EP2873920A1 - Glühkerze - Google Patents
Glühkerze Download PDFInfo
- Publication number
- EP2873920A1 EP2873920A1 EP20140191865 EP14191865A EP2873920A1 EP 2873920 A1 EP2873920 A1 EP 2873920A1 EP 20140191865 EP20140191865 EP 20140191865 EP 14191865 A EP14191865 A EP 14191865A EP 2873920 A1 EP2873920 A1 EP 2873920A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- less
- content ratio
- aluminum
- glow plug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 79
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 79
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- 239000000470 constituent Substances 0.000 claims abstract description 21
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 33
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 229910052742 iron Inorganic materials 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 230000005611 electricity Effects 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 4
- 230000000903 blocking effect Effects 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 description 25
- 238000002474 experimental method Methods 0.000 description 25
- 230000001590 oxidative effect Effects 0.000 description 21
- 238000003466 welding Methods 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000004020 conductor Substances 0.000 description 5
- 238000004453 electron probe microanalysis Methods 0.000 description 5
- 229910000765 intermetallic Inorganic materials 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000005121 nitriding Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000008685 targeting Effects 0.000 description 3
- 230000008646 thermal stress Effects 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 230000009545 invasion Effects 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910001005 Ni3Al Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000000866 electrolytic etching Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004451 qualitative analysis Methods 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q7/00—Incandescent ignition; Igniters using electrically-produced heat, e.g. lighters for cigarettes; Electrically-heated glowing plugs
- F23Q7/001—Glowing plugs for internal-combustion engines
Definitions
- the present invention relates to a glow plug.
- the glow plug includes a sheath heater.
- the sheath heater is employed as an auxiliary heat source for an internal combustion engine (for example, a diesel engine) by compression ignition system.
- the glow plug is required to have durability like, for example, enduring usage environment inside of a combustion chamber. To improve such characteristics, there has been proposed various combinations of materials (for example, see JP-A-2004-264013 ).
- the problem of the above-described prior art is that there is a room for improvement in durability. Assuming the case where electricity is transmitted to the glow plug, if the glow plug contains chrome in the surface, an oxide film of Cr 2 O 3 is generated on the surface, and if the glow plug contains aluminum in the surface, an oxide film of Al 2 O 3 is generated on the surface.
- the oxide film enhances the durability of a bulk by protecting the bulk from oxidation.
- the bulk means a part positioning inside more than the oxide film.
- the oxide film is present on the surface of the glow plug as described above.
- thermal stress is applied to the oxide film.
- This thermal stress may peel off the oxide film from the bulk.
- a surface layer of the exposed bulk changes to the oxide film.
- a newly generated oxide film may be peeled off due to the thermal stress.
- the improvement of durability which is the object of the present invention, especially means improvement of a property suppressing such oxidative consumption (oxidation resistance).
- the present invention solves the above-described problem, and is, for example, achieved as the following configurations.
- the embodiments of the present invention can be achieved in various configurations other than the above-described configurations.
- the embodiments of the present invention can be achieved as a method for manufacturing a glow plug or a similar method.
- FIG. 1 illustrates a glow plug 10.
- FIG. 1 illustrates an external constitution of the glow plug 10 on the right side of an axial line O on the paper.
- a cross-sectional structure of the glow plug 10 is illustrated on the left side of the axial line O on the paper.
- the glow plug 10 functions as a heat source assisting an ignition at a start of a diesel engine.
- the glow plug 10 includes a center rod member 200, a metal shell 500, and a sheath heater 800.
- the sheath heater 800 generates heat by transmission of electricity. These members are assembled along the axial line O of the glow plug 10.
- the sheath heater 800 side in the glow plug 10 is referred to as a "front end side” while the opposite side is referred to as a "rear end side.”
- the metal shell 500 is formed into a tubular shape and made of carbon steel.
- the metal shell 500 holds the sheath heater 800 at an end portion on the front end side.
- the metal shell 500 holds the center rod member 200 at the end portion on the rear end side via an insulating member 410 and an O-ring 460.
- a position of the insulating member 410 in the axial line O direction is secured by crimping a ring 300 in contact with a rear end of the insulating member 410 to the center rod member 200.
- the insulating member 410 insulates the rear end side of the metal shell 500.
- the metal shell 500 incorporates a part of the center rod member 200 from the insulating member 410 to the sheath heater 800.
- the metal shell 500 includes an axial hole 510, a tool engagement portion 520, and an external thread portion 540.
- the axial hole 510 is a through hole formed along the axial line O.
- the axial hole 510 has a diameter larger than the center rod member 200.
- a space is formed between the axial hole 510 and the center rod member 200 so as to provide an electrical insulation therebetween.
- the sheath heater 800 is press-fitted to the front end side of the axial hole 510 and is bonded.
- the external thread portion 540 fits an internal thread formed at an internal combustion engine (not illustrated).
- the tool engagement portion 520 engages a tool (not illustrated) used for installation and removal of the glow plug 10.
- the center rod member 200 includes a cylindrically-formed conductive material.
- the center rod member 200 is assembled along the axial line O while being inserted into the axial hole 510 of the metal shell 500.
- the center rod member 200 includes a center rod member front end portion 210 formed at the front end side and a connecting portion 290 formed at the rear end side.
- the center rod member front end portion 210 is inserted to the inside of the sheath heater 800.
- the connecting portion 290 is an external thread projected from the metal shell 500.
- the engaging member 100 is fitted to the connecting portion 290.
- FIG. 2 is a sectional view illustrating a detailed constitution of the sheath heater 800.
- the sheath heater 800 includes a sheath tube 810, a heat generating coil 820 as a heating unit, a control coil 830, and insulating powder 840.
- the sheath tube 810 extends in the axial line O direction.
- the sheath tube 810 is a tubular member whose front end is blocked.
- the sheath tube 810 incorporates the heat generating coil 820, the control coil 830, and the insulating powder 840.
- the sheath tube 810 includes a sheath tube front end portion 811 and a sheath tube rear end portion 819.
- the sheath tube front end portion 811 is an end portion formed to a rounded shape to the outside at the front end side of the sheath tube 810.
- the sheath tube rear end portion 819 is an end portion open at the rear end side of the sheath tube 810.
- the center rod member front end portion 210 of the center rod member 200 is arranged at the inside from the sheath tube rear end portion 819 to the sheath tube 810.
- a packing 600 and the insulating powder 840 electrically insulate the sheath tube 810 from the center rod member 200.
- the packing 600 is an insulating member sandwiched between the center rod member 200 and the sheath tube 810.
- the sheath tube 810 is electrically connected to the metal shell 500.
- the control coil 830 is a coil made of a conductive material.
- the control coil 830 has a temperature coefficient of electrical resistivity larger than a material forming the heat generating coil 820.
- this conductive material nickel is preferable.
- the conductive material may be an alloy mainly containing cobalt or nickel.
- the control coil 830 is disposed inside of the sheath tube 810.
- the control coil 830 controls electric power supplied to the heat generating coil 820.
- the control coil 830 includes a control coil front end portion 831 and a control coil rear end portion 839.
- the control coil front end portion 831 is at the end portion on the front end side.
- the control coil rear end portion 839 is at the end portion on the rear end side.
- the control coil front end portion 831 is electrically connected to the heat generating coil 820 by being welded to a heat generating coil rear end portion 829 of the heat generating coil 820.
- the control coil rear end portion 839 is electrically connected to the center rod member 200 by being bonded to the center rod member front end portion 210 of the center rod member 200.
- the insulating powder 840 is powder having an electrical insulating property.
- the insulating powder 840 for example, powder of Magnesium Oxide (MgO) is employed.
- the insulating powder 840 is filled inside of the sheath tube 810.
- the insulating powder 840 electrically insulates respective clearances of the sheath tube 810, the heat generating coil 820, the control coil 830, and the center rod member 200.
- the heat generating coil 820 is a coil made of a conductive material.
- the heat generating coil 820 is disposed at the inside of the sheath tube 810 along the axial line O direction.
- the heat generating coil 820 is generates heat by transmission of electricity.
- the heat generating coil 820 includes a heat generating coil front end portion 821 and the heat generating coil rear end portion 829.
- the heat generating coil front end portion 821 is at the end portion on the front end side.
- the heat generating coil rear end portion 829 is at the end portion on the rear end side.
- the heat generating coil front end portion 821 is electrically connected to the sheath tube 810 by being welded to a part near the front end of the sheath tube 810.
- FIG. 3 is a sectional view of near front ends of the sheath tube 810 and the heat generating coil 820 before welding the sheath tube 810 and the heat generating coil 820.
- the front end of the sheath tube 810 is open before being welded with the heat generating coil 820.
- the heat generating coil 820 is arranged so as to penetrate an opening end of the sheath tube 810 before welding.
- the front end of the heat generating coil 820 before the welding extends obliquely with respect to the axial line O as illustrated in FIG. 3 .
- Welding the sheath tube 810 and the heat generating coil 820 at the arrangements forms the part near the front end to the shape as illustrated in FIG. 2 . In this embodiment, this welding is achieved by arc welding.
- FIG. 4 is a sectional view of near a welded portion 850 after welding the sheath tube 810 and the heat generating coil 820.
- the welded portion 850 is formed such that the heat generating coil 820 and the sheath tube 810 are mixed in a melted state, and the thus-melted portion hardens.
- the welded portion 850 is hatched in FIG. 4 .
- the outer surface of the welded portion 850 forms the sheath tube front end portion 811.
- a tube portion 860 illustrated in FIG. 4 is a remaining part excluding the welded portion 850 from the sheath tube 810.
- the welded portion 850 is formed by welding.
- the welded portion 850 at least contains the main constituent of the heat generating coil 820 and the main constituent of the tube portion 860.
- the following describes a constituent analysis of the welded portion 850. This analysis is performed as a preparation of experiment described later. The part to be analyzed is near the boundary between the welded portion 850 and the tube portion 860.
- the part to be analyzed is determined as follows. At the left side with respect to the axial line O in FIG. 4 , a point A and a point B are determined. The point A is at a most front end side on the interface of the welded portion 850 and the tube portion 860. The point B is a most rear end side on the interface. Afterwards, a straight line W passing through the point A and the point B is drawn. This straight line W is not limited to the interface between the welded portion 850 and the tube portion 860.
- the left side of the axial line O corresponds to the negative direction of the X-axis.
- the interface between the welded portion 850 and the tube portion 860 is, for example, determined as follows. First, a cross section near the welded portion 850 is mirror-finished. Then, electrolytic etching is performed with oxalic acid dehydrate on this cross section. Then, based on an enlarged image of this cross section, the interface between the welded portion 850 and the tube portion 860 is visually determined.
- a straight line X obtained by translating a straight line W to the axial line O side by 0.3 mm is drawn.
- a part of the welded portion 850 along the straight line X is linearly (along the straight line X) analyzed at 10 ⁇ m-intervals.
- An average value of content ratios of aluminum at the respective points, which are obtained by this analysis, is calculated as a content ratio of aluminum near the boundary.
- this part is excluded from the analysis result.
- a point C and a point D are determined.
- the point C is at a most front end side on the interface of the welded portion 850 and the tube portion 860.
- the point D is a most rear end side on the interface.
- a straight line Y passing through the point C and the point D is drawn.
- a straight line Z obtained by translating the straight line Y to the axial line O side by 0.3 mm is drawn.
- a part of the welded portion 850 along the straight line Z is linearly (along the straight line Z) analyzed at 10 ⁇ m-intervals. However, at a part up to 0.03 mm from the surface of the welded portion 850 is more likely to contain an oxide film. In view of this, this part is excluded from the analysis result.
- the reason for determining the analysis part as described above is that these parts are likely to generate a crack.
- the crack means a rift generated at the interface.
- An intermetallic compound having low toughness is likely to occur near the boundary between the welded portion 850 and the tube portion 860.
- the intermetallic compound has thermal expansion characteristics different from the original metal.
- the part near the boundary is mechanically fragile. In view of this, repeated thermal expansion and thermal shrinkage may generate a crack at the interface near the boundary.
- This embodiment employs the above-described part as one example of the part near the boundary.
- the qualitative analysis of the welded portion 850 is performed. This analysis specifies an element contained in the welded portion 850. This analysis also specifies an element having the maximum mass% as the main constituent.
- the EPMA refers to an Electron Probe Micro Analyzer.
- the WDS refers to a Wavelength Dispersive X-ray Spectrometer.
- a measuring condition for the EPMA is determined. This is determined to enhance analysis accuracy. For example, when analyzing (detecting) an element specified as the main constituent at the first step by the amount of beam current, the measuring conditions for the EPMA includes: the amount of beam current does not cause a count loss due to incident of a large amount of X-rays and the number of measured counts of 10000 counts or more is obtained.
- the element specified at the first step is quantitatively-analyzed under the conditions determined at the second step.
- the above-described average value regarding the plurality of analysis target points is calculated as the content ratio of aluminum.
- the accelerating voltage was set to 20 kV
- a probe current was set to 2.5 x 10 -8 A
- an irradiation diameter of the beam was set to 10 ⁇ m.
- the main peak is taken in for 10 seconds.
- backgrounds on respective high angle side and low angle side are taken in for five seconds. From net strength, a Count Per Second (CPS) of each element is obtained.
- CPS Count Per Second
- FIG. 5 is a table showing an experimental result regarding the relationship between a content ratio of aluminum and generation of a crack at the above-described part near the boundary.
- the heat generating coil 820 formed by a material containing nickel as the main constituent and also containing chrome, but not containing aluminum was employed.
- the expression of "not containing aluminum” includes the case where aluminum is contained at the content ratio of around a level of an error.
- the tube portion 860 formed by a material not containing aluminum (for example, SUS310S) was employed.
- the content ratio of aluminum of the welded portion 850 (part near the boundary of the tube portion 860 and the welded portion 850) in Experiment No. 1 was 0.00 mass%.
- the heat generating coil 820 formed by a material containing iron as the main constituent and also containing chrome and aluminum was employed. Furthermore, the tube portion 860 formed by Alloy 602 was employed. Alloy 602 means a DIN2.4633 alloy specified by Deutsche Industrie Normen (DIN) at the time of this application. The Alloy 602 has the content ratio of chrome of 24 mass% or more to 26 mass% or less and the content ratio of aluminum is 1.8 mass% or more to 2.4 mass% or less. Consequently, the content ratio of aluminum of the welded portion 850 (part near the boundary between the welded portion 850 and the tube portion 860) became 3.00 to 5.50 mass%.
- the content ratio of aluminum of the welded portion 850 (part near the boundary of the welded portion 850 and the tube portion 860) was changed by adjusting the front end shape of the heat generating coil 820 before melting and the content ratio of aluminum contained in the heat generating coil 820.
- thermal shock was repeatedly applied as a load, whether a crack occurred in the welded portion 850 or not was confirmed.
- the load of the thermal shock heating and cooling were conducted on the glow plug 10 by 8000 cycles. The heating was conducted for 20 seconds such that the surface of the glow plug 10 became 1150°C. The cooling was conducted for 60 seconds under the condition that the glow plug 10 was reduced by 149°C after one second from the start of cooling.
- a temperature width lowered after one second from the start of cooling may be 139 to 159°C.
- a surface temperature of the glow plug 10 in the heating may be 1140 to 1160°C.
- the content ratio of aluminum in the welded portion 850 (part near the boundary between the welded portion 850 and the tube portion 860) is preferable to be less than 5.00 mass% and more preferable to be 4.95 mass% or less.
- This content ratio is, for example, preferable to be 2.00 mass% or less and more preferable to be 1.00 mass% or less.
- constituent analysis targeting the part near the surface of the welded portion 850 The constituent analysis targeting the part near the surface is performed to analyze mass% of respective aluminum, chrome, and iron.
- the part subject to this analysis is hatched in FIG. 6.
- FIG. 6 is, similar to FIG. 4 , a sectional view near the welded portion 850.
- the part to be the analysis target is the part of the welded portion 850 where a depth from the surface is in a range of 0.03 mm to 0.5 mm.
- the depth direction is approximately vertical direction to the surface as illustrated in FIG. 6 .
- the reason for removing the range up to 0.03 mm is, as described above, to remove the oxide film from the analysis target.
- the content ratio of aluminum at each of the predetermined number of points (for example, 10 points) selected from the part to be analyzed is obtained.
- the average value of the content ratios is calculated as the average content ratio of aluminum near the surface.
- the average content ratio of chrome and iron are calculated.
- the analysis targeting the respective points is performed by the same method as the method for the first to the third steps, which is described as the analysis near the boundary. However, the irradiation diameter of the beam was changed to 100 ⁇ m.
- the analysis target points may be selected, for example, randomly.
- the analysis target points may also be selected such that the analysis target points are dispersed as much as possible.
- FIG. 7 is a table showing an experimental result examining the relationship between the average content ratios of aluminum and chrome near the surface of the welded portion 850 and the oxidative consumption.
- the oxidative consumption means that due to repeated thermal loads, the surface of the welded portion 850 is peeled off, falls, and is thinned.
- the condition of thermal load is the same as the already-described condition as an experiment regarding the crack.
- FIG. 7 also shows compositions of the heat generating coil 820 and the tube portion 860 employed to achieve the average content ratios of aluminum and chrome regarding the respective experiment Nos.
- the "residual" in the compositions of the heat generating coil 820 and the tube portion 860 means a trace additive and impurities.
- the impurities mean, for example, carbon, silicon, titanium, manganese or the like.
- the evaluation A on the oxidative consumption shown in FIG. 7 means that a thickness of the part thinned due to the oxidative consumption (hereinafter referred to as a "wearing rate") is less than 0.05 mm.
- the evaluation B means that the wearing rate is 0.05 mm or more to less than 0.10 mm.
- the evaluation C means that the wearing rate is 0.10 mm or more to less than 0.15 mm.
- the evaluation D means that the wearing rate is 0.15 mm or more to less than 0.20 mm.
- the average content ratio of aluminum was 2.5 mass% or less (Experiment Nos. 11 to 37)
- the evaluation on the oxidative consumption was C or higher.
- the average content ratio of aluminum was 2.6 mass% (Experiment No. 38)
- the evaluation on the oxidative consumption was D. Accordingly, the average content ratio of aluminum near the surface of the welded portion 850 is preferable to be 2.5 mass% or less.
- the reason for the average content ratio of aluminum affects the oxidative consumption is as follows.
- the oxide film of aluminum has an action of securing the oxide film of chrome to a base material. Accordingly, in the case where the oxide film of aluminum is too thick, if the thermal load is repeatedly applied and peels off the oxide film of aluminum, the oxide film of chrome is also peeled off.
- the reason for the evaluation of Experiment No. 38 being D was considered as follows. Since the average content ratio of aluminum was too high, 2.6 mass%, the generated oxide film of aluminum was too thick. In contrast to this, in the case where the average content ratio of aluminum was 2.5 mass% or less, since the generated oxide film of aluminum was not too thick, the evaluation of C or higher was obtained.
- the average content ratio of aluminum is preferable to be less from the viewpoint of the oxidative consumption.
- the average content ratio of aluminum is, for example, preferable to be 1.2 mass% or less.
- the average content ratio of aluminum is 0.03 mass% or less (Experiment No. 39) since the content of aluminum suppressing invasion of nitrogen is too little, nitrogen invades the inside of the sheath tube 810. Nitrogen invaded the inside of the sheath tube 810 causes nitriding of the heat generating coil 820, resulting in degrade of the durability of the heat generating coil 820. Accordingly, the average content ratio of aluminum is preferable to be a value greater than 0.03 mass% (for example, 0.04 mass% or more) from the viewpoint of the durability of the heat generating coil 820. Note that Experiment No. 39 obtained the evaluation of A from the viewpoint of the oxidative consumption.
- the average content ratio of aluminum was 0.04 mass% or more to 2.5 mass% or less and the average content ratio of chrome was 10 mass% or more to 40 mass% or less, (Experiment Nos. 11 to 37), the evaluation was C or higher. Accordingly, the average content ratio of chrome near the surface of the welded portion 850 is preferable to be 10 mass% or more to 40 mass% or less.
- the average content ratio of aluminum was 0.04 mass% or more to 2.5 mass% or less and the average content ratio of chrome was 15 mass% or more to 30 mass% or less (Experiment Nos. 13 to 33), the evaluation was B or higher. Accordingly, the average content ratio of chrome near the surface of the welded portion 850 is preferable to be 15 mass% or more to 30 mass% or less.
- the average content ratio of aluminum was 0.04 mass% or more to 2.5 mass% or less and the average content ratio of chrome was 15 mass% or more to 21 mass% or less (Experiment Nos. 13 to 18), the evaluation was A. Accordingly, the average content ratio of chrome near the surface of the welded portion 850 is preferable to be 15 mass% or more to 21 mass% or less.
- the reason for the average content ratio of chrome affects the oxidative consumption is as follows.
- An alloy containing chrome and aluminum forms an oxide film where an oxide of the chrome is formed on the surface. If the thermal load is repeatedly applied, as described above, the oxide film is repeatedly generated and peeled off, thus rapidly accelerating the oxidative consumption. In view of this, it is preferable that the oxide film be not thick too much.
- the oxide film is formed so as not to be thick too much and further is formed minutely. In view of this, the oxidative consumption is suppressed.
- the average content ratios of iron of Experiment Nos. 11 to 21, 23, and 25 to 38 were 17 mass% or more to 21 mass% or less (not shown). In the case where the average content ratio of iron is 17 mass% or more to 21 mass% or less, this prevents or suppresses the aggregated iron being exposed on the surface in association with the oxidative consumption. When the aggregated iron is exposed on the surface, the aggregated iron is rapidly oxidized. This locally accelerates the oxidative consumption. Therefore, iron is preferable not to be aggregated at the welded portion. To achieve this, as described above, the average content ratio of iron is preferable to be 17 mass% or more to 21 mass% or less.
- the heat generating coil 820 contains aluminum while the sheath tube 810 does not contain aluminum. In Experiment Nos. 22 and 24, the heat generating coil 820 does not contain aluminum while the sheath tube 810 contains aluminum. In Experiment Nos. 22 and 24, the main constituent of the heat generating coil 820 is nickel.
- a nickel base alloy As the material of the tube portion 860, a nickel base alloy is employed. However, in Experiment Nos. 16, 17, 20 to 22, 24, 26, and 27, as the material of the tube portion 860, INCONEL 601 (INCONEL is a registered trademark) may be employed. Further, in Experiment Nos. 18, 19, 25, 29, 30, and 38, an Alloy 602 may be employed as the material of the tube portion 860.
- the techniques of the present invention are not limited to the above-described embodiments.
- the techniques of the present invention may be practiced in various forms without departing from its spirit and scope.
- the technical features in the embodiments corresponding to the technical features in the respective embodiments described in SUMMARY may be, as necessary, replaced or combined. If the technical feature is not described as essential in the description, it can be deleted as necessary.
- the following embodiments are illustrative.
- FIG. 8 illustrates shapes of the sheath tube 810 and a heat generating coil 820a before welding the sheath tube 810 and the heat generating coil 820a as another embodiment.
- the heat generating coil 820a substitutes for the heat generating coil 820 in the embodiment.
- the front end of the heat generating coil 820a, as illustrated in FIG. 8 extends almost parallel to the axial line O.
- FIG. 9 illustrates shapes of the sheath tube 810 and a heat generating coil 820b before welding the sheath tube 810 and the heat generating coil 820b as yet another embodiment.
- the heat generating coil 820b substitutes for the heat generating coil 820 in the embodiment.
- the front end of the heat generating coil 820b, as illustrated in FIG. 9 is formed such that the part projecting from the opening end is closely coiled.
- the shape of the heat generating coil before welding may have a different shape from the heat generating coils illustrated in FIG. 3 , FIG. 8 , and FIG. 9 .
- the method for analyzing the content ratio of aluminum in the welded portion is not limited to the methods described in the embodiments.
- the method may change an apparatus used for the analysis.
- the part to be analyzed may be changed.
- the part where a crack is likely to be generated is selected, and the part may be set as an analysis target.
- the part where aluminum is aggregated most may be selected as the part where a crack is likely to be generated.
- an observer may select the part where aluminum is aggregated most, based on an image illustrating a distribution of the content ratio of aluminum. This magnification of the image, for example, may be 30.
- the number of measurement points and an interval of the measurement points may be changed appropriately for appropriate evaluation on durability.
- the welded portion means the tube portion extending in an axial direction and disposed at the outer circumference of the heating unit, and a part that contains at least the main constituent of the tube portion and the main constituent of the heating unit and blocks the front end of the tube portion.
- the welded portion is not limited to a part manufactured by welding.
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EP3012530A1 (de) * | 2014-10-21 | 2016-04-27 | NGK Spark Plug Co., Ltd. | Glühkerze und verfahren zur deren herstellung |
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JP6946048B2 (ja) * | 2017-05-17 | 2021-10-06 | 日本特殊陶業株式会社 | グロープラグ |
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JP2004264013A (ja) | 2003-02-13 | 2004-09-24 | Ngk Spark Plug Co Ltd | シーズヒータの製造方法及びグロープラグの製造方法 |
JP2011038720A (ja) * | 2009-08-12 | 2011-02-24 | Ngk Spark Plug Co Ltd | グロープラグ |
EP2410243A2 (de) * | 2010-07-21 | 2012-01-25 | NGK Spark Plug Co., Ltd. | Glühstiftkerze |
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JP2852552B2 (ja) * | 1990-04-16 | 1999-02-03 | 自動車機器株式会社 | シーズヒータおよびその製造方法 |
JP2806195B2 (ja) * | 1993-01-14 | 1998-09-30 | 株式会社デンソー | グロープラグ |
JP4288850B2 (ja) * | 2000-03-17 | 2009-07-01 | 株式会社デンソー | グロープラグの製造方法 |
JP2009162409A (ja) * | 2007-12-28 | 2009-07-23 | Ngk Spark Plug Co Ltd | グロープラグ |
EP2587156B1 (de) * | 2010-06-22 | 2019-04-17 | NGK Spark Plug Company Limited | Glühkerze, herstellungsverfahren dafür und erhitzungsvorrichtung damit |
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JP2004264013A (ja) | 2003-02-13 | 2004-09-24 | Ngk Spark Plug Co Ltd | シーズヒータの製造方法及びグロープラグの製造方法 |
JP2011038720A (ja) * | 2009-08-12 | 2011-02-24 | Ngk Spark Plug Co Ltd | グロープラグ |
EP2410243A2 (de) * | 2010-07-21 | 2012-01-25 | NGK Spark Plug Co., Ltd. | Glühstiftkerze |
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EP3012530A1 (de) * | 2014-10-21 | 2016-04-27 | NGK Spark Plug Co., Ltd. | Glühkerze und verfahren zur deren herstellung |
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