EP2652176B1 - Électrolyseur doté d'un tuyau d'entrée en forme de spirale - Google Patents
Électrolyseur doté d'un tuyau d'entrée en forme de spirale Download PDFInfo
- Publication number
- EP2652176B1 EP2652176B1 EP20110788370 EP11788370A EP2652176B1 EP 2652176 B1 EP2652176 B1 EP 2652176B1 EP 20110788370 EP20110788370 EP 20110788370 EP 11788370 A EP11788370 A EP 11788370A EP 2652176 B1 EP2652176 B1 EP 2652176B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrolyte
- spiral
- mbar
- electrolysis
- electrolyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003792 electrolyte Substances 0.000 claims description 70
- 238000005868 electrolysis reaction Methods 0.000 claims description 33
- 238000009792 diffusion process Methods 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 7
- 239000003014 ion exchange membrane Substances 0.000 claims description 6
- 150000004820 halides Chemical class 0.000 claims description 4
- 230000010287 polarization Effects 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 15
- 239000007789 gas Substances 0.000 description 15
- 239000012267 brine Substances 0.000 description 9
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 238000004364 calculation method Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011552 falling film Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000002706 hydrostatic effect Effects 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000009827 uniform distribution Methods 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000006829 Ficus sundaica Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- -1 hydroxide ions Chemical class 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/06—Detection or inhibition of short circuits in the cell
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
Definitions
- Electrolysis converts electrical energy into chemical energy. This is achieved by the decomposition of a chemical compound under the action of an electric current.
- the solution used as electrolyte contains positively and negatively charged ions. Accordingly, the main electrolytes used are acids, bases or salts.
- the pressure of the electrolyte in the channel-shaped electrolyte inlet increases above the gap.
- the pressure in the electrolyte inlet can be adjusted. As the pressure increases, more electrolyte can therefore be passed through the gap and the flow velocity in the gap can be selectively varied.
- the pressure in the electrolyte inlet can be adjusted in a targeted manner.
- an electrolyzer 1 is considered below as an example, as in FIG Fig. 1 A , which consists of 160 individual electrolysis elements, which are arranged in two electrolyzer stacks 2 and 3.
- a polarization current of 27 A is fed on the anode side, so that a total voltage of theoretically about 250 V is obtained without stray current losses.
- An electrical model which takes into account the different ohmic resistances of the elemental components and the electrolytes as well as the corresponding electrochemical equations, can be used to calculate the current intensity per element.
- the results are in Fig. 1 B reproduced, which maps the current in the element relative to the element number, ie the position in the electrolyzer.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Claims (7)
- Electrolyseur comprenant au moins un élément électrolyseur individuel dont chacun comporte une demi-cellule anodique avec une anode, une demi-cellule cathodique avec une cathode et une membrane d'échange d'ions disposée entre la demi-cellule anodique et la demi-cellule cathodique, l'anode et/ou la cathode étant une électrode à diffusion de gaz, une fente étant prévue entre l'électrode à diffusion de gaz et la membrane d'échange d'ions, une arrivée d'électrolyte étant prévue au-dessus de la fente et un départ d'électrolyte ainsi qu'une entrée de gaz et une sortie de gaz étant prévus en-dessous de la fente, le départ d'électrolyte débouchant dans un canal collecteur de départ, et l'arrivée d'électrolyte étant reliée à un récipient de stockage d'électrolyte et pourvue d'un trop-plein, le trop-plein étant relié au canal collecteur de départ,
caractérisé en ce qu'un tuyau spiralé est prévu pour la liaison entre le récipient de stockage et l'arrivée d'électrolyte et en ce qu'un tuyau spiralé est prévu pour la liaison entre le trop-plein et le canal collecteur de départ. - Procédé selon la revendication 1, caractérisé en ce que des tuyaux spiralés d'une longueur de 1,5 m à 3,5 m, de préférence de 1,75 m à 3 m, et particulièrement préféré de 2,25 m à 2,75 m sont prévus.
- Procédé selon la revendication 1 ou 2, caractérisé en ce que des tuyaux spiralés ayant un diamètre intérieur de 5 mm à 15 mm, de préférence de 7,5 mm à 12,5 mm, et particulièrement préféré de 9 mm à 11 mm sont prévus.
- Procédé selon l'une des revendications 1 à 3, caractérisé en ce que le trop-plein est pourvu d'une ouverture continue qui présente un diamètre de 2 mm à 4 mm, et de préférence de 2,5 mm à 3,5 mm.
- Procédé selon l'une des revendications 1 à 4, caractérisé en ce que 50 à 200 éléments électrolyseur individuels, de préférence 70 à 180 éléments électrolyseur individuels, et particulièrement préféré 100 à 160 éléments électrolyseur individuels sont prévus.
- Electrolyse d'une solution aqueuse d'halogénure d'alkali par utilisation d'un électrolyseur selon la revendication 1, caractérisé en ce que la chute de pression au trop-plein pourvu du tuyau spiralé est d'un montant jusqu'à 200 mbar, de préférence de 100 à 200 mbar.
- Electrolyse selon la revendication 6, caractérisé en ce que en ce que la chute de pression à l'arrivée d'électrolyte pourvue du tuyau spiralé est de 30 mbar à 200 mbar, de préférence de 80 à 170 mbar et particulièrement préféré de 100 mbar à 150 mbar.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010054643A DE102010054643A1 (de) | 2010-12-15 | 2010-12-15 | Elektrolyseur mit spiralförmigem Einlaufschlauch |
| PCT/EP2011/005738 WO2012079670A1 (fr) | 2010-12-15 | 2011-11-15 | Électrolyseur doté d'un tuyau d'entrée en forme de spirale |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2652176A1 EP2652176A1 (fr) | 2013-10-23 |
| EP2652176B1 true EP2652176B1 (fr) | 2015-05-06 |
Family
ID=45047710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20110788370 Active EP2652176B1 (fr) | 2010-12-15 | 2011-11-15 | Électrolyseur doté d'un tuyau d'entrée en forme de spirale |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9045837B2 (fr) |
| EP (1) | EP2652176B1 (fr) |
| JP (1) | JP2013545898A (fr) |
| KR (1) | KR20130138295A (fr) |
| CN (1) | CN103370449B (fr) |
| BR (1) | BR112013014396A2 (fr) |
| CA (1) | CA2817164A1 (fr) |
| DE (1) | DE102010054643A1 (fr) |
| EA (1) | EA023659B1 (fr) |
| WO (1) | WO2012079670A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102016210349A1 (de) | 2016-06-10 | 2017-12-14 | Thyssenkrupp Uhde Chlorine Engineers Gmbh | Elektrolyseur sowie Verfahren zum Betrieb eines Elektrolyseurs |
| CN106245057A (zh) * | 2016-09-08 | 2016-12-21 | 中国水利水电科学研究院 | 一种带有极化整流装置的次氯酸钠发生器 |
| DE102017204096A1 (de) | 2017-03-13 | 2018-09-13 | Siemens Aktiengesellschaft | Herstellung von Gasdiffusionselektroden mit Ionentransport-Harzen zur elektrochemischen Reduktion von CO2 zu chemischen Wertstoffen |
| DE102018210458A1 (de) | 2018-06-27 | 2020-01-02 | Siemens Aktiengesellschaft | Gasdiffusionselektrode zur Kohlendioxid-Verwertung, Verfahren zu deren Herstellung sowie Elektrolysezelle mit Gasdiffusionselektrode |
| EP3805429A1 (fr) * | 2019-10-08 | 2021-04-14 | Covestro Deutschland AG | Procédé et dispositif d'électrolyse destinés à la fabrication de chlore, de monoxyde de carbone et, le cas échéant, d'hydrogène |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE553783C (de) * | 1928-03-16 | 1932-10-10 | Jakob Emil Noeggerath Dr Ing | Elektrolytischer Zersetzer |
| ATE275T1 (de) * | 1978-05-15 | 1981-10-15 | Ernst Spirig | Knallgasgenerator. |
| JPS5524969A (en) * | 1978-08-14 | 1980-02-22 | Tokuyama Soda Co Ltd | Liquid feed method |
| JPS5891179A (ja) | 1981-11-24 | 1983-05-31 | Chlorine Eng Corp Ltd | イオン交換膜法電解槽 |
| US4614575A (en) | 1984-11-19 | 1986-09-30 | Prototech Company | Polymeric hydrogel-containing gas diffusion electrodes and methods of using the same in electrochemical systems |
| DE9413003U1 (de) * | 1994-08-11 | 1994-10-13 | Huang, Ching-Chiang, Chia Yi | Gerät zum Erzeugen eines Gemisches aus Wasserstoff und Sauerstoff |
| DE19641125A1 (de) | 1996-10-05 | 1998-04-16 | Krupp Uhde Gmbh | Elektrolyseapparat zur Herstellung von Halogengasen |
| DE69803570T2 (de) | 1997-06-03 | 2002-10-10 | Uhdenora Technologies Srl | Bipolare elektrolyseur mit ionenaustauscher membran |
| CN1148823C (zh) * | 2001-04-23 | 2004-05-05 | 华南理工大学 | 使用液体燃料的燃料电池 |
| ITMI20012379A1 (it) * | 2001-11-12 | 2003-05-12 | Uhdenora Technologies Srl | Cella di elettrolisi con elettrodi a diffusione di gas |
| JP2003183867A (ja) * | 2001-12-19 | 2003-07-03 | Asahi Glass Co Ltd | 塩化アルカリ水溶液の電解方法 |
| DE10249508A1 (de) | 2002-10-23 | 2004-05-06 | Uhde Gmbh | Elektrolysezelle mit Innenrinne |
| GB0328124D0 (en) * | 2003-12-04 | 2004-01-07 | Daly James | Membrane electrolyser with a two part end design |
| DE102004018748A1 (de) | 2004-04-17 | 2005-11-10 | Bayer Materialscience Ag | Elektrochemische Zelle |
| DE102004019671A1 (de) * | 2004-04-22 | 2005-11-17 | Basf Ag | Verfahren zum Erzeugen einer gleichmäßigen Durchströmung eines Elektrolytraumes einer Elektrolysezelle |
| NO20055593D0 (no) * | 2005-11-25 | 2005-11-25 | Age Jorgen Skomsvold | HODE(Hydrogen og Oksygen Differanse Energi) Ved og utsette et medium i et u-kammer for store G-krefter og spalter mediumet i det ene kammeret (f.eks. elektrolyse) vil en bygge opp et trykk pa toppen av dette kammer pa grunn av densitet forskjellen |
-
2010
- 2010-12-15 DE DE102010054643A patent/DE102010054643A1/de not_active Ceased
-
2011
- 2011-11-15 EA EA201390869A patent/EA023659B1/ru not_active IP Right Cessation
- 2011-11-15 US US13/994,042 patent/US9045837B2/en not_active Expired - Fee Related
- 2011-11-15 JP JP2013543549A patent/JP2013545898A/ja active Pending
- 2011-11-15 CA CA2817164A patent/CA2817164A1/fr not_active Abandoned
- 2011-11-15 BR BR112013014396A patent/BR112013014396A2/pt not_active IP Right Cessation
- 2011-11-15 KR KR1020137018257A patent/KR20130138295A/ko not_active Application Discontinuation
- 2011-11-15 WO PCT/EP2011/005738 patent/WO2012079670A1/fr active Application Filing
- 2011-11-15 EP EP20110788370 patent/EP2652176B1/fr active Active
- 2011-11-15 CN CN201180058885.5A patent/CN103370449B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2652176A1 (fr) | 2013-10-23 |
| US9045837B2 (en) | 2015-06-02 |
| WO2012079670A1 (fr) | 2012-06-21 |
| DE102010054643A1 (de) | 2012-06-21 |
| CA2817164A1 (fr) | 2012-06-21 |
| EA201390869A1 (ru) | 2013-10-30 |
| EA023659B1 (ru) | 2016-06-30 |
| CN103370449A (zh) | 2013-10-23 |
| CN103370449B (zh) | 2016-10-12 |
| US20130256151A1 (en) | 2013-10-03 |
| BR112013014396A2 (pt) | 2016-09-27 |
| KR20130138295A (ko) | 2013-12-18 |
| JP2013545898A (ja) | 2013-12-26 |
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