EP2940202B1 - Heat-resistant fabric - Google Patents

Heat-resistant fabric Download PDF

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Publication number
EP2940202B1
EP2940202B1 EP13869555.6A EP13869555A EP2940202B1 EP 2940202 B1 EP2940202 B1 EP 2940202B1 EP 13869555 A EP13869555 A EP 13869555A EP 2940202 B1 EP2940202 B1 EP 2940202B1
Authority
EP
European Patent Office
Prior art keywords
heat
fiber
resistant fabric
aromatic polyamide
meta
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13869555.6A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2940202A4 (en
EP2940202A1 (en
Inventor
Hiroki Shimada
Hajime Izawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Publication of EP2940202A1 publication Critical patent/EP2940202A1/en
Publication of EP2940202A4 publication Critical patent/EP2940202A4/en
Application granted granted Critical
Publication of EP2940202B1 publication Critical patent/EP2940202B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/80—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides
    • D01F6/805—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides from aromatic copolyamides
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D03D1/0041—Cut or abrasion resistant
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D03D1/007—UV radiation protecting
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/04—Heat-responsive characteristics
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation

Definitions

  • the heat-resistant fabric of the invention is a heat-resistant fabric containing a meta-type wholly aromatic polyamide fiber, characterized in that the abrasion resistance of the heat-resistant fabric in accordance with the JIS L1096 8.19.1 A-1 method (universal type method (plane method), abrasion tester press load: 4.45 N (0.454 kf), paper: #600) is 200 rubs or more, the tear strength of the heat-resistant fabric in accordance with the JIS L1096 8.17.4 D method (pendulum method) is 20 N or more, and the retention of the abrasion resistance and the retention of the tear strength after 100 washes in accordance with JIS L0844 No.
  • JIS L1096 8.19.1 A-1 method universal type method (plane method), abrasion tester press load: 4.45 N (0.454 kf), paper: #600
  • the tear strength of the heat-resistant fabric in accordance with the JIS L1096 8.17.4 D method pendulum method
  • the pilling resistance of the heat-resistant fabric in accordance with the 11. JIS L1096 A method is Level 4 or higher.
  • the heat-resistant fabric of the invention it is preferable that the heat-resistant fabric contains cellulose and is dyed with a fluorescent dye.
  • the above object can be achieved by using the below-mentioned fiber having improved dyeing affinity and discoloration/fading resistance as a meta-type wholly aromatic polyamide fiber to form the heat-resistant fabric.
  • appropriate materials for the heat-resistant fabric are selected, and they are mixed in appropriate proportions.
  • the single-fiber toughness of the meta-type wholly aromatic polyamide fiber is 130 or less, more preferably 110 or less, and still more preferably 100 or less.
  • the heat-resistant fabric contains at least one member selected from a cellulose fiber, a polyester fiber, an acrylic fiber, and a polyamide fiber in an amount of 2 to 50 mass%, more preferably 2 to 48 mass%, based on the mass of the heat-resistant fabric.
  • a specific substituted benzotriazole is preferable.
  • Specific examples thereof include 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol, 2-[5-chloro(2H)-benzotriazol-2-yl]-4-methyl-6-(tert-butyl) phenol, 2-[2H-benzotriazol-2-yl]-4-6-bis(1-methyl-1-phenylethyl)ph enol, and 2-[2H-benzotriazol-2-yl]-4-(1,1,3,3-tetramethylbutyl)pheno 1.
  • 2-[2H-benzotriazol-2-yl]-4-6-bis(1-methyl-1-phenylethyl)ph enol is particularly preferable because of its high hydrophobicity and low absorption in the visible region.
  • a meta-type wholly aromatic aramid fiber was prepared by the following method.
  • the spinning dope was discharged and spun from a spinneret (hole diameter: 0.07 mm, the number of holes: 500) into a coagulation bath at a bath temperature of 30°C.
  • the spinning dope was discharged and spun into the coagulation bath at a yarn speed of 7 m/min.
  • the brightness L was adjusted with a dye so that fabrics after dyeing had an L value of 49 (neutral color) regardless of the foundation fabrics. Redyeing was performed as necessary to accurately control the L value.
  • the conditions for dyeing and the conditions for washing a dyed product in a reducing bath (pH 5.5) were as follows.
  • Staple fibers of a meta-type wholly aromatic polyamide fiber (MA), a para-type wholly aromatic polyamide fiber (PA), a polyester fiber (PE), and a flame-retardant rayon fiber (RY) were blend-spun in a mass ratio MA/PA/PE/RY of 55/5/15/25 into a spun yarn (36 count, 2-ply yarn), and woven at a weaving density of warp: 100 yarns/25.4 mm and weft: 56 yarns/25.4 mm, thereby giving a twill-woven fabric having an areal weight of 230 g/m 2 .
  • the abrasion resistance of the obtained fabric was measured. As a result, the resistance before washing (L0) was 67 rubs, while the resistance after 100 washes (L100) was 41 rubs. Thus, the retention of abrasion resistance (L100/L0 ⁇ 100) was 61%.
  • the tear strength of the obtained fabric was measured. As a result, the strength before washing (L0) was 21 N in the longitudinal direction and 10 N in the transverse direction, while the strength after 100 washes (L100) was 11 N in the longitudinal direction and 6 N in the transverse direction. Thus, the retention of tear strength (L100/L0 ⁇ 100) was 52% in the longitudinal direction and 60% in the transverse direction. Further, pilling was Level 3 in the longitudinal direction and Level 3 in the transverse direction.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Coloring (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Artificial Filaments (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Laminated Bodies (AREA)
EP13869555.6A 2012-12-28 2013-12-27 Heat-resistant fabric Active EP2940202B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012287423 2012-12-28
PCT/JP2013/085353 WO2014104411A1 (ja) 2012-12-28 2013-12-27 耐熱布帛

Publications (3)

Publication Number Publication Date
EP2940202A1 EP2940202A1 (en) 2015-11-04
EP2940202A4 EP2940202A4 (en) 2015-12-23
EP2940202B1 true EP2940202B1 (en) 2017-02-01

Family

ID=51021462

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13869555.6A Active EP2940202B1 (en) 2012-12-28 2013-12-27 Heat-resistant fabric

Country Status (13)

Country Link
US (1) US20150299905A1 (zh)
EP (1) EP2940202B1 (zh)
JP (1) JPWO2014104411A1 (zh)
KR (1) KR20150103101A (zh)
CN (1) CN104903502A (zh)
BR (1) BR112015015161A2 (zh)
CA (1) CA2895042A1 (zh)
ES (1) ES2621358T3 (zh)
HK (1) HK1213606A1 (zh)
MX (1) MX349902B (zh)
RU (1) RU2015131087A (zh)
TW (1) TW201504492A (zh)
WO (1) WO2014104411A1 (zh)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6158602B2 (ja) * 2013-06-11 2017-07-05 帝人株式会社 伸縮性難燃布帛および繊維製品
RU2671648C2 (ru) * 2014-09-03 2018-11-06 Тейдзин Лимитед Ткань и волоконный продукт
JP6449616B2 (ja) * 2014-10-23 2019-01-09 帝人株式会社 布帛および繊維製品および布帛の処理方法
CN110446805B (zh) * 2017-02-27 2023-03-31 帝人芳纶有限公司 织物和由其制造的工作服
US10612166B1 (en) 2017-05-03 2020-04-07 Waubridge Specialty Fabrics, Llc Fire resistant fabric with stitchbonding
JP2019014994A (ja) * 2017-07-06 2019-01-31 帝人株式会社 布帛および繊維製品
WO2020262671A1 (ja) * 2019-06-28 2020-12-30 帝人株式会社 染色布帛、それを用いた繊維製品、および、布帛の染色方法
IT202000005650A1 (it) * 2020-03-17 2021-09-17 Manteco S P A Metodo di simulazione dell’invecchiamento di un tessuto
CN115443354B (zh) * 2020-04-21 2024-05-28 帝人富瑞特株式会社 防水性布帛和纤维制品
CN112080812B (zh) * 2020-08-28 2023-11-21 泰和新材集团股份有限公司 一种舒适性间位芳纶及制备方法
CN113724797B (zh) * 2021-09-02 2024-03-08 成都慧成科技有限责任公司 一种聚酰胺拉伸成膜稳定性的评价方法

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JP4447476B2 (ja) * 2005-01-21 2010-04-07 一村産業株式会社 洗濯耐久性の改善された織編物
CN100343426C (zh) * 2005-12-29 2007-10-17 中国人民解放军海军医学研究所 一种耐热阻燃织物及其制备方法
CN201074263Y (zh) * 2006-12-06 2008-06-18 上海新纺织产业用品有限公司 一种高强、复合结构的防护织物
US9994978B2 (en) * 2008-01-04 2018-06-12 Southern Mills, Inc. Flame resistant fabrics having improved resistance to surface abrasion or pilling and methods for making them
JP5188841B2 (ja) 2008-03-05 2013-04-24 ユニチカトレーディング株式会社 複合紡績糸及び織編物
JP2009249758A (ja) 2008-04-04 2009-10-29 Toyobo Co Ltd 被覆性及び耐摩耗性に優れた芯鞘複合糸及び織編物
JP4647680B2 (ja) * 2008-09-29 2011-03-09 帝人テクノプロダクツ株式会社 易染色性メタ型全芳香族ポリアミド繊維
JP2011202327A (ja) * 2010-03-26 2011-10-13 Teijin Techno Products Ltd 易染色性メタ型全芳香族ポリアミド繊維を含む布帛
JP4804590B1 (ja) * 2010-04-14 2011-11-02 帝人テクノプロダクツ株式会社 メタ型全芳香族ポリアミド繊維
JP2012052249A (ja) * 2010-08-31 2012-03-15 Teijin Techno Products Ltd 複合紡績糸
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Also Published As

Publication number Publication date
ES2621358T3 (es) 2017-07-03
CA2895042A1 (en) 2014-07-03
TW201504492A (zh) 2015-02-01
US20150299905A1 (en) 2015-10-22
HK1213606A1 (zh) 2016-07-08
CN104903502A (zh) 2015-09-09
WO2014104411A1 (ja) 2014-07-03
KR20150103101A (ko) 2015-09-09
JPWO2014104411A1 (ja) 2017-01-19
RU2015131087A (ru) 2017-02-02
BR112015015161A2 (pt) 2017-07-11
EP2940202A4 (en) 2015-12-23
MX349902B (es) 2017-08-18
EP2940202A1 (en) 2015-11-04
MX2015008229A (es) 2015-09-29

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