EP2987875B1 - Feuerfeste magnesiumlegierung und herstellungsverfahren dafür - Google Patents

Feuerfeste magnesiumlegierung und herstellungsverfahren dafür Download PDF

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Publication number
EP2987875B1
EP2987875B1 EP14785713.0A EP14785713A EP2987875B1 EP 2987875 B1 EP2987875 B1 EP 2987875B1 EP 14785713 A EP14785713 A EP 14785713A EP 2987875 B1 EP2987875 B1 EP 2987875B1
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Prior art keywords
magnesium alloy
atomic
flame
retardant magnesium
total
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French (fr)
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EP2987875A4 (de
EP2987875A1 (de
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Yoshihito Kawamura
Jonghyun Kim
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Kumamoto University NUC
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Kumamoto University NUC
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • C22C23/06Alloys based on magnesium with a rare earth metal as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/002Castings of light metals
    • B22D21/007Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/02Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
    • B22D21/04Casting aluminium or magnesium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • C22C23/04Alloys based on magnesium with zinc or cadmium as the next major constituent

Claims (8)

  1. Ein Verfahren zum Herstellen einer flammenhemmenden Magnesiumlegierung, aufweisend einen Schritt des Schmelzens einer flammenhemmenden Magnesiumlegierung, die a Atom-% Zn, b Atom-% Y, x Atom-% Ca und einen Rest Mg enthält, wobei a, b und x die nachfolgenden Formeln 1 bis 4 erfüllen,
    wobei die flammenhemmende Magnesiumlegierung optional y Atom-% Al enthält und y die nachfolgende Formel 5 erfüllt,
    wobei die flammenhemmende Magnesiumlegierung optional insgesamt c Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus La, Ce, Pr, Eu, Mm und Gd ausgewählt ist, und c die nachfolgende Formel 6 und Formel 7 oder die nachfolgende Formel 7 und Formel 8 erfüllt, oder
    optional insgesamt c' Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus Yb, Tb, Sm und Nd ausgewählt ist, und c' die nachfolgende Formel 8' und Formel 9 erfüllt, oder
    optional insgesamt c" Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus Yb, Tb, Sm und Nd ausgewählt ist, insgesamt d Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus La, Ce, Pr, Eu, Mm und Gd ausgewählt ist, und c" und d die Formeln 6" bis 8" oder die nachfolgenden Formeln 8" und 9" erfüllen, und
    wobei die flammenhemmende Magnesiumlegierung optional insgesamt mehr als 0 Atom-% und nicht mehr als 2,5 Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus Th, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B, C, Sn, Au, Ba, Ge, Bi, Ga, In, Ir, Li, Pd, Sb und V ausgewählt ist, 0,5 a < 5,0
    Figure imgb0059
    0,5 < b < 5,0
    Figure imgb0060
    2 / 3 a 5 / 6 b
    Figure imgb0061
    0,1 x 0,5
    Figure imgb0062
    0 < y 0,5
    Figure imgb0063
    0 c < 2,0
    Figure imgb0064
    0,2 b + c 6,0
    Figure imgb0065
    c / b 1,5
    Figure imgb0066
    0 c 3,0
    Figure imgb0067
    0.2 b + c 6,0
    Figure imgb0068
    0 c " 3,0
    Figure imgb0069
    0 d < 2,0
    Figure imgb0070
    0,2 b + c " + d 6,0
    Figure imgb0071
    d / b 1,5.
    Figure imgb0072
  2. Das Verfahren zum Herstellen einer flammenhemmenden Magnesiumlegierung gemäß Anspruch 1,
    wobei die flammenhemmende Magnesiumlegierung eine Zündtemperatur von 800°C oder mehr hat.
  3. Das Verfahren zum Herstellen einer flammenhemmenden Magnesiumlegierung gemäß Anspruch 1 oder 2,
    wobei die flammenhemmende Magnesiumlegierung bei einer Temperatur von 800°C oder weniger geschmolzen wird.
  4. Das Verfahren zum Herstellen einer flammenhemmenden Magnesiumlegierung gemäß irgendeinem der Ansprüche 1 bis 3,
    wobei die flammenhemmende Magnesiumlegierung geschmolzen wird und dann die geschmolzene flammenhemmende Magnesiumlegierung gegossen wird.
  5. Das Verfahren zum Herstellen einer flammenhemmenden Magnesiumlegierung gemäß Anspruch 4,
    wobei eine Abkühlgeschwindigkeit beim Gießen der flammenhemmenden Magnesiumlegierung 1000 K/Sekunde oder weniger beträgt.
  6. Eine flammenhemmende Magnesiumlegierung, aufweisend a Atom-% Zn, b Atom-% Y, x Atom-% Ca und einen Rest Magnesium,
    wobei a, b und x die nachfolgenden Formeln 1 bis 4 erfüllen und die Legierung eine kristalline Struktur mit einer langperiodische-Stapelordnung-Strukturphase aufweist,
    wobei die flammenhemmende Magnesiumlegierung optional y Atom-% Al enthält und y die nachfolgende Formel 5 erfüllt,
    wobei die flammenhemmende Magnesiumlegierung optional insgesamt c Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus La, Ce, Pr, Eu, Mm und Gd ausgewählt ist, und c die nachfolgende Formel 6 und Formel 7 oder die nachfolgende Formel 7 und Formel 8 erfüllt, oder
    optional insgesamt c' Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus Yb, Tb, Sm und Nd ausgewählt ist, und c' die nachfolgende Formel 8' und Formel 9 erfüllt, oder
    optional insgesamt c" Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus Yb, Tb, Sm und Nd ausgewählt ist, insgesamt d Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus La, Ce, Pr, Eu, Mm und Gd ausgewählt ist, und c" und d die Formeln 6" bis 8" oder die nachfolgenden Formeln 8" und 9" erfüllen, und
    wobei die flammenhemmende Magnesiumlegierung optional insgesamt mehr als 0 Atom-% und nicht mehr als 2,5 Atom-% von mindestens einem Element enthält, das aus einer Gruppe bestehend aus Th, Si, Mn, Zr, Ti, Hf, Nb, Ag, Sr, Sc, B, C, Sn, Au, Ba, Ge, Bi, Ga, In, Ir, Li, Pd, Sb und V ausgewählt ist, 0,5 a < 5,0
    Figure imgb0073
    0,5 < b < 5,0
    Figure imgb0074
    2 / 3 a 5 / 6 b
    Figure imgb0075
    0,1 x 0,5
    Figure imgb0076
    0 < y 0,5
    Figure imgb0077
    0 c < 2,0
    Figure imgb0078
    0,2 b + c 6,0
    Figure imgb0079
    c / b 1,5
    Figure imgb0080
    0 c 3,0
    Figure imgb0081
    0.2 b + c 6,0
    Figure imgb0082
    0 c " 3,0
    Figure imgb0083
    0 d < 2,0
    Figure imgb0084
    0,2 b + c " + d 6,0
    Figure imgb0085
    d / b 1,5.
    Figure imgb0086
  7. Die flammenhemmende Magnesiumlegierung gemäß Anspruch 6,
    wobei die Legierung eine Zündtemperatur von 800°C oder mehr hat.
  8. Die flammenhemmende Magnesiumlegierung gemäß Anspruch 6 oder 7,
    wobei die Legierung ein Guss ist.
EP14785713.0A 2013-04-15 2014-04-14 Feuerfeste magnesiumlegierung und herstellungsverfahren dafür Active EP2987875B1 (de)

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JP2013084866 2013-04-15
PCT/JP2014/061105 WO2014171549A1 (ja) 2013-04-15 2014-04-14 難燃マグネシウム合金及びその製造方法

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EP2987875B1 true EP2987875B1 (de) 2018-10-10

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EP (2) EP2987874B1 (de)
JP (3) JP6439683B2 (de)
KR (2) KR20150140828A (de)
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WO (3) WO2014171550A1 (de)

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WO2014171548A1 (ja) 2014-10-23
KR20150140829A (ko) 2015-12-16
CN105283566A (zh) 2016-01-27
WO2014171550A9 (ja) 2015-12-30
EP2987874A4 (de) 2017-01-25
WO2014171550A1 (ja) 2014-10-23
WO2014171549A1 (ja) 2014-10-23
US20160168666A1 (en) 2016-06-16
KR20150140828A (ko) 2015-12-16
EP2987875A4 (de) 2016-11-30
KR101863573B1 (ko) 2018-06-01
JPWO2014171550A1 (ja) 2017-02-23
EP2987875A1 (de) 2016-02-24
JPWO2014171548A1 (ja) 2017-02-23
JP6361051B2 (ja) 2018-07-25
US20160068933A1 (en) 2016-03-10
JP6439683B2 (ja) 2018-12-19
CN105408508A (zh) 2016-03-16
EP2987874A1 (de) 2016-02-24
JPWO2014171549A1 (ja) 2017-02-23
EP2987874B1 (de) 2019-11-20

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