EP2704980A1 - Verfahren zum befüllen eines behältnisses mit einer flüssigkeit - Google Patents
Verfahren zum befüllen eines behältnisses mit einer flüssigkeitInfo
- Publication number
- EP2704980A1 EP2704980A1 EP12715577.8A EP12715577A EP2704980A1 EP 2704980 A1 EP2704980 A1 EP 2704980A1 EP 12715577 A EP12715577 A EP 12715577A EP 2704980 A1 EP2704980 A1 EP 2704980A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- balloon
- container
- liquid
- expansion medium
- filling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000005283 ground state Effects 0.000 claims 1
- 239000003570 air Substances 0.000 description 29
- 238000005429 filling process Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000003780 insertion Methods 0.000 description 3
- 230000037431 insertion Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 2
- 239000012080 ambient air Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/06—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus using counterpressure, i.e. filling while the container is under pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/06—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus using counterpressure, i.e. filling while the container is under pressure
- B67C3/10—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus using counterpressure, i.e. filling while the container is under pressure preliminary filling with inert gases, e.g. carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C3/26—Filling-heads; Means for engaging filling-heads with bottle necks
- B67C3/2614—Filling-heads; Means for engaging filling-heads with bottle necks specially adapted for counter-pressure filling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C9/00—Devices for emptying bottles, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
- B65B31/04—Evacuating, pressurising or gasifying filled containers or wrappers by means of nozzles through which air or other gas, e.g. an inert gas, is withdrawn or supplied
- B65B31/046—Evacuating, pressurising or gasifying filled containers or wrappers by means of nozzles through which air or other gas, e.g. an inert gas, is withdrawn or supplied the nozzles co-operating, or being combined, with a device for opening or closing the container or wrapper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
- B65B31/04—Evacuating, pressurising or gasifying filled containers or wrappers by means of nozzles through which air or other gas, e.g. an inert gas, is withdrawn or supplied
- B65B31/06—Evacuating, pressurising or gasifying filled containers or wrappers by means of nozzles through which air or other gas, e.g. an inert gas, is withdrawn or supplied the nozzle being arranged for insertion into, and withdrawal from, the mouth of a filled container and operating in conjunction with means for sealing the container mouth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C3/26—Filling-heads; Means for engaging filling-heads with bottle necks
- B67C2003/2688—Means for filling containers in defined atmospheric conditions
Definitions
- the invention relates to a method for filling a container with a particular intended for consumption liquid.
- this liquid is supplied to the container, for example by means of a feed probe.
- a feed probe For filling a container, in particular bottle, with a liquid intended for consumption, in particular beverage, this liquid is supplied to the container, for example by means of a feed probe.
- the problem with this is that the liquid is exposed to the ambient air with the result of unwanted gas release, gas exchange or gas entry.
- the invention is therefore based on the invention to develop a method for filling a container with a particular intended for consumption liquid, without the liquid comes into contact with the gas in the bottle.
- an effective method for gas contactless filling of a container with a particular intended for consumption liquid is created.
- the method is characterized in that the liquid does not come into contact with a gas during the filling process, for example air or another gas.
- a gas during the filling process for example air or another gas.
- the advantage of this method is thus that the liquid during filling of the container is not subject to any gas release, gas exchange or gas entry.
- the implementation of the method provides that in the container initially at least one balloon-like body is introduced. This can be arbitrarily shaped in the initial state. By this balloon-like body is filled after insertion into the container by means of a medium, thereby the interior of the container is completely filled.
- the expansion medium can be supplied with overpressure to the balloon-like body, so that it inflates in this way.
- a negative pressure can be applied to the space between the balloon-like body and the inner wall of the container, so that due to the resulting pressure difference of the balloon-like body sucks the expansion medium and thereby inflates.
- After filling the balloon-like body with the expansion medium escapes the expansion medium again from this balloon-like body.
- the expansion medium can be additionally sucked off to improve the effect. It forms in the container, a space between the balloon-like body and the inner wall of the container to which the liquid is supplied, so that the container fills with this liquid.
- the expansion of the expansion medium builds up a negative pressure which sucks in the liquid to be filled.
- a further support is given by the fact that the liquid has an overpressure with respect to the expansion medium and is therefore supplied to the container with overpressure.
- a back pressure can be maintained by throttling the re-flowing expansion medium, which suppresses the unbinding, for example, the C0 2 during the inflow of the liquid into the container. Since the balloon-like body is liquid-tight and gas-tight, the expansion medium contained in this balloon-like body does not come into contact with the liquid. After the container has been completely filled, the balloon-like body is removed again from the container and made available for the next filling process.
- the balloon-like body is expandable. This means that this balloon-like body expands during filling of the medium in the manner of a balloon and - vice versa - returns to its original shape when escaping or when pumping the medium. For example, when the expandable balloon-like body is filled with air and then the air supply of the then full balloon-like body is reopened to fill the container with the liquid, the air from the balloon-like body escapes automatically, as if the air is released from a balloon. Because the balloon-like body contracts due to its flexibility and pushes out the air therein.
- the balloon-like body has the advantage that it occupies only a very small volume when inserted into the container, so that the insertion process can be performed easily.
- the balloon-like body is not expandable.
- a preferred embodiment according to claim 4 suggests that the balloon-like body inflate targeted and above all can be emptied again, in such a way that all liquid to be introduced into the container can be easily fed to the container.
- this can be implemented such that the balloon-like body accordingly is profiled, ie that when emptying with the expansion medium, the profile first emptied in the region of the container opening, and then to move gradually towards the container bottom.
- a plurality of balloon-like body are provided, for example a first balloon-like body in the bottom region of the container, a second balloon-like body in the central region of the container and finally a third balloon-like body in the container opening region. These are inflated one after the other and - especially - emptied during the filling process with the liquid.
- the at least one balloon-like body is associated with an elongated carrier, with the aid of which the balloon-like body is inserted into the container.
- This elongated carrier is to be understood in the most general sense. Basically, this carrier is an elongated, narrow structure, which can be easily introduced together with the balloon-like body through the opening of the container into this container. Conversely, the assembly of elongate carrier and balloon-like body can easily pull out of the container again, when the filling process is completed with the liquid.
- the previously blessed cap according to the embodiment in claim 7 an opening through which the liquid is supplied.
- the development according to claim 8 proposes a first embodiment of the carrier in the form of a tube.
- the basic idea is that the balloon-like body or bodies is / are arranged on a tube, wherein the balloon-like body surrounds this tube. Then, when an expansion medium is supplied to the balloon-like body through the tube, the balloon-like body inflates around the tube.
- the tube is provided according to the number of balloon-like body with corresponding openings for the exit of the expansion medium.
- the use of a tube has the advantage that it can be easily inserted into the container together with the balloon-like body.
- the development according to claim 9 proposes a second embodiment of the carrier in the form of one or more rods, against which the balloon-like body.
- the two embodiments tube / rod are combined.
- the staff is to be understood in the most general sense. It is an elongated structure.
- this rod is not inside the balloon-like body, but the rod and the balloon-like body are adjacent.
- the advantage of this rod is, on the one hand, that the balloon-like body can be easily introduced into the container, since the rod and the balloon-like body, so to speak, form a structural unit.
- the rod has the advantage that it comes to rest during the gradual expansion of the balloon-like body between the outer shell of this balloon-like body and the inner wall of the container. This automatically creates a small gap between the outer shell of the balloon-like body and the inner wall of the container, through which air can escape to the container opening.
- the advantage is therefore that even after the complete inflation of the balloon-like body no air bubbles can form in the container. The air of these air bubbles can easily escape through the container opening through the above-described gap.
- the development according to claim 10 proposes various embodiments of the rod.
- it can be bendable, so that it automatically adapts to the respective contours.
- the rod can also be relatively rigid. In this case, it is shaped so that it is adapted to the inner contour of the container.
- a plastic cord or the like serve.
- the advantage is that in the initial position of the balloon-like body assumes a stretched starting position by the fixation at the front end of the rod and thereby can be easily inserted through the container opening into the container.
- Another advantage is that a possibly remaining air bubble must escape in the bottom region of the container towards the carrier.
- the outer surface of the balloon-like body has elevations, in particular knob-shaped elevations. Between these elevations, a gap may form to escape the air. Because this can - as already described in connection with the rod - automatically adjust a gap between the outer shell of the balloon-like body and the inner wall of the container through which air can escape to the container opening.
- the advantage therefore, again lies in the fact that even after the complete inflation of the balloon-like body no air bubbles can form in the container. The air of these bubbles can easily escape through the container opening through the above-described gap.
- the knob-shaped elevations may be formed, for example, diamond-shaped.
- a gas in particular air, or a liquid, in particular water, can be used as the medium for filling the balloon-like body or bodies.
- FIG. 1a to 1g a first embodiment, wherein various process sections are shown;
- Fig. 2 shows a second embodiment of the device
- Fig. 1a of the first embodiment of the filling device shows a container 1 in the form of a bottle with a container opening 2.
- the filling device initially consists of a tube 3, which is held in a cap 4.
- This tube 3 is open on the underside. In addition, it has a feed opening for a medium at the upper end.
- the cap 4 finally still has a lateral opening 5.
- a flexible body 6 is pushed and fastened with its upper peripheral edge close to the cap 4. This body 6 can be inflated into a kind of balloon.
- Fig. 1b shows the situation when the filling device completely is introduced while the cap 4 is located at a distance above the container opening 2, so does not close tight.
- FIG. 1c shows how the pipe 3, an expansion medium 8, in particular air (but also alternatively a hydraulic expansion medium), is supplied.
- This expansion medium 8 exits the lower opening of the tube 3 and thereby gradually inflates the body 6 into a balloon-like body 6.
- the air in the container 1 escapes through the annular intermediate gap between the container opening 2 and the cap 4.
- FIG. 1d It shows how the balloon-shaped body 6 completely rests against the inner wall of the container 1. Also, the cap 4 was now placed tightly on the container 1.
- the expansion medium 8 can be supplied to the balloon-like body 6 with overpressure, so that this inflates in this way.
- a negative pressure can be applied to the space between the balloon-like body 6 and the inner wall of the container 1, so that due to the resulting pressure difference of the balloon-like body 6 sucks the expansion medium 8 and thereby inflates.
- the filling device is pulled out of the container 1 again (FIG. 1f).
- the balloon-like body 6 inflates profiled during filling of the expansion medium 8 in such a way that first the bottom area of the container 1 is filled in, then the middle container area and finally the neck area of the container 1. The emptying of the balloon-like body 6 for the filling then takes place in the reverse order.
- FIGS. 3a to 3d show a further modified embodiment of the filling device.
- a total of three superposed balloon-shaped body 6 are provided, which are arranged on the tube 3 enveloping this.
- Each of these three balloon-shaped body 6 is associated with an outlet opening from the tube 3.
- the lowermost balloon-shaped body 6 is inflated (FIG. 3b), then the middle balloon-shaped body 6 (FIG. 3c) and finally the uppermost balloon-shaped body 6 (FIG. 3d).
- the emptying of the balloon-like body 6 for the filling then takes place in the reverse order.
- Fig. 4a to 4d shows a further modified embodiment of the filling device.
- the basic principle here is that instead of a tube 3 on the cap 4, a rod 9 is arranged.
- This rod 9 is in particular made of plastic and is designed as an elongated, flexible structure.
- the rod 9 does not protrude into the balloon-like body 6, but rather the balloon-like body 6 and the rod 9 are located side by side.
- the front end of the balloon-like body 6 is connected to the front end of the rod 9 via a cord 10 or the like.
- the basic principle of filling corresponds to that basic principle, as has already been described above.
- the rod 9 is introduced with its balloon-like body 6 in the container opening 2 of the container 1 (Fig. 4a and 4b).
- the balloon-like body 6 is filled with air, so that by the associated displacement effect via an outlet valve, the air in the container 1 is forced out and thus exits (Fig. 4c and 4d).
- a vacuum can also be applied here in the container 1, so that due to the pressure difference of the balloon-like body 6 fills with air. Subsequently, the air is discharged from the balloon-like body 6 again.
- this balloon-like body 6 is a kind of balloon, it automatically contracts when the air is exhausted, thereby pushing out the air contained in the balloon-like body 6 (FIG. 4e). At the same time, the liquid 7 is sucked into the container 1 or the liquid 7 is supplied with pressure. Finally, then the filling can be pulled out of the container 1 and used for a subsequent filling (Fig. 4f).
- the advantage of using the above-described rod 9 is that it comes to rest during filling of the balloon-like body 6 with air between the outer surface of this balloon-like body 6 and the inner surface of the container 1 such that forms a gap along the rod 9. This creates a possibility that all air can escape from the container 1, if any air bubbles should form, if the balloon-like body 6 should inflate correspondingly unfavorable. This can be seen in the sectional view to Fig. 4d. In this case, the gap reduces automatically with increasing expansion of the balloon-like body 6. The air gap virtually ensures itself to minimize or eliminate.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Basic Packing Technique (AREA)
- Toys (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011100560A DE102011100560B3 (de) | 2011-05-05 | 2011-05-05 | Vorrichtung zum Befüllen eines Behältnisses mit einer zum Verzehr bestimmten Flüssigkeit |
PCT/DE2012/000309 WO2012149917A1 (de) | 2011-05-05 | 2012-03-22 | Verfahren zum befüllen eines behältnisses mit einer flüssigkeit |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2704980A1 true EP2704980A1 (de) | 2014-03-12 |
EP2704980B1 EP2704980B1 (de) | 2016-02-03 |
Family
ID=45756393
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12715577.8A Active EP2704980B1 (de) | 2011-05-05 | 2012-03-22 | Verfahren zum befüllen eines behältnisses mit einer flüssigkeit |
Country Status (8)
Country | Link |
---|---|
US (2) | US20140047797A1 (de) |
EP (1) | EP2704980B1 (de) |
JP (1) | JP5893130B2 (de) |
CN (1) | CN103502136B (de) |
AU (1) | AU2012250379C1 (de) |
DE (1) | DE102011100560B3 (de) |
ES (1) | ES2569667T3 (de) |
WO (1) | WO2012149917A1 (de) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012010903A1 (de) * | 2012-06-01 | 2013-12-05 | Leibinger Gmbh | Verfahren und Vorrichtung zum Befüllen eines Behältnisses mit einer zum Verzehr bestimmten Flüssigkeit |
DE102012021775B4 (de) * | 2012-11-06 | 2014-08-21 | Leibinger Gmbh | Vorrichtung zum Befüllen oder zum Entleeren eines Behältnisses |
WO2014198413A1 (de) * | 2013-06-11 | 2014-12-18 | Leibinger Gmbh | Ventilaufsatz zum befüllen und entleeren von behältnissen |
CN103523251B (zh) * | 2013-10-25 | 2015-04-15 | 浙江钱锦气雾剂制品有限公司 | 一种环保的自动灌装设备 |
DE102013022261B4 (de) | 2013-12-06 | 2018-09-27 | Leibinger Gmbh | Vorrichtung zum Befüllen eines Behältnisses |
DE102014010676A1 (de) | 2014-07-22 | 2016-01-28 | Leibinger Gmbh | Ventilaufsatz, Befüll- und Entleervorrichtung sowie Befüllverfahren für Behältnisse |
DE102014014317B4 (de) | 2014-10-01 | 2018-06-07 | Leibinger Gmbh | Vorrichtung und Verfahren zum messmittellosen Befüllen eines Behältnisses |
DE102015204627A1 (de) | 2015-03-13 | 2016-09-15 | Raumedic Ag | Aufblasbarer Ballonkörper |
ES2786560T3 (es) | 2017-01-05 | 2020-10-13 | Leibinger Gmbh | Disposición de llenado y procedimiento para el llenado de contenedores cilíndricos |
KR102164809B1 (ko) * | 2018-05-17 | 2020-10-14 | (주)이너보틀 | 용기 제조 방법 및 용기 제조 장치 |
CN114007756B (zh) * | 2019-06-14 | 2023-08-22 | 株式会社大造 | 排出装置 |
EP4098569A1 (de) * | 2021-06-02 | 2022-12-07 | Aptar Radolfzell GmbH | Abfüllverfahren und befüllungsanlage zu dessen durchführung |
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2011
- 2011-05-05 DE DE102011100560A patent/DE102011100560B3/de active Active
-
2012
- 2012-03-22 WO PCT/DE2012/000309 patent/WO2012149917A1/de active Application Filing
- 2012-03-22 ES ES12715577.8T patent/ES2569667T3/es active Active
- 2012-03-22 CN CN201280021850.9A patent/CN103502136B/zh not_active Expired - Fee Related
- 2012-03-22 AU AU2012250379A patent/AU2012250379C1/en not_active Ceased
- 2012-03-22 US US14/113,427 patent/US20140047797A1/en not_active Abandoned
- 2012-03-22 EP EP12715577.8A patent/EP2704980B1/de active Active
- 2012-03-22 JP JP2014508680A patent/JP5893130B2/ja not_active Expired - Fee Related
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2017
- 2017-03-03 US US15/448,617 patent/US10427927B2/en active Active
Non-Patent Citations (1)
Title |
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See references of WO2012149917A1 * |
Also Published As
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ES2569667T3 (es) | 2016-05-12 |
US20170174492A1 (en) | 2017-06-22 |
AU2012250379B2 (en) | 2015-07-23 |
CN103502136A (zh) | 2014-01-08 |
DE102011100560B3 (de) | 2012-03-15 |
JP2014514221A (ja) | 2014-06-19 |
CN103502136B (zh) | 2015-12-09 |
AU2012250379A1 (en) | 2014-01-09 |
US20140047797A1 (en) | 2014-02-20 |
AU2012250379C1 (en) | 2015-11-19 |
WO2012149917A1 (de) | 2012-11-08 |
US10427927B2 (en) | 2019-10-01 |
JP5893130B2 (ja) | 2016-03-23 |
EP2704980B1 (de) | 2016-02-03 |
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