EP2670879A1 - Hot metal sheet forming or stamping tools with cr-si-n coatings - Google Patents

Hot metal sheet forming or stamping tools with cr-si-n coatings

Info

Publication number
EP2670879A1
EP2670879A1 EP12703689.5A EP12703689A EP2670879A1 EP 2670879 A1 EP2670879 A1 EP 2670879A1 EP 12703689 A EP12703689 A EP 12703689A EP 2670879 A1 EP2670879 A1 EP 2670879A1
Authority
EP
European Patent Office
Prior art keywords
hot
metal sheet
coatings
crsin
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12703689.5A
Other languages
German (de)
English (en)
French (fr)
Inventor
Arnd MÜLLER
Mathias Lukas SOBIECH
Christian MARINGER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oerlikon Surface Solutions AG Pfaeffikon
Original Assignee
Oerlikon Trading AG Truebbach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oerlikon Trading AG Truebbach filed Critical Oerlikon Trading AG Truebbach
Publication of EP2670879A1 publication Critical patent/EP2670879A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00—Tools as parts of machines covered by this subclass
    • B21D37/01—Selection of materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02—Stamping using rigid devices or tools
    • B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D26/00—Shaping without cutting otherwise than using rigid devices or tools or yieldable or resilient pads, i.e. applying fluid pressure or magnetic forces
    • B21D26/02—Shaping without cutting otherwise than using rigid devices or tools or yieldable or resilient pads, i.e. applying fluid pressure or magnetic forces by applying fluid pressure
    • B21D26/021—Deforming sheet bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D35/00—Combined processes according to or processes combined with methods covered by groups B21D1/00 - B21D31/00
    • B21D35/002—Processes combined with methods covered by groups B21D1/00 - B21D31/00
    • B21D35/005—Processes combined with methods covered by groups B21D1/00 - B21D31/00 characterized by the material of the blank or the workpiece
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00—Tools as parts of machines covered by this subclass
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641—Nitrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02—Stamping using rigid devices or tools
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon

Definitions

  • the present invention relates to the use of a Cr-Si-N coating system that enables life time and performance improvement of hot forming tools. A very good control of the friction level during this kind of operations is also attained thereby.
  • high-strength steel sheets are used more and more for manufacturing automobile components in order to reduce the weight of automobiles and thus to reduce environmental problems and to improve collision safety at the same time.
  • Many car components and structural members can be made significantly lighter by reducing the thickness of the high-strength steel sheets used for their manufacture.
  • a hot metal sheet forming method called die quenching, hot forming, hot stamping or hot pressing is employed for fabricating automobile structural members having a strength of around 1 ,500 MPa. By this method, the strength of a steel sheet is increased through quenching after heating it to a temperature in the austenite temperature range, say, around 900 °C.
  • Heated steel sheet is extracted from a heating furnace, transferred to a pressing machine, formed into a prescribed shape using hot metal sheet forming tools maintained at room temperature, and thus quenched. At the forming work, the press machine is retained at the lower dead point until the entire steel sheet is quenched sufficiently ( Senuma, T.: ISIJ Int. 41 , 520 (2001)).
  • the press machine is retained at the lower dead point until the entire steel sheet is quenched sufficiently.
  • various types of high-strength steel sheet products have been developed. For example, high-strength steel sheet with controlled microstructures or with Zn- or Al-Zn- or AlSi-coatings have been developed. In spite of these efforts, however, press forming complicated shapes is difficult when the strength of a steel sheet is as high as approximately 1 ,500 MPa ( Senuma, T.: ISIJ Int. 41 , 520 (2001)).
  • the required lubrication may deteriorate the workshop environment and unhealthy degreasing agents are needed to remove the lubricant from the formed parts.
  • the coating should provide enough abrasive wear resistance, enough adhesive wear resistance and enough temperature stability. Principally, the coating should improve the protection against galling observed in AlSi-coated steel sheets after hot metal sheet forming operations in comparison to the coating that are currently used.
  • hot forming tools are coated with CrSiN coatings.
  • the inventors observed that CrSiN coatings improve considerably service lifetime and performance of hot metal sheet forming tools used by hot sheet metal forming processes.
  • CrSiN coatings are up to now known to be used as protection coating for dry machining tools (JP2005186184), where the operational demands and stress collective are completely different as the corresponding for hot metal sheet forming tools, where one of the big problems is for example the galling phenomenon that occurs when AlSi-coated steel sheets are used as workpiece as was mentioned before.
  • the CrSiN coatings applied according to the invention exhibited very good abrasive wear, excellent temperature stability and an outstanding good reduction of AlSi- adhesion on the surface of the hot metal sheet forming tools and thus a very good solution to the galling problem that is normally observed in the surface of components manufactured from AlSi-coated steel sheets by means of hot metal sheet forming operations.
  • a coating thickness of between 4pm and 8pm of CrSiN is applied onto the substrate
  • the Cr-Si-N coatings were deposited according to the invention on hot metal sheet forming tools by means of physical vapour deposition (PVD) methods, particularly by means of reactive arc ion plating. Alloyed Cr:Si targets with different Cr and Si contents were used as material source for the deposition of the CrSiN coatings. The targets were activated in a nitrogen atmosphere producing the CrSiN coatings on the tool surface.
  • the hot metal sheet forming tools or stamping tools made of nitride steels and non-nitrided steels as well as the further test samples of different metal sorts were heated, etched and coated in the vacuum chamber of the coating machine by means of arc ion plating PVD process. During deposition the substrates were continuous rotated. In the coating step nitrogen was introduced in the vacuum chamber maintaining a pressure of -2x10 "2 mbar, six alloyed Cr:Si target with composition 95:5 at% were activated and a DC bias voltage of 40 V was applied.
  • the CrSiN-coated hot stamping tools were tested by hot sheet metal forming of Usibor 1500 P® (Arcelor), which consists in fine-grain boron steel with Al-Si-based coating that is ca. 30 pm thick.
  • the element composition of the CrSiN coatings deposited on hot forming tools according to the invention exhibited the following composition in atomic percentage taking into account as well the metallic elements as the non-metallic elements contained in the coating:
  • deposited CrSiN coatings were investigated by X- ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) examinations. The formation of a crystalline structure was confirmed for all deposited coatings. All deposited coatings showed the preferred face centred cubic lattice. In the XRD patterns of the deposited CrSiN coatings peaks corresponding to preferential orientations of (111) and (200) lattice planes were observed. It was also observed that the peaks shifted by varying of Si-concentration in coating due to modifications of the chemical composition, the grain size and the residual stress.
  • XRD X- ray diffraction
  • SEM scanning electron microscopy
  • TEM transmission electron microscopy
  • Coatings according to a preferred embodiment according to the present invention show peaks corresponding to preferential orientations of (111) and (222) lattice planes which are shifted as compared to the peaks of corresponding planes of pure CrN coatings.
  • the degree of such shift gives an indication of the amount of the Si incorporated into the coating.
  • the values of Si content in the CrSiN coatings for the following preferred embodiments of the invention are to be considered as calculated taking only the metallic elements in the coating into account. That means taking only Cr and Si into account.
  • a preferred embodiment according to the invention is obtained using CrSiN coatings having Si content in the coating of > 0 up to 15 at%.
  • a further preferred embodiment according to the invention is obtained using CrSiN coatings having Si content in the coating of 2 - 10 at%.
  • a most preferred embodiment according to the invention is obtained using CrSiN coatings having Si content in the coating of 3 - 8 at%.
  • a CrSiN coating is used as coating for a hot forming tool.
  • the present invention discloses a tool for hot metal sheet forming having a CrSiN hard coating. Said CrSiN hard coating specially having a Si content in a film in range of >0 up to 15 at%, preferably 2 - 10 at%, more preferably 3 - 8 at% taking into account only the metallic elements for calculating the mentioned Si content in atomic percentage.
  • a further preferred embodiment according to the present invention is obtained using hot thermal conductivity steel (HTCS) or nitrided steel or carbonitrided steel as tool substrate or any other previous surface treated steel tool as tool substrate.
  • HTCS hot thermal conductivity steel
  • nitrided steel or carbonitrided steel as tool substrate or any other previous surface treated steel tool as tool substrate.
  • the present invention discloses a tool for hot metal sheet forming coated with CrSiN according to the invention, wherein said CrSiN hard coating is formed by an arc ion plating method.
  • the present invention discloses a hot sheet metal forming process where a tool coated according to the invention is used in order to improve the service life time of the hot forming tool and overall performance and thereby also to improve the quality of the by means of this process manufactured metal sheet.
  • the present invention considers specially a hot sheet metal forming process where a tool coated according to the invention is used to form AISi coated metal sheets and/or to form metal sheets, whose material possesses strength of around 1 ,500 MPa or more.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Physical Vapour Deposition (AREA)
  • Mounting, Exchange, And Manufacturing Of Dies (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Coating With Molten Metal (AREA)
EP12703689.5A 2011-02-04 2012-01-28 Hot metal sheet forming or stamping tools with cr-si-n coatings Withdrawn EP2670879A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011010401A DE102011010401A1 (de) 2011-02-04 2011-02-04 Mit Cr-Si-N Schichten versehene Werkzeuge zum Formen oder Stanzen von heissen Metallplatten
PCT/EP2012/000387 WO2012104048A1 (en) 2011-02-04 2012-01-28 Hot metal sheet forming or stamping tools with cr-si-n coatings

Publications (1)

Publication Number Publication Date
EP2670879A1 true EP2670879A1 (en) 2013-12-11

Family

ID=45592309

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12703689.5A Withdrawn EP2670879A1 (en) 2011-02-04 2012-01-28 Hot metal sheet forming or stamping tools with cr-si-n coatings

Country Status (13)

Country Link
US (1) US20140144200A1 (es)
EP (1) EP2670879A1 (es)
JP (1) JP2014509262A (es)
KR (1) KR20140002728A (es)
CN (1) CN103370438B (es)
AR (1) AR085117A1 (es)
BR (1) BR112013019516A2 (es)
CA (1) CA2825237A1 (es)
DE (1) DE102011010401A1 (es)
MX (1) MX2013008949A (es)
RU (1) RU2604158C2 (es)
SG (2) SG10201600789WA (es)
WO (1) WO2012104048A1 (es)

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US10550477B2 (en) 2012-10-22 2020-02-04 Ihi Ionbond Ag. Fatigue-resistant coating for metal forming members
CN105431563B (zh) * 2013-07-19 2019-06-11 欧瑞康表面处理解决方案股份公司普费菲孔 用于成型工具的涂层
EP2876184B1 (en) 2013-11-26 2018-02-14 Oerlikon Surface Solutions AG, Pfäffikon Use of a coated hot forming tool with a hard coating comprising a-C:H:W hard layer system for enhancing performance
CN103789725B (zh) * 2014-01-29 2016-08-31 仪征亚新科双环活塞环有限公司 一种活塞环表面的多层多元复合硬质pvd镀层、活塞环及制备工艺
US10240229B2 (en) 2014-05-26 2019-03-26 Oerlikon Surface Solutions Ag, Pfäffikon Mo—Si—B layers and method for the production thereof
WO2017057453A1 (ja) * 2015-09-29 2017-04-06 日立金属株式会社 熱間鍛造用金型及びそれを用いた鍛造製品の製造方法並びに熱間鍛造用金型の製造方法
CN107177824B (zh) * 2017-05-16 2020-01-03 福建新越金属材料科技有限公司 基于磁控共同溅射技术在不锈钢基材上制备的装饰性涂层
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KR102434141B1 (ko) * 2021-08-18 2022-08-19 덕성금속공업(주) 오일팬 제조장치
CN116180011A (zh) * 2022-12-26 2023-05-30 兰州空间技术物理研究所 一种轻质合金构件表面纳米多层耐蚀涂层及制备方法

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Also Published As

Publication number Publication date
CN103370438A (zh) 2013-10-23
CN103370438B (zh) 2015-11-25
KR20140002728A (ko) 2014-01-08
RU2604158C2 (ru) 2016-12-10
DE102011010401A1 (de) 2012-08-23
MX2013008949A (es) 2013-09-06
JP2014509262A (ja) 2014-04-17
AR085117A1 (es) 2013-09-11
SG191981A1 (en) 2013-08-30
US20140144200A1 (en) 2014-05-29
WO2012104048A1 (en) 2012-08-09
SG10201600789WA (en) 2016-03-30
BR112013019516A2 (pt) 2019-09-24
RU2013140668A (ru) 2015-03-10
CA2825237A1 (en) 2012-08-09

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