EP2616580B1 - Non-tissé par filature directe hautement fonctionnel, formé de fibres renfermant des particules, et procédé de production correspondant - Google Patents

Non-tissé par filature directe hautement fonctionnel, formé de fibres renfermant des particules, et procédé de production correspondant Download PDF

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Publication number
EP2616580B1
EP2616580B1 EP20110767163 EP11767163A EP2616580B1 EP 2616580 B1 EP2616580 B1 EP 2616580B1 EP 20110767163 EP20110767163 EP 20110767163 EP 11767163 A EP11767163 A EP 11767163A EP 2616580 B1 EP2616580 B1 EP 2616580B1
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EP
European Patent Office
Prior art keywords
fibers
functional
web
spunbonded web
functional additives
Prior art date
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EP20110767163
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German (de)
English (en)
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EP2616580A1 (fr
Inventor
Yvonne Ewert
Frank-Günter NIEMZ
Marcus Krieg
Bernd Riedel
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Thueringisches Institut fuer Textil und Kunststoff Forschung eV
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Thueringisches Institut fuer Textil und Kunststoff Forschung eV
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Priority to PL11767163T priority Critical patent/PL2616580T3/pl
Priority to SI201130159T priority patent/SI2616580T1/sl
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/12Stretch-spinning methods
    • D01D5/14Stretch-spinning methods with flowing liquid or gaseous stretching media, e.g. solution-blowing
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/724Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged forming webs during fibre formation, e.g. flash-spinning
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/018Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the shape
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/609Cross-sectional configuration of strand or fiber material is specified
    • Y10T442/61Cross-sectional configuration varies longitudinally along strand or fiber material

Definitions

  • the invention relates to highly functional spunbonded nonwovens as textile fabrics which can be produced directly from dissolved polymers by means of known spunbonding processes and which are constructed from fibers filled with liquid and / or solid functional additives.
  • the fibers consist of more than 40 wt.%, Based on the total weight of the fibers, from functional additive, their average fiber diameter is 0.1 to 500 microns and the diameter variations within a fiber or each other is at least 30%.
  • the spunbonded fabric is characterized by a high degree of functionality as a result of very high concentrations of the functional additives and can be used in a variety of ways, for example as a lining material, for hygiene applications, for wound dressings, as support materials, as construction and transport material, as a cosmetic material or as a filter.
  • Filled textile fabrics e.g. those with thermo-regulating, antimicrobial or absorbing properties are already known.
  • the materials hitherto used in the prior art are structures which have been processed into a textile surface after the production of functional fibers by at least one additional process step and / or contain only small amounts of functional particles.
  • the additive components are limited to zinc white (ZnO and ZnS), whereby their proportion is limited to a maximum of 30% and particle sizes are smaller than 15 ⁇ m. It is mentioned that for Fleece applications, the particle content may also be higher, but there is no teaching taught how such nonwovens are produced.
  • the aim was not a functional nonwoven with high particle content, but washable and dyeable bactericidal bodies / fibers with controlled release of the active ingredients with prescribed washing permanence.
  • the melts can be processed into a spunbonded, for example in the EP 1 199 393 A2 , This is a spunbond made of thermoplastic polymers with hydrophobic additives.
  • the aim is an enrichment of the hydrophobic additives on the fiber surface. This is achieved by the fact that the fiber is warped by the air flow so far that the mean fiber diameter is equal to the particle diameter or is reduced to at most half of the particle diameter.
  • the proportion of masterbatches with the additives is between 10 and 20 wt .-% and may not be higher, so as not to affect the further processing to roofing membranes or use in sanitary napkins.
  • Particle-containing filaments or fibers can not be stably spun in a very high proportion of functional particles from 40% in normal filament or fiber spinning processes, since frequent breaks would result.
  • fiber materials with functional added value for the end user, which should also be inexpensive to produce and easy to process.
  • Areas of application of such fiber materials are, for example, in the clothing industry as an insert material, in technical textiles, for example hygiene applications, for wound dressings, as support materials, as construction and transport material, as a cosmetic material or as a filter, for example for the filtration of wastewater or exhaust air and binding of air and water ingredients.
  • Fabrics with functional additives can be prepared in principle either by the surface formation along a textile value chain or web formation from each provided with functional additives fibers, the coating of flat textile structures with additive dispersions or the incorporation of solid or liquid functional additives in already produced nonwoven structures.
  • Fibers with a content of functional additives of more than 40% by weight can not be stably spun in normal fiber spinning processes, since frequent fiber breaks are the result. Although this disadvantage can be partially compensated by the use of functional fibers which are produced by solution spinning processes, the downstream textile surface forming processes also require at least one additional processing step in each case.
  • the materials hitherto produced in the prior art are structures that have been processed into a textile surface by at least one additional process step after separate production of functional fibers and / or only small amounts of functional particles include. Due to the separate nonwoven production process, the highly filled fibers are additionally stressed and thereby damaged and only meet lower quality requirements in terms of functionality or mechanical resistance.
  • the aim of the present invention is to provide a versatile sheet of particulate filaments and fibers having high functional utility for various applications, Depending on the nature of the functional particles to make available, wherein the particulate filaments or fibers consist of more than 40 wt .-% of functional additives and have an average diameter of 0.1 to 500 microns.
  • the fabrics are said to have already reached such a level of stability immediately after being deposited that they are suitable for further processing or for direct use. Due to the high content of functional additives, these fabrics should have such functional properties as are otherwise achieved only by additional process steps such as coating or surface finishing.
  • the subject of the present invention is accordingly a highly functional spunbonded non-meltable polymer-based fiber containing one or more functional additives characterized in that the fibers are intertwined and entangled, have a different length with aspect ratios above 1,000 and a solid one Form nonwoven composite, wherein the fibers have a middle Diameters of 0.1 to 500 micrometers and diameter variations within a fiber and / or with each other of at least 30% and wherein the fibers in addition to the non-meltable polymer more than 40 wt .-%, based on the total weight of the fibers, of functional additives in solid and / or liquid form, which are finely distributed in the fibers
  • the textile fabrics which can be used for various fields of application, depending on the type of functional additives are composed of additives containing more than 40% by weight and up to 96% by weight, optionally even more, in each case based on the total weight of the fibers, of functional additive contained and have a mean diameter 0.1 to 500 microns.
  • the proportion of functional additives is more than 40 wt .-% up to 90 wt .-%, based on the total weight of the fibers.
  • the incorporated and permanent functions of the additives range from, for example, electrically conductive, absorbing, ion-exchanging, antibacterial, temperature-regulating to flame-retardant, abrasive or caring or combinations thereof.
  • the functional additives are, in particular, activated carbon, superabsorbents, ion exchange resins, PCM, metal oxides, flame retardants, abrasives, zeolites, sheet silicates, such as bentonites, or modified sheet silicates, cosmetics or mixtures thereof.
  • liquid lipophilic substances such as paraffins, waxes or oils, can be introduced as a functional additive.
  • one or more component (s) can be introduced in lower concentrations, for example nanosilver or dyes or even active substances, for example pharmaceutical substances or insecticides.
  • the volume fraction of the functional additives (in the context of the present invention also referred to as functional particles or functional materials) in the spinning mixture is preferably chosen such that it makes up the main volume component in the non-woven air-moist filaments or fibers with more than 50%.
  • the diameter of the functional particles in about 1/4 of the average filament or fiber diameter of the air-damp spunbonded fabric, it is achieved that the individual particles in the filaments or fibers have points of contact and so the functional properties in can train advantageously.
  • the production of the additive-containing fabrics from particle-containing filaments or fibers is effected by a spunbonding process.
  • a doped polymer-containing spinning solution is used in the fiber-forming process, wherein the direct solvent is preferably an aprotic solvent.
  • Particularly suitable as direct solvents, especially for cellulose are N-methyl-morpholine-N-oxide or N-methyl-morpholine-N-oxide-monohydrate, ionic liquids, such as 1-ethyl-3-methylimidazolium-acetate, 3- Ethyl 1-methylimidazolium chloride or 3-butyl-1-methylimidazolium chloride, dimethylformamide, dimethylacetamide or dimethyl sulfoxide mixed with lithium chloride or NaOH-thiourea-water or possibly also mixtures thereof.
  • the spinning solution with the functional particles and the dissolved polymer is extruded, wherein the nozzle bores have a diameter of 0.1 to 1.1 mm, preferably from 0.3 to 0.7
  • the strands thus generated are immediately after leaving the nozzles by its own weight and / or an obliquely from the rear acting air flow whose intensity is adapted to the reduced by the functional particles thread creep of the spinning mixture, within a short distance in the longitudinal direction into filaments and fibers with aspect ratios greater than 1,000, preferably greater than 5,000, and most preferably greater than 40,000, tapered.
  • the resulting fiber cracks do not lead to a termination of the process and do not adversely affect the process of web formation. They lead to fibers of different lengths and varying diameters being present in a nonwoven.
  • the fibers are subsequently stabilized in their shape (during the transition into the stress-free space) before the onset of longitudinal relaxation.
  • the fibers or filaments are deposited on a wire belt or a screen drum to form a nonwoven, which may also be layered, and compressed by suction.
  • the solvent-enriched excess water is separated off, the remaining solvent rinsed by washing several times and then optionally the resulting nonwoven can be dried, wherein the functional particles in the non-woven filaments and / or fibers by the taking place swelling of the polymer property determining mutually reinforced touch and connect.
  • the directly dissolved and the particle-binding polymer is a non-melting polymer, ie a polymer in which the softening point is above the decomposition point.
  • a non-melting polymer ie a polymer in which the softening point is above the decomposition point.
  • It is preferably a member of the group of natural polymers, for example the polysaccharides, particularly preferably cellulose, the polysaccharide derivatives or the proteins or protein derivatives and / or from the group of solution-formable synthetic polymers, for example polyacrylonitrile, polyvinyl alcohol, Polyethylene oxide, polysulfone, meta-aramid or their copolymers.
  • the wet spunbonded fabric obtained in this way can be consolidated, finished and shaped by textile processes (needle punching, hydroentanglement, chemical bonding), the solidification and refinement of the nonwoven fabric being able to take place before or after drying. Aftertreatment by, for example, lubricants, impregnations or with ionic active substances may follow.
  • a spunbond web is understood to mean a web of fibers and continuous fibers laid down directly in random orientation after the extrusion, in which case it is also possible to lay several layers one above the other.
  • the mixture of fibers and continuous fibers is caused by fiber breaks after the nozzle, resulting from the high particle content, but do not lead to an interruption of the process.
  • the spunbonded nonwoven not only consists of fibers of different lengths, but the fibers themselves have different fiber thicknesses over their length or with each other. The fiber thickness is determined by various factors, such as the concentration of the solution, the rate of blowing, the type of polymer, the particle size, as well as interaction of the additives to other components of the solution and content of additives.
  • Characteristic features are the irregularities in the mean diameter of the fibers due to the high particle content, the size of the particles and the fiber breaks, which are visually very easily discernible under a microscope.
  • the highly functional spunbonded nonwoven has a basis weight of 2 to 1000 g / m 2 , preferably of 5 to 500 g / m 2 and a thickness of 0.01 to 20 mm, preferably from 0.05 to 5 mm. It has incorporated and permanent additional functions, such as electrically conductive, absorbent, ion-exchanging, antibacterial, temperature-regulating, flame-retardant, abrasive, caring or combinations thereof.
  • particulate pore formers for example Glauber's salt
  • the pore formers then lead, during the washing process, to a spunbonded web of highly porous fibers and filaments, which have a much larger surface area in comparison with area-like sponges.
  • a highly functional spunbond web of particulate filaments or fibers ranges from apparel materials, such as heat-trapping or active ingredient release liners, to technical textiles with high functional utility for various applications - depending on the type of functional particles, for example for hygiene applications, as wound dressings, as carrier materials for active ingredients or as support materials in composites, as Construction and transport material, as a cosmetic material or as a filter, for example for the filtration and binding of air and water ingredients such as phosphates, nitrates and ammonium-nitrogen compounds. Due to the special characteristics of the functional properties, due to the high concentration of additives, these nonwovens are also suitable for layered composites with other fabrics. This can happen by producing the highly functional spunbonded fabric on another, already introduced fabric during spunbonding production.
  • Some of the resulting fiber cable pieces were completely freed of solvent and cut, as far as possible, to a staple length of 40 mm, with the described bonds sorted out as far as possible.
  • the fibers were treated with a 1% sodium chloride solution and dried at 55 ° C to constant weight. A secondary spinning to the yarn was not possible. A fleece formation was only partially possible, while a large number of short fibers and extreme shortening of the fibers was observed. The irregular loose fleece sections could not be further processed or used. A consolidation by needling for stabilization was not possible because the fleece was completely destroyed and fell apart.
  • a cellulose solution prepared according to Example 1 was solidified by melt-blown spinning (solution blowing) at a solution temperature of 95 ° C, blowing with 80 ° C warm air, and spraying with a water mist directly at the exit of the nozzle blower unit and depositing on a screen belt deformed into a direct web.
  • the deformation process was stable and the resulting nonwoven fabric could be used after complete extraction of the solvent and drying at 60 ° C without difficulty as an ion exchange nonwoven.
  • the functional fleece was mechanically stable enough to be cut to size and fed into the water treatment plant. An additionally performed moderate needling and thus further compaction was also possible without the fleece was destroyed.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Cosmetics (AREA)

Claims (12)

  1. Non tissé hautement fonctionnel constitué de fibres à base de polymères non fusibles, qui contiennent un ou plusieurs additifs fonctionnels, caractérisé en ce que les fibres sont mutuellement entrelacées et accrochées, présentent une longueur différente avec des rapports d'aspect de plus de 1000 et forment un composite nappé solide, dans lequel les fibres présentent un diamètre moyen de 0,1 à 500 micromètres ainsi que des variations de diamètre au sein d'une fibre et/ou entre fibres d'au moins 30 % et dans lequel les fibres contiennent, à côté du polymère non fusible, plus de 40 % en poids, par rapport au poids total des fibres, d'additifs fonctionnels sous forme solide et/ou liquide, qui sont finement répartis dans les fibres.
  2. Non tissé selon la revendication 1, caractérisé en ce que les additifs fonctionnels sont des substances solides ou liquides, de préférence lipophiles, en particulier du charbon actif, des superabsorbants, des résines échangeuses d'ions, des matériaux piézoélectriques, des matériaux de commutation de phases, des paraffines spéciales, des oxydes métalliques, des agents pare-flammes, des abrasifs, des zéolites, des silicates stratifiés, des silicates stratifiés modifiés et/ou des cosmétiques.
  3. Non tissé selon la revendication 1 ou la revendication 2, caractérisé en ce que le polymère non fusible liant les additifs fonctionnels est un polymère naturel, de préférence un polysaccharide, mieux encore de la cellulose, un dérivé de polysaccharide et/ou une protéine ou un dérivé de protéine et/ou en ce qu'il s'agit d'un polymère synthétique façonnable en solution, de préférence du polyacrylonitrile ou un copolymère avec des unités d'acrylonitrile, de l'alcool polyvinylique, du poly(oxyde d'éthylène), une polysulfone et/ou un méta-aramide.
  4. Non tissé selon au moins l'une quelconque des revendications précédentes, caractérisé en ce qu'il présente une structure stratifiée formée de filaments ou de fibres liés mécaniquement mutuellement entrelacés.
  5. Non tissé selon au moins l'une quelconque des revendications précédentes, caractérisé en ce qu'il possède une masse spécifique de 2 à 1000 g/m2, de préférence de 5 à 500 g/m2.
  6. Non tissé selon au moins l'une quelconque des revendications précédentes, caractérisé en ce qu'il possède une épaisseur de 0,1 à 20 mm, de préférence de 0,5 à 5 mm.
  7. Non tissé selon une ou plusieurs des revendications 1 à 6, caractérisé en ce que la fraction des additifs fonctionnels atteint plus de 40 % en poids jusqu'à 96 % en poids, éventuellement même plus, par rapport au poids total des fibres.
  8. Procédé de fabrication d'un non tissé fonctionnel selon une ou plusieurs des revendications 1 à 7, caractérisé en ce que :
    - la solution de filage constituée d'un ou plusieurs additifs fonctionnels, d'un solvant et d'un polymère dissous dans celui-ci est pressée hors de la filière, dans lequel :
    les orifices de la filière présentent un diamètre de 0,1 à 1,5 mm, de préférence de 0,3 à 0,7 mm,
    - les coulées de polymère ainsi formées sont étirées, immédiatement après avoir quitté les filières, en raison de leur poids spécifique et/ou d'un courant de soufflage opérant en oblique par le dessus, dont l'intensité est adaptée au pouvoir d'allongement de fil du mélange de filage réduit par les additifs fonctionnels, sur une courte distance dans la direction longitudinale, en filaments et/ou en fibres,
    - ceux-ci, ensuite, au passage dans l'espace exempt de tension, encore avant l'application de la relaxation longitudinale, sont stabilisés en forme au moyen d'un courant d'air tempéré et/ou de fines gouttelettes d'eau par consolidation ou gélification et en partie par remplacement du solvant par de l'eau, dans lequel la stabilisation peut se faire localement plus ou moins en décalage avec la sortie de la filière et les non tissés peuvent donc être maintenus avec plus ou moins de fibres de gel collées,
    - après avoir atteint cet état stabilisé, le non tissé se dépose sur une bande tamis ou un tambour tamis pour obtenir un non tissé, le solvant restant est rincé par lavages multiples et le non tissé peut ensuite éventuellement être séché.
  9. Procédé selon la revendication 8, caractérisé en ce que le solvant comprend un solvant aprotique ou en est constitué.
  10. Procédé selon la revendication 8 ou la revendication 9, caractérisé en ce que le non tissé hautement fonctionnel est encore consolidé, ennobli et façonné par des traitements textiles et en ce que la consolidation et l'ennoblissement du non tissé sont effectués avant ou après le séchage.
  11. Procédé selon une ou plusieurs des revendications 8 à 10, caractérisé en ce que le non tissé hautement fonctionnel est stabilisé par aiguilletage ou consolidation par jet d'eau et/ou également réticulé par voie chimique.
  12. Utilisation d'un non tissé hautement fonctionnel formé de filaments ou de fibres contenant des additifs fonctionnels selon les revendications 1 à 7 pour la fabrication de matériaux de revêtement, en particulier de matériaux de garnitures, ainsi que de textiles techniques, en particulier pour applications hygiéniques, pour pansements pour plaies, comme matériaux de support pour additifs ou matériaux de support pour matériaux composites, comme matériau de construction et de transport, comme matériau cosmétique ou comme filtre, avec une exploitation fonctionnelle élevée pour divers domaines d'utilisation - en fonction du type des additifs fonctionnels.
EP20110767163 2010-09-14 2011-09-13 Non-tissé par filature directe hautement fonctionnel, formé de fibres renfermant des particules, et procédé de production correspondant Active EP2616580B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL11767163T PL2616580T3 (pl) 2010-09-14 2011-09-13 Włóknina spod filiery o wysokiej funkcjonalności wytworzona z włókien zawierających cząstki i sposób jej wytwarzania
SI201130159T SI2616580T1 (sl) 2010-09-14 2011-09-13 Visokofunkcionalna predilna koprena iz vlaken, ki vsebujejo delce, in postopek za njeno izdelavo

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010045242 2010-09-14
PCT/EP2011/004591 WO2012034679A1 (fr) 2010-09-14 2011-09-13 Non-tissé par filature directe hautement fonctionnel, formé de fibres renfermant des particules, et procédé de production correspondant

Publications (2)

Publication Number Publication Date
EP2616580A1 EP2616580A1 (fr) 2013-07-24
EP2616580B1 true EP2616580B1 (fr) 2014-04-02

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EP20110767163 Active EP2616580B1 (fr) 2010-09-14 2011-09-13 Non-tissé par filature directe hautement fonctionnel, formé de fibres renfermant des particules, et procédé de production correspondant

Country Status (12)

Country Link
US (1) US20120215148A1 (fr)
EP (1) EP2616580B1 (fr)
JP (1) JP5579870B2 (fr)
KR (1) KR101497360B1 (fr)
CN (1) CN102753746B (fr)
AU (1) AU2011301355B8 (fr)
BR (1) BR112012017019A2 (fr)
DE (1) DE112011100474B4 (fr)
PL (1) PL2616580T3 (fr)
RU (1) RU2522186C2 (fr)
SI (1) SI2616580T1 (fr)
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JP5579870B2 (ja) 2014-08-27
EP2616580A1 (fr) 2013-07-24
DE112011100474A5 (de) 2012-12-13
AU2011301355B8 (en) 2014-02-20
SI2616580T1 (sl) 2014-06-30
BR112012017019A2 (pt) 2016-04-05
RU2012130176A (ru) 2014-01-27
KR20120113288A (ko) 2012-10-12
CN102753746B (zh) 2014-09-10
KR101497360B1 (ko) 2015-03-02
AU2011301355A1 (en) 2012-05-31
RU2522186C2 (ru) 2014-07-10
DE112011100474B4 (de) 2021-12-09
CN102753746A (zh) 2012-10-24
PL2616580T3 (pl) 2014-08-29
JP2013515869A (ja) 2013-05-09
AU2011301355A8 (en) 2014-02-20
WO2012034679A1 (fr) 2012-03-22
US20120215148A1 (en) 2012-08-23
AU2011301355B2 (en) 2014-02-06

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