pr) 4.
  • the proportion by weight of the total of the metal compounds in the mixture G is preferably higher than the proportion by weight of the total of the organofunctional silanes of the general structure (I).
  • a primer according to the invention may comprise further constituents in addition to the abovementioned substances, for example additives such as other polymers, resins, plasticizers, stabilizers, rheological additives, fillers, pigments, crosslinkers, initiators, catalysts, accelerators and the like.
  • a water scavenger was added to the primer according to the invention during its preparation.
  • tosylisocyanate (CAS No. 4083-64-1) was added.
  • the proportion of water scavenger used is preferably 1 to 15 wt .-%, particularly preferably 5 to 10 wt .-%, based on the totality of all copolymers of the mixture G.
  • the primer according to the invention is preferably free of polymers other than the copolymer (s) of the mixture G, in particular of chlorinated polyolefins.
  • the primer according to the invention advantageously contains no block copolymers of the polystyrene / polydiene or polystyrene / hydrogenated polydiene type.
  • block copolymers of the polystyrene / polydiene or polystyrene / hydrogenated polydiene type are to be understood as meaning all polymers whose molecules consist of linked blocks of polystyrene and polydiene units or hydrogenated or partially hydrogenated polydiene units or contain such blocks at least substantially .
  • Typical examples of polydiene and hydrogenated or partially hydrogenated polydiene units are polybutadiene, polyisoprene, polymerized ethylene / butylene and ethylene / propylene blocks.
  • block copolymers of the polystyrene / polydiene or polystyrene / hydrogenated polydiene type have the disadvantage of impairing the adhesion of the primer to hydrophilic surfaces, in particular glass or ceramic, as an additional constituent in the primer according to the invention, compared with a primer according to the invention without this additional constituent .
  • the addition of block copolymers of the polystyrene / polydiene or polystyrene / hydrogenated polydiene type to the primer of the invention requires a different, less polar solvent or mixture of solvents than would be necessary without this addition.
  • the addition of toluene or gasoline is necessary to obtain a homogeneous primer solution.
  • these solvents have a comparatively high boiling point, so that the desire for a fast drying time of the primer can not be met.
  • the primer according to the invention is free of epoxy resins.
  • the primer according to the invention preferably contains one or more fluorescent optical brighteners. This is advantageous because in this way a primed background can be identified. Without optical identification, it is often difficult to distinguish a primed surface from a non-primed surface, since the application rate of a primer is usually very thin and thus optically barely perceptible.
  • a preferred fluorescent optical brightener is 2,5-thiophenediylbis (5-tert-butyl-1,3-benzoxazole), CAS-No. 7128-64-5, commercially available under the trade name Tinopal ® OB.
  • the sum of the proportions by weight of mixture G and of the solvents on the primer according to the invention is preferably at least 80%, more preferably at least 85%, in particular at least 90%, for example at least 92% and very particularly preferably at least 95%.
  • a primer according to the invention preferably contains the following components in the stated proportions, in each case based on the total weight of the primer:
  • Copolymer (e) 3 to 9% by weight
  • Silane (s) of structure (I) 0.5 to 7% by weight
  • Another object of the invention is the use of a primer according to the invention for the preparation of an adhesion-promoting layer, preferably for producing a pigment and / or other functional fillers containing, adhesion-promoting layer, in particular a carbon black-containing, adhesion-promoting layer.
  • Another object of the invention is a method for producing an adhesion-promoting layer on a substrate, which comprises the application of a according to the invention on a substrate and the removal of the one or more solvents.
  • Primers according to the invention have excellent adhesion to glass in particular, but also to many other hydrophilic surfaces such as ceramics.
  • Adhesive tapes with polar pressure-sensitive adhesives adhere excellently to a primer according to the invention.
  • the excellent adhesion is reflected in the fact that the adhesive tape is mainly only under destruction, that is, under internal tape splitting, removable.
  • the adhesion-promoting effect of a primer according to the invention surprisingly sets in very quickly.
  • An adhesive tape glued onto the primer layer can often no longer be detached from the primer layer applied to a glass or ceramic surface in a non-destructive manner even after a short time after the adhesive has been applied, usually after about 30 minutes. This means that the adhesive tape is pulled up very quickly and very strongly due to the adhesion-promoting influence of the primer.
  • the term "mounting" is understood by the person skilled in the art as increasing the bonding strength during storage of an adhesive bond made of substrate and adhesive tape.
  • Inventive primers could also be adjusted so that an adhesive tape after several weeks of moist heat storage or climatic change camps (temperatures of 60 ° to 90 ° C with simultaneous relative humidity of greater than or equal to 80%) of the adhesive composite from the substrate coated with the primer and adhered thereto Adhesive tape can be removed predominantly only with destruction of the adhesive tape.
  • the adhesion-promoting action of the primer is not impaired - at least not measurably - if color pigments or other functional fillers, in particular mineral fillers, are added to the primer. Also, the speed with which the adhesion-promoting effect begins and builds up, and its strength is not impaired by the addition of color pigments or other functional fillers, even if the color pigments or other functional fillers in such a high concentration in the primer layer are that the primer layer at a Application thickness of about 5 - 20 ⁇ on glass opaque, so opaque. Depending on the color pigment, the necessary concentration of color pigments is between 50 and 200% by weight, based on the copolymer.
  • the adhesive tapes adhere so well that cohesive failure within the adhesive tape occurs during the peeling test on adhesives on glass or ceramic, and this effect already occurs 30 minutes after the adhesive tape has been stuck to the glass - Or ceramic surface applied primer layer is achieved.
  • the primer according to the invention can equip the primer according to the invention with certain functionalities, namely when functional fillers are used.
  • the primer can be colored as described when color pigments such as carbon black or titanium dioxide are added, but the primer can also be rendered electrically or thermally conductive if, for example, metal particles are added.
  • the primer can be adjusted in its pH by the choice of the filler, whereby for example by the use of calcium oxide, an antibacterial effect can be produced.
  • rheologically active fillers such as fumed silicas can be used, so that, for example, relatively thick, dimensionally stable primer layers can be produced. Furthermore, it is possible to reduce the cost of the primer by a high proportion of inexpensive mineral fillers, such as chalk, without the performance is measurably impaired.
  • an adhesion-promoting layer with the primer according to the invention is carried out in a known manner, namely by first applying the primer to a substrate. Subsequently, the solvent or solvents are allowed to evaporate, whereupon the adhesive tape can be applied. Between application / evaporation of the solvent and the application of the adhesive tape can be only a few minutes, but also a few days or weeks. Examples
  • DMA Dynamic mechanical analysis
  • the measurements were carried out with the shear stress controlled rheometer DSR 200 N from Rheometric Scientific in the oscillation test with a sinusoidally oscillating shear stress in a plate-plate arrangement.
  • the storage modulus G 'and the loss modulus G " were determined in the frequency sweep from 10 " 1 to 10 2 rad / sec at a temperature of 23 ° C.
  • the unit is rad / sec.
  • the thickness of the measured pressure-sensitively adhesive copolymer samples was always between 0.9 and 1.1 mm (1 +/- 0.1 mm).
  • the pressure-sensitively adhesive copolymer samples were prepared by spreading the copolymers described below on a double-sided siliconized polyester film (release liner), evaporating off the solvent at 70 ° C. and stacking the 100 ⁇ m thick coatings thus obtained until a thickness of about 1 mm was reached.
  • the sample diameter was 25 mm in each case.
  • the preload was carried out with a load of 3N.
  • the stress of the specimens was 2500 Pa in all measurements.
  • the bond strength was determined based on PSTC-101 at room temperature.
  • the primer was first applied to the substrate (the substrate) in a thin layer. This was done with a brush spread of the primer on the substrate.
  • the adhesive tape to be measured was applied to the now provided with the primer in a layer thickness of about 1 ⁇ to 10 ⁇ substrate (glued).
  • a strip of the adhesive tape in a defined width was glued to the substrate coated with the primer with the dimensions 50 mm 125 mm 1, 1 mm by rolling ten times with a 5 kg steel roller.
  • the time between the last roll over of the adhesive tape and the peeling off was: a) 30 minutes, b) 3 days.
  • the take-off angle was 90 °, the take-off speed 300 mm / min.
  • the force required for stripping is the bond strength, which is expressed in units of N / cm and thus refers to a standardized adhesive tape width of 1 cm.
  • the type of failure of the adhesive bond was determined.
  • the measured adhesive strips were back-reinforced with a 23 ⁇ thick, etched with trichloroacetic acid polyester film. All measurements were carried out in an air-conditioned room at 23 ° C and 50% relative humidity.
  • the composites of the substrate coated with the primer according to the invention and the adhesive tape adhered thereto were subjected to storage at selected climatic conditions in order to determine the climatic loading capacity of the bond.
  • the light transmission was measured with the UV / VIS spectrometer UVIKON 923 from Kontron in the wavelength range from 190 to 850 nm.
  • the static glass transition temperature is determined by differential scanning calorimetry according to DIN 53765.
  • the information on the glass transition temperature T g refer to the glass transition temperature value T g according to DIN 53765: 1994-03, unless stated otherwise in individual cases.
  • Heating curves run at a heating rate of 10 K / min. The samples are measured in AI crucibles with perforated lid and nitrogen atmosphere. The second heating curve is evaluated. A glass transition temperature can be seen as a turning point in the thermogram.
  • the determination of the average molecular weight Mw or the average molecular weight MN and the polydispersity D was carried out by means of gel permeation chromatography (GPC).
  • the eluent used was THF containing 0.1% by volume of trifluoroacetic acid. The measurement was carried out at 25 ° C.
  • the precolumn used was PSS-SDV, 5 ⁇ m, 103 ⁇ (10-7 m), ID 8.0 mm ⁇ 50 mm.
  • the columns PSS-SDV, 5 m, 103 A (10-7 m), 105 A (10-5 m) and 106 A (10-4 m) were used each with ID 8.0 mm ⁇ 300 mm.
  • the sample concentration was 4 g / l, the flow rate 1, 0 ml per minute. It was measured against PMMA standards.
  • the solids content is a measure of the proportion of non-volatile constituents in a polymer solution. It is determined gravimetrically by weighing the solution, then evaporating the vaporizable fractions for 2 hours at 120 ° C in a drying oven and weighing back the residue.
  • the K value is a measure of the average molecular size of high polymer substances.
  • one percent (1 g / 100 ml) of toluene polymer solutions were prepared and determined with the aid of a VOGEL OSSAG Viskositmeters their kinematic viscosities. After normalization to the viscosity of the toluene, the relative viscosity is obtained, from which, according to FIKENTSCHER, the K value can be calculated (Polymer 8/1967, 381 ff.).
  • substrates substrates to which the primer was first applied and then the adhesive tape was adhered thereto
  • substrates substrates to which the primer was first applied and then the adhesive tape was adhered thereto
  • test tapes used to test the primer were based on polyacrylate pressure-sensitive adhesives.
  • polyacrylate pressure-sensitive adhesives To prepare these polyacrylate pressure-sensitive adhesives, the following raw materials were used:
  • the expandability of the microballoons can be described by determining the TMA density [kg / m 3 ] (Stare Thermal Analysis System from Mettler Toledo, heating rate 20 ° C / min).
  • the TMA density is the minimum achievable density at a certain temperature T ma x under normal pressure before the microballoons collapse.
  • the determination of the softening point of the resins is carried out according to DIN ISO 4625.
  • Test Adhesive Tape 1 An exemplary polyacrylate pressure-sensitive adhesive 1 for preparing Test Adhesive Tape 1 was prepared as follows: A conventional reactor for radical polymerizations was charged with 54.4 kg 2-ethylhexyl acrylate, 20.0 kg methyl acrylate, 5.6 kg acrylic acid and 53.3 kg Acetone / isopropanol (94: 6). After passing nitrogen gas for 45 minutes with stirring, the reactor was heated to 58 ° C and 40 g of Vazo 67 dissolved in 400 g of acetone was added. Subsequently, the outer heating bath was heated to 75 ° C and the reaction was carried out constantly at this external temperature.
  • This base polymer was melted in a feed extruder (single screw extruder from TROESTER GmbH & Co KG, Germany) and with this as Polymer melt promoted via a heated hose in a planetary roller extruder from Entex (Bochum).
  • the molten resin Dertophene T 1 10 was then added via a metering orifice, resulting in a concentration of the resin in the melt of 28.3% by mass.
  • the crosslinker Polypox R16 was added. Its concentration in the melt was 0.14% by mass. All components were mixed to a homogeneous polymer melt.
  • the polymer melt was transferred to a twin-screw extruder (Berstorff). There the accelerator Epikure 925 was added. Its concentration in the melt was 0.14% by mass. Subsequently, the entire polymer mixture was freed in a Vakuumdom at a pressure of 175 mbar of all gas inclusions. Following the vacuum zone, the microballoons were metered in and incorporated homogeneously into the polymer mixture by means of a mixing element. Their concentration in the melt was 0.7 percent by mass. The resulting melt mixture was transferred to a nozzle.
  • the incorporated microballoons expanded, whereby the pressure drop resulted in a shear-free cooling of the polymer mass.
  • the result was a foamed polyacrylate pressure-sensitive adhesive, which was then formed by means of a roll calender web-shaped in a thickness of 0.8 mm and covered with a double-sided siliconized release film (50 ⁇ polyester), while the chemical cross-linking reaction progressed.
  • the wound film was stored at room temperature for four weeks before being further used for the primer test.
  • the wound film is the test adhesive tape 1.
  • An exemplary polyacrylate pressure-sensitive adhesive 2A for producing the middle layer of the three-layer test adhesive tape 2 was prepared as follows:
  • a reactor conventional for radical polymerizations was charged with 30.0 kg of 2-ethylhexyl acrylate, 67.0 kg of butyl acrylate, 3.0 kg of acrylic acid and 66.7 kg of acetone / isopropanol (96: 4). After passage of nitrogen gas for 45 minutes with stirring, the reactor was heated to 58 ° C. and 50 g of Vazo 67 dissolved in 500 g of acetone were added. Subsequently, the outer heating bath was heated to 70 ° C and the reaction was carried out constantly at this external temperature. After 1 h again 50 g Vazo 67, dissolved in 500 g acetone, and after 2 h with 10 kg of acetone / isopropanol mixture (96: 4) diluted.
  • This base polymer was melted in a feed extruder (single screw extruder from TROESTER GmbH & Co KG, Germany) and conveyed with this as polymer melt through a heatable hose into a planetary roller extruder from Entex (Bochum).
  • the crosslinking agent Polypox R16 has now been added via a metering orifice. Its concentration in the melt was 0.22% by mass. All components were mixed to a homogeneous polymer melt.
  • the polymer melt was transferred to a twin-screw extruder (Berstorff). There the accelerator Epikure 925 was added. Its concentration in the melt was 0.14% by mass. Subsequently, the entire polymer mixture was freed in a Vakuumdom at a pressure of 175 mbar of all gas inclusions. Following the vacuum zone, the microballoons were metered in and homogeneously incorporated into the polymer mixture by means of a mixing element. Its concentration in the melt was 2.0% by mass. The resulting melt mixture was transferred to a nozzle.
  • a conventional 100 L glass reactor for free-radical polymerizations was charged with 4.8 kg of acrylic acid, 11.6 kg of butyl acrylate, 23.6 kg of 2-ethylhexyl acrylate and 26.7 kg of acetone / special gasoline 60/95 (1: 1). After passing nitrogen gas with stirring for 45 minutes, the reactor was heated to 58 ° C and 30 g of AIBN was added. Subsequently, the outer heating bath was heated to 75 ° C and the reaction was carried out constantly at this external temperature. After 1 h of reaction time, 30 g of AIBN were again added. After 4 and 8 h was diluted with 10.0 kg of acetone / special gasoline 60/95 (1: 1) mixture.
  • the wound film was stored for two days at room temperature before being further used for the preparation of the test adhesive tape 2.
  • a film of the polyacrylate pressure-sensitive adhesive 2B was laminated on both sides.
  • the double-sided siliconized release film of the foamed polyacrylate pressure-sensitive adhesive 2A was uncovered.
  • one of the two-sided siliconized release films of the two foamed polyacrylate pressure-sensitive adhesives 2B was also covered.
  • the three-layer composite of polyacrylate pressure sensitive adhesive 2B / polyacrylate pressure sensitive adhesive 2A / polyacrylate pressure sensitive adhesive 2B was wound up and held for four weeks Stored room temperature before it was further used for the primer test.
  • the wound composite is the test adhesive tape 2.
  • Polyacrylate pressure-sensitive adhesives for use as a component in the primer according to the invention were prepared as follows: Primer pressure-sensitive adhesive 1
  • a conventional 100 L glass reactor for free-radical polymerizations was charged with 12.0 kg of N-vinylcaprolactam, 28.0 kg of butyl acrylate and 26.7 kg of acetone / special gasoline 60/95 (1: 1). After passing nitrogen gas with stirring for 45 minutes, the reactor was heated to 58 ° C and 30 g of AIBN was added. Subsequently, the outer heating bath was heated to 75 ° C and the reaction was carried out constantly at this external temperature. After 1 h of reaction time, 30 g of AIBN were again added. After 4 and 8 h was diluted with 10.0 kg of acetone / special gasoline 60/95 (1: 1) mixture.
  • a conventional 100 L glass reactor for free-radical polymerizations was charged with 8.0 kg of N-vinylcaprolactam, 32.0 kg of 2-ethylhexyl acrylate and 26.7 kg of acetone / special gasoline 60/95 (1: 1). After passing nitrogen gas with stirring for 45 minutes, the reactor was heated to 58 ° C and 30 g of AIBN was added. Subsequently, the outer heating bath was heated to 75 ° C and the reaction was carried out constantly at this external temperature. After 1 h of reaction time, 30 g of AIBN were again added. After 4 and 8 h was diluted with 10.0 kg of acetone / special gasoline 60/95 (1: 1) mixture.
  • a conventional 100 L glass reactor for free-radical polymerizations was charged with 8.0 kg of N-vinyl-2-pyrrolidone, 32 kg of butyl acrylate, and 26.7 kg of acetone / special gasoline 60/95 (1: 1). After passing nitrogen gas with stirring for 45 minutes, the reactor was heated to 58 ° C and 30 g of AIBN was added. Subsequently, the outer heating bath was heated to 75 ° C and the reaction was carried out constantly at this external temperature. After 1 h of reaction time, 30 g of AIBN were again added. After 4 and 8 h was diluted with 10.0 kg each acetone / special gasoline 60/95 (1: 1) mixture.
  • a conventional 100 L glass reactor for free-radical polymerizations was charged with 15.4 kg of butyl acrylate, 24.4 kg of 2-ethylhexyl acrylate and 26.7 kg of acetone / special gasoline 60/95 (1: 1). After passing nitrogen gas with stirring for 45 minutes, the reactor was heated to 58 ° C and 30 g of AIBN was added. Subsequently, the outer heating bath was heated to 75 ° C and the reaction was carried out constantly at this external temperature. After 1 h of reaction time, 30 g of AIBN were again added. After 4 and 8 h was diluted with 10.0 kg of acetone / special gasoline 60/95 (1: 1) mixture.
  • Primer adhesives 1 to 4 were briefly characterized by DMA measurements.
  • the G 'and G "curves of the primer pressure-sensitive adhesives 1 to 4 were always in the deformation frequency range of 10 ° to 10 1 rad / sec at 23 ° C at least partially in the range of 10 3 to 10 7 Pa.
  • the primer pressure-sensitive adhesives described above with regard to their preparation and composition were used, as well as the following raw materials:
  • the following solvent was used to prepare the primers according to the invention: Designation CAS no. Manufacturer or
  • composition of the primer is composition of the primer:
  • composition of the primer is composition of the primer:
  • the primer was tested in the same manner with the same test adhesive tapes as the pigment-free primer of Example 1, with the same results being obtained, that is, in all cases the test adhesive tape split cohesively.
  • composition of the primer is composition of the primer:
  • a 10 ⁇ thick layer of this primer on glass was opaque.
  • the transmission in the wavelength range from 300 nm to 650 nm was 0%.
  • the primer was tested in the same way with the same test adhesive tapes as the color pigment-free primer of Example 1, with the same results being obtained, that is, in all cases the test adhesive tape split cohesively.
  • composition of the primer is composition of the primer:
  • Example 2a The compositions of the color pigments and optionally rheological additives containing primers while retaining the basic primer composition of Example 2 were as follows: Example 2a
  • composition of the primer is composition of the primer:
  • the primer was tested in the same way with the same test adhesive tapes as the color pigment-free primer of Example 2, with the same results being obtained, that is, in all cases the test adhesive tape split cohesively.
  • composition of the primer is composition of the primer:
  • a 10 ⁇ thick layer of this primer on glass was opaque.
  • the transmission in the wavelength range from 300 nm to 650 nm was 0%.
  • composition of the primer is composition of the primer:
  • Example 3a The compositions of the color pigments and optionally rheological additives containing primers while retaining the basic primer composition of Example 3 were as follows: Example 3a
  • composition of the primer is composition of the primer:
  • composition of the primer is composition of the primer:
  • a 10 ⁇ thick layer of this primer on glass was opaque.
  • the transmission in the wavelength range from 300 nm to 650 nm was 0%.
  • composition of the primer is composition of the primer:
  • Example 4a The composition of the color pigment-containing primer while retaining the basic primer composition of Example 4 was as follows: Example 4a
  • composition of the primer is composition of the primer:
  • composition of the primer is composition of the primer:
  • composition of the color pigment-containing primer while retaining the basic primer composition of Example 5 was as follows:
  • composition of the primer is composition of the primer:
  • composition of the primer is composition of the primer:
  • composition of the color pigment-containing primer while retaining the basic primer composition of Example 6 was as follows:
  • composition of the primer is composition of the primer:
  • the primer was tested in the same way with the same test adhesive tapes as the color pigment-free primer of Example 6, with the same results being obtained, that is, in all cases the test adhesive tape split cohesively.
  • composition of the primer is composition of the primer:
  • composition of the color pigment-containing primer while retaining the basic primer composition of Example 7 was as follows:
  • composition of the primer is composition of the primer:
  • the primer was tested in the same way with the same test adhesive tapes as the color pigment-free primer from Example 7, with the same results being obtained, that is, in all cases the test adhesive tape split cohesively. Furthermore, it was possible to incorporate the fluorescent optical brightener in a functional concentration in all examples, without causing any loss of the adhesion-promoting effect. This functional concentration was chosen to be 1.5 mass percent based on the solvent-free portion of the primer.
  • composition of the comparative primer Raw material / component mass percentage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un primaire comprenant un mélange G qui est dissous ou dispersé dans un ou plusieurs solvants et qui constitué d'au moins un copolymère, obtenu par copolymérisation d'un mélange de monomères, comprenant jusqu'à au moins 90% en poids les monomères suivants : du vinylcaprolactame et/ou de la vinylpyrrolidone et un ou plusieurs des monomères a) et/ou b) : a) un ester d'acide acrylique d'un alcool primaire linéaire ayant de 2 à 10 atomes de carbone dans le radical alkyle de l'alcool, b) un ester d'acide acrylique d'un alcool non cyclique ramifié ayant 3 à 12 atomes de carbone dans le radical alkyle de l'alcool, au moins un silane organofonctionnel de la formule générale (I) : (R1O-)xSi(R2)y(R3)z, les radicaux R1 étant, indépendamment, un radical alkyle en C1-C4, un radical alcoxyalkyle en C2-C6 ou un radical acétyle ; le radical R2 étant un radical aminoalkyle, un radical vinyle, un radical méthacryloxyalkyle, un radical isocyanatoalkyle, un radical O-méthylcarbamatoalkyle, un radical glycidoxyalkyle ou un radical phényle ; les radicaux R3 étant, indépendamment, un radical alkyle en C1-C18 et x = 1, 2 ou 3 ; y = = 0 ou 1, et z = 4-x-y ; au moins un composé métallique choisi dans le groupe comportant des acétylacétonates métalliques, des alcoolates métalliques et des acétylacétonates alcoxymétalliques. Un tel primaire permet une bonne adhérence entre des bandes adhésives et des surfaces hydrophiles telles que le verre et permet en particulier l'incorporation de charges fonctionnelles.
EP15718199.1A 2014-05-09 2015-04-20 Primaire pour améliorer l'adhérence de bandes adhésives à surfaces hydrophiles Withdrawn EP3140344A1 (fr)

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DE102014208814.3A DE102014208814A1 (de) 2014-05-09 2014-05-09 Primer zur Verbesserung der Adhäsion von Klebebändern auf hydrophilen Oberflächen
PCT/EP2015/058495 WO2015169575A1 (fr) 2014-05-09 2015-04-20 Primaire pour améliorer l'adhérence de bandes adhésives à surfaces hydrophiles

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US20170066947A1 (en) 2017-03-09
KR20170007358A (ko) 2017-01-18
CN106459714B (zh) 2019-08-09
WO2015169575A1 (fr) 2015-11-12
DE102014208814A1 (de) 2015-11-12
CN106459714A (zh) 2017-02-22
JP2017519093A (ja) 2017-07-13

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