EP2467507B1 - Alliage de laiton - Google Patents

Alliage de laiton Download PDF

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Publication number
EP2467507B1
EP2467507B1 EP10768172.8A EP10768172A EP2467507B1 EP 2467507 B1 EP2467507 B1 EP 2467507B1 EP 10768172 A EP10768172 A EP 10768172A EP 2467507 B1 EP2467507 B1 EP 2467507B1
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EP
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Prior art keywords
weight
per cent
content
brass alloy
alloy according
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EP10768172.8A
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German (de)
English (en)
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EP2467507A1 (fr
Inventor
Karl Zeiger
Ulrich Lorenz
Michael Hoppe
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Aurubis Stolberg GmbH and Co KG
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Aurubis Stolberg GmbH and Co KG
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Application filed by Aurubis Stolberg GmbH and Co KG filed Critical Aurubis Stolberg GmbH and Co KG
Priority to PL10768172T priority Critical patent/PL2467507T3/pl
Publication of EP2467507A1 publication Critical patent/EP2467507A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon

Definitions

  • the invention relates to a brass alloy for use in the manufacture of semi-finished products intended for machining, consisting of copper, zinc and additional alloy components.
  • Corresponding brass alloys are often produced as semi-finished products in strip or wire form and subsequently processed into finished products. The further processing takes place frequently by application of cutting operations.
  • lead When machining brass, it has proven advantageous in the past to add lead to the alloy in an amount of up to four percent by weight.
  • the lead has a positive effect as a chipbreaker, extends tool life and reduces the tensile forces. Important material parameters such as strength and corrosion resistance are not adversely affected by an addition of lead.
  • a brass alloy of the aforementioned type has become known, which contains in a variant except copper and zinc components of iron, nickel and tin and less than 0.1 weight percent lead, but additionally has a proportion of 0.49 weight percent bismuth.
  • a brass alloy has become known which has no content of lead, but except copper, zinc, iron and tin a Contains 2.3 wt% bismuth.
  • Object of the present invention is to define a lead-free brass alloy of the aforementioned type such that it achieves good machinability, sufficient mechanical properties and the lowest possible wear on the cutting tools used and that at the same time the lowest possible content of expensive and / or having environmentally harmful alloying elements.
  • the invention is further based on the object to achieve specific properties by the targeted combination of non-polluting alloying elements and on the manufacturing process.
  • the content of lead is at most 0.1 percent by weight, that the proportion of zinc 40.5 to 46 weight percent and the proportion of copper is at most 59 percent by weight and that the alloy mixed crystal having proportions of both an alpha microstructure and a beta microstructure, wherein the weight fraction of the beta microstructure is at least 30% and at most 70%, and that the proportion of each of the additional alloying components is selected from the group consisting of iron, nickel, tin, manganese and silicon is at most 1.0 weight percent and the sum of the proportions of all of these additional alloy components is at least 0.5 weight percent.
  • a particularly important feature for solving the problem underlying the invention is further that the proportion of elements that are not copper, zinc, iron, nickel, tin, manganese or silicon is less than 0.2 weight percent.
  • each of the mentioned alloying elements in a higher concentration in each case, without thereby increasing the total amount of alloying elements (except copper and zinc).
  • the precipitations contained in the microstructure which are also found in the soft alpha microstructure, support the chipping behavior positively.
  • the alpha microstructure of the mixed crystal forms a cubic surface-centered spatial structure.
  • the beta-mixed crystal forms a cubic body-centered structure.
  • the proportion of the beta structure is at least 50%. This is particularly supported by the fact that a zinc content of about 42 percent by weight is present.
  • the elements iron and nickel have a regulative influence on the grain growth of the alpha and beta phase, with nickel additionally promoting the stabilization of the alpha structure. Too high levels lead to embrittlement of the alloy.
  • the elements tin, silicon, manganese and iron stabilize and increase the proportion of the beta phase.
  • phosphorus may be provided.
  • a maximum proportion of phosphorus in the range of 0.1% by weight is intended.
  • the content of copper is 54 to 59.0% by weight.
  • the proportion of zinc is 40 to 46 weight percent.
  • a first additional alloying component is defined by the proportion of iron being from 0.1 to 0.5 percent by weight. Iron is used to control the grain size of the alpha and beta phases. Contents less than 0.1% do not have a sufficient effect. Shares greater than 0.5% would lead to very large iron precipitates, which have a negative effect on the mechanical properties of the alloy. In particular, it is contemplated that the proportion of iron is 0.2 to 0.3 weight percent.
  • a second additional alloying component is defined by the proportion of nickel being from 0.1 to 0.5 percent by weight. Nickel stabilizes the alpha phase.
  • the proportion of nickel is 0.2 to 0.3 weight percent.
  • An additional optional alloying component is defined by the proportion of silicon being 0.01 to 0.20 percent by weight. Silicon stabilizes the beta phase and together with other elements forms fine precipitates, which have a positive effect on the cutting behavior and are responsible for grain refining. In particular, it is contemplated that the proportion of silicon is 0.03-0.08% by weight.
  • An additional optional alloying component is defined by the proportion of manganese being 0.01 to 0.20 percent by weight.
  • Manganese stabilizes the beta phase and together with other elements forms fine precipitates, which have a positive effect on the cutting behavior and are responsible for grain refining.
  • the proportion of manganese is 0.03 to 0.08 weight percent.
  • a third additional alloying component is defined by the proportion of tin being from 0.1 to 0.5 percent by weight.
  • the proportion of tin is 0.2 to 0.3 weight percent.
  • Phosphor leads to an improved corrosion resistance of the alloy, in particular P also counteracts dezincification.
  • a preferred embodiment of the alloy preferably has the following percentages by weight with respect to its composition. Copper in the range of 54% to 59.5%, zinc in the range of 36% to 40.5%, iron in the range of 0.1% to 0.5%, nickel in the range of 0.1% to 0.5 %, Silicon in the range of 0.01% to 0.2%, manganese in the range of 0.01% to 0.2% and tin in the range of 0.1% to 0.5% and lead with a maximum of 0.1%.
  • the lead content of the alloy is, also due to the use of scrap in the production of such alloys, max. 0.1%.
  • the proportions of copper and / or zinc are optionally reduced.
  • the proportion of copper is 57.0% to 57.5%, the proportion of zinc 41.9 to 42.5, the proportion of nickel 0.2% to 0.3%, the proportion of iron 0.2% to 0.3%, the proportion of silicon 0.03% to 0.08%, the proportion of manganese 0.03% to 0.08% and the proportion of tin 0.2% to 0.3 % and lead content less than 0.1%.
  • the sum of the weight proportions of all other possible components is not more than 0.2%.
  • compositions it is basically possible to add only some of the listed elements to the alloy. According to a very particularly preferred embodiment, however, it is envisaged to add all the above-listed elements with a weight proportion within the respectively defined intervals in combination with one another to the alloy.
  • the lead content is in an interval of 0.01% to 0.1%. Due to the relationship between the alpha-mixed crystal and the beta-mixed crystal according to the invention, the desired material properties can be achieved even with reduced lead contents.
  • the alpha-mixed crystal leads to a relatively good deformability of the alloy and gives this tough properties.
  • the beta-mixed crystal is, however, relatively poorly deformable and brittle. These properties are desirable for good machinability.
  • the relationship of the alpha and beta fractions according to the invention thus gives the alloy sufficient toughness to aid ductility and brittleness to aid machinability.
  • a preferred production process may be carried out by first performing extrusion molding in a temperature range of 600 to 750 ° C. This produces a microstructure which has a proportion of the beta mixed crystal of about 50 percent by weight.
  • an intermediate annealing at a temperature of about 500 to 600 ° C. is carried out after a first forming step.
  • the intermediate annealing leads to a recrystallization and thus to a Kornneu Struktur. As a result, a fine-grained microstructure is supported.
  • the brass alloy of copper and zinc with a lead content of 0.01 to 0.1 percent and with at least one further alloying component.
  • This further alloying component influences the microstructure of the mixed crystal in order to achieve the respective desired material properties depending on the application.
  • This embodiment leads to a particularly high proportion of beta-mixed crystals between 55 and 70% beta-portion, which causes a particularly short-breaking chip.
  • Another preferred embodiment is provided in terms of weight percent by the following alloy.
  • the brass alloy according to the invention serves to produce so-called semi-finished products which are subjected to at least one further processing step.
  • the semi-finished products are typically produced by a casting process. Typical embodiments of such semi-finished products are wires, profiles and / or rods.
  • the further processing step comprises at least one machining operation.
  • the further processing step may comprise a combination of shaping and machining.
  • the shaping can be carried out both at room temperature and at an elevated temperature. At the elevated temperatures, a warm half-temperature can reach up to about 450 ° Celsius and a hot working temperature be distinguished in a range of 600 ° Celsius to 850 ° Celsius.

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  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Conductive Materials (AREA)
  • Contacts (AREA)
  • Secondary Cells (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Claims (12)

  1. Alliage de laiton destiné à une utilisation lors de la fabrication d'un produit semi-fini, qui est prévu pour un usinage, constitué par du cuivre, du zinc et des composants d'alliage supplémentaires, la teneur en plomb étant d'au plus 0,1 pour cent en poids, la proportion de zinc étant de 40,5 à 46 pour cent en poids, et la proportion de cuivre étant d'au moins 54 et d'au plus 59 pour cent en poids, l'alliage contenant en tant que composants d'alliage supplémentaires du fer, du nickel et de l'étain, de telle sorte que la proportion de fer soit de 0,1 à 0,5 pour cent en poids, que la proportion de nickel soit de 0,1 à 0,5 pour cent en poids, que la proportion d'étain soit de 0,1 à 0,5 pour cent en poids, la proportion de chacun des composants d'alliage supplémentaires étant d'au plus 1,0 pour cent en poids, et la somme des proportions de tous les composants d'alliage supplémentaires étant d'au moins 0,5 pour cent en poids, celui-ci présentant un cristal mixte comprenant des fractions aussi bien d'une structure alpha que d'une structure bêta, et la proportion en poids de la structure bêta étant d'au moins 30 % et d'au plus 70 %, et des découpes étant formées dans la structure, et la proportion de substances qui ne sont pas du cuivre, du zinc, du fer, du nickel, du silicium, du manganèse ou de l'étain étant inférieure à 0,2 pour cent en poids, et une proportion optionnelle de silicium étant de 0,01 à 0,20 pour cent en poids, et une proportion optionnelle de manganèse étant de 0,01 à 0,20 pour cent en poids.
  2. Alliage de laiton selon la revendication 1, caractérisé en ce que la proportion de zinc est d'environ 42 pour cent en poids.
  3. Alliage de laiton selon l'une quelconque des revendications 1 ou 2, caractérisé en ce que la proportion de fer est de 0,2 à 0,3 pour cent en poids.
  4. Alliage de laiton selon l'une quelconque des revendications 1 à 3, caractérisé en ce que la proportion de nickel est de 0,2 à 0,3 pour cent en poids.
  5. Alliage de laiton selon l'une quelconque des revendications 1 à 4, caractérisé en ce que la proportion de silicium est de 0,03 à 0,08 pour cent en poids.
  6. Alliage de laiton selon l'une quelconque des revendications 1 à 5, caractérisé en ce que la proportion de manganèse est de 0,03 à 0,08 pour cent en poids.
  7. Alliage de laiton selon l'une quelconque des revendications 1 à 6, caractérisé en ce que la proportion d'étain est de 0,2 à 0,3 pour cent en poids.
  8. Alliage de laiton selon l'une quelconque des revendications 1 à 7, caractérisé en ce que la proportion de la structure bêta est d'au moins 50 pour cent en poids.
  9. Alliage de laiton selon l'une quelconque des revendications 1 à 8, caractérisé en ce que les pourcentages en poids suivants sont réalisés : Cu 55 à 56 %, Fe 0,2 à 0,3 %, Ni 0,1 à 0,2 %, Si 0,01 à 0,03 %, Mn 0,1 à 0,2 %, Sn 0,3 à 0,5 %, le reste étant Zn.
  10. Alliage de laiton selon l'une quelconque des revendications 1 à 9, caractérisé en ce que les pourcentages en poids suivants sont réalisés : Cu 57 à 57,5 %, Fe 0,2 à 0,3 %, Ni 0,2 à 0,3 %, Si 0 %, Mn 0 %, Sn 0,2 à 0,3 %, le reste étant Zn.
  11. Alliage de laiton selon l'une quelconque des revendications 1 à 10, caractérisé en ce que les pourcentages en poids suivants sont réalisés : Cu 56 à 56,5 %, Fe 0,4 à 0,5 %, Ni 0,2 à 0,3 %, Si 0 %, Mn 0,1 à 0,2 %, Sn 0,35 à 0,5 %, le reste étant Zn.
  12. Alliage de laiton selon l'une quelconque des revendications 1 à 11, caractérisé en ce qu'une teneur maximale en phosphore d'environ 0,1 pour cent en poids est contenue.
EP10768172.8A 2009-08-18 2010-08-17 Alliage de laiton Active EP2467507B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10768172T PL2467507T3 (pl) 2009-08-18 2010-08-17 Stop mosiężny

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009038657A DE102009038657A1 (de) 2009-08-18 2009-08-18 Messinglegierung
PCT/DE2010/000976 WO2011020468A1 (fr) 2009-08-18 2010-08-17 Alliage de laiton

Publications (2)

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EP2467507A1 EP2467507A1 (fr) 2012-06-27
EP2467507B1 true EP2467507B1 (fr) 2019-02-27

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Country Status (9)

Country Link
US (1) US20120207642A1 (fr)
EP (1) EP2467507B1 (fr)
DE (2) DE102009038657A1 (fr)
ES (1) ES2724152T3 (fr)
HU (1) HUE043477T2 (fr)
PL (1) PL2467507T3 (fr)
PT (1) PT2467507T (fr)
TR (1) TR201906400T4 (fr)
WO (1) WO2011020468A1 (fr)

Cited By (1)

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EP4124667A1 (fr) 2021-07-27 2023-02-01 Diehl Brass Solutions Stiftung & Co. KG Alliage de laiton sans plomb et antimoine

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DE102011053823A1 (de) 2011-09-21 2013-03-21 Phoenix Contact Gmbh & Co. Kg Klemmkörper für einen elektrischen Leiter
WO2014032635A1 (fr) 2012-08-28 2014-03-06 Heinrich Stamm Gmbh Fil-électrode pour découpage d'objets par électroérosion
US10287653B2 (en) 2013-03-15 2019-05-14 Garrett Transportation I Inc. Brass alloys for use in turbocharger bearing applications
CN104087781B (zh) * 2013-04-01 2016-12-28 台州艾迪西投资有限公司 一种无铋低铅黄铜合金及其制备方法
DE102015212937A1 (de) * 2015-07-10 2017-01-12 Aurubis Stolberg Gmbh & Co. Kg Messinglegierung
DE202016102696U1 (de) * 2016-05-20 2017-08-29 Otto Fuchs - Kommanditgesellschaft - Sondermessinglegierung sowie Sondermessinglegierungsprodukt
DE202018104958U1 (de) 2018-08-30 2018-09-12 Harting Electric Gmbh & Co. Kg Steckverbinder mit Komponenten aus verbessertem Material
LU101955B1 (de) 2020-07-24 2022-01-24 Phoenix Contact Gmbh & Co Verfahren zum Herstellen eines wenigstens abschnittsweise aus einer Messinglegierung gebildeten Kontaktelements sowie ein Kontaktelement
DE102020119603A1 (de) 2020-07-24 2022-01-27 Phoenix Contact Gmbh & Co. Kg Verfahren zum Herstellen eines wenigstens abschnittsweise aus einer Messinglegierung gebildeten Kontaktelements sowie ein Kontaktelement
EP3971312A1 (fr) 2020-09-17 2022-03-23 Société BIC Alliage de laiton pour pointes d'instrument d'écriture
DE102020128955A1 (de) 2020-11-03 2022-05-05 Aurubis Stolberg Gmbh & Co. Kg Messinglegierung
DE102021102120A1 (de) 2021-01-29 2022-08-04 HME Brass Germany GmbH Messinglegierung und Verfahren zum Herstellen eines Halbzeugs aus dieser Messinglegierung

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DE10308779B3 (de) 2003-02-28 2004-11-04 Wieland-Werke Ag Bleifreie Kupferlegierung und deren Verwendung
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CA2662814A1 (fr) 2008-12-02 2009-07-07 Xiamen Lota International Co., Ltd. Alliage de laiton-silicium d'usinage facile sans plomb

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SPIEKERMANN P: "Legierungen - ein besonderes patentrechtliches Problem?", MITTEILUNGEN DER DEUTSCHEN PATENTANWAELTE, HEYMANN, KOLN, DE, vol. 34, 1 January 1993 (1993-01-01), pages 178 - 190, XP002152326, ISSN: 0026-6884 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4124667A1 (fr) 2021-07-27 2023-02-01 Diehl Brass Solutions Stiftung & Co. KG Alliage de laiton sans plomb et antimoine
DE102021119474A1 (de) 2021-07-27 2023-02-02 Diehl Brass Solutions Stiftung & Co. Kg Blei- und Antimonfreie Messinglegierung

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DE112010003316A5 (de) 2012-06-28
PT2467507T (pt) 2019-05-13
DE102009038657A1 (de) 2011-02-24
ES2724152T3 (es) 2019-09-06
TR201906400T4 (tr) 2019-05-21
EP2467507A1 (fr) 2012-06-27
US20120207642A1 (en) 2012-08-16
WO2011020468A1 (fr) 2011-02-24
PL2467507T3 (pl) 2019-08-30

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