EP3081595B1 - Polyacetal resin composition, and sulfur-containing fuel contact body provided with molded article comprising said polyacetal resin composition - Google Patents

Polyacetal resin composition, and sulfur-containing fuel contact body provided with molded article comprising said polyacetal resin composition Download PDF

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Publication number
EP3081595B1
EP3081595B1 EP15782256.0A EP15782256A EP3081595B1 EP 3081595 B1 EP3081595 B1 EP 3081595B1 EP 15782256 A EP15782256 A EP 15782256A EP 3081595 B1 EP3081595 B1 EP 3081595B1
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EP
European Patent Office
Prior art keywords
polyacetal resin
resin composition
mass
parts
polyacetal
Prior art date
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EP15782256.0A
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German (de)
English (en)
French (fr)
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EP3081595A4 (en
EP3081595A1 (en
Inventor
Akihide Shimoda
Satomi Nakada
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Polyplastics Co Ltd
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Polyplastics Co Ltd
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Publication of EP3081595A4 publication Critical patent/EP3081595A4/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
    • C08L59/04—Copolyoxymethylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/14—Chemical modification with acids, their salts or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C08J2359/02—Copolyoxymethylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
    • F02M2200/90—Selection of particular materials
    • F02M2200/9015—Elastomeric or plastic materials

Definitions

  • the present invention relates to a polyacetal resin composition and to a sulfur-containing fuel contact body provided by a molded article of this polyacetal resin composition.
  • Polyacetal resins have excellent chemical resistance, thus molded articles having a polyacetal resin as a raw material have been widely used for automobile components. For example, they have been used for large components which directly contact fuel oil such as fuel delivery units and the like, represented by fuel pump modules and the like.
  • a polyacetal resin composition having a high acid resistance As a polyacetal resin composition having a high acid resistance, a polyacetal resin composition comprising (A) 100 parts by mass of a polyacetal resin; (B) 0.1 to 3.0 parts by mass of a hindered phenolic antioxidant; (C) 0.001 to 3.0 parts by mass of a nitrogen-containing compound; (D) 0.1 to 3.0 parts by mass of a fatty acid calcium salt; and (E) 0.1 to 3.0 parts by mass of a lubricant has been proposed (refer to Patent Document 1). Polyacetal resin compositions are also disclosed in WO2010/119826 . Patent Document 1: Japanese Unexamined Patent Application, Publication No. 2010-031200
  • the present invention has the objective of providing a polyacetal resin composition which, when made into a molded article, is capable of restraining to a minimum the deterioration when contacting a sulfur-containing fuel.
  • the present inventors as a result of repeated diligent research to solve the above mentioned problem, discovered that by making the composition of a polyacetal resin composition a specified composition, when making a molded article, it is possible to restrain to a minimum the deterioration when contacting a sulfur-containing fuel, and thus completed the present invention.
  • the present invention provides the following.
  • a polyacetal resin composition which, when making a molded article, is capable of restraining to a minimum the deterioration when contacted with a sulfur-containing fuel.
  • the polyacetal resin composition of the present invention comprises (A) 100 parts by mass of a polyacetal resin, (B) 0.1 to 1.0 parts by mass of a hindered phenolic antioxidant, (C) 0.1 to 2.0 parts by mass of an alkaline earth metal oxide, (D) 0.5 to 3.0 parts by mass of a polyalkylene glycol, and (E) 0.01 to 1.0 parts by mass of a polyvalent fatty acid full ester.
  • the (A) polyacetal resin may also be referred to as component (A)
  • the (B) hindered phenolic antioxidant may also be referred to as component (B)
  • the (C) alkaline earth metal oxide may also be referred to as component (C)
  • the (D) polyalkylene glycol may also be referred to as component (D)
  • the (E) polyvalent fatty acid full ester may also be referred to as component (E).
  • the (A) polyacetal resin used in the present invention is a high molecular compound having an oxymethylene group (-CH 2 O-) as the main structural unit, and a polyacetal polymer consisting substantially only of oxymethylene group repeating units, or a polyacetal copolymer comprising a small content of constituent units other than the oxymethylene groups, and the like may be mentioned. It is possible to use any of these, but from the viewpoint of acid resistance which is an objective of the present invention, it is preferable to use a polyacetal copolymer as the base resin.
  • the component (A) is a polyacetal copolymer
  • a polyacetal copolymer copolymerized with 0.5 to 30 mass% of the comonomer component is preferable, and one copolymerized with 0.5 to 10 mass% of the comonomer is particularly preferable.
  • a polyacetal copolymer copolymerized with a comonomer component, along with having excellent acid resistance, is also able to maintain excellent thermal stability, mechanical strength and the like.
  • the polyacetal copolymer may be not only one where the molecule has a linear structure, but may also be one having a branched structure or a crosslinked structure.
  • cyclic oligomers of formaldehyde represented by trioxane are used as the main monomer.
  • a compound selected from a cyclic formal and/or a cyclic ether having at least one carbon-carbon bond is used as the comonomer component.
  • comonomers for example, ethylene oxide, 1,3-dioxolane, diethylene glycol formal, 1,4-butanediol formal, 1,3-dioxane, propylene oxide and the like may be mentioned.
  • a melt index (MI) measured at a temperature of 190°C and a load of 2.16 kg is preferably 1 to 100 g/10 min, and particularly preferably 5 to 30 g/10 min.
  • (B) hindered phenolic antioxidant used in the present invention 2,2'-methylenebis(4-methyl-6-t-butylphenol), hexamethylene glycol-bis(3,5-di-t-butyl-4-hydroxyhydrocinnamate), tetrakis[methylene-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionat e]methane, triethylene glycol-bis-3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionate, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxy benzyl)benzene, n-octadecyl-3-(4'-hydroxy-3',5'-di-t-butylphenol)propionate, 4,4'-methylenebis(2,6-di-t-butylphenol), 4,4'-butylidene-bis-(6-t-butyl-3
  • the content of the (B) hindered phenolic antioxidant in the present invention is 0.1 to 1.0 parts by mass with respect to 100 parts by mass of the (A) polyacetal resin, and preferably 0.2 to 0.5 parts by mass. If the blended amount of the (B) antioxidant is low, the oxidation prevention property which is its primary objective will be insufficient, an in addition, the fuel resistance, which is an objective of the present invention, will also be inferior. In the case that the blended amount of the (B) antioxidant is excessive, unfavorable effects on the mechanical properties and formability and the like of the resin composition will arise.
  • magnesium oxide As the (C) alkaline earth metal oxide used in the present invention, magnesium oxide, calcium oxide, barium oxide and the like may be mentioned. Among these metal oxides, magnesium oxide is preferable because it provides the most improvement in fuel resistance and an excellent balance of performance such as mechanical properties and formability.
  • the content of the (C) alkaline earth metal oxide in the present invention is 0.1 to 2.0 parts by mass with respect to 100 parts by mass of the (A) polyacetal resin, and preferably 1.0 to 2.0 parts by mass. If the blended amount of the (C) alkaline earth metal oxide is low, the fuel resistance which is an objective of the present invention will be degraded. In the case that the blended amount of the (C) alkaline earth metal oxide is excessive, decomposition of unstable terminals in the polyacetal resin will be promoted, and an unfavorable effect on the mechanical properties and formability and the like will arise.
  • the type of the (D) polyalkylene glycol used in the present invention is not particularly limited, but from the viewpoint of affinity with the polyacetal resin, one comprising polyethylene glycol and/or polypropylene glycol is preferable, and one comprising polyethylene glycol is more preferable.
  • the number average molecular weight (Mn) of the polyalkylene glycol is not particularly limited, but from the viewpoint of dispersibility in the polyacetal resin 1, 000 to 50, 000 is preferable, and 5,000 to 30,000 is more preferable. Further, in the present specification, the number average molecular weight is a polystyrene-converted molecular weight determined by gel permeation chromatography (GPC) with tetrahydrofuran (THF) as the solvent.
  • GPC gel permeation chromatography
  • THF tetrahydrofuran
  • the content of the (D) polyalkylene glycol in the present invention is 0.5 to 3.0 parts by mass with respect to 100 parts by mass of the (A) polyacetal resin, and preferably 1.0 to 2.0 parts by mass. If the blended amount of the (D) polyalkylene glycol is low, there is the possibility that sufficient stress relaxation will not be carried out. In the case that the blended amount of the (D) polyalkylene glycol is excessive, there is the possibility that the mechanical properties of the molded article will be degraded.
  • the (E) polyvalent fatty acid full ester used in the present invention is preferably a full ester compound polyvalent fatty acid ester of a polyvalent alcohol with a carbon number of 3 or more and a fatty acid.
  • the esterification rate of the "full ester compound” is not necessarily 100%, and 80% or more is sufficient, 85% or more is preferable, and 90% or more is more preferable.
  • the polyvalent alcohol may be aliphatic, or may be aromatic, but in the point of affinity for the polyacetal resin, it is preferably aliphatic.
  • the valence number of the polyvalent alcohol is not particularly limited, but is preferably 3 to 4. Further, the carbon number of the polyvalent alcohol is not particularly limited, but in the point of affinity for the polyacetal resin, it is preferably 3 to 10, and more preferably 3 to 5.
  • the polyvalent alcohol for forming the component (E) for example, glycerin, trimethylolpropane, pentaerythritol, meso-erythritol, pentitol, hexitol, sorbitol and the like may be mentioned, but in the point of restraining to a low level the mass reduction of the polyacetal resin composition after immersion in a sulfur-containing fuel, the polyvalent alcohol is preferably pentaerythritol.
  • the type of the fatty acid is not particularly limited, but in the point of affinity for the polyacetal resin, a fatty acid with a carbon number of 10 to 30 is preferable, and an aliphatic carboxylic acid with a carbon number of 10 to 20 is more preferable.
  • a fatty acid which is preferable for forming the ester of component (E) for example, stearic acid, palmitic acid, lauric acid and the like may be mentioned, and stearic acid may be preferably mentioned.
  • ester of the component (E) As the ester of the component (E), glycerin tristearylate or pentaerythritol tetrastearylate may be suitably used, but pentaerythritol tetrastearylate is more suitably used. Further, for the component (E), two or more ester compounds having differing constituent polyvalent alcohols or fatty acids, or two or more ester compounds having differing esterification rates, may be used in combination.
  • the content of the (E) polyvalent fatty acid full ester in the present invention is 0.01 to 1.0 parts by mass with respect to 100 parts by mass of the (A) polyacetal resin, and more preferably 0.05 to 1.0 parts by mass. If the blended amount of the (E) polyvalent fatty acid full ester is low, there is the possibility of worsening of the mold release characteristics of the molded article. In the case that the blended amount of the (E) polyvalent fatty acid full ester is excessive, there is the possibility that the processability of the molded article is reduced.
  • the fuel contact body of the present invention is provided with a molded article of the above mentioned polyacetal resin composition.
  • This molded article can be obtained by molding by a common molding method using the above mentioned polyacetal resin composition, for example methods such as injection molding, extrusion molding, compression molding, blow molding,vacuum molding, foam molding, rotational molding, and the like.
  • the fuel contact body of the present invention is not limited to low sulfur-containing fuels, and may also be one which is contacted with a high sulfur-containing fuel. Even when contacted with a high sulfur-containing fuel, because it is possible to suppress the generation of cracks, and to maintain a good exterior surface of the molded article, it is possible to suppress leakage of the fuel.
  • low sulfur-containing fuel refers to fuel where the concentration of sulfur is 50 ppm or less, for example, JIS No. 2 diesel fuel of Japan, or EN590 diesel fuel of the European Union and the like may be mentioned.
  • a "high sulfur-containing fuel” is a fuel with a concentration of sulfur exceeding 50 ppm, and the high sulfur diesel fuels distributed in China, India and elsewhere and the like may be mentioned.
  • Example Comparative Example 1 2 3 4 1 2 3 4 5 6 (A) polyacetal resin 97.6 95.4 95.2 97 98.4 98.7 98.4 96.7 97.4 96.4 (B) hindered phenolic antioxidant, 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 (C)alkaline earth metal oxide 1 2 2 1.5 1 1 1 1 1 (D)polyalkylene glycol 1 2 2 1 1 2 1 2 (E1)polyvalent fatty acid full ester 1 0.1 0.3 0.5 0.3 0.3 (E2)polyvalent fatty acid full ester 2 0.2 (E'1)polyvalent fatty acid ester with an Esterification Rate of Less than 80% 0.3 (E'2)monovalent fatty acid ester 0.3 (units: parts by mass)
  • Magnesium oxide (product name: Kyowamag MF-150, manufactured by Kyowa Chemical Industry Co., Ltd.)
  • Pentaerythritol Stearic Acid Ester product name: Unister H-476, manufactured by NOF Corporation
  • Glycerine tristearate product name: Poem S-95, manufactured by Riken Vitamin Co., Ltd.
  • Glycerin monostearate product name: Rikemal S-100A, manufactured by Riken Vitamin Co., Ltd.
  • a resin molded article having as a raw material a polyacetal resin composition comprising (A) 100 parts by mass of a polyacetal resin, (B) 0.1 to 1.0 parts by mass of a hindered phenolic antioxidant, (C) 0.1 to 2.0 parts by mass of an alkaline earth metal oxide, (D) 0.5 to 3.0 parts by mass of a polyalkylene glycol, and (E) 0.01 to 1.0 parts by mass of a polyvalent fatty acid full ester, was confirmed to have a mass change rate which was restrained to within -10% even after immersion in a sulfur-containing fuel.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
EP15782256.0A 2014-04-25 2015-03-25 Polyacetal resin composition, and sulfur-containing fuel contact body provided with molded article comprising said polyacetal resin composition Active EP3081595B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2014091119A JP5814419B1 (ja) 2014-04-25 2014-04-25 ポリアセタール樹脂組成物、及びこのポリアセタール樹脂組成物の成形品を備える硫黄燃料接触体
PCT/JP2015/059219 WO2015163081A1 (ja) 2014-04-25 2015-03-25 ポリアセタール樹脂組成物、及びこのポリアセタール樹脂組成物の成形品を備える硫黄燃料接触体

Publications (3)

Publication Number Publication Date
EP3081595A1 EP3081595A1 (en) 2016-10-19
EP3081595A4 EP3081595A4 (en) 2017-02-22
EP3081595B1 true EP3081595B1 (en) 2017-08-16

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EP15782256.0A Active EP3081595B1 (en) 2014-04-25 2015-03-25 Polyacetal resin composition, and sulfur-containing fuel contact body provided with molded article comprising said polyacetal resin composition

Country Status (6)

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US (1) US10072147B2 (ko)
EP (1) EP3081595B1 (ko)
JP (1) JP5814419B1 (ko)
KR (1) KR101679383B1 (ko)
CN (1) CN105683282B (ko)
WO (1) WO2015163081A1 (ko)

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US11485856B2 (en) * 2017-05-05 2022-11-01 Ticona Llc Polyoxymethylene polymer composition that is chemical resistant

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JP7078687B2 (ja) 2020-10-09 2022-05-31 ポリプラスチックス株式会社 ポリアセタール樹脂組成物及び自動車部品
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JP5814419B1 (ja) 2015-11-17
EP3081595A4 (en) 2017-02-22
US10072147B2 (en) 2018-09-11
EP3081595A1 (en) 2016-10-19
JP2015209474A (ja) 2015-11-24
KR20160055970A (ko) 2016-05-18
CN105683282B (zh) 2017-03-29
US20160251509A1 (en) 2016-09-01
WO2015163081A1 (ja) 2015-10-29
CN105683282A (zh) 2016-06-15
KR101679383B1 (ko) 2016-11-25

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