EP2302130A1 - Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien - Google Patents

Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien Download PDF

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Publication number
EP2302130A1
EP2302130A1 EP09012250A EP09012250A EP2302130A1 EP 2302130 A1 EP2302130 A1 EP 2302130A1 EP 09012250 A EP09012250 A EP 09012250A EP 09012250 A EP09012250 A EP 09012250A EP 2302130 A1 EP2302130 A1 EP 2302130A1
Authority
EP
European Patent Office
Prior art keywords
component
weight
components
parts
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09012250A
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German (de)
English (en)
French (fr)
Inventor
Andreas Dr. Fuchs
Isabella Rettenbacher
Rolf Dr. Moors
Walter Nassl
Jürgen Arnold
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Textile Effects Germany GmbH
Original Assignee
Huntsman Textile Effects Germany GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Textile Effects Germany GmbH filed Critical Huntsman Textile Effects Germany GmbH
Priority to EP09012250A priority Critical patent/EP2302130A1/de
Priority to EP10812849.7A priority patent/EP2480713B1/en
Priority to CN201410207027.8A priority patent/CN103966855B/zh
Priority to KR1020127003841A priority patent/KR101761096B1/ko
Priority to ES10812849.7T priority patent/ES2438166T3/es
Priority to IN465DEN2012 priority patent/IN2012DN00465A/en
Priority to US13/394,354 priority patent/US8840964B2/en
Priority to BR112012006454A priority patent/BR112012006454B1/pt
Priority to CN201080043192.4A priority patent/CN102549212B/zh
Priority to JP2012530166A priority patent/JP6030957B2/ja
Priority to PCT/EP2010/005812 priority patent/WO2011035906A2/en
Priority to MX2012002194A priority patent/MX2012002194A/es
Publication of EP2302130A1 publication Critical patent/EP2302130A1/de
Priority to US14/464,890 priority patent/US8993067B2/en
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007—After-treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/427—Amino-aldehyde resins modified by alkoxylated compounds or alkylene oxides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

Definitions

  • the invention relates to an aqueous composition which is excellent for the treatment of textile fabrics of fibrous materials such as e.g. Woven, knitted or nonwovens (nonwovens). It further relates to a process for the treatment of the fabrics.
  • fibrous materials such as e.g. Woven, knitted or nonwovens (nonwovens).
  • Such polymers are particularly useful as ingredients of formulations for the oil / water repellent finishing of textile materials.
  • the EP 1493 761 A1 describes compositions in which the chain length of the polymers of the R F group is from 3 to 4 carbon atoms. According to this document, values for the oil- and water-repellent effect can be obtained in the context of the textile finishing, which are approximately at the level which is obtained when using fluoropolymers having a chain length of the R F group of 8 carbon atoms. Despite an ecological advantage, the oil and water repellency effect achieved with the compositions of this EP is not yet fully satisfactory.
  • compositions of WO 2008/022985 A1 also describe perfluoroalkyl-containing polymers in which the R F groups contain less than 8 carbon atoms. These are special polymers, in the preparation of which a thermally crosslinkable or reactive isocyanate is used as the monomer unit. Even with the compositions of this document, no optimal oil and / or water-repellent properties of finished textiles are obtained.
  • the object of the present invention was to provide a composition which brings ecological and cost advantages over known compositions in which the R F groups of the polymers containing perfluoroalkyl groups contain 8 or more carbon atoms and with which at least the level of effect of these known Compositions can be achieved, which relates to oil and water repellent properties of finished textile fiber materials.
  • aqueous composition which contains at least the components A, B and C, wherein
  • Component A is either a mixture containing at least the components A1 to A3, wherein Component A1 is a paraffin wax, Component A2 is a condensation product of an alcohol having 12 to 22 carbon atoms, an etherified, preferably quaternized polymethylol melamine and optionally additionally a polyhydric ethanolamine, which may contain 0.05 to 1.5 wt.% Of an acid, preferably acetic acid, Component A3 is water, or where Component A is a mixture which contains at least the components A4 to A6, where component A4 is a polysiloxane which, in addition to alkyl groups bonded to Si atoms, also contains hydrogen atoms bonded to Si atoms, that is to say an alkyl-hydrogen-polysiloxane, Component A5 is water and Component A6 is a dispersant, preferably an ethoxylated alcohol or a mixture of ethoxylated alcohols, preferably ethoxylated linear or branched alcohol
  • a crucial point in the compositions according to the invention is the length of the chain of R F groups.
  • the maximum of the chain length distribution must be 6 carbon atoms, ie 55 to 100%, preferably 70 to 100%, of the number of all R F groups present must have 6 carbon atoms.
  • Especially good Results are obtained when 100% of all R F groups present contain 6 carbon atoms.
  • the optimum results are obtained when about 100% of the R F groups contain 6 carbon atoms. It is therefore preferred if 70 to 100% of the R F chains contain 6 carbon atoms.
  • Those R F groups which do not contain 6 carbon atoms have for the most part a chain length of 4 or 8 carbon atoms.
  • they are polymers which units of the formula respectively. contain.
  • the polymers may contain other units derived from copolymerizable monomers. Examples of these are: vinyl chloride, vinylidene chloride, styrene, N-methylolacrylamide and fluorine-free long-chain (meth) acrylates such as stearyl acrylate or hydroxy derivatives thereof.
  • Suitable as component C polymers can be prepared in a known manner by reacting (meth) acrylic acid or its esters with alcohols having R F groups, and then polymerized radically, optionally with the concomitant use of other polymerizable monomers.
  • the alcohols containing R F groups have predominantly 6 carbon atoms in the R F group, ie 55 to 100% of all R F groups contain 6 carbon atoms.
  • R F groups preferably fall under the formula where a in the majority of R F radicals has the value 4.
  • Structures of suitable (meth) acrylates and their preparation are in the WO 2009/000370 A1 , of the EP 234 724 A1 as well as the FR 2 213 333 A described.
  • Polymers suitable as component C for compositions according to the invention can be prepared analogously to the statements in these publications, but care must be taken to the chain length of the R F groups.
  • Component A of compositions according to the invention is a mixture, either a mixture containing at least the components A1 to A3, or a mixture containing at least the components A4 to A6.
  • Component A1 is a paraffin wax. Such waxes are available on the market and described by CAS numbers 8002-74-2 and 64742-43-4, respectively. Preferably, waxes are used with a melting range of 50 ° C to 80 ° C.
  • Component A2 is a condensation product which can be obtained by reacting an alcohol having 12 to 22 carbon atoms, preferably a linear monohydric alcohol, with a polymethylol melamine which is etherified and preferably quaternized, on the one hand, and optionally additionally a polyhydric ethanolamine on the other. Particularly suitable is a Hexamethylolmelamin, which is etherified with methanol and quaternized with an alkyl sulfate. This condensation product is formed when the longer-chain alcohol is reacted simultaneously with the melamine and the polyhydric ethanolamine. Diethanolamine and triethanolamine are well suited as ethanolamine.
  • component A2 contains even smaller ones
  • Component A3 is water.
  • Component B of compositions according to the invention is a mixture which contains at least the components B1 to B3.
  • Suitable as component B1 polyurethanes and their preparation are in the EP 872 503 A1 described.
  • Component B2 is a dispersant or a mixture of dispersants.
  • Component B2 contains one or more ethoxylated alcohols based on relatively long-chain, preferably linear, monohydric alcohols, and optionally additionally a divalent aliphatic alcohol and optionally small amounts of an inorganic acid, for example hydrochloric acid.
  • the chain length of the monohydric alcohol on which the ethoxylated alcohol is based is preferably 8 to 22 carbon atoms.
  • the optionally present dihydric alcohol preferably has 2 to 6 carbon atoms.
  • Well suited are ethylene glycol and 1,2-propanediol.
  • Component B3 is water.
  • compositions according to the invention additionally contain, as component D, a zirconium salt, for which purpose zirconium acetate is particularly well suited.
  • compositions according to the invention may also contain other products such as, for example, montan wax acids (CAS No. 68476-03-9), which is particularly suitable when zirconium acetate is present or, in addition to the paraffin already contained in component A, further paraffin.
  • montan wax acids CAS No. 68476-03-9
  • Another product that may optionally be included is an ethoxylated fatty acid derivative (CAS # 61791-12-6).
  • further dispersants may be present, in particular cationic surfactants.
  • compositions according to the invention are normally aqueous dispersions. They can be prepared by known methods, e.g. by mixing the individual components at room temperature or optionally at elevated temperature and subsequent mechanical homogenization.
  • component C is added only shortly before the use of the composition according to the invention.
  • compositions according to the invention are outstandingly suitable for the treatment of textile fabrics of fiber materials, which can thereby be given excellent oil and / or water repellency properties.
  • the fabrics are usually fabric, knitwear or nonwovens. You can u. a. for the production of the following end articles: rainwear and work clothing.
  • the textiles preferably consist of polyamide, polyester or polyester / cotton mixtures.
  • the treatment of the fabrics with compositions according to the invention can be carried out by known methods, e.g. by means of a padding process, wherein the fabrics are dried after the application of the compositions and are usually condensed at a further elevated temperature.
  • compositions according to the invention first only components A and B are mixed with one another and, if appropriate, mechanically homogenized and component C is added just before the use of the composition for textile treatment. Subsequently, the treatment liquor is adjusted to a usual use concentration.
  • Example 1 (according to the invention):
  • Component C used herein is a polyacrylate having R F groups in the alcohol component, with about 100% of all R F groups containing 6 carbon atoms.
  • the component A used each contained a component A1, A2 and A3.
  • Example 2 non-inventive comparative example
  • Example 1 was repeated, except that a different component C (OLEOPHOBOL ® S) was used and in an amount of 14.5 g / l.
  • This component C is also a polyacrylate with R F groups. However, the vast majority of these R F groups contain 8 carbon atoms. The liquor thus obtained is referred to below as F2.
  • a liquor F3 was prepared containing 34 g / l of a component A, 26 g / l of a component B and 9.5 g / l of the same component C as in Example 1.
  • the component A used here contained in each case one component A1, A2, A3, A4 and A6.
  • Example 4 (noninventive comparative example ):
  • Example 3 was repeated except that the same acrylate was used as component C as in Example 2 and in an amount of 7.5 g / l.
  • Each of the liquors F1 to F4 additionally contained 1 g / l of 60% acetic acid.
  • washes 60 ° C with detergent additive of the sample.
  • the washes were carried out according to DIN EN ISO 6330, washing process 2A and drying process E-drum drying.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP09012250A 2009-09-26 2009-09-26 Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien Withdrawn EP2302130A1 (de)

Priority Applications (13)

Application Number Priority Date Filing Date Title
EP09012250A EP2302130A1 (de) 2009-09-26 2009-09-26 Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien
BR112012006454A BR112012006454B1 (pt) 2009-09-26 2010-09-22 composição aquosa repelente de óleo e/ou água, e processo para tratamento de tecidos de material têxtil compostos de materiais de fibra
CN201080043192.4A CN102549212B (zh) 2009-09-26 2010-09-22 用于纤维材料的防油和/或防水整理的组合物
KR1020127003841A KR101761096B1 (ko) 2009-09-26 2010-09-22 섬유 재료의 발유 및／또는 발수 가공용 조성물
ES10812849.7T ES2438166T3 (es) 2009-09-26 2010-09-22 Composición para acabado repelente al aceite y/o al agua de materiales de fibra
IN465DEN2012 IN2012DN00465A (OSRAM) 2009-09-26 2010-09-22
US13/394,354 US8840964B2 (en) 2009-09-26 2010-09-22 Composition for oil- and/or water-repellent finishing of fiber materials
EP10812849.7A EP2480713B1 (en) 2009-09-26 2010-09-22 Composition for oil- and/or water-repellent finishing of fiber materials
CN201410207027.8A CN103966855B (zh) 2009-09-26 2010-09-22 用于纤维材料的防油和/或防水整理的组合物
JP2012530166A JP6030957B2 (ja) 2009-09-26 2010-09-22 繊維材料の撥油及び／又は撥水加工用組成物
PCT/EP2010/005812 WO2011035906A2 (en) 2009-09-26 2010-09-22 Composition for oil- and/or water-repellent finishing of fiber materials
MX2012002194A MX2012002194A (es) 2009-09-26 2010-09-22 Composicion para acabado repelente al aceite y/o al agua en materiales de fibras.
US14/464,890 US8993067B2 (en) 2009-09-26 2014-08-21 Composition for oil- and/or water-repellent finishing of fiber materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP09012250A EP2302130A1 (de) 2009-09-26 2009-09-26 Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien

Publications (1)

Publication Number Publication Date
EP2302130A1 true EP2302130A1 (de) 2011-03-30

Family

ID=41682877

Family Applications (2)

Application Number Title Priority Date Filing Date
EP09012250A Withdrawn EP2302130A1 (de) 2009-09-26 2009-09-26 Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien
EP10812849.7A Active EP2480713B1 (en) 2009-09-26 2010-09-22 Composition for oil- and/or water-repellent finishing of fiber materials

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP10812849.7A Active EP2480713B1 (en) 2009-09-26 2010-09-22 Composition for oil- and/or water-repellent finishing of fiber materials

Country Status (10)

Country Link
US (2) US8840964B2 (OSRAM)
EP (2) EP2302130A1 (OSRAM)
JP (1) JP6030957B2 (OSRAM)
KR (1) KR101761096B1 (OSRAM)
CN (2) CN102549212B (OSRAM)
BR (1) BR112012006454B1 (OSRAM)
ES (1) ES2438166T3 (OSRAM)
IN (1) IN2012DN00465A (OSRAM)
MX (1) MX2012002194A (OSRAM)
WO (1) WO2011035906A2 (OSRAM)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013083110A1 (de) * 2011-12-05 2013-06-13 Guido Radde Imprägnierflüssigkeit zum wasserabweisendmachen von papierartigem material und textilen flächengebilde und die verwendung desselben
CN103469586A (zh) * 2013-08-21 2013-12-25 昆山铁牛衬衫厂 防水透气面料的制备方法
WO2014184097A1 (de) * 2013-05-17 2014-11-20 Cht R. Beitlich Gmbh Wasserabweisende effekte auf textilen oberflächen

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101910682B1 (ko) * 2011-04-25 2018-10-22 에이지씨 가부시키가이샤 발수발유제 조성물, 그 제조 방법 및 물품
CN102965925A (zh) * 2012-11-20 2013-03-13 吴江市新丝源纺织有限公司 一种防水涂层面料
US8952420B1 (en) 2013-07-29 2015-02-10 Stmicroelectronics, Inc. Method to induce strain in 3-D microfabricated structures
US9099559B2 (en) 2013-09-16 2015-08-04 Stmicroelectronics, Inc. Method to induce strain in finFET channels from an adjacent region
CN103628324A (zh) * 2013-12-02 2014-03-12 广东德美精细化工股份有限公司 无氟防水剂及其制备方法、纺织品
KR101514370B1 (ko) * 2014-07-30 2015-04-23 이영선 발수발유제 제조방법
JP6932081B2 (ja) * 2015-02-13 2021-09-08 スリーエム イノベイティブ プロパティズ カンパニー イソシアネートから誘導された（メタ）アクリレート含有ポリマー化合物を含む、フッ素非含有組成物を使用して繊維基材を処理するための方法
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