EP2855725B1 - Acier lamine a chaud ou a froid a faible densite, son procede de mise en oeuvre et son utilisation - Google Patents
Acier lamine a chaud ou a froid a faible densite, son procede de mise en oeuvre et son utilisation Download PDFInfo
- Publication number
- EP2855725B1 EP2855725B1 EP13732225.1A EP13732225A EP2855725B1 EP 2855725 B1 EP2855725 B1 EP 2855725B1 EP 13732225 A EP13732225 A EP 13732225A EP 2855725 B1 EP2855725 B1 EP 2855725B1
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- steel sheet
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- 238000000034 method Methods 0.000 title claims description 10
- 239000010960 cold rolled steel Substances 0.000 title description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 56
- 239000010959 steel Substances 0.000 claims description 56
- 229910000859 α-Fe Inorganic materials 0.000 claims description 50
- 238000005096 rolling process Methods 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 36
- 238000004519 manufacturing process Methods 0.000 claims description 35
- 229910001566 austenite Inorganic materials 0.000 claims description 30
- 239000002244 precipitate Substances 0.000 claims description 21
- 238000001816 cooling Methods 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- 239000011265 semifinished product Substances 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052725 zinc Inorganic materials 0.000 claims description 10
- 230000009467 reduction Effects 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 description 34
- 229910052782 aluminium Inorganic materials 0.000 description 33
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 28
- 229910052799 carbon Inorganic materials 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
- 229910052748 manganese Inorganic materials 0.000 description 15
- 239000004411 aluminium Substances 0.000 description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 12
- 238000004804 winding Methods 0.000 description 12
- 238000001953 recrystallisation Methods 0.000 description 9
- 238000005098 hot rolling Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910000734 martensite Inorganic materials 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000010955 niobium Substances 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 238000005097 cold rolling Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000009864 tensile test Methods 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- 230000004807 localization Effects 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000001812 pycnometry Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- KRQUFUKTQHISJB-YYADALCUSA-N 2-[(E)-N-[2-(4-chlorophenoxy)propoxy]-C-propylcarbonimidoyl]-3-hydroxy-5-(thian-3-yl)cyclohex-2-en-1-one Chemical compound CCC\C(=N/OCC(C)OC1=CC=C(Cl)C=C1)C1=C(O)CC(CC1=O)C1CCCSC1 KRQUFUKTQHISJB-YYADALCUSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 101150087698 alpha gene Proteins 0.000 description 1
- KCZFLPPCFOHPNI-UHFFFAOYSA-N alumane;iron Chemical compound [AlH3].[Fe] KCZFLPPCFOHPNI-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000012345 traction test Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 208000016261 weight loss Diseases 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
- B21B1/463—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0203—Cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C47/00—Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
- B21C47/02—Winding-up or coiling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0436—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
- C21D8/0473—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/004—Dispersions; Precipitations
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
Definitions
- the present invention relates to a rolled steel sheet having a mechanical strength greater than or equal to 600 MPa and an elongation at break greater than or equal to 20% and its manufacturing method.
- the patent application JP2006118000 is a lightweight steel with high strength and good ductility.
- the composition of the proposed steel contains in weight percentage: 0.1 to 1.0% C, less than 3.0% Si, 10.0 to 50.0% Mn, less than 0.01 % P, less than 0.01% S, 5.0 to 15.0% Al and 0.001 to 0.05% N, the remainder being iron and unavoidable impurities, equation (1) below in front of be satisfied, the steel will have a density less than or equal to 7.0.
- the patent application WO2007 / 024092 is intended to provide easily rolled hot-rolled sheet.
- This application relates to a sheet containing 0.2-1% C, 8-15% Mn, with a product of mechanical strength by elongation of 24000 MPa. It appears that this application is a totally austenitic structure, but this type of microstructure is particularly difficult to roll.
- One of the aims of the invention is also to provide a method of manufacturing these sheets that is compatible with usual industrial applications while being insensitive to manufacturing conditions.
- the invention firstly relates to a rolled steel sheet whose density is less than or equal to 7.3 and whose composition comprises, the contents being expressed by weight: 0 , 10 ⁇ VS ⁇ 0 , 30 % 6 , 0 ⁇ mn ⁇ 15 , 0 % 6 , 0 ⁇ al ⁇ 15 , 0 % and optionally, one or more elements selected from: Yes ⁇ 2 , 0 % Ti ⁇ 0 , 2 % V ⁇ 0 , 6 % Nb ⁇ 0 , 3 % the remainder of the composition being composed of iron and unavoidable impurities resulting from the elaboration, the ratio of the weight of manganese to that of aluminum being such that mn al > 1 , 0 , the microstructure of the sheet consisting of ferrite, austenite and up to 5% Kappa precipitates in surface fraction.
- the composition comprises, the content being expressed by weight: 0 , 18 ⁇ VS ⁇ 0 , 21 %
- the composition comprises, the content being expressed by weight: 7 , 0 ⁇ mn ⁇ 10 , 0 %
- the composition comprises, the content being expressed by weight: 6 , 0 ⁇ al ⁇ 12 , 0 %
- the composition comprises, the content being expressed by weight: 6 , 0 ⁇ al ⁇ 9 , 0 %
- the composition comprises, the content being expressed by weight: Yes ⁇ 1 %
- the ratio of the weight of manganese to that of aluminum is such that: mn al ⁇ 1 , 1 , even more preferably, the ratio is such that mn al ⁇ 1 , 5 , even more preferably, the ratio is such that mn al ⁇ 2 , 0.
- the sheet according to the invention is such that the tensile strength is greater than or equal to 600 MPa and the elongation at break is greater than or equal to 20%.
- the invention also relates to a method of manufacturing a rolled sheet such that said semi-finished product is cast directly in the form of thin slabs or thin strips.
- the end of rolling temperature T FL is between 900 and 980 ° C.
- the cooling rate V ref1 is less than or equal to 55 ° C / s.
- the winding temperature is between 450 and 550 ° C.
- the temperature T m is between 800 and 900 ° C.
- the cooling rate V ref2 is greater than or equal to 30 ° C / s.
- the cooling rate V ref2 is maintained up to a temperature of between 500 ° C and 460 ° C.
- the cooled sheet is coated with zinc, a zinc alloy or a zinc-based alloy.
- the steel sheets according to the invention may be used for the manufacture of structural parts or skin parts for motorized land vehicles.
- the present invention relates to hot-rolled or cold-rolled steel sheets having a reduced density relative to conventional steels and less than or equal to 7.3, while retaining mechanical properties of shaping, of mechanical strength. , weldability and satisfactory coating.
- the invention also relates to a manufacturing method for hot or cold rolling the steel of the invention to obtain a hot or cold sheet having a microstructure comprising ferrite, austenite and up to to 5% of Kappa precipitates in surface fraction.
- the surface density of the Kappa precipitates can be up to 5% because above 5%, the ductility drops and the 20% breaking elongation of the invention is not reached.
- less than 2% Kappa precipitates are contemplated. It is specified that the microstructure being uniform, the surface fraction is equal to the volume fraction.
- the reheating temperature is between 1150 and 1280 ° C.
- composition of the steels shown in Table 1 consists of iron and unavoidable impurities resulting from processing.
- the sheets I1 and I2 are sheets whose chemical composition and the method of implementation are according to the invention.
- the two chemical compositions are different and have different Mn / Al ratios.
- the sheets referenced R1, R2 and R3 have chemical compositions which do not satisfy the conditions according to the invention respectively for the content of Mn, for the contents of C and Mn or for the Mn / Al ratio.
- R2a and R2b are two tests from the same grade R2 in Table 1.
- the hot rolling was carried out with at least one rolling pass in the presence of ferrite.
- Air cooling has a cooling rate of less than 55 ° C / sec.
- the two steel sheets I1 and I2 correspond to the sheets according to the invention.
- the microstructure of the sheet I1 is illustrated by the figure 1 . None of these sheets has crack after rolling.
- the mechanical strengths are greater than 600 MPa, their elongation at break is well above 20% and they are weldable and can be coated.
- the presence of ferrite and austenite was confirmed by a scanning electron microscope and the presence of Kappa precipitates was confirmed by the indexing of the diffraction pattern. obtained after observation with a transmission electron microscope (cf. figure 6 ).
- the sheet R1 has an Mn content of less than 6%, an Mn / Al ratio of less than 1 and a reheat temperature of greater than 1280 ° C.
- the letter "X" means that there has been no traction test.
- the sheets R2a and R2b come from the sheet R2 and have an Mn / Al ratio of less than 1 and a manganese content of less than 6%.
- R2a was coiled at a temperature above 600 ° C which led to a decomposition of the austenite into Kappa and ferrite as illustrated by the figure 4 . The lengthening does not reach the necessary 20%.
- the sheet R2b has undergone rolling conditions according to the invention but the chemical composition does not satisfy the conditions referred to, that is to say that the Mn / Al ratio is below 1, the elongation of 20% n is not reached.
- Sheet R3 has an Mn / Al ratio of less than 1.0; despite rolling conditions according to the invention and alloying elements in the ranges covered by the invention, cracks appeared during hot rolling.
- Example 2 Cold-rolled and annealed sheets
- composition of the steels in Table 4 consists of iron and unavoidable impurities resulting from processing.
- Table 4: Composition of steel (% weight) .I invention VS mn al Yes Ti V Nb Mn / Al Density measured by pycnometry I3 0.21 8.2 7.4 0.26 ⁇ 0.030 ⁇ 0.030 ⁇ 0.030 1.11 7.04 I4 0.21 8.6 6.1 0 ⁇ 0.030 ⁇ 0.030 ⁇ 0.030 1.41 7.17 I5 0.2 8.6 6.1 0.89 ⁇ 0.030 ⁇ 0.030 0.1 1.41 7.12 I6 0.19 8.7 7.2 0 ⁇ 0.030 ⁇ 0.030 ⁇ 0.030 1.21 not measured
- the density of I6 was estimated at 7.1 thanks to the curve of the figure 8 .
- the sheets I3a, I3b, I4, I5 and I6 are sheets whose chemical composition and the method of implementation are according to the invention.
- the cold-rolled steel sheets of Table 7 correspond to sheets according to the invention.
- the microstructure of the sheet I3a is illustrated by the figure 5 . None of these sheets has crack after rolling.
- the mechanical strengths are greater than 600 MPa, their elongation at break is greater than 20% and they are weldable and the I3a sheet was coated with Zn by a quenching process in a Zn bath at 460 ° C, called the galvanizing process by soaking.
- the sheet, both bare and coated, has good weldability.
- the steels according to the invention thus have good continuous galvanizing properties, in particular.
- the steels according to the invention have a good combination of properties of interest for structural or skin parts in the automobile (low density, good deformability, good mechanical properties, good weldability and good resistance to corrosion with coating).
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
- Parts Printed On Printed Circuit Boards (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/FR2012/000220 WO2013178887A1 (fr) | 2012-05-31 | 2012-05-31 | Acier laminé a chaud ou a froid a faible densite, son procede de mise en oeuvre et son utilisation |
PCT/IB2013/001057 WO2013179115A1 (fr) | 2012-05-31 | 2013-05-27 | Acier lamine a chaud ou a froid a faible densite, son procede de mise en oeuvre et son utilisation |
Publications (2)
Publication Number | Publication Date |
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EP2855725A1 EP2855725A1 (fr) | 2015-04-08 |
EP2855725B1 true EP2855725B1 (fr) | 2016-07-06 |
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Application Number | Title | Priority Date | Filing Date |
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EP13732225.1A Active EP2855725B1 (fr) | 2012-05-31 | 2013-05-27 | Acier lamine a chaud ou a froid a faible densite, son procede de mise en oeuvre et son utilisation |
Country Status (17)
Country | Link |
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US (1) | US10900105B2 (ru) |
EP (1) | EP2855725B1 (ru) |
JP (2) | JP6074031B2 (ru) |
KR (3) | KR20160129916A (ru) |
CN (1) | CN104350169B (ru) |
BR (1) | BR112014029177B1 (ru) |
CA (1) | CA2873578C (ru) |
ES (1) | ES2594328T3 (ru) |
HU (1) | HUE028856T2 (ru) |
IN (1) | IN2014DN09576A (ru) |
MA (1) | MA37508B1 (ru) |
MX (1) | MX359361B (ru) |
PL (1) | PL2855725T3 (ru) |
RU (1) | RU2614491C2 (ru) |
UA (1) | UA111285C2 (ru) |
WO (2) | WO2013178887A1 (ru) |
ZA (1) | ZA201408109B (ru) |
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CN104928568B (zh) * | 2015-06-30 | 2017-07-28 | 宝山钢铁股份有限公司 | 一种铁素体低密度高强钢及其制造方法 |
CN104928456B (zh) * | 2015-06-30 | 2017-08-25 | 宝山钢铁股份有限公司 | 一种提高普冷铁素体轻质钢延展性的制造方法 |
WO2017203315A1 (en) * | 2016-05-24 | 2017-11-30 | Arcelormittal | Cold rolled and annealed steel sheet, method of production thereof and use of such steel to produce vehicle parts |
CN106011653B (zh) * | 2016-07-05 | 2018-02-06 | 东北大学 | 高强度高韧性低密度钢及其制造方法 |
CN106756571A (zh) * | 2016-11-18 | 2017-05-31 | 扶绥县科学技术情报研究所 | 超细晶粒的高强度钢铁材料生产方法 |
CN106756570A (zh) * | 2016-11-18 | 2017-05-31 | 扶绥县科学技术情报研究所 | 超细晶粒的高韧性钢铁材料生产方法 |
CN106636915A (zh) * | 2016-11-18 | 2017-05-10 | 扶绥县科学技术情报研究所 | 改善钢铁材料力学性质的生产方法 |
CN106756569A (zh) * | 2016-11-18 | 2017-05-31 | 扶绥县科学技术情报研究所 | 提高钢铁材料强度的生产方法 |
CN106399841B (zh) * | 2016-11-18 | 2018-07-03 | 扶绥县科学技术情报研究所 | 超细晶粒的强耐蚀钢铁材料生产方法 |
CN106756478B (zh) * | 2016-12-07 | 2018-03-27 | 钢铁研究总院 | 一种经济型耐海水腐蚀用低密度低合金钢及其制备方法 |
EP3559297A1 (en) * | 2016-12-22 | 2019-10-30 | ArcelorMittal | Cold rolled and heat treated steel sheet, method of production thereof and use of such steel to produce vehicle parts |
WO2019122960A1 (en) | 2017-12-19 | 2019-06-27 | Arcelormittal | Cold rolled and heat treated steel sheet, method of production thereof and use of such steel to produce vehicle parts |
CN109694997B (zh) * | 2019-02-25 | 2021-08-06 | 上海大学 | 利用γ→α同素异构转变提升Fe-Mn-Al-C双相钢力学性能的热处理工艺 |
CN110592487B (zh) * | 2019-10-22 | 2021-12-10 | 成都先进金属材料产业技术研究院股份有限公司 | 700MPa级奥氏体铁素体双相低密度铸钢及其制备方法 |
KR102415068B1 (ko) * | 2020-09-07 | 2022-06-29 | 주식회사 포스코 | 고강도 저비중 강판 및 그 제조 방법 |
MX2024007034A (es) * | 2021-12-10 | 2024-06-19 | Arcelormittal | Acero laminado en caliente de baja densidad, metodo de produccion del mismo y uso de tal acero para producir piezas de vehiculos. |
CN115537660B (zh) * | 2022-09-30 | 2023-07-14 | 武汉钢铁有限公司 | 一种低密度高强度热轧弹簧扁钢及其生产方法 |
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SU768846A1 (ru) * | 1978-12-13 | 1980-10-07 | Институт Проблем Литья Ан Украинской Сср | Сплав на основе железа |
JPH03500305A (ja) * | 1988-07-08 | 1991-01-24 | ファムシー スティール コーポレイション | 2相高減衰能を有するFe‐Mn‐Al‐C基合金 |
JPH03140439A (ja) | 1989-10-27 | 1991-06-14 | Res Inst Electric Magnetic Alloys | 低い比重、高い硬度および高い減衰能を有する吸振合金 |
JP2849059B2 (ja) | 1995-09-28 | 1999-01-20 | 日鉱グールド・フォイル株式会社 | 印刷回路用銅箔の処理方法 |
FR2836930B1 (fr) * | 2002-03-11 | 2005-02-25 | Usinor | Acier lamine a chaud a tres haute resistance et de faible densite |
US6984456B2 (en) | 2002-05-13 | 2006-01-10 | Mitsui Mining & Smelting Co., Ltd. | Flexible printed wiring board for chip-on flexibles |
JP2004098659A (ja) | 2002-07-19 | 2004-04-02 | Ube Ind Ltd | 銅張積層板及びその製造方法 |
DE10259230B4 (de) | 2002-12-17 | 2005-04-14 | Thyssenkrupp Stahl Ag | Verfahren zum Herstellen eines Stahlprodukts |
JP4235077B2 (ja) | 2003-06-05 | 2009-03-04 | 新日本製鐵株式会社 | 自動車用高強度低比重鋼板とその製造方法 |
JP4084733B2 (ja) * | 2003-10-14 | 2008-04-30 | 新日本製鐵株式会社 | 延性に優れた高強度低比重鋼板およびその製造方法 |
JP2005120390A (ja) * | 2003-10-14 | 2005-05-12 | Jfe Steel Kk | 鋼帯製造ラインにおける鋼帯の乾燥方法 |
JP2005325388A (ja) * | 2004-05-13 | 2005-11-24 | Kiyohito Ishida | 低比重鉄合金 |
JP4324072B2 (ja) | 2004-10-21 | 2009-09-02 | 新日本製鐵株式会社 | 延性に優れた軽量高強度鋼とその製造方法 |
KR100711361B1 (ko) | 2005-08-23 | 2007-04-27 | 주식회사 포스코 | 가공성이 우수한 고망간형 고강도 열연강판 및 그 제조방법 |
JP4654440B2 (ja) * | 2005-09-22 | 2011-03-23 | 国立大学法人東北大学 | 低加工硬化型鉄合金 |
EP1995336A1 (fr) | 2007-05-16 | 2008-11-26 | ArcelorMittal France | Acier à faible densité présentant une bonne aptitude à l'emboutissage |
EP2090668A1 (en) * | 2008-01-30 | 2009-08-19 | Corus Staal BV | Method of producing a high strength steel and high strength steel produced thereby |
KR100985298B1 (ko) | 2008-05-27 | 2010-10-04 | 주식회사 포스코 | 리징 저항성이 우수한 저비중 고강도 열연 강판, 냉연강판, 아연도금 강판 및 이들의 제조방법 |
JP5403660B2 (ja) * | 2009-03-09 | 2014-01-29 | 本田技研工業株式会社 | 高強度鋼板およびその製造方法 |
-
2012
- 2012-05-31 WO PCT/FR2012/000220 patent/WO2013178887A1/fr active Application Filing
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2013
- 2013-05-27 UA UAA201414024A patent/UA111285C2/uk unknown
- 2013-05-27 MA MA37508A patent/MA37508B1/fr unknown
- 2013-05-27 EP EP13732225.1A patent/EP2855725B1/fr active Active
- 2013-05-27 IN IN9576DEN2014 patent/IN2014DN09576A/en unknown
- 2013-05-27 KR KR1020167030369A patent/KR20160129916A/ko not_active Application Discontinuation
- 2013-05-27 CA CA2873578A patent/CA2873578C/fr active Active
- 2013-05-27 HU HUE13732225A patent/HUE028856T2/en unknown
- 2013-05-27 RU RU2014153550A patent/RU2614491C2/ru active
- 2013-05-27 WO PCT/IB2013/001057 patent/WO2013179115A1/fr active Application Filing
- 2013-05-27 MX MX2014014613A patent/MX359361B/es active IP Right Grant
- 2013-05-27 KR KR1020177010838A patent/KR20170053727A/ko not_active Application Discontinuation
- 2013-05-27 KR KR1020147034966A patent/KR20150003918A/ko active Search and Examination
- 2013-05-27 CN CN201380027985.0A patent/CN104350169B/zh active Active
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- 2013-05-27 JP JP2015514609A patent/JP6074031B2/ja active Active
- 2013-05-27 US US14/404,750 patent/US10900105B2/en active Active
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Also Published As
Publication number | Publication date |
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ZA201408109B (en) | 2015-11-25 |
KR20170053727A (ko) | 2017-05-16 |
MX2014014613A (es) | 2015-08-10 |
CN104350169B (zh) | 2017-02-22 |
KR20160129916A (ko) | 2016-11-09 |
JP6074031B2 (ja) | 2017-02-01 |
US10900105B2 (en) | 2021-01-26 |
RU2614491C2 (ru) | 2017-03-28 |
MA37508B1 (fr) | 2016-03-31 |
JP2017106108A (ja) | 2017-06-15 |
CN104350169A (zh) | 2015-02-11 |
JP2015520298A (ja) | 2015-07-16 |
WO2013179115A8 (fr) | 2014-11-06 |
ES2594328T3 (es) | 2016-12-19 |
WO2013179115A1 (fr) | 2013-12-05 |
BR112014029177B1 (pt) | 2019-03-26 |
MX359361B (es) | 2018-09-26 |
RU2014153550A (ru) | 2016-07-20 |
IN2014DN09576A (ru) | 2015-07-17 |
BR112014029177A2 (pt) | 2017-06-27 |
JP6242990B2 (ja) | 2017-12-06 |
KR20150003918A (ko) | 2015-01-09 |
US20150147221A1 (en) | 2015-05-28 |
UA111285C2 (uk) | 2016-04-11 |
MA20150361A1 (fr) | 2015-10-30 |
WO2013178887A1 (fr) | 2013-12-05 |
PL2855725T3 (pl) | 2016-12-30 |
HUE028856T2 (en) | 2017-01-30 |
EP2855725A1 (fr) | 2015-04-08 |
CA2873578C (fr) | 2017-10-10 |
CA2873578A1 (fr) | 2013-12-05 |
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