EP2470632B1 - Pouvoir détergent amélioré par des capteurs de radicaux libres - Google Patents

Pouvoir détergent amélioré par des capteurs de radicaux libres Download PDF

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Publication number
EP2470632B1
EP2470632B1 EP10744954.8A EP10744954A EP2470632B1 EP 2470632 B1 EP2470632 B1 EP 2470632B1 EP 10744954 A EP10744954 A EP 10744954A EP 2470632 B1 EP2470632 B1 EP 2470632B1
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Prior art keywords
red
stains
dyes
use according
blue
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EP10744954.8A
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German (de)
English (en)
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EP2470632A1 (fr
Inventor
Christian Kropf
Andreas Buhl
André HÄTZELT
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0084—Antioxidants; Free-radical scavengers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents

Definitions

  • the present invention relates to the use of radical scavengers in detergents and cleaners to improve cleaning performance, particularly with respect to stains containing polymerizable dyes.
  • a similar problem also exists for bleach-free color detergents in which the bleaching agent is omitted in order to protect the dyes in the textile and to prevent their bleaching.
  • the washing process In the absence of the bleaching agent, it is aggravating that instead of removing the soils normally removed by the bleaching agent, the washing process often intensifies and / or worsens the removability of the soiling, not least due to initiated chemical reactions attributable, for example, in the polymerization of certain dyes contained in the stains.
  • the polymerizable substances are, above all, polyphenolic dyes, preferably flavonoids, in particular from the class of anthocyanidins or anthocyanins.
  • the stains may in particular be red wine stains or spots of fruits or vegetables containing red and / or blue dyes, in particular polyphenolic dyes, especially those from the class of anthocyanidins or anthocyanins.
  • the stains may have been caused in particular by food products or beverages containing corresponding dyes.
  • radical scavengers in detergents and cleaners has already been described in the prior art.
  • the use of radical scavengers described in the prior art serves to stabilize contained components which can be inactivated and / or decomposed by oxidative degradation.
  • EP1144580 describes the use of free-radical scavengers in transparent packaging to prevent damage to UV light by components contained therein.
  • aqueous liquid detergents which contain alkoxylated carboxylic acid esters and, for their hydrolysis stability improvement, radical scavengers, among which n-propyl gallate is mentioned.
  • a first object of the present invention is therefore the use of radical scavengers as defined below in detergents and cleaners to improve the cleaning performance.
  • polymerizable dyes in detergents to improve the cleaning performance, which consists in an improved removal of stains containing polymerizable substances, especially polymerizable dyes, wherein the polymerizable dyes are preferably polyphenolic dyes, in particular flavonoids, especially anthocyanidins or anthocyanins or oligomers of these compounds.
  • the polymerizable dyes are preferably polyphenolic dyes, in particular flavonoids, especially anthocyanidins or anthocyanins or oligomers of these compounds.
  • red- to blue-colored stains in particular red wine stains or spots of fruits or vegetables which contain red to blue-colored dyes, in particular stains caused by food products or drinks containing corresponding dyes.
  • red to blue stains are to be understood according to the invention, which may have a color from the color spectrum of red to blue.
  • stains in the colors red or blue stains in intermediate colors, in particular in violet, purple, purple or pink, as well as stains which have a red, violet, purple, purple, pink or blue tint, are therefore not considered even having to completely consist of this color.
  • the said colors may also be light or dark in each case, i. especially light and dark red as well as light and dark blue are possible colors.
  • the stains to be removed according to the invention can be caused in particular by cherries, red grapes, pomegranate, aronia, plums, sea-buckthorn, acai, berries, especially red or black currants, elderberries, blackberries, raspberries, blueberries, cranberries, strawberries or blueberries, red cabbage, Blood orange, aubergine, black carrot, red meat or blue meat potato or red onion.
  • R is a linear or branched radical selected from hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl and tetradecyl.
  • the radical scavenger is used according to the invention preferably in an amount of 0.001 to 10 wt.%, In particular in an amount of 0.01 to 5 wt .-%, particularly preferably in an amount of 0.05 to 2 Ges .-%.
  • the washing or cleaning agent may be present in any of the prior art and / or any suitable administration form.
  • These include, for example, solid, powdery, liquid, gelatinous or pasty dosage forms, optionally also of several phases, compressed or uncompressed; further include, for example: extrudates, granules, tablets or pouches, packed both in large containers and in portions.
  • the detergent is in a particularly preferred embodiment, a liquid laundry detergent.
  • the detergent is a powdered color detergent, ie a powdered textile detergent for dyed textiles.
  • the textile detergent is preferably a liquid laundry detergent and / or a laundry detergent that is free from bleaches.
  • the laundry detergents and detergents in which the use according to the invention is carried out may additionally comprise customary other constituents of detergents and cleaners, in particular laundry detergents, in particular selected from the group of builders, surfactants, polymers, enzymes, textile-softening substances, in particular esterquats, protein hydrolysates, electrolytes, pH adjusters, fluorescers, hydrotopes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, shrinkage inhibitors, anti-crease agents, dye transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, repellents and impregnating agents, Swelling and anti-slip agents, UV absorbers, disintegration aids, fragrances, dyes and perfume carriers.
  • laundry detergents in particular selected from the group of builders, surfactants, polymers, enzymes, textile-softening substances, in particular esterquats, protein hydrolysates, electrolytes, pH adjusters,
  • nonionic, anionic, cationic and / or amphoteric surfactants can be used as surfactants.
  • proteases amylases, lipases, hemicellulases, cellulases, perhydrolases and / or oxidoreductases can be used as enzymes.
  • Example 1 Use of propyl gallate (PG) to improve the washing performance
  • the evaluation was carried out by color distance measurement according to the Lab values and the Y values calculated therefrom as a measure of the brightness.
  • the following table shows the dY values resulting from the difference Y (after washing) - Y (before washing) for the 5 above stains.
  • cherry Blackcurrant bilberry Red grape red wine FWM 35.7 50 27.6 52.8 40.6 FWM + PG 41.7 54 33.3 62 54.5
  • the dY values with addition of PG are greater for all stains than with the pure FWM, which corresponds to a higher degree of whiteness and thus improved stain removal.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Biochemistry (AREA)
  • Detergent Compositions (AREA)

Claims (6)

  1. Utilisation de capteurs de radicaux libres répondant à la formule générale (I)
    Figure imgb0004
     dans laquelle
    W représente un résidu -C(O)X ou -NLC(O)X ;
    X représente un résidu OR ;
    L représente un atome d'hydrogène ou un groupe alkyle en C1-C6 ;
    R représente un résidu alkyle en C1-C40 à chaîne droite où ramifiée, en particulier un résidu alkyle en C4-C20 ; avant tout un résidu alkyle en C6-C14 ;
    R1 et R5 représentent un atome d'hydrogène ;
    R2, R3 et R4 représentent un groupe hydroxyle ;
    dans des agents de lavage et de nettoyage pour l'amélioration de la puissance de nettoyage qui consiste en une meilleure élimination des salissures qui contiennent des substances polymérisables, avant tout des colorants polymérisables.
  2. Utilisation selon la revendication 1, caractérisée en ce que les colorants polymérisables sont choisis parmi des colorants polyphénoliques, en particulier parmi des flavonoïdes, avant tout parmi des colorants faisant partie de la classe des anthocyanidines ou des anthocyanes ou des oligomères de ces composés.
  3. Utilisation selon la revendication 1 ou 2, caractérisée en ce que la puissance de nettoyage améliorée consiste en une meilleure élimination de salissures de couleur rouge à bleu, en particulier de taches de vin rouge ou de taches de fruits ou de légumes qui contiennent des colorants de couleur rouge à bleu.
  4. Utilisation selon l'une quelconque des revendications 1 à 3, caractérisée en ce que les salissures sont choisies parmi des salissures qui sont dues à des cerises, à du raisin noir, à des grenades, à de l'aronia, à des prunes, à de l'argousier, à des baies d'açaï, à des baies, avant tout à des groseilles noires ou rouges, à des baies de sureau, à des mûres, à des framboises, à des myrtilles à baies noires, à de la canneberge, à des fraises ou à des myrtilles, a du chou rouge, à des oranges sanguines, à des aubergines, à des carottes noires, à des pommes de terre à chair rouge ou à chair bleue ou à des oignons rouges.
  5. Utilisation selon l'une quelconque des revendications 1 à 4, caractérisée en ce que les agents de lavage ou de nettoyage ne contiennent aucun agent de blanchiment.
  6. Utilisation selon l'une quelconque des revendications 1 à 5, caractérisée en ce que, en ce qui concerne l'agent de lavage, il s'agit d'un agent de lavage des textiles sous forme liquide ou sous forme pulvérulente.
EP10744954.8A 2009-08-26 2010-08-25 Pouvoir détergent amélioré par des capteurs de radicaux libres Active EP2470632B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009028891A DE102009028891A1 (de) 2009-08-26 2009-08-26 Verbesserte Waschleistung durch Radikalfänger
PCT/EP2010/062375 WO2011023716A1 (fr) 2009-08-26 2010-08-25 Pouvoir détergent amélioré par des capteurs de radicaux libres

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EP2470632A1 EP2470632A1 (fr) 2012-07-04
EP2470632B1 true EP2470632B1 (fr) 2016-06-08

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US (1) US20120157370A1 (fr)
EP (1) EP2470632B1 (fr)
KR (1) KR20120062712A (fr)
DE (1) DE102009028891A1 (fr)
ES (1) ES2588757T3 (fr)
PL (1) PL2470632T3 (fr)
WO (1) WO2011023716A1 (fr)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3279319B1 (fr) 2010-04-26 2020-06-10 Novozymes A/S Granules enzymatiques
CN104204179A (zh) 2011-06-20 2014-12-10 诺维信公司 颗粒组合物
MX349517B (es) 2011-06-24 2017-08-02 Novozymes As Polipeptidos que tienen actividad de proteasa y polinucleotidos que codifican los mismos.
DK3543333T3 (da) 2011-06-30 2022-02-14 Novozymes As Fremgangsmåde til screening af alfa-amylaser
US10711262B2 (en) 2011-07-12 2020-07-14 Novozymes A/S Storage-stable enzyme granules
US9000138B2 (en) 2011-08-15 2015-04-07 Novozymes A/S Expression constructs comprising a Terebella lapidaria nucleic acid encoding a cellulase, host cells, and methods of making the cellulase
ES2628190T3 (es) 2011-09-22 2017-08-02 Novozymes A/S Polipéptidos con actividad de proteasa y polinucleótidos que codifican los mismos
WO2013076269A1 (fr) 2011-11-25 2013-05-30 Novozymes A/S Variants de subtilase et polynucléotides codants pour ceux-ci
DE102011088984A1 (de) 2011-12-19 2013-06-20 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
DE102011088982A1 (de) 2011-12-19 2013-06-20 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
WO2013092635A1 (fr) 2011-12-20 2013-06-27 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2013110766A1 (fr) 2012-01-26 2013-08-01 Novozymes A/S Utilisation de polypeptides à activité protéasique dans les aliments pour animaux et les détergents
CN104114698A (zh) 2012-02-17 2014-10-22 诺维信公司 枯草杆菌蛋白酶变体以及编码它们的多核苷酸
WO2013131964A1 (fr) 2012-03-07 2013-09-12 Novozymes A/S Composition détergente et substitution d'azurants optiques dans des compositions détergentes
CN113201519A (zh) 2012-05-07 2021-08-03 诺维信公司 具有黄原胶降解活性的多肽以及编码其的核苷酸
AU2013279440B2 (en) 2012-06-20 2016-10-06 Novozymes A/S Use of polypeptides having protease activity in animal feed and detergents
BR112015014396B1 (pt) 2012-12-21 2021-02-02 Novozymes A/S Composição, construto de ácido nucleico ou vetor de expressão, microorganismo recombinante, métodos de melhoria do valor nutricional de uma ração animal, aditivo de ração animal, e, uso de uma ou mais proteases
EP2941485B1 (fr) 2013-01-03 2018-02-21 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
GB2505977A (en) * 2013-02-12 2014-03-19 Reckitt Benckiser Brands Ltd Use of sorbic acid or water soluble sorbate as a radical scavenger
US20160083703A1 (en) 2013-05-17 2016-03-24 Novozymes A/S Polypeptides having alpha amylase activity
EP3004315A2 (fr) 2013-06-06 2016-04-13 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
WO2014207224A1 (fr) 2013-06-27 2014-12-31 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3013956B1 (fr) 2013-06-27 2023-03-01 Novozymes A/S Variantes substitulases et polynucléotides les codant
CN105358670A (zh) 2013-07-04 2016-02-24 诺维信公司 具有抗再沉积效果的具黄原胶裂解酶活性的多肽与编码它们的多核苷酸
EP3309249B1 (fr) 2013-07-29 2019-09-18 Novozymes A/S Variants de protéases et polynuclétides les codant
CN105358686A (zh) 2013-07-29 2016-02-24 诺维信公司 蛋白酶变体以及对其进行编码的多核苷酸
EP2832853A1 (fr) 2013-07-29 2015-02-04 Henkel AG&Co. KGAA Composition détergente comprenant des variantes de protéases
DE102013217034A1 (de) 2013-08-27 2015-03-05 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
DE102013217390A1 (de) 2013-09-02 2015-03-05 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
WO2015049370A1 (fr) 2013-10-03 2015-04-09 Novozymes A/S Composition détergente et utilisation de celle-ci
DE102013226003A1 (de) 2013-12-16 2015-06-18 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
US10030239B2 (en) 2013-12-20 2018-07-24 Novozymes A/S Polypeptides having protease activity and polynucleotides encoding same
US20160333292A1 (en) 2014-03-05 2016-11-17 Novozymes A/S Compositions and Methods for Improving Properties of Cellulosic Textile Materials with Xyloglucan Endotransglycosylase
WO2015134729A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés destinés à améliorer les propriétés de matériaux textiles non-cellulosiques par l'utilisation d'endo-xyloglucane transférase
CN106103708A (zh) 2014-04-01 2016-11-09 诺维信公司 具有α淀粉酶活性的多肽
WO2015189371A1 (fr) 2014-06-12 2015-12-17 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ces derniers
CN106661566A (zh) 2014-07-04 2017-05-10 诺维信公司 枯草杆菌酶变体以及编码它们的多核苷酸
US10626388B2 (en) 2014-07-04 2020-04-21 Novozymes A/S Subtilase variants and polynucleotides encoding same
DE102014222834A1 (de) * 2014-11-10 2016-05-12 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
DE102014222833A1 (de) 2014-11-10 2016-05-12 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
US10287562B2 (en) 2014-11-20 2019-05-14 Novoszymes A/S Alicyclobacillus variants and polynucleotides encoding same
EP3227444B1 (fr) 2014-12-04 2020-02-12 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3608403A3 (fr) 2014-12-15 2020-03-25 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
CN108012544A (zh) 2015-06-18 2018-05-08 诺维信公司 枯草杆菌酶变体以及编码它们的多核苷酸
EP3106508B1 (fr) 2015-06-18 2019-11-20 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
CN108291212A (zh) 2015-10-14 2018-07-17 诺维信公司 多肽变体
US20180171318A1 (en) 2015-10-14 2018-06-21 Novozymes A/S Polypeptides Having Protease Activity and Polynucleotides Encoding Same
CA3024276A1 (fr) 2016-06-03 2017-12-07 Novozymes A/S Variants de subtilase et polynucleotides codant pour ceux-ci
JP6858850B2 (ja) 2016-07-13 2021-04-14 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ バチルス・シビ（ＢＡＣＩＬＬＵＳ ＣＩＢＩ）ＤＮａｓｅ変異体及びその使用
DE102016214660A1 (de) 2016-08-08 2018-02-08 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
AU2017317563B8 (en) * 2016-08-24 2023-03-23 Henkel Ag & Co. Kgaa Detergent compositions comprising xanthan lyase variants I
BR112020008251A2 (pt) 2017-10-27 2020-11-17 Novozymes A/S variantes de dnase
CN111247245A (zh) 2017-10-27 2020-06-05 宝洁公司 包含多肽变体的洗涤剂组合物
DE102018200960A1 (de) 2018-01-23 2019-07-25 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit verbesserter Leistung
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DE102018217397A1 (de) 2018-10-11 2020-04-16 Henkel Ag & Co. Kgaa Verwendung von übergangsmetallfreien Abtönungsfarbstoffen in Kombination mit Catecholderivaten
DE102018217398A1 (de) 2018-10-11 2020-04-16 Henkel Ag & Co. Kgaa Flüssigwaschmittel mit Dihydroxyterephthalsäurediamid-Verbindung
DE102018217392A1 (de) 2018-10-11 2020-04-16 Henkel Ag & Co. Kgaa Mehrkomponenten-Waschmittel mit Catechol-Metallkomplex
AU2020242303A1 (en) 2019-03-21 2021-06-24 Novozymes A/S Alpha-amylase variants and polynucleotides encoding same
DE102019204792A1 (de) 2019-04-04 2020-10-08 Henkel Ag & Co. Kgaa Verwendung von Mannanase-Enzym in Kombination mit Catecholderivaten
WO2020207944A1 (fr) 2019-04-10 2020-10-15 Novozymes A/S Variants polypeptidiques
CN114787329A (zh) 2019-08-27 2022-07-22 诺维信公司 洗涤剂组合物
CN114616312A (zh) 2019-09-19 2022-06-10 诺维信公司 洗涤剂组合物
US20220340843A1 (en) 2019-10-03 2022-10-27 Novozymes A/S Polypeptides comprising at least two carbohydrate binding domains
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
CN116507725A (zh) 2020-10-07 2023-07-28 诺维信公司 α-淀粉酶变体
EP4291646A2 (fr) 2021-02-12 2023-12-20 Novozymes A/S Variants d'alpha-amylase
WO2022268885A1 (fr) 2021-06-23 2022-12-29 Novozymes A/S Polypeptides d'alpha-amylase
WO2024131880A2 (fr) 2022-12-23 2024-06-27 Novozymes A/S Composition détergente comprenant une catalase et une amylase

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE13562T1 (de) * 1981-01-16 1985-06-15 Procter & Gamble Textilbehandlungsmittel.
EP0209228B2 (fr) 1985-06-17 1999-06-09 The Clorox Company Compositions de blanchiment stables liquides de péroxyde d'hydrogène
US4764302A (en) * 1986-10-21 1988-08-16 The Clorox Company Thickening system for incorporating fluorescent whitening agents
US5336419A (en) * 1990-06-06 1994-08-09 The Procter & Gamble Company Silicone gel for ease of ironing and better looking garments after ironing
CA2157178C (fr) * 1993-03-01 2002-08-20 Errol Hoffman Wahl Compositions d'assouplissant pour tissus, a base de concentre de sel d'ammonium quaternaire biodegradable et de composes contenant des chaines d'acides gras insatures a valeur intermediaire d'indice d'iode
ES2169062T3 (es) 1994-02-22 2002-07-01 Procter & Gamble Composiciones blanqueadoras de hipoclorito.
US5534487A (en) * 1995-05-16 1996-07-09 Rohm And Haas Company Stabilization of 3-isothiazolone solutions
US6001794A (en) * 1996-06-14 1999-12-14 The Procter & Gamble Company Laundry pretreatment peroxygen bleach with radical scavenger giving improved fabric/color safety
EP0843001B1 (fr) 1996-11-13 2003-04-23 The Procter & Gamble Company Compositions de blanchiment aqueuses alcalines contenant des composés peroxygéniques
US6242407B1 (en) * 1996-11-22 2001-06-05 The Procter & Gamble Company Laundry bleaching compositions
FR2762324A1 (fr) * 1997-04-16 1998-10-23 Rhodia Chimie Sa Utilisation d'un systeme anti-oxydant en detergence et compositions obtenues
US6448214B1 (en) * 1997-10-08 2002-09-10 The Proctor & Gamble Company Liquid aqueous bleaching compositions
EP0964047B1 (fr) * 1998-06-01 2003-10-29 Johnson & Johnson Consumer Companies, Inc. Système anti-oxydant
US6894015B1 (en) * 1998-11-11 2005-05-17 Procter & Gamble Company Bleaching compositions
ES2195306T3 (es) 1998-11-11 2003-12-01 Procter & Gamble Composiciones de blanqueo.
AU749498B2 (en) 1998-12-16 2002-06-27 Unilever Plc Transparent/translucent liquid enzyme compositions in clear bottles comprising antioxidants
US6653270B2 (en) * 1999-03-02 2003-11-25 Procter & Gamble Company Stabilized bleach compositions
US7012053B1 (en) * 1999-10-22 2006-03-14 The Procter & Gamble Company Fabric care composition and method comprising a fabric care polysaccharide and wrinkle control agent
FR2807763A1 (fr) * 2000-04-17 2001-10-19 Cognis Deutschland Gmbh Produits de nettoyage aqueux concentres en pate de lavage pour les mains
DE60116339T3 (de) * 2000-09-11 2013-09-05 The Procter & Gamble Company Waschkit sowie verfahren zur kombinierten pflege und reinigung von gewebe
US6794348B2 (en) * 2002-09-20 2004-09-21 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Gel laundry detergent and/or pre-treater composition
DE60325936D1 (de) 2003-03-28 2009-03-12 Procter & Gamble Trimethoxybenzoesäure oder ihre Salze enthaltende Bleichmittelzusammensetzung
BRPI0416944A (pt) * 2003-12-05 2007-02-13 Unilever Nv composição detergente lìquida para lavagem de roupa, e, método para limpar um substrato de tecido
BRPI0417366A (pt) * 2003-12-11 2007-04-10 Unilever Nv composição detergente lìquida, método de limpeza de um substrato de tecido, e, uso de um antioxidante
GB0511313D0 (en) 2005-06-03 2005-07-13 Unilever Plc Incorporation of antioxidant in detergent composition
DE102005041436A1 (de) * 2005-08-31 2007-03-01 Henkel Kgaa Flüssiges hypohalogenithaltiges Bleichmittel
US7291582B2 (en) * 2005-09-20 2007-11-06 Conopco, Inc., D/B/A Unilever Liquid laundry detergent with an alkoxylated ester surfactant
EP1865051B1 (fr) 2006-06-08 2019-03-20 The Procter and Gamble Company Compositions de blanchiment
MX2009001197A (es) * 2006-08-01 2009-02-11 Procter & Gamble Particulas de suministro que contienen agentes beneficos.
US7879744B2 (en) * 2007-08-30 2011-02-01 Kimberly-Clark Worldwide, Inc. Stabilized decolorizing composition
US20090092561A1 (en) * 2007-10-09 2009-04-09 Lupia Joseph A Body-care and household products and compositions comprising specific sulfur-containing compounds

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DE102009028891A1 (de) 2011-03-03
EP2470632A1 (fr) 2012-07-04
WO2011023716A1 (fr) 2011-03-03
PL2470632T3 (pl) 2016-12-30
US20120157370A1 (en) 2012-06-21
ES2588757T3 (es) 2016-11-04
KR20120062712A (ko) 2012-06-14

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