EP3006610B1 - Ungecrimpte stapelfaser mit organischem harz - Google Patents

Ungecrimpte stapelfaser mit organischem harz Download PDF

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Publication number
EP3006610B1
EP3006610B1 EP14804999.2A EP14804999A EP3006610B1 EP 3006610 B1 EP3006610 B1 EP 3006610B1 EP 14804999 A EP14804999 A EP 14804999A EP 3006610 B1 EP3006610 B1 EP 3006610B1
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EP
European Patent Office
Prior art keywords
fiber
crimped staple
staple fiber
cut
crimped
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EP14804999.2A
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English (en)
French (fr)
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EP3006610A4 (de
EP3006610A1 (de
Inventor
Noritaka Ban
Hironori Goda
Shinichi Takahashi
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Teijin Ltd
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Teijin Ltd
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01G—PRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G1/00—Severing continuous filaments or long fibres, e.g. stapling
    • D01G1/02—Severing continuous filaments or long fibres, e.g. stapling to form staple fibres not delivered in strand form
    • D01G1/04—Severing continuous filaments or long fibres, e.g. stapling to form staple fibres not delivered in strand form by cutting
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/26—Formation of staple fibres
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/435—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

Definitions

  • the present invention relates to an organic resin non-crimped staple fiber having uniform dispersibility in media.
  • Wet-laid nonwoven fabrics made from a raw material that is partially or fully a staple fiber (as a short fiber as it is also called) obtained from a wholly aromatic polyamide having desirable properties such as mechanical characteristics, electrical characteristics, heat resistance, flame-retardation, and dimensional stability, or from more cost advantageous polyester are used in applications such as in electrical insulation paper, and a cleaning web for copiers (see, for example, PTL 1).
  • Such wet-laid nonwoven fabrics are also used in a wide range of applications, including industrial materials such as reinforcing materials for resin molded products, and daily commodities.
  • the increasing demand for more flexible, thinner and denser nonwoven fabrics has created a demand to increase the fineness of organic resin stable fibers used for the wet-laid nonwoven fabrics.
  • the dispersibility of the stable fiber in a dispersion medium needs to be improved for the formation of the wet-laid nonwoven fabric. This requires further reducing the fiber length of the stable fiber.
  • the fibers become more likely to intertangle as they become finer and increase the aspect ratio (fiber length-to-fiber diameter ratio).
  • a nonwoven fabric made with such fibers tends to involve fluff ball defects. Such defects can be circumvented by reducing the fiber length and keeping the aspect ratio small. While this can reduce the fluff ball defects due to intertangling of fibers, defects at the cut-end of the fibers cause the stable fibers to be entangled with each other and aggregate, with the result that the product (e.g., nonwoven fabric) becomes defective.
  • Ultrafine fibers of 0.6 decitex or less can be cut into essentially any fiber length as short as less than 1 millimeter with a known guillotine cutter. Specifically, the aspect ratio can be reduced.
  • the present invention was made under these circumstances, and the invention is concerned with an organic resin non-crimped staple fiber (stable fiber) that uniformly disperses in a medium without causing aggregation defects.
  • the present inventors conducted intensive studies to solve the foregoing problems, and arrived at using the following configurations as a solution to the foregoing problems.
  • the present invention enables uniformly dispersing a non-crimped staple fiber of organic resin in a dispersion medium, and reducing generation of an aggregated clump in using a non-crimped staple fiber for wet-laid nonwoven fabrics or staple fiber reinforced resins.
  • the nonwoven fabric or other products made from such non-crimped staple fibers contain staple fibers uniformly dispersed therein.
  • the product nonwoven fabric is thus free from defects such as microscopic nonuniform dispersion of staple fibers, and variation of basis weight and thickness, and can have desirable properties such as uniform breathability and liquid permeability.
  • the final product produced by processing such nonwoven fabrics involves few defects, and can have physical properties with improved reliability (reliable product warranty).
  • the yield of the interim product e.g., nonwoven fabric, and resin molded body
  • the present invention is thus also highly advantageous in terms of resource saving and economy.
  • FIG. 1 is a schematic view at the cut end of an organic resin non-crimped staple fiber of the present invention.
  • the polyester is any of polyesters of aromatic dicarboxylic acid and aliphatic diol, including, for example, polyalkylene terephthalates such as polyethylene terephthalate, polytrimethylene terephthalate, and polybutylene terephthalate (polytetramethylene terephthalate), and polyalkylene naphthalates such as polyethylene naphthalate, polytrimethylene naphthalate, and polybutylene naphthalate (polytetramethylene naphthalate).
  • polyalkylene terephthalates such as polyethylene terephthalate, polytrimethylene terephthalate, and polybutylene terephthalate (polytetramethylene terephthalate)
  • polyalkylene naphthalates such as polyethylene naphthalate, polytrimethylene naphthalate, and polybutylene naphthalate (polytetramethylene naphthalate).
  • polyesters obtained from alicyclic dicarboxylic acid and aliphatic diol such as polyalkylene cyclohexane dicarboxylate, polyesters obtained from aromatic dicarboxylic acid and alicyclic diol such as polycyclohexane dimethylene terephthalate, polyesters obtained from aliphatic dicarboxylic acid and aliphatic diol such as polyethylene succinate, polybutylene succinate, and polyethylene adipate, and polyesters obtained from polyhydroxycarboxylic acid such as polylactic acid, and polyhydroxybenzoic acid.
  • polyesters obtained from alicyclic dicarboxylic acid and aliphatic diol such as polyalkylene cyclohexane dicarboxylate
  • polyesters obtained from aromatic dicarboxylic acid and alicyclic diol such as polycyclohexane dimethylene terephthalate
  • polyesters obtained from aliphatic dicarboxylic acid and aliphatic diol such as polyethylene
  • one or more dicarboxylic acid components may be copolymerized.
  • examples of such components include isophthalic acid, phthalic acid, alkali metal salts of 5-sulfoisophthalic acid, quaternary ammonium salts of 5-sulfoisophthalic acid, quaternary phosphonium salts of 5-sulfoisophthalic acid, succinic acid, adipic acid, suberic acid, sebacic acid, cyclohexane dicarboxylic acid, ⁇ , ⁇ -(4-carboxyphenoxy)ethane, 4,4-dicarboxyphenyl, 2,6-naphthalene dicarboxylic acid, 2,7-naphthalene dicarboxylic acid, 1,3-cyclohexane dicarboxylic acid, 1, 4-cyclohexane dicarboxylic acid, and diester compounds of these organic groups of
  • one of more diol components may be copolymerized.
  • diol components include diethylene glycol, 1,2-propanediol, 1,2-butanediol, 1,3-butanediol, 1,6-hexanediol, neopentyl glycol, 1,4-cyclohexane dimethanol, 2,2-bis(p- ⁇ -hydroxyethylphenyl)propane, polyethylene glycol, poly(1,2-propylene)glycol, poly(trimethylene)glycol, and poly(tetramethylene)glycol.
  • polyester also includes mixtures of these and other polyesters of different compositions.
  • a meta-type wholly aromatic polyamide staple fiber is described as an exemplary embodiment of the wholly aromatic polyamide staple fiber.
  • the meta-type wholly aromatic polyamide as a raw material of the meta-type wholly aromatic polyamide staple fiber used for the organic resin non-crimped staple fiber of the present invention is configured from a meta-type aromatic diamine component and a meta-type aromatic dicarboxylic acid component, and may be copolymerized with other copolymer component, such as a para-type component, provided that it does not interfere with the objects of the present invention.
  • meta-type wholly aromatic polyamides that contain a m-phenylene isophthalamide unit as a primary component.
  • the meta-type wholly aromatic polyamides configured from a m-phenylene isophthalamide unit preferably contain the m-phenylene isophthalamide unit in 90 mol% or more, more preferably 95 mol% or more, particularly preferably 100 mol% of the total repeating unit.
  • meta-type aromatic diamine component as a raw material of the meta-type wholly aromatic polyamide
  • meta-type aromatic diamine component examples include m-phenylenediamine, 3,3'-diaminodiphenyl ether, 3,3'-diaminodiphenylsulfone, 3,4'-diaminodiphenyl ether, 3,4'-diaminodiphenylsulfone, and derivatives thereof having a substituent such as halogen, C 1-3 alkyl, and C 1-3 alkoxy in one or two of the aromatic rings of these aromatic diamine compounds.
  • 2,4-tolylenediamine 2,6-tolylenediamine, 2,4-diaminochlorobenzene, and 2,6-diaminochlorobenzene.
  • Particularly preferred are wholly aromatic diamine components containing only m-phenylenediamine, or 70 mol% or more of m-phenylenediamine as the meta-type aromatic diamine component.
  • meta-type aromatic dicarboxylic acid component as a raw material of the meta-type wholly aromatic polyamide
  • meta-type aromatic dicarboxylic acid dihalides examples include isophthalic acid dihalides such as isophthalic acid dichloride, isophthalic acid bromide, isophthalic acid diiodide, and derivatives thereof having a substituent such as halogen, C 1-3 alkyl, C 1-3 alkoxy in the aromatic rings, for example, such as 3-chloroisophthalic acid dichloride, and 3-methoxyisophthalic acid dichloride.
  • Particularly preferred are wholly aromatic dicarboxylic acid dihalides that contain only isophthalic acid dichloride, or 70 mol% or more of isophthalic acid dichloride.
  • copolymer components maybe used other than the foregoing meta-type aromatic diamine components and meta-type aromatic dicarboxylic acid components.
  • aromatic diamines as such copolymer components include benzene derivatives (such as p-phenylenediamine, 2,5-diaminochlorobenzene, 2,5-diaminobromobenzene, and aminoanisidine(2-amino-4-methoxyaniline)), 1,5-naphthylenediamine, 1,6-naphthylenediamine, 4,4'-diaminodiphenyl ether, 4,4'-diaminodiphenylketone, 4,4'-diaminodiphenylamine, and 4,4'-diaminodiphenylmethane.
  • benzene derivatives such as p-phenylenediamine, 2,5-diaminochlorobenzene, 2,5-diaminobromobenzene, and
  • aromatic dicarboxylic acid components as copolymer components include terephthalic acid dichloride, 1,4-naphthalene dicarboxylic acid dichloride, 2,6-naphthalene dicarboxylic acid dichloride, 4,4'-biphenyl dicarboxylic acid dichloride, and 4,4'-diphenyl ether dicarboxylic acid dichloride.
  • These copolymer components are contained in preferably 20 mol% or less of the total dicarboxylic acid component of the meta-type wholly aromatic polyamide because the properties of the meta-type wholly aromatic polyamide tend to deteriorate when the copolymerization ratio of these copolymer components is too high.
  • the meta-type wholly aromatic polyamide is preferably a polyamide containing the m-phenylene isophthalamide unit in 90 mol% or more of the total repeating unit, particularly preferably poly m-phenylene isophthalamide.
  • para-type wholly aromatic polyamide staple fiber as an embodiment of the staple fiber made of wholly aromatic polyamide.
  • the para-type wholly aromatic polyamide as a raw material of the para-type wholly aromatic polyamide staple fiber used as an example of the organic resin non-crimped staple fiber of the present invention include para-type wholly aromatic polyamides of polyparaphenylene terephthalamide or polyparaphenylene terephthalamide copolymerized with 3,3'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 4,4'-diaminodiphenyl ether, 3,3'-diaminodiphenylsulfone, 3,4'-diaminodiphenylsulfone, or 4,4'-diaminodiphenylsulfone, and para-type wholly aromatic polyamides copolymerized with small quantities of isophthalic acid or m-phenylenediamine.
  • copolyparaphenylene-3,4'-oxydiphenylene terephthalamide and polyparaphenylene terephthalamide. More preferred is copolyparaphenylene-3,4'-oxydiphenylene terephthalamide, a wholly aromatic polyamide containing terephthalic acid as an acid component, and a mixed diamine component containing 40 mol% or more of p-phenylenediamine and 40 mol% or more of 3,4'-diaminodiphenyl ether.
  • aromatic diamines include 2,5-tolylenediamine, 2,5-diaminochlorobenzene, and 2,5-diaminobromobenzene.
  • Particularly preferred are wholly aromatic diamine components that contain only p-phenylenediamine, or 70 mol% or more of p-phenylenediamine as the para-type aromatic diamine component.
  • para-type aromatic dicarboxylic acid component as a raw material of the para-type wholly aromatic polyamide
  • para-type aromatic dicarboxylic acid dihalides examples include para-type aromatic dicarboxylic acid dihalides.
  • the para-type aromatic dicarboxylic acid dihalides include terephthalic acid dihalides such as terephthalic acid dichloride, terephthalic acid bromide, and terephthalic acid diiodide, and derivatives thereof having a substituent such as halogen, C 1-3 alkyl, and C 1-3 alkoxy in the aromatic rings, for example, such as 3-chloroterephthalic acid dichloride, and 3-methoxyterephthalic acid dichloride.
  • Particularly preferred are wholly aromatic dicarboxylic acid dihalides that contain only terephthalic acid dichloride, or 70 mol% or more of terephthalic acid dichloride.
  • copolymer components maybe used other than the foregoing para-type aromatic diamine components and para-type aromatic dicarboxylic acid components.
  • aromatic diamines as such copolymer components include benzene derivatives (such as m-phenylenediamine, 2,4-diaminochlorobenzene, 2,6-diaminochlorobenzene, 2,4-diaminobromobenzene, 2,6-diaminobromobenzene, 2-amino-4-methoxyaniline, and 3-amino-4-methoxyaniline), 1,3-naphthylenediamine, 1,4-naphthylenediamine, 1,5-naphthylenediamine, 1,6-naphthylenediamine, 3,4'-diaminodiphenyl ether, 3,4'-diaminodiphenylketone, 3,4'-diaminodiphenylamine, and 3,4'
  • aromatic dicarboxylic acid components as copolymer components include isophthalic acid dichloride, 1,3-naphthalene dicarboxylic acid dichloride, 2,7-naphthalene dicarboxylic acid dichloride, 3,4'-biphenyl dicarboxylic acid dichloride, and 3,4'-diphenyl ether dicarboxylic acid dichloride.
  • These copolymer components are contained in preferably 20 mol% or less of the total dicarboxylic acid component of the meta-type wholly aromatic polyamide because the properties of the meta-type wholly aromatic polyamide tend to deteriorate when the copolymerization ratio of these copolymer components is too high.
  • polyolefin as a specific example of the organic resin forming the non-crimped staple fiber of the present invention.
  • Preferred examples of the polyolefin used as the organic resin in the present invention include isotactic polypropylene, syndiotactic polypropylene, atactic polypropylene, high-density polyethylene, medium-density polyethylene, linear low-density polyethylene, low-density polyethylene, ethylene-propylene random copolymerization polyolefin, and polyethylene or polypropylene copolymerized with a third component by block copolymerization or graft copolymerization.
  • Examples of the third component include vinyl acetate, vinyl chloride, styrene, methyl acrylate, ethyl acrylate, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, isopropyl methacrylate, acrylic acid, methacrylic acid, maleic acid, maleic acid anhydride, vinyl chloride, vinylidene chloride, acrylonitrile, and acrylamide.
  • At least one polyolefin selected from the group consisting of high-density polyethylene, an ethylene-propylene random copolymer, polyethylene block or graft copolymerized with maleic acid anhydride, and polypropylene block copolymerized with maleic acid anhydride. More than one polyolefin may be selected from these polyolefins, and used as a mixture.
  • organic resins such as polyamide (e.g., nylon-6, and nylon-6,6), polyoxymethylene, polyphenylene ether, polyphenylene sulfide, cellulose, polysulfone, polyethersulfone, polycarbonate, and polyallylate.
  • organic resins may be polyester compositions containing known additives, for example, such as pigments, dyes, flatting agents, stain-proofing agents, antimicrobial agents, deodorants, fluorescent bleach, antioxidants, fire retardants, stabilizers, UV absorbers, and lubricants.
  • the non-crimped staple fiber in the organic resin non-crimped staple fiber of the present invention is preferably any of organic resin non-crimped staple fibers selected from a polyester non-crimped staple fiber, a wholly aromatic polyamide non-crimped staple fiber, and a polyolefin non-crimped staple fiber.
  • the non-crimped staple fiber is any of organic resin non-crimped staple fibers selected from a polyethylene terephthalate non-crimped staple fiber, a polytrimethylene terephthalate non-crimped staple fiber, a polytetramethylene terephthalate non-crimped staple fiber, a polyethylene naphthalate non-crimped staple fiber, a polytrimethylene naphthalate non-crimped staple fiber, a polytetramethylene naphthalate non-crimped staple fiber, a meta-type wholly aromatic polyamide non-crimped staple fiber, a para-type wholly aromatic polyamide non-crimped staple fiber, a polyethylene non-crimped staple fiber, and a polypropylene non-crimped staple fiber.
  • organic resin non-crimped staple fibers selected from a polyethylene terephthalate non-crimped staple fiber, a polytrimethylene terephthalate non-crimped staple fiber, a polytetramethylene terephthalate non-crimped staple fiber
  • the fiber may be a solid fiber, a hollow fiber, or a conjugate fiber, provided that the transverse plane orthogonal to the fiber axial direction has a circular cross section at the circumference.
  • the shape of the fiber transverse plane is not limited to a circular cross section, and may have an oval cross section, a multi-lobed cross section such as a cross section with 3 to 8 lobes, or a modified cross section such as a triangular to octangular polygonal cross section.
  • fiber transverse plane means a fiber cross section taken at right angle to the fiber axis.
  • the fiber configuration is not limited to fibers of a single organic resin.
  • the non-crimped staple fiber of the present invention may be a conjugate fiber configured from two or more organic resins.
  • the conjugate fiber may have a form of, for example, a concentric sheath-core conjugate fiber, an eccentric sheath-core conjugate fiber, a side-by-side conjugate fiber, an island-in-the-sea conjugate fiber, and a segmented pie conjugate fiber.
  • the organic resin non-crimped staple fiber of the present invention may be provided as, for example, a fine fiber of 0.01 dtex or less, or a binder fiber bonded to other fibers under heat and pressure.
  • polyester-containing conjugate fiber examples include sheath-core conjugate fibers in which polyalkylene terephthalates such as polyethylene terephthalate, polytrimethylene terephthalate, and polybutylene terephthalate, or polyalkylene naphthalates such as polyethylene naphthalate, polytrimethylene naphthalate, or polybutylene naphthalate are disposed as the core component, and a copolymerized polyester or polyolefin is disposed as the sheath component.
  • polyalkylene terephthalates such as polyethylene terephthalate, polytrimethylene terephthalate, and polybutylene terephthalate
  • polyalkylene naphthalates such as polyethylene naphthalate, polytrimethylene naphthalate, or polybutylene naphthalate
  • a copolymerized polyester or polyolefin is disposed as the sheath component.
  • the conjugate fiber also may be, for example, an island-in-the-sea conjugate fiber in which a core component organic resin such as above is disposed as the island component, and a sheath component organic resin such as above is disposed as the sea component.
  • the conjugate fiber also may be, for example, a side-by-side conjugate fiber or a segmented pie conjugate fiber in which a core component organic resin such as above, and a sheath component organic resin such as above are separately disposed.
  • the copolymer components of the copolymerized polyester include one or more of the compounds, for example, isophthalic acid, and polyethylene glycol, that can be copolymerized with the polyester components above.
  • the polyolefin-containing conjugate fiber may be, for example, a sheath-core conjugate fiber in which polypropylene (may be any of the polypropylenes above) is disposed as the core component, and polyethylene (may be any of the polyethylenes above), a randomly copolymerized polyolefin of ethylene and propylene, or copolymer polyethylene of polyethylene or polypropylene copolymerized with a third component by block or graft copolymerization is disposed as the sheath component.
  • polypropylene may be any of the polypropylenes above
  • polyethylene may be any of the polyethylenes above
  • copolymer polyethylene of polyethylene or polypropylene copolymerized with a third component by block or graft copolymerization is disposed as the sheath component.
  • the polyolefin-containing conjugate fiber also may be, for example, an island-in-the-sea conjugate fiber in which an organic resin such as the core components above is disposed as the island component, and an organic resin such as the sheath components above is disposed as the sea component.
  • the polyolefin-containing conjugate fiber also may be, for example, a side-by-side conjugate fiber or a segmented pie conjugate fiber in which a core component organic resin such as above, and a sheath component organic resin such as above are separately disposed.
  • the non-crimped staple fiber of the present invention may be an undrawn staple fiber or a drawn staple fiber.
  • An undrawn staple fiber is preferable for use as a binder fiber, which is bonded to other fibers under heat and pressure using a calender roller or the like.
  • the organic resin non-crimped ultrafine staple fiber of the present invention has a single yarn fineness of 0.0001 to 0.6 decitex, preferably 0.007 to 0.55 decitex, more preferably 0.01 to 0.53 decitex. With a single yarn fineness of less than 0.0001 decitex, the staple fibers tend to seriously intertangle, and a nonwoven fabric made from the non-crimped staple fiber of the present invention may have a defective texture. Small single yarn finenesses also cause difficulties in yarn making. Specifically, small finenesses are not preferable as they cause breaking of yarn or fluffing during yarn making, which makes it difficult to stably produce fibers of desirable quality, and increases the cost of the staple fiber.
  • an ultrafine non-crimped staple fiber with a fineness as small as 0.0002 to 0.006 decitex has desirable properties such as moisture permeability and waterproofing, odor adsorption, and the efficiency for trapping microscopic objects, and can provide desirable effects different from the effects of the staple fibers of the foregoing fineness ranges, for example, in applications such as abrasive cloths for magnetic discs, and separator or capacitor papers for batteries.
  • Staple fibers with such small finesses thus also represent a preferred form of the present invention.
  • a single yarn fineness exceeding 0.6 decitex it becomes difficult to exploit the advantages of the ultrafine fiber, specifically the high nonwoven fabric strength, the high paper strength, and the high density of the nonwoven fabric or the like in a low basis weight region.
  • the organic resin non-crimped staple fiber of the present invention has a fiber length of 1.0 to 5.0 milimeters. When the fiber length exceeds 5.0 millimeters, the fibers tend to intertangle, and cause defects.
  • a fiber length may be selected according to such factors as the intended use, and processibility.
  • the staple fiber of the present invention needs to be non-crimped, and there is no need to actively impart crimps.
  • the staple fiber may not uniformly disperse upon being dispersed in a dispersion medium, or a nonwoven fabric produced from such staple fibers may not be able to have a low basis weight.
  • the organic resin non-crimped staple fiber of the present invention needs to have a cut-end coefficient of 1.01 to 1.30.
  • the cut-end coefficient represents the extent of cut-end defect as defined in the present invention.
  • the cut-end coefficient is described below in detail with reference to FIG. 1 , which schematically represents an end portion of the non-crimped staple fiber of the present invention. Referring to FIG. 1 , which schematically represents an end portion of the non-crimped staple fiber of the present invention. Referring to FIG.
  • the cut-end coefficient is represented by b/a, where b is the maximum width along a direction orthogonal to the fiber axis at the cut end portion (or the maximum diameter when the cut end shape is circular or substantially circular), and a is the thickness of a single yarn (or the fiber diameter or fiber width of a single yarn) on the side surface at the cut end of the non-crimped staple fiber magnified with a light microscope.
  • the cut-end coefficient is a measure of the spread of the shape of the staple fiber at the cut end portion relative to a normal single yarn thickness, and can be used as an index of the appropriateness of the shape at the cut end portion.
  • Such a wide shape is not a simple expansion of the shape of the fiber transverse plane, but can be described as a shape with no point symmetry.
  • the large wide shape is often different from the shape of the fiber transverse plane, and does not usually have a circular cross section when the fiber transverse plane has a circular cross section.
  • the large wide shape also does not usually reflect the modified cross section of the fiber transverse plane when the transverse plane cross section is irregular in shape.
  • the fiber When the cut-end coefficient as an index of the fiber shape is 1.01 to 1.30, the fiber can uniformly disperse in a dispersion medium, and generation of aggregated clumps can be reduced even when the cut-end has a shape different from the shape of the fiber transverse plane itself of the single yarn fiber. The effects of the present invention still can be obtained in this case.
  • an index above 1.30 makes the shape defective by making the maximum width b of the large wide shape excessively large.
  • a staple fiber with such a defective cut-end shape has a terminal projection, and becomes entangled with other staple fibers when dispersed in a dispersion medium.
  • Such tangles serve as the trapping points of staple fibers having normal cut-ends, and often cause undispersed clumps in the staple fibers in the dispersion medium.
  • the undispersed clumps lead to defective appearance or performance in a nonwoven fabric or other such products produced with the non-crimped staple fiber of the present invention.
  • the proportion of fibers with defective cut-ends thus needs to be reduced below certain levels to reduce such defects.
  • Studies by the present inventors revealed that the defects can be reduced when the cut-end coefficient ranges from 1.01 to 1.30, and that a cut-end coefficient above 1.30 creates a cut-end projection, or a shape that causes tangles.
  • the present invention was completed on the basis of these findings.
  • a cut-end coefficient of 1.00 means that the shape of the cut-end portion of the staple fiber and the shape of the fiber transverse plane completely match in all non-crimped staple fibers.
  • the cut-end coefficient cannot take values below 1.0 with cutting methods that are generally considered practicable.
  • the cut-end coefficient was measured by observing the side surface at the cut-end of randomly collected 50 non-crimped staple fibers with a light microscope or a scanning electron microscope, using the length measurement functionality of the microscope. The results were averaged for evaluation.
  • the fibers show desirable medium dispersibility with no aggregated clumps when the cut-end coefficient is 1.01 to 1.30. The most desirable state is when the cut-end coefficient is 1.00, as mentioned above.
  • Fiber length variation needs to be reduced in the non-crimped staple fiber of the present invention.
  • the coefficient of variation relative to fiber length (the percentage of the standard deviation relative to mean value) is 0.0% to 15.0%, preferably 0.01% to 14.0%, more preferably 0.1% to 13.0% in a fiber length measurement of randomly selected 50 non-crimped staple fibers.
  • the non-crimped staple fiber of the present invention is preferably a drawn yarn. With a drawn yarn, a wet-laid nonwoven fabric or other such products made from the non-crimped staple fiber of the present invention can have a sufficient tensile strength, or other strengths necessary as a nonwoven fabric.
  • the non-crimped staple fiber of the present invention needs to have a moisture content of 10 to 100 weight%.
  • a moisture content of less than 10 weight% is not preferable because it makes it difficult for the staple fibers to form a bundle, and tends to increase the cut-end coefficient or the variation coefficient of fiber length.
  • a moisture content above 100 weight% is not preferable because it causes a large amount of water to become removed from the fiber tow, and may interfere with the ease of handling of the fiber bundle in the cutting process.
  • moisture is imparted before the cutting process in staple fiber production.
  • the moisture content can be adjusted by imparting water with an oiling roller when the desired moisture content is toward the lower end of the foregoing range, or with nip rollers by which the fibers dipped in water are held and squeezed when the desired moisture content is toward the upper end of the foregoing range.
  • water may be imparted by spraying.
  • spraying water water may be imparted after the cutting process.
  • the organic resin non-crimped staple fiber of the present invention above may be produced by using, for example, the following processes.
  • a process for producing the polyester non-crimped staple fiber is described first.
  • a polyester polymer is melted, ejected through a spinneret of known spinning equipment, and taken up at a rate of 100 to 2000 m/min while being cooled with cooled air to obtain an undrawn yarn.
  • the undrawn yarn is drawn in 70 to 100°C hot water or in a 100 to 125°C steam, and an oil is imparted to obtain a drawn yarn.
  • the drawn yarn is then subjected to drying, and, as required, a relaxation heat treatment to obtain a fiber bundle, which is then cut into a fiber length of 0.01 to 5.0 millimeters to obtain a non-crimped staple fiber.
  • water is imparted to the fiber bundle before cutting the fiber bundle, as described above.
  • the method of imparting water to the fiber bundle is not particularly limited, and water may be imparted by using, for example, a spray method, an oiling roller method, or a dipping method, after the relaxation heat treatment and before feeding the fiber bundle to the cutter.
  • the oiling roller method is preferred in terms of uniformly imparting moisture in the foregoing ranges.
  • water should be imparted from the both sides of the fiber bundle to uniformly impart water to the fiber bundle.
  • the method for cutting the fiber bundle into a predetermined fiber length is not particularly limited.
  • a guillotine fiber-bundle cutter device when used to cut fibers of fine single yarns, the fibers easily bend or buckle, and the cutting blade may not contact the fibers at right angle, producing obliquely cut fibers, or fibers of different lengths.
  • Such nonuniformity is believed to be due to the cutting method of the guillotine fiber-bundle cutter device, whereby a fiber bundle is pushed for the predetermined cut length toward the shear blades composed of a fixed blade and a movable blade. This may not be desirable as it increases the cut-end coefficient or the coefficient of variation relative to fiber length (fiber length variation) of the present invention.
  • fiber bundles are restricted by being wrapped in a sheet-like material. It is, however, not always possible to sufficiently restrict movement of the fiber bundle with a method that wraps the fiber bundle in, for example, paper.
  • the fiber bundle is dipped in water, and frozen after being degassed to make an ice pillar and fix the fiber bundle. The fiber bundle is then cut in the ice pillar with a guillotine cutter, and the ice (water) is removed. This method involves less fiber displacement, and makes the coefficient of variation relative to fiber length (fiber length variation) desirable to prevent the cut-end defect.
  • the ice pillar may be replaced by a dry ice pillar.
  • Another method to cut a fiber bundle into a predetermined length uses an Eastman or other such rotary cutters with multiple cutter blades that are radially disposed outwardly at regular intervals.
  • a fiber bundle is rolled onto the rotary cutter blades, and is continuously cut into a predetermined length while being pressed against the cutting blades.
  • This cutting method has limitations in the cutter blade intervals with which the cut non-crimped staple fibers can be discharged.
  • the method is nonetheless preferable because of the advantage that the cut-end defect or the fiber length variation due to single yarn displacement can be reduced by applying a moderate tension to the fiber bundle with the constituent single yarns being uniformly aligned without a slack before feeding the fiber bundle to the rotary cutter device.
  • the method involves problems intrinsic to the device structure, including the large discharge resistance of the cut fibers, and breaking of the cutter blade.
  • the discharge resistance can be reduced by providing a large space for the cut fibers in the device structure, whereas breaking of the cutter blade can be prevented by reducing the fiber-metal friction with a diamond-like coating applied to the cutter blade surface.
  • a fiber with the desired fiber length of 5.0 millimeters or less, or a shorter fiber of a 3.0 millimeters or less can be stably obtained.
  • the rotary cutter device typically includes cutter blades, and feed rollers for supplying a fiber bundle to the cutter blade.
  • the draft rate of the rotary cutter and the feed rollers [(circumferential velocity of rotary cutter)/(circumferential velocity of feed rollers)] is set to 1.01 to 1.05. With a draft rate of less than 1.01, the tension created in the single yarn fibers of the fiber bundle tends to vary when cutting long fibers, and variation often occurs in the fiber length of the resulting staple fibers.
  • a draft rate above 1.05 is not preferable because it has the possibility of mechanically stretching the fiber itself, and altering the physical properties of the fiber.
  • a staple fiber with a coefficient of variation relative to fiber length of 0.0 to 15.0% can be obtained by setting the draft ratio as above.
  • the fiber bundle is cut by being pressed with pressure rollers installed at a certain clearance between the rollers and the edge of the cutter blade of the rotary cutter.
  • the cut fibers experience less resistance as they pass between the cutter blades, and can have less deformation at the cut-end.
  • the pressure applied to the edge of the cutter blade at a certain clearance between the rollers and the edge the amount of the fiber bundle rolled onto the rotary cutter can remain constant during a continuous operation.
  • the fiber bundle at the outermost periphery becomes relaxed in fiber direction as it approaches the rotor center, and is cut upon contacting the cutter blade.
  • any fluctuation in the roll amount of the fiber bundle leads to variation of the extent of relaxation, and varies the fiber length.
  • the following describes a process for producing the wholly aromatic polyamide non-crimped staple fiber.
  • the process will be described through the case of a meta-type wholly aromatic polyamide staple fiber as a specific example of the wholly aromatic polyamide staple fiber of the present invention.
  • the process is described in steps, which include a meta-type wholly aromatic polyamide producing step, a spinning solution preparation step, a spinning and coagulation step, a plasticization draw bath drawing step, a washing step, a saturated water vapor treatment step, a dry heat treatment step, and a cutting step.
  • the meta-type wholly aromatic polyamide producing process is not particularly limited, and processes such as solution polymerization and interface polymerization may be used that use, for example, a meta-type aromatic diamine component and a meta-type aromatic dicarboxylic acid dichloride component as raw materials.
  • a meta-type aromatic diamine component and a meta-type aromatic dicarboxylic acid dichloride component may be used as raw materials.
  • m-phenylenediamine and isophthalic acid dichloride may be used as raw materials.
  • the degree of polymerization of the meta-type wholly aromatic polyamide should be 1.3 to 3.0 dL/g in terms of an inherent viscosity (IV) as measured by using 30°C concentrated sulfuric acid as solvent.
  • a typical example of the producing process of the meta-type wholly aromatic polyamide non-crimped staple fiber used in the present invention is described below.
  • a long fiber is produced in the steps described below.
  • the long fiber is then fed to the cutting step to obtain the meta-type wholly aromatic polyamide staple fiber.
  • the meta-type wholly aromatic polyamide is dissolved in an amide solvent to prepare a spinning solution (meta-type wholly aromatic polyamide polymer solution).
  • the spinning solution is typically prepared with an amide solvent.
  • the amide solvent include N-methyl-2-pyrrolidone (NMP), dimethylformamide (DMF), and dimethylacetoamide (DMAc). Preferred for solubility and safety of handling are NMP and DMAc.
  • the concentration of the spinning solution may be appropriately selected taking into consideration the coagulation rate, and the solubility of the meta-type wholly aromatic polyamide in the next spinning and coagulation step. Typically, the concentration is preferably, for example, 10 to 30 mass% when the meta-type wholly aromatic polyamide is poly m-phenylene isophthalamide, and the solvent is NMP.
  • the spinning solution (meta-type wholly aromatic polyamide polymer solution) obtained above is spun into a coagulation solution to coagulate, and a porous fiber material is obtained.
  • the spinning device is not particularly limited, and a known wet spinning device may be used. Conditions such as the number of spinning holes in the spinneret, the hole arrangement, and the hole shape are not particularly limited, as long as the solution can be stably wet spun. For example, a multi-hole spinneret for staple fibers (short fibers) with 500 to 30,000 holes, and a spinning hole diameter of 0.05 to 0.2 millimeters may be used.
  • the temperature of the spinning solution (meta-type wholly aromatic polyamide polymer solution) spun out of the spinneret should be 10 to 90°C.
  • the coagulation bath is configured as a two-component aqueous solution of substantially amide solvent and water.
  • the amide solvent in the coagulation bath composition is not particularly limited, as long as it can dissolve the meta-type wholly aromatic polyamide, and is desirably miscible with water.
  • Preferred examples include N-methyl-2-pyrrolidone, dimethylacetoamide, dimethylformamide, and dimethylimidazolidinone (e.g., 1,3-dimethyl-2-imidazolidinone).
  • the mixing ratio (weight ratio) of the amide solvent to water is preferably 10/90 to 90/10, more preferably 30/70 to 70/30.
  • an inorganic sodium salt, a potassium salt, a magnesium salt, or a calcium salt may be dissolved in the coagulation bath in 0.1 to 8.0 weight%.
  • the fiber bundle is drawn in a plasticization draw bath while the porous fiber (yarn) bundle obtained after the coagulation in the coagulation bath is in a plastic state.
  • the plasticization draw bath used to obtain the fiber used in the present invention is prepared from an aqueous solution containing an amide solvent, and is substantially salt free.
  • the amide solvent is not particularly limited, as long as it can swell the meta-type wholly aromatic polyamide, and is desirably miscible with water. Examples of the amide solvent include N-methyl-2-pyrrolidone, dimethylacetoamide, dimethylformamide, and dimethylimidazolidinone.
  • the temperature and the composition of the plasticization draw bath are closely related to each other.
  • the plasticization draw bath contains 20 to 70 mass% of the amide solvent, and has a temperature of 20 to 70°C.
  • the mass concentration of the amide solvent, or the temperature is below these ranges, the porous fiber material does not sufficiently plasticize, and it becomes difficult to ensure a sufficient draw ratio in the plasticization drawing.
  • the porous fiber surface melts and fuses, and makes it difficult to desirably make yarns.
  • the draw ratio in the plasticization draw bath is preferably 1.5 to 10, more preferably 2.0 to 6.0.
  • the resulting fiber suffers from poor mechanical characteristics (e.g., strength, and modulus), and it may become difficult to provide the necessary break strength for the nonwoven fabric or other such products produced with the fiber of the present invention. It also becomes difficult to promote sufficient removal of the solvent from the porous fiber material, making it difficult to produce a fiber with 1.0 mass% or less of residual solvent.
  • the fiber from the plasticization draw bath drawing step is sufficiently washed with water.
  • washing is performed in stages to avoid adverse effects on fiber quality.
  • the temperature of the washing bath, and the concentration of the amide solvent in the washing bath in the washing step have effects on the state of the amide solvent extracted from the fiber, and the state of water entering the fiber from the washing bath.
  • the fiber washed in the washing step is subjected to a heat treatment in a saturated water vapor.
  • the saturated water vapor treatment enables improving alignment while reducing fiber crystallization.
  • the heat treatment in a saturated water vapor atmosphere allows the heat to more uniformly reach inside the fiber bundle than in a dry heat treatment, and enables producing a more uniform fiber.
  • the draw ratio in the saturated water vapor treatment step is also closely related to development of fiber strength. Any draw ratio may be chosen, taking into account the required physical properties of the product. In the present invention, the draw ratio is 0.7 to 5.0, preferably 1.1 to 2.0. A draw ratio below 0.7 is not preferable as it lowers the cohesion of the fiber bundle (yarn) in a saturated water vapor atmosphere.
  • a draw ratio above 5.0 is not preferable as it increases the occurrence of single yarn breakage during the draw, and generates a fluff or broken yarns.
  • the saturated water vapor treatment is performed for 0.5 to 5.0 seconds.
  • the most effective treatment time should be selected by appropriately adjusting factors that determine the treatment time, specifically the running distance and the running speed of the fiber bundle in a water vapor treatment vessel.
  • the fiber from the saturated water vapor treatment step is subjected to a dry heat treatment.
  • the dry heat treatment method is not particularly limited, and may be, for example, a method that uses a hot plate, a heat roller, or the like. After the dry heat treatment, a long fiber of meta-type wholly aromatic polyamide can be finally obtained.
  • the heat treatment temperature of the dry heat treatment step preferably ranges from 250 to 400°C, more preferably 300 to 380°C. When the dry heat treatment temperature is less than 250°C, the porous fiber cannot be sufficiently densified, and the mechanical characteristics of the fiber become insufficient. On the other hand, a dry heat treatment temperature above 400°C is not preferable because it causes heat deterioration on fiber surface, and lowers quality.
  • the draw ratio in the dry heat treatment step is closely related to development of fiber strength. Any draw ratio may be chosen according to the strength or other required properties of the fiber.
  • the draw ratio in the dry heat treatment step is preferably 0.7 to 4.0, more preferably 1.5 to 3.0. When the draw ratio is less than 0.7, the step tension decreases, and the fiber suffers from poor mechanical characteristics. On the other hand, when the draw ratio is above 4.0, the single yarn becomes more likely to break while being drawn, and generates a fluff or broken yarns.
  • draw ratio is the ratio of the treated fiber length to the undrawn fiber length, as with the case of the draw rate described in conjunction with the saturated water vapor treatment step.
  • a draw ratio of 0.7 means that the fiber becomes 70% of the original length after it restrictively shrinks in the dry heat treatment step.
  • a draw ratio of 1.0 means a fixed-length heat treatment.
  • the process time of the dry heat treatment step is preferably 1.0 to 45 seconds. The treatment time may be adjusted according to the running speed of the fiber bundle, and the contact length with a hot plate, a heat roller, or the like.
  • the meta-type wholly aromatic polyamide long fiber after the dry heat treatment is cut into a predetermined length in a cutting step.
  • the method used to cut the fiber into a predetermined length is not particularly limited. However, considerations need to be given with regard to use of a guillotine fiber-bundle cutter device that includes shear blades composed of a fixed blade and a movable blade, and in which a fiber bundle is pushed for a predetermined cut length toward the shear blades.
  • the fibers when cutting fibers of fine single yarns, the fibers easily bend or buckle, and the cutting blade may not contact the fibers at right angle, producing obliquely cut fibers, or fibers of different lengths. This may not be appropriate as it increases the cut-end coefficient, or the coefficient of variation relative to fiber length (fiber length variation) of the present invention.
  • a staple fiber of predetermined physical properties can be obtained also for the meta-type wholly aromatic polyamide non-crimped fiber.
  • a process for producing the polyolefin non-crimped staple fiber is described below.
  • the polyester used as the organic resin in the polyester non-crimped staple fiber producing process is replaced with a desired polyolefin.
  • the desired polyolefin non-crimped staple fiber can be produced by melt-spinning the selected polyolefin under the common melt-spinning conditions after replacing some of or all of these conditions with the conditions used in the polyester non-crimped staple fiber producing process above.
  • the moisture content of the fiber bundle fed to the rotary cutter is desirably 10 to 100% in the non-crimped staple fiber of any organic resin, whether it is a polyester, a wholly aromatic polyamide, or a polyolefin, as described above.
  • the fibers in a fiber bundle with a moisture content of 10% or more bind together, and the fiber bundle uniformly contacts the cutter blade at right angle when being cut. The fibers thus contact the cutter blade under uniform pressure while being cut. This improves the cut-end coefficient, and the coefficient of variation relative to fiber length.
  • the resulting staple fibers with the desirable cut-end coefficient and the desirable coefficient of variation relative to fiber length are thus less likely to include fibers of large aspect ratios.
  • the fibers are thus less likely to be entangled with each other, and can uniformly disperse in a medium without causing aggregation defects.
  • a moisture content above 100% causes a large amount of water to become removed from the tow, or the fibers in a fiber bundle state, and may interfere with the ease of handling.
  • the moisture content should therefore be at most 100%.
  • the surface of the organic resin non-crimped staple fiber may be treated with a surface treatment agent such as a dispersant, a lightfast agent, a smoothing agent, an adhesive, or a mixture of these, provided that such a surface treatment is not detrimental to the effects of the present invention.
  • a surface treatment agent such as a dispersant, a lightfast agent, a smoothing agent, an adhesive, or a mixture of these, provided that such a surface treatment is not detrimental to the effects of the present invention.
  • a surface treatment agent such as a dispersant, a lightfast agent, a smoothing agent, an adhesive, or a mixture of these, provided that such a surface treatment is not detrimental to the effects of the present invention.
  • a surface treatment agent such as a dispersant, a lightfast agent, a smoothing agent, an adhesive, or a mixture of these, provided that such a surface treatment is not detrimental to the effects of the present invention.
  • the non-crimped staple fiber is a polyester non-crimped staple fiber or
  • the organic resin non-crimped staple fiber of the present invention can uniformly disperse in a dispersion medium, and can reduce generation of aggregated clumps in applications such as wet-laid nonwoven fabrics, and staple fiber reinforced resins.
  • the staple fibers in a nonwoven fabric or other such products made from the non-crimped staple fiber are also uniformly dispersed.
  • the product nonwoven fabric is thus free from defects such as microscopic nonuniform dispersion of staple fibers, and variation of basis weight and thickness, and can have desirable properties such as uniform breathability and liquid permeability.
  • the final product produced by processing such nonwoven fabrics involves few defects, and can have physical properties with improved reliability (reliable product warranty).
  • the yield of the interim product e.g., nonwoven fabric, and resin molded body
  • the present invention is thus also highly advantageous in terms of resource saving and economy.
  • polyester fiber 0.12 g of a fiber (polymer) sample was dissolved in 10 mL of a tetrachloroethane/phenol mixed solvent (volume ratio 1/1), and measured for inherent viscosity (dL/g) at 35°C.
  • the fiber (polymer) was dissolved in 97 mass% concentrated sulfuric acid, and measured for inherent viscosity (dL/g) at 30°C with an Ostwald viscometer.
  • melt flow rate was measured according to condition 4 of JIS K 7210 (measurement temperature 190°C, load 21.18 N).
  • the melt flow rate is a measured value of a polymer pellet sample immediately before melt-spinning.
  • the TA Instruments product TA-2920 differential scanning calorimeter DSC was used.
  • a polymer sample (10 mg) was heated from room temperature to 260°C at 10°C/min in a nitrogen atmosphere.
  • the melting point was defined as the peak temperature at the crystal melting endothermic peak.
  • the mean value of the measured values of each fiber was used for the evaluation of cut-end coefficient.
  • the dispersibility of fibers in water was evaluated to determine the presence or absence of a fiber aggregation defect due to cut-end and fiber length.
  • Soft water 500 cc
  • fibers 0.5 g that had been cut into a predetermined fiber length were put in the beaker, and stirred with a magnetic stirrer (stirrer) at ordinary temperature for 20 min.
  • the fibers were filtered through a 0.15 mm-mesh metal net, and the number of fiber clumps with a size of 1 mm 2 or more remaining on the metal net was counted.
  • the results are represented as Good when the number of fiber clumps was 3 or less, Acceptable when 3 to 5 fiber clumps were observed, and Poor when there were 5 or more fiber clumps.
  • a polyethylene terephthalate (PET) chip with an inherent viscosity of 0.64 dL/g containing 0.3 weight% of titanium dioxide was melted at 290°C, ejected through a spinneret having 3000 round holes at an ejection rate of 450 g/min, and taken up at a rate of 1320 m/min to obtain polyethylene terephthalate undrawn yarns having a single yarn fineness of 1.14 decitex.
  • the undrawn yarns were aligned, and a tow of 140000 decitex was obtained.
  • the tow was drawn in two stages in hot water at a total draw ratio of 2.51, and a polyester-polyether copolymer was imparted in 0.3 weight% of the polyester fiber weight.
  • the yarns were dried, and heat set at 120°C in a relaxed state to obtain an uncrimped drawn polyethylene terephthalate fiber bundle having a single yarn fineness of 0.51 decitex.
  • Water was imparted to the drawn polyethylene terephthalate fiber bundle with an oiling roller to make the moisture content 15%, and the fibers were cut into staple fibers with a fiber length of 3.0 millimeters, using an Eastman rotary cutter fiber cutting device with a blade interval of 3.0 millimeters.
  • the fibers were cut with a draft rate of 1.02 between the rotary cutter and feed rollers under the pressure of a pressure roller pressing the fiber bundle against the cutter blade.
  • Table 1 shows the evaluation results, including the fineness, the moisture content, the cut-end coefficient, the coefficient of variation relative to fiber length, and the water dispersibility of the polyester non-crimped staple fiber.
  • Example 1 The same procedures used in Example 1 were performed to obtain a non-crimped staple fiber, except that the fiber was cut into a staple fiber with a fiber length of 1.5 millimeters.
  • the evaluation results for the polyester non-crimped staple fiber are presented in Table 1.
  • the non-crimped drawn polyethylene terephthalate fiber bundle obtained in Example 1 was dipped in water, and held and squeezed with nip rollers to make the moisture content 30%.
  • Four of the fiber bundles prepared in this fashion were disposed side by side to make a fiber bundle.
  • the fiber bundle was dipped in a cylindrical container that had been charged with boiled processing water, and frozen at an atmospheric temperature of -12°C over the course of 15 h to obtain a fiber bundle contained in ice.
  • the fiber bundle in ice was then cut into a fiber length of 1. 5 millimeters using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length.
  • the polyester non-crimped staple fiber was evaluated after being thawed. The results are presented in Table 1.
  • the notation "ice pillar + guillotine" used in Tables 1 and 3 refers to the fiber bundles of Examples 3 to 5 that were cut in ice with a guillotine cutter.
  • An ultrafine long fiber bundle was produced from an island-in-the-sea conjugate fiber by using the following procedures.
  • Polyethylene terephthalate with a melt viscosity of 120 Pa ⁇ sec at 285°C was used as the island component.
  • As the sea component altered copolymerized polyethylene terephthalate with a 285°C melt viscosity of 135 Pa ⁇ sec was used that was prepared by copolymerizing 4 weight% of polyethylene glycol having a number average molecular weight of 4000, and 9 mol% of 5-sodium sulfoisophthalic acid.
  • the fiber was melt-spun at a spinning speed of 1500 m/min to obtain an ultrafine fiber precursor fiber (island-in-the-sea conjugate fiber) that was drawn 3.9 times, using a spinneret designed to produce a conjugate fiber containing 400 islands in a sea component:island component weight ratio of 30:70.
  • the drawn ultrafine fiber precursor fibers were bundled together to obtain a fiber bundle of 500000 decitex, and dipped and passed through a 75°C, 4 weight% sodium hydroxide aqueous solution at such a rate that the fibers were in the solution for 15 min. This produced an ultrafine long fiber bundle (single yarn fiber diameter of 750 nanometers, 0.0056 decitex) that was 27.6 weight% less than the fiber bundle of the ultrafine fiber precursor fibers.
  • the ultrafine long fiber bundle was dipped in water, and held and squeezed with nip rollers to make the moisture content 100%.
  • Four of the fiber bundles prepared in this fashion were disposed side by side to make a fiber bundle.
  • the fiber bundle was dipped in a cylindrical container that had been charged with boiled processing water, and frozen at an atmospheric temperature of -12°C over the course of 15 h to obtain a fiber bundle contained in ice.
  • the fiber bundle in ice was then cut into a fiber length of 0.05 millimeters using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length.
  • the polyester non-crimped staple fiber was evaluated after being thawed. The results are presented in Table 1.
  • Example 2 Ten of the non-crimped drawn polyethylene terephthalate fiber bundles obtained in Example 1 were bundled to obtain a fiber bundle of 1400000 decitex. The fiber bundle was then wrapped in paper. The wrapped fiber bundle was cut into a fiber length of 3.0 millimeters to obtain a non-crimped staple fiber, using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length. The evaluation results for the polyester non-crimped staple fiber are presented in Table 2.
  • NMP N-methyl-2-pyrrolidone
  • the polymer solution (spinning solution) had a polymer concentration of 14 (in terms of weight parts of the polymer with respect to the total 100 weight parts of the polymer and the NMP), and the resultant poly m-phenylene isophthalamide polymer had an inherent viscosity (IV) of 2.37 dL/g.
  • the polymer solution (spinning solution) had a calcium chloride concentration of 46.6 parts, and a water concentration of 15.1 parts with respect to 100 parts of the polymer.
  • the spinning solution prepared in the spinning solution preparation step was ejected and spun into a 40°C coagulation bath through a spinneret having 500 holes with a hole diameter of 0.07 millimeters.
  • the coagulation solution had a composition with a water:NMP:calcium chloride mass ratio of 48:48:4, and was passed through the coagulation bath over a dip length (effective coagulation bath length) of 70 cm at a yarn rate of 5 m/min.
  • the porous fiber material after the coagulation in the coagulation bath had a density of 0.71 g/cm 3 .
  • the fiber bundle was drawn in a plasticization draw bath at a draw ratio of 3.0.
  • the plasticization draw bath had a composition with a water:NMP:calcium chloride mass ratio of 44:54:2, and a temperature of 40°C.
  • the plasticized and drawn fiber bundle was thoroughly washed first with 30°C cold water, and then with 60°C hot water.
  • the cold water and the hot water were checked for sufficiently lowered levels of amide solvent concentration after the washing.
  • the fibers were then subjected to a saturated water vapor heat treatment at a draw ratio of 1.1 in a container with the maintained saturated water vapor pressure of 0.05 MPa.
  • the heat treatment was performed under adjusted conditions, for example, by adjusting the running distance and the running speed of the fiber bundle, so that the fiber bundle was treated with saturated water vapor for about 1.0 second.
  • a dry heat treatment was performed at a draw ratio of 1.0 (constant length) on a hot plate with a surface temperature of 360°C.
  • the resulting poly m-phenylene isophthalamide fiber was rolled.
  • the poly m-phenylene isophthalamide drawn fiber was sufficiently dense with a fineness of 0.8 decitex, a density of 1.33 g/cm 3 , a tensile strength of 3.68 cN/ dtex, and an elongation of 42%.
  • the fiber had desirable mechanical characteristics, and there was no variation in quality. There was also not observed any abnormal yarn.
  • a fiber bundle was produced from the roll of the poly m-phenylene isophthalamide fiber after the dry heat treatment. Water was imparted to the fiber bundle to make the moisture content 15%. The fiber bundle was then cut into staple fibers with a fiber length of 3.0 millimeters, using an Eastman rotary cutter fiber cutting device with a blade interval of 3.0 millimeters. The fiber bundle was cut with a draft rate of 1.02 between the rotary cutter and feed rollers under the pressure of a pressure roller pressing the fiber bundle against the cutter blade. Table 3 shows the evaluation results, including the fineness, the moisture content, the cut-end coefficient, the coefficient of variation relative to fiber length, and the water dispersibility of the meta-type wholly aromatic polyamide non-crimped staple fiber.
  • the fiber bundle produced by imparting water to the poly m-phenylene isophthalamide fiber rolled after the dry heat treatment in the manner described in Reference Example 6 was cut into a fiber length of 3.0 millimeters to obtain a non-crimped staple fiber, using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length.
  • the evaluation results for the meta-type wholly aromatic polyamide non-crimped staple fiber are presented in Table 4.
  • the fiber bundle produced by imparting water to the poly m-phenylene isophthalamide fiber rolled after the dry heat treatment in the manner described in Reference Example 6 was cut into a fiber length of 1.0 millimeters to obtain a non-crimped staple fiber, using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length.
  • the evaluation results for the meta-type wholly aromatic polyamide non-crimped staple fiber are presented in Table 4.
  • Fiber configuration Single component fiber Single component fiber Single component fiber Organic resin - meta-type Wholly aromatic polyamide meta-type Wholly aromatic polyamide meta-type Wholly aromatic polyamide Cutting method - Guillotine Guillotine Rotary cutter Fineness dtex 0.80 0.80 0.80 Fiber length mm 3.0 1.0 3.0 Moisture content weight% 15 15 15 Cut-end coefficient - 1.60 1.80 1.08 coefficient of variation relative to fiber length % 33.0 60.0 17.0 Water dispersibility - Poor Poor Acceptable
  • High-density polyethylene with an MFR of 20 g/10 min and a melting point Tm of 131°C was selected as a low-melting-point thermal binder component
  • isotactic polypropylene with an MFR of 39 g/10 min and a Tm of 160°C was selected as a fiber forming component.
  • the polymers were ejected as a conjugate of 245°C molten polymers with a composition containing an HDPE sheath component and a PP core component in a sheath-to-core ratio of 50:50 (weight ratio).
  • the polymers were melt ejected at a rate of 190 g/min with a spinneret temperature of 260°C.
  • the ejected polymer was cooled with 27°C cool air at a position 31 mm below the spinneret, and a polyether ⁇ polyester copolymer emulsion was imparted to the yarns with an oiling roller.
  • the fiber was then taken up at 1300 m/min to obtain an undrawn yarn.
  • the undrawn yarn was bundled, and drawn 4.10 times in 95°C hot water.
  • the fiber was dried at 105°C for 60 min to obtain a polyethylene/polypropylene conjugate fiber bundle having a single yarn fineness of 0.32 decitex, and a total fineness of 70000 denier.
  • the fibers were cut into staple fibers with a fiber length of 3.0 millimeters, using an Eastman rotary cutter fiber cutting device with a blade interval of 3.0 millimeters.
  • the fiber bundle was cut with a draft rate of 1.02 between the rotary cutter and feed rollers under the pressure of a pressure roller pressing the fiber bundle against the cutter blade.
  • Table 3 shows the evaluation results, including the fineness, the moisture content, the cut-end coefficient, the coefficient of variation relative to fiber length, and the water dispersibility of the polyolefin non-crimped conjugate staple fiber.
  • Isotactic polypropylene (PP) with an MFR of 39 g/10 min and a melting point Tm of 160°C was selected as an organic resin for forming a staple fiber.
  • the isotactic polypropylene was melted with an extruder, and melt ejected as a 255°C molten polymer using a spinneret having 3000 round ejection holes.
  • the polymer was ejected at a rate of 190 g/min with a spinneret temperature of 260°C.
  • the ejected polymer was cooled with 27°C cool air at a position 25 mm below the spinneret, and taken up at 1300 m/min to obtain an undrawn yarn.
  • the undrawn yarn was bundled, and drawn 2.70 times in 95°C hot water. After imparting a polyether-polyester copolymer as draw oil, the drawn yarn was dried at 110°C for 60 min to obtain a polypropylene fiber bundle having a single yarn fineness of 0.30 decitex, and a total fineness of 70000 denier. After imparting water to the polypropylene fiber bundle with an oiling roller to make the moisture content 15%, the fibers were cut into staple fibers with a fiber length of 3.0 millimeters, using an Eastman rotary cutter fiber cutting device with a blade interval of 3.0 millimeters. The fibers were cut with a draft rate of 1.02 between the rotary cutter and feed rollers under the pressure of a pressure roller pressing the fiber bundle against the cutter blade. Table 5 shows the evaluation results for the polypropylene non-crimped staple fiber.
  • High-density polyethylene with an MFR of 20 g/10 min and a melting point Tm of 131°C was selected as an organic resin for forming a staple fiber.
  • the high-density polyethylene was melted with an extruder, and melt ejected as a 210°C molten polymer using a spinneret having 144 round ejection holes.
  • the polymer was ejected at a rate of 15 g/min with a spinneret temperature of 210°C.
  • the ejected polymer was cooled with 27°C cool air at a position 25 mm below the spinneret, and taken up at 1000 m/min to obtain an undrawn yarn.
  • the undrawn yarn was bundled, and drawn 3.60 times in 95°C hot water. After imparting a polyether-polyester copolymer as draw oil, the drawn yarn was dried at 105°C for 60 min to obtain a polyethylene fiber bundle having a single yarn fineness of 0.32 decitex, and a total fineness of 70000 denier. After imparting water to the polyethylene fiber bundle with an oiling roller to make the moisture content 15%, the fibers were cut into staple fibers with a fiber length of 3.0 millimeters, using an Eastman rotary cutter fiber cutting device with a blade interval of 3.0 millimeters. The fibers were cut with a draft rate of 1.02 between the rotary cutter and feed rollers under the pressure of a pressure roller pressing the fiber bundle against the cutter blade.
  • Table 5 shows the evaluation results for the polyethylene non-crimped staple fiber.
  • Unit Ex. 9 Ex. 10 Ex. 11 Fiber configuration - Sheath-core conjugate fiber Single component fiber Single component fiber Organic resin - Core component: PP, Sheath component: PE PP HDPE Cutting method - Rotary cutter Rotary cutter Rotary cutter Fineness dtex 0.32 0.30 0.32 Fiber length mm 3.0 3.0 3.0 Moisture content weight% 15 15 15 Cut-end coefficient - 1.03 1.03 1.04 coefficient of variation relative to fiber length % 3.8 4.5 4.8 Water dispersibility - Good Good Good Good Good
  • Example 9 Twenty of the non-crimped polypropylene/polyethylene sheath-core conjugate fiber bundles obtained after imparting water in the manner described in Example 9 were bundled to obtain a fiber bundle of 1400000 decitex. The fiber bundle was then wrapped in paper. The wrapped sheath-core conjugate fiber bundle was cut into a fiber length of 3.0 millimeters to obtain a non-crimped staple fiber, using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length. The evaluation results for the polypropylene/polyethylene sheath-core conjugate staple fiber are presented in Table 6.
  • Example 10 Twenty of the polypropylene fiber bundles obtained after imparting water in the manner described in Example 10 were bundled to obtain a fiber bundle of 1400000 decitex. The fiber bundle was then wrapped in paper. The wrapped polypropylene fiber bundle was cut into a fiber length of 3.0 millimeters to obtain a non-crimped staple fiber, using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length. The evaluation results for the polypropylene non-crimped staple fiber are presented in Table 6.
  • Example 11 Twenty of the polyethylene fiber bundles obtained after imparting water in the manner described in Example 11 were bundled to obtain a fiber bundle of 1400000 decitex. The fiber bundle was then wrapped in paper. The wrapped polyethylene fiber bundle was cut into a fiber length of 3.0 millimeters to obtain a non-crimped staple fiber, using a known guillotine fiber-bundle cutter device (Onouchi Seisakusho, Model: D100) that had been adjusted to make this fiber length. The evaluation results for the polyethylene non-crimped staple fiber are presented in Table 6. [Table 6] Unit Com. Ex. 7 Com. Ex. 8 Com. Ex.
  • Example 9 The same procedures used in Example 9 were performed to obtain a non-crimped staple fiber, except that the fibers were cut at a draft rate of 0.98 between the rotary cutter and the feed rollers.
  • the evaluation results for the polyethylene/polypropylene sheath-core conjugate non-crimped staple fiber are presented in Table 7.
  • Example 10 The same procedures used in Example 10 were performed to obtain a non-crimped staple fiber, except that the fibers were cut at a draft rate of 0.98 between the rotary cutter and the feed rollers.
  • the evaluation results for the polypropylene non-crimped staple fiber are presented in Table 7.
  • Example 7 The same procedures used in Example 1 were performed to obtain a non-crimped staple fiber, except that water was sprayed to make the moisture content 1.0% before being supplied to the rotary cutter to be cut.
  • the evaluation results for the polyester non-crimped staple fiber are presented in Table 7. [Table 7] Unit Com. Ex. 10 Com. Ex. 11 Com. Ex.

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Claims (4)

  1. Ungekräuselte Stapelfaser aus organischem Harz für Nassvliesstoffe,
    wobei die ungekräuselte Stapelfaser aus organischem Harz über eine Feinheit von 0,0001 bis 0,6 Dezitex, über eine Faserlänge von 1,0 bis 5,0 Millimeter, über einen Feuchtigkeitsgehalt von 10 bis 100 Gew.-%, über einen Schnittendenkoeffizienten von 1,01 bis 1,30 sowie über einen auf die Faserlänge bezogenen Variationskoeffizienten (CV%) von 0,0 bis 15,0% verfügt,
    wobei der Schnittendenkoeffizient und der auf die Faserlänge bezogene Variationskoeffizient jeweils wie folgt definiert sind: Schnittendenkoeffizient = b / a ,
    Figure imgb0009
     wobei a für den Faserdurchmesser eines Einzelgarns aus der ungekräuselten Stapelfaser und b für den Maximaldurchmesser am Schnittende steht, auf die Faserlänge bezogener Variationskoeffizient CV % = Standardabweichung der Faserlänge / Mittelwert der Faserlänge × 100 % ,
    Figure imgb0010
     wobei die Anzahl der in (1) und (2) vermessenen Einzelgarne bei 50 liegt.
  2. Ungekräuselte Stapelfaser aus organischem Harz nach Anspruch 1, bei der es sich bei dem organischen Harz um Polyester, um vollaromatisches Polyamid oder um Polyolefin handelt.
  3. Ungekräuselte Stapelfaser aus organischem Harz nach Anspruch 1 oder 2, bei der es sich bei dem organischen Harz um Polyethylenterephthalat, um Polytrimethylenterephthalat, um Polytetramethylenterephthalat, um Polyethylennaphthalat, Polytrimethylennaphthalat, Polytetramethylennaphthalat, um vollaromatisches Polyamid des Typs meta, um vollaromatisches Polyamid des Typs para, um Polyethylen oder um Polypropylen handelt.
  4. Ungekräuselte Stapelfaser aus organischem Harz nach Anspruch 1, bei der es sich um eine aus zwei oder mehr organischen Harzen ausgebildete Konjugatfaser handelt.
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