EP2877806B2 - Procédé et dispositif destinés à nettoyer des surfaces d'un échangeur de chaleur à ailettes - Google Patents
Procédé et dispositif destinés à nettoyer des surfaces d'un échangeur de chaleur à ailettes Download PDFInfo
- Publication number
- EP2877806B2 EP2877806B2 EP13759427.1A EP13759427A EP2877806B2 EP 2877806 B2 EP2877806 B2 EP 2877806B2 EP 13759427 A EP13759427 A EP 13759427A EP 2877806 B2 EP2877806 B2 EP 2877806B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- compressed air
- pressure
- jet nozzle
- jet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004140 cleaning Methods 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 56
- 230000000694 effects Effects 0.000 claims description 13
- 239000012159 carrier gas Substances 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 2
- 241000446313 Lamella Species 0.000 description 5
- 238000005422 blasting Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001739 rebound effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28G—CLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
- F28G9/00—Cleaning by flushing or washing, e.g. with chemical solvents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/0075—Nozzle arrangements in gas streams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/02—Spray pistols; Apparatus for discharge
- B05B7/04—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
- B05B7/0416—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid
- B05B7/0483—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid with gas and liquid jets intersecting in the mixing chamber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28G—CLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
- F28G1/00—Non-rotary, e.g. reciprocated, appliances
- F28G1/16—Non-rotary, e.g. reciprocated, appliances using jets of fluid for removing debris
- F28G1/166—Non-rotary, e.g. reciprocated, appliances using jets of fluid for removing debris from external surfaces of heat exchange conduits
Definitions
- the invention relates to a method for cleaning the lamellae of lamellar heat exchangers, with the features of the preamble of claim 1
- a cleaning system for lamellar heat exchangers is, for example, from WO 2010/133932 A1 known.
- Chemical cleaning agents are also used for cleaning, which then have to be removed again with a water jet, whereby larger amounts of wastewater contaminated with chemicals arise.
- This wastewater has to be collected on the earth's surface - if at all possible.
- the area around the lamellar heat exchanger must be protected in order to prevent damage to the environment.
- the aim and purpose of the invention is to provide a method for cleaning lamellar heat exchangers which has a gentle but effective cleaning effect with little use of water and the avoidance of chemicals.
- a cleaning process is provided by means of a low-pressure cleaning process using compressed air and small amounts of water as the blasting agent, which is particularly suitable for cleaning lamellar heat exchangers. Since compressed air with a low water content has a much lower density than a water jet and can also be brought to a very high speed through a corresponding nozzle, complete penetration of the heat exchanger is achieved even at low pressure of the carrier gas.
- the use of a low jet pressure which is only generated by means of compressed air and a small amount of pure water without additives, enables gentle but effective cleaning of the lamellas in the entire depth of the exchanger.
- the lamellar surfaces to be cleaned are aligned parallel to the nozzle jet. Since, in contrast to the use of the method for other surfaces, such as B. graphite or foils, the jet angle on the surfaces to be cleaned is close to 0 °, the jet pressure exerted on the surfaces is very low here.
- the surprising cleaning effect here cannot result from the impact of the nozzle jet on the surface, but rather results surprisingly from the frictional effect of the nozzle jet on the surfaces of the lamellas.
- the problem is solved according to the invention in that compressed air is fed to a jet nozzle which has a section converging to a constriction and an adjoining diverging section, and the water is preferably fed into the carrier gas flow upstream of the constriction, possibly in or downstream of the constriction of the jet nozzle fed in and thus brought to high speed, at least approximately the speed of sound or to supersonic speed.
- Tests have shown that at a relatively low pressure of the compressed air from 1 bar, preferably from 1.5 bar and thus a relatively low jet contact pressure, a complete penetration of the nozzle jet by the lamellar heat exchanger is achieved.
- the jet pressure can be increased as much as the strength of the lamellas allows. This also removes solid or sticky layers of dirt without bending or otherwise damaging the thin lamellae.
- a flat nozzle is preferably used to achieve uniform cleaning with as few overlapping areas as possible. The flat nozzle is used for cleaning "Normal" surfaces often have a lower cleaning effect than a round nozzle, but when cleaning lamellar heat exchangers, the nozzle jet gets into the narrow channels of the lamellar heat exchanger more effectively, as the rebound effects on the front of the exchanger are greatly reduced. This leads to an improved and even cleaning effect.
- the throughput of the carrier gas is 4000 liters per minute, preferably 6000 liters per minute.
- the amount of water supplied in liters in relation to the compressed air should preferably be less than 1: 1000 a distance of at least 30 mm in front of the constriction of the jet nozzle be at least 50% of the pressure of the compressed air, but preferably be similar to or higher than the pressure of the compressed air. If the supplied water is metered in at a distance of less than 30 mm from the nozzle constriction or in or downstream of the nozzle constriction, the water pressure can be reduced or added without pressure depending on the pressure of the compressed air, which decreases due to the increase in speed. The water is then sucked in by the high flow speed of the water.
- the nozzle jet can be made to pulsate through the design of the water pump and / or through corresponding valves in the water and / or compressed air supply, which leads to an intensification of the cleaning effect. If there is sufficient pre-pressure of the water, an additional pump to increase the pressure of the water can be dispensed with. An improvement in the cleaning effect can also be achieved by heating the compressed air e.g. B. are caused by means of heat exchangers to z. B. to be able to clean heavily oil-contaminated surfaces faster and more successfully.
- the required water preferably has drinking water quality, but also properties close to drinking water quality.
- a device for carrying out the cleaning of fins of a lamellar heat exchanger is provided for the method. Only compressed air and water are preferably used for cleaning.
- the device here comprises a jet nozzle with a feed for the compressed air, the jet nozzle having a section that converges to a constriction and a section that adjoins it.
- a supply line for the water is also provided, which is used to add the water before, in or after the Jet nozzle is formed.
- the ratio of the volume of the amount of water to the volume of the amount of compressed air is less than 1: 1000, preferably less than 1: 2000.
- the jet nozzle is designed to be convergent-divergent, preferably as a Laval nozzle.
- a suitable throttle valve for regulating the amount of water is fitted in the liquid supply upstream of the jet device.
- the water / liquid is fed to the carrier gas directly or via a distribution chamber with at least one outlet opening.
- a membrane pump or a piston pump is preferably provided for conveying the water / the liquid.
- the displacement should be less than 1.00 liters.
- a pressure booster can be arranged behind the diaphragm pump. Interrupter valves for water and / or compressed air can be provided in order to generate a pulsating nozzle jet; additional changing line diameters from the water inlet to the pump can also bring about desired voltage changes in the water.
- the water can be conveyed by any type of pump, preferably a diaphragm pump or piston pump, which draws in the water, but can also accept it from a water hose under pressure.
- a water pump operated by compressed air is that no additional power supply is required, with hour meters, etc. being able to be supplied by a miniature battery or other external power sources.
- a pressure booster is installed behind the diaphragm pump or piston pump, the pressure of the control air can be kept low, although the water pressure can be increased well above the control pressure.
- the generation of a pulsating jet can be caused by the design of the pump as a diaphragm pump and / or by the use of interrupter valves for water and / or compressed air.
- the line from the water inlet to the pump can have different diameters.
- a flat nozzle is used for the device particularly advantageous.
- the use of a lance with an adjustable jet angle is particularly advantageous for cleaning hard-to-reach areas.
- Figure 1 shows a sectional view of a jet nozzle 1 in which the line 2 serving to supply the water is led into a distribution space 3 and then through the outlet openings 4 into the jet line 5 which opens into the jet nozzle 1.
- the pressurized compressed air 9 and water are fed to the jet nozzle 1.
- the jet nozzle 1 here has a section 7 converging to a constriction 6 and an adjoining diverging section 8 Compressed air flow are metered.
- Figure 2 shows a further example of a jet nozzle 1, in which the line 2 serving to supply the water opens directly into the jet line 5.
- Figure 3 shows a further example of a jet nozzle 1, the line 2 serving to supply the water opening into the jet nozzle 1 directly in front of the constriction 6.
- Figure 4 shows a modified example of the flat jet nozzle 1, in which the line 2 used to supply the water is led into a distribution space 3 and then through the outlet openings 4 into the jet line 5 which opens into the jet nozzle 1.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Nozzles (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Cleaning In General (AREA)
Claims (8)
- Procédé de nettoyage de surfaces d'un échangeur de chaleur à ailettes, dans lequel on utilise, pour le nettoyage, de l'air comprimé et de l'air sans additifs, et l'air comprimé est acheminé jusqu'à une buse d'éjection (1) qui présente une partie convergente (7) vers un goulot (6) et une partie divergente (8) étant contiguë à celle-ci, et l'eau est dosée dans le flux d'air comprimé en amont, dans le goulot (6) de la buse d'éjection ou en aval de celui-ci,
dans lequel la buse d'éjection (1), qui est de préférence configurée sous la forme d'une buse plate, est orientée sur la cavité d'un échangeur de chaleur à ailettes formée entre les ailettes, le jet de la buse traversant, en raison du nettoyage des surfaces des ailettes, la cavité existant entre des ailettes adjacentes. - Procédé selon la revendication 1, caractérisé en ce que l'eau est acheminée à une pression qui, lors d'un dosage à une distance minimum de 80 mm en amont du goulot de la buse d'éjection (1), est de préférence égale ou supérieure à la pression de l'air comprimé, mais au moins à 80 % de la pression de l'air comprimé, dans lequel, lors d'un dosage à une distance inférieure à 80 mm en amont du goulot (6) de la buse d'éjection (1), respectivement dans le goulot (6) de la buse d'éjection (1) ou en aval de celui-ci, en fonction de l'augmentation de la vitesse allant de pair il est possible d'opérer avec une diminution de la pression avec une très faible pression du liquide ou même sans aucune pression par le biais de l'utilisation de l'effet d'aspiration.
- Procédé selon la revendication 1 ou 2, caractérisé en ce que la quantité d'eau/quantité de liquide acheminée est, par rapport à l'air comprimé en pourcentage volumique, inférieure à 1:1000 et/ou en ce que la pression du gaz porteur est au moins de 1,5 bar.
- Procédé selon une des revendications précédentes 1 à 3, caractérisé en ce que le mélange d'air comprimé et d'eau dans la buse d'éjection (1) est accéléré selon une certaine vitesse, à savoir approchant de la vitesse du son ou de la vitesse supersonique.
- Procédé selon une des revendications précédentes 1 à 4, caractérisé en ce que la buse d'éjection (1) est une buse plate afin d'obtenir un nettoyage efficace, soigneux et homogène des ailettes sans détériorations.
- Procédé selon une des revendications précédentes 1 à 5, caractérisé en ce que la vitesse d'écoulement du mélange d'air comprimé et d'eau est variée par une soupape d'étranglement respectivement un réducteur de pression (10) dans l'acheminement de liquide (2) et/ou une soupape d'étranglement respectivement un réducteur de pression dans l'acheminement d'air comprimé (9).
- Procédé selon une ou plusieurs des revendications précédentes, caractérisé en ce que l'eau et/ou l'air comprimé est acheminé(e) à la buse d'éjection (1) de manière puisée.
- Procédé selon une ou plusieurs des revendications précédentes, caractérisé en ce que l'air comprimé est acheminé par réchauffement au moyen d'un échangeur de chaleur.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13759427T PL2877806T3 (pl) | 2009-02-16 | 2013-07-23 | Metoda i urządzenie dla czyszczenia powierzchni płytkowego wymiennika ciepła |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE202009018911.2U DE202009018911U1 (de) | 2009-02-16 | 2009-02-16 | Reinigungsvorrichtung für die Reinigung empfindlicher Oberflächen |
DE102012014605.1A DE102012014605A1 (de) | 2009-02-16 | 2012-07-24 | Reinigungsvorrichtung für die Reinigung von Lamellenwärmetauschern |
PCT/DE2013/100273 WO2014015860A1 (fr) | 2009-02-16 | 2013-07-23 | Procédé et dispositif destinés à nettoyer des surfaces d'un échangeur de chaleur à ailettes |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2877806A1 EP2877806A1 (fr) | 2015-06-03 |
EP2877806B1 EP2877806B1 (fr) | 2018-04-11 |
EP2877806B2 true EP2877806B2 (fr) | 2021-11-17 |
Family
ID=55411114
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13759427.1A Active EP2877806B2 (fr) | 2009-02-16 | 2013-07-23 | Procédé et dispositif destinés à nettoyer des surfaces d'un échangeur de chaleur à ailettes |
Country Status (6)
Country | Link |
---|---|
US (1) | US20150129171A1 (fr) |
EP (1) | EP2877806B2 (fr) |
JP (1) | JP2015524546A (fr) |
DE (2) | DE202009018911U1 (fr) |
PL (1) | PL2877806T3 (fr) |
WO (1) | WO2014015860A1 (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102015106914A1 (de) | 2014-11-18 | 2016-05-19 | Jens-Werner Kipp | Verfahren und Vorrichtung zur Reinigung von Rohren, Tanks und sonstigen Oberflächen von Teilen, mit Rückständen aus Fett, Oel und ähnlichen Stoffen |
CN104588357A (zh) * | 2014-12-31 | 2015-05-06 | 苏州原点工业设计有限公司 | 一种实验室雾滴吹洗装置 |
DE102015201945A1 (de) | 2015-02-04 | 2016-08-04 | Sivantos Pte. Ltd. | Höreinrichtung zur binauralen Versorgung sowie Verfahren zum Betrieb |
WO2017117255A1 (fr) | 2015-12-28 | 2017-07-06 | Thick Coil Clean, Inc. | Appareil et procédé pour le nettoyage de serpentins de refroidissement de systèmes de cvc |
US11788807B2 (en) | 2015-12-28 | 2023-10-17 | Coil Flow Max, Inc. | Apparatus and method for cleaning HVAC cooling coils |
RU170745U1 (ru) * | 2016-06-10 | 2017-05-05 | Акционерное Общество "Сибтехэнерго" Инженерная Фирма По Наладке, Совершенствованию Технологий И Эксплуатации Электро-Энергооборудования Предприятий И Систем | Устройство для очистки поверхностей нагрева энерготехнологического оборудования |
JP6558806B2 (ja) * | 2016-06-27 | 2019-08-14 | 株式会社ダイフク | 洗車機及び洗車方法 |
DE102017101850A1 (de) * | 2016-10-31 | 2018-05-03 | Mycon Gmbh | Installationsanordnung und Verfahren zur automatisierten Reinigung von Lamellenwärmetauschern |
DE102017119113A1 (de) * | 2017-08-22 | 2019-02-28 | Jens-Werner Kipp | Fassadenreinigungsvorrichtung und Verfahren zur Reinigung einer Fassade |
DE102018101520A1 (de) * | 2018-01-24 | 2019-07-25 | Karlsruher Institut für Technologie | Zweistoffdüse |
DE102019005166A1 (de) * | 2019-07-25 | 2021-01-28 | Mycon Gmbh | Vorrichtung zur Reinigung von Lamellenwärmetauschern in Horizontal- oder Schrägstellung |
WO2021023328A1 (fr) | 2019-08-06 | 2021-02-11 | Mycon Gmbh | Dispositif de protection enroulable pour buses à jet pour nettoyer des surfaces dans le but de réduire le bruit du jet de buse |
DE102020001000A1 (de) | 2020-02-17 | 2021-08-19 | Mycon Gmbh | Verfahren zur Reinigung von Luft/Luft Wärmeübertragungsapparaten z.B. aus dem Luftfahrtbereich |
CN112792050B (zh) * | 2021-02-01 | 2022-04-29 | 江西中烟工业有限责任公司 | 一种烟草喂料机出料斗视窗的清洁装置及其清洁方法 |
DE202022103564U1 (de) * | 2021-07-09 | 2022-07-11 | RIBO Reinigungs- und Gebäude-Service Gesellschaft mit beschränkter Haftung | Reinigungsvorrichtung für Lamellenwärmetauscher |
PL442523A1 (pl) * | 2022-10-13 | 2024-04-15 | 3N Solutions Spółka Z Ograniczoną Odpowiedzialnością | Lanca zestawu czyszczącego urządzeń energetycznych pozostających pod napięciem średnim |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2907810C2 (de) * | 1979-02-28 | 1985-07-04 | MTU Motoren- und Turbinen-Union München GmbH, 8000 München | Wärmetauscher zur Führung von Gasen stark unterschiedlicher Temperaturen |
DE3507203C1 (de) * | 1985-03-01 | 1986-06-12 | DEC Engineering GmbH, 4650 Gelsenkirchen | Vorrichtung zum Reinigen von Plattenwaermetauschern fuer die Waermerueckgewinnung von Abluft |
US4841999A (en) * | 1987-08-21 | 1989-06-27 | Donald Danko | Brake durm cleaner assembly and method of cleaning |
DE9110027U1 (de) | 1991-08-14 | 1991-09-26 | Kipp, Angelika | Reinigungsgerät |
EP1470865A3 (fr) * | 2000-06-30 | 2009-02-18 | Shibuya Kogyo Co., Ltd. | Buse et appareil de nettoyage |
DE10243693B3 (de) | 2002-09-20 | 2004-04-01 | Jens Werner Kipp | Strahlverfahren und-vorrichtung |
DK1501655T3 (da) | 2002-09-20 | 2006-08-07 | Jens-Werner Kipp | Strålefremgangsmåde og -indretning |
DE102004023246B3 (de) | 2004-05-07 | 2005-10-27 | Jens-Werner Kipp | Strahlverfahren |
US8114222B2 (en) * | 2004-08-27 | 2012-02-14 | Ecolab Usa Inc. | Method for cleaning industrial equipment with pre-treatment |
KR100870588B1 (ko) * | 2007-10-22 | 2008-11-25 | 에스케이에너지 주식회사 | 열교환기용 에어팬쿨러 튜브 핀 클리닝장치 |
DE102009009014A1 (de) | 2009-02-16 | 2010-08-19 | Jens Werner Kipp | Reinigungsvorrichtung für die Reinigung empfindlicher Oberflächen |
IT1394362B1 (it) * | 2009-05-18 | 2012-06-15 | Termosanitaria S R L | Sistema per igienizzare e/o detergere uno scambiatore di calore |
-
2009
- 2009-02-16 DE DE202009018911.2U patent/DE202009018911U1/de not_active Expired - Lifetime
-
2012
- 2012-07-24 DE DE102012014605.1A patent/DE102012014605A1/de not_active Withdrawn
-
2013
- 2013-07-23 EP EP13759427.1A patent/EP2877806B2/fr active Active
- 2013-07-23 PL PL13759427T patent/PL2877806T3/pl unknown
- 2013-07-23 WO PCT/DE2013/100273 patent/WO2014015860A1/fr active Application Filing
- 2013-07-23 US US14/404,991 patent/US20150129171A1/en not_active Abandoned
- 2013-07-23 JP JP2015523421A patent/JP2015524546A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
DE202009018911U1 (de) | 2014-07-08 |
EP2877806A1 (fr) | 2015-06-03 |
EP2877806B1 (fr) | 2018-04-11 |
WO2014015860A1 (fr) | 2014-01-30 |
DE102012014605A1 (de) | 2014-03-06 |
PL2877806T3 (pl) | 2018-08-31 |
JP2015524546A (ja) | 2015-08-24 |
US20150129171A1 (en) | 2015-05-14 |
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