EP2236307B1 - Herstellung von Transferpapier für den Tintenstrahldruck - Google Patents
Herstellung von Transferpapier für den Tintenstrahldruck Download PDFInfo
- Publication number
- EP2236307B1 EP2236307B1 EP09004614A EP09004614A EP2236307B1 EP 2236307 B1 EP2236307 B1 EP 2236307B1 EP 09004614 A EP09004614 A EP 09004614A EP 09004614 A EP09004614 A EP 09004614A EP 2236307 B1 EP2236307 B1 EP 2236307B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- paper
- transfer paper
- printed
- ammonium polyacrylate
- aqueous fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000007641 inkjet printing Methods 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 25
- 229920000058 polyacrylate Polymers 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 15
- 238000007639 printing Methods 0.000 claims description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 7
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 238000010020 roller printing Methods 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 10
- 239000007788 liquid Substances 0.000 description 30
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000004753 textile Substances 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920001477 hydrophilic polymer Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 2
- 238000010023 transfer printing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0355—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Definitions
- the present invention relates to a process for producing transfer papers, transfer papers produced by the process and transfer printing processes.
- Transfer printing refers to the printing of different materials, such as textiles, using transfer papers. Transfer papers are coated with pigments, which are then transferred to the printable materials by sublimation using a thermal transfer press.
- WO 00/06392 discloses a transfer paper, in particular for inkjet printing, which is provided at least on the side to be printed with a release or barrier layer, wherein the layer has a porosity of at most 100 ml / min.
- US 2001/031344 discloses a method of making transfer paper by applying ink to a receptor.
- transfer papers A disadvantage often encountered with known transfer papers is that the e.g. smeared by ink jet printing applied pigments. This problem occurs even with the use of transfer papers coated with hydrophilic polymers such as carboxymethylcellulose prior to application of the pigment layer.
- the starting material used for the preparation of the transfer paper is a common paper, for example white or unbleached paper, with a weight of usually 60-140 g, in particular 80-120 g per m 2 of paper.
- the front side to be printed i. the side which is subsequently coated with pigments is contacted with a first aqueous liquid containing ammonium polyacrylate.
- the ammonium polyacrylate used for coating usually has a weight-average molecular weight of 500 Da or more, e.g. 1000-5000 Da and in particular 1000-2000 Da.
- the first aqueous liquid preferably contains ammonium polyacrylate in a proportion of 10-50% by weight, in particular in a proportion of 20-40% by weight, based on the total weight of the liquid.
- the first aqueous liquid may be prepared by conventional methods, e.g. by means of a doctor such as a doctor blade or a roller blade, or by spraying. After application, the paper is usually heated at elevated temperature, e.g. 40-80 ° C, dried.
- Step (b) preferably comprises applying a second aqueous liquid to the back of the paper and then drying.
- the second aqueous liquid contains a hydrophilic organic polymer, in particular ammonium polyacrylate.
- the second aqueous liquid preferably contains ammonium polyacrylate or another organic polymer in a proportion of 5 to 30% by weight, in particular in a proportion of 10 to 20% by weight, based on the total weight of the liquid.
- the application of the second liquid and The subsequent drying can be carried out by known methods as in the case of the first liquid.
- the first and optionally the second aqueous liquid are usually applied in an amount of 10-40 g, in particular 15-25 g per m 2 of paper, and in some embodiments, higher or lower amounts can be applied. It is further preferred that the ammonium polyacrylate is applied in an amount of 1-25 g, in particular 2-20 g dry weight on the front side of the paper. On the back side, the ammonium polyacrylate (or another hydrophilic polymer) is preferably applied in an amount of 0.5-15 g, in particular 1-10 g dry weight.
- the first aqueous liquid and optionally also the second aqueous liquid may have a neutral to alkaline pH, e.g. have a pH ⁇ 7, for example ⁇ 9.
- the remainder of the liquid is preferably water.
- the proportion of water in the first liquid is preferably ⁇ 50 wt .-%, in particular ⁇ 70 wt .-%.
- Organic volatile solvents are preferably absent.
- colloidal SiO 2 10-30% by weight NaOH 0.1-0.5% by weight ammonium polyacrylate 20-40% by weight Balance H 2 O
- a preferred example of an aqueous liquid for coating the paper back is as follows: ammonium polyacrylate 10-20% by weight Balance H 2 O
- Another aspect of the invention is the use of an aqueous liquid containing ammonium polyacrylate for the production of transfer paper, in particular for ink-jet printing.
- the aqueous liquid can be used to coat the front and / or back of transfer paper as previously described.
- Yet another aspect of the present invention is a transfer paper, especially for ink jet printing, on the front side to be printed and optionally on the back with ammonium polyacrylate, in particular in the amounts given above, for example in an amount of 1-25 g per m 2 paper on the front and eg 0.5-15 g per m 2 of paper on the back, is coated.
- the coating in particular the coating of the front side, may additionally contain additives as indicated above.
- Yet another aspect of the invention is a process for printing transfer paper comprising applying a layer of sublimable pigments to the front side of a transfer paper as previously described, e.g. by ink jet printing, applying.
- the pigments can be used in conventional printing inks with common equipment, e.g. Inkjet printers are applied by known methods. After application, the printed transfer paper is dried at room temperature or at elevated temperature up to 80 ° C. Surprisingly, it was found that the pigments show no tendency to smear during application and drying.
- the printed transfer paper can be used in a known manner for printing on objects, in particular textiles.
- Yet another aspect of the present invention is thus a printed transfer paper for printing on objects, in particular textiles, which is coated on the front with sublimable pigments and ammonium polyacrylate.
- the textiles to be printed are usually uncoloured or white.
- pre-dyed textiles can be used. These are usually textiles containing a share of contain at least 50-60 wt.% Polyester and / or polyamide fibers, or which are coated with polyester and / or polyamide.
- stretchable textiles can also be coated without smearing with the transfer paper according to the invention.
- a first coating liquid is advantageously used, which contains in addition to the ammonium polyacrylate, a polyhydric alcohol, such as glycerol, and / or a cellulose derivative, such as carboxymethyl cellulose.
- the paper coated with such a liquid adheres to the material to be printed upon heating, so that the ink transfer of paper to the material to be printed by conventional roller printing without smearing the pigments is possible.
- Yet another object of the invention is thus a method for printing objects, in particular textiles, characterized in that one brings the object to be printed with a printed transfer paper as described above at elevated temperature, for example 160-240 ° C, in contact that sublimable pigments are transferred from the transfer paper to the object to be printed.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Paper (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Decoration By Transfer Pictures (AREA)
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09004614A EP2236307B1 (de) | 2009-03-30 | 2009-03-30 | Herstellung von Transferpapier für den Tintenstrahldruck |
ES09004614T ES2391803T3 (es) | 2009-03-30 | 2009-03-30 | Producción de papel de transferencia para la impresión por chorro de tinta |
SI200930364T SI2236307T1 (sl) | 2009-03-30 | 2009-03-30 | Izdelava transfernega papirja za brizgalni tisk |
PL09004614T PL2236307T3 (pl) | 2009-03-30 | 2009-03-30 | Wytwarzanie papieru przedrukowego do atramentowego druku strumieniowego |
RS20120454A RS52506B (en) | 2009-03-30 | 2009-03-30 | MANUFACTURE OF PAPER INK-JET PRINTING PAPER |
PT09004614T PT2236307E (pt) | 2009-03-30 | 2009-03-30 | Produção de papel de transferência para a impressão por jato de tinta |
DK09004614.5T DK2236307T3 (da) | 2009-03-30 | 2009-03-30 | Fremstilling af transferpapir til inkjetprintning |
US13/262,290 US20120160119A1 (en) | 2009-03-30 | 2010-03-30 | Production of transfer paper for ink-jet printing |
PCT/EP2010/054204 WO2010112507A1 (de) | 2009-03-30 | 2010-03-30 | Herstellung von transferpapier für den tintenstrahldruck |
CA2757235A CA2757235A1 (en) | 2009-03-30 | 2010-03-30 | Production of transfer paper for ink-jet printing |
AU2010230208A AU2010230208A1 (en) | 2009-03-30 | 2010-03-30 | Production of transfer paper for ink-jet printing |
JP2012502638A JP2012521909A (ja) | 2009-03-30 | 2010-03-30 | インクジェット印刷用の転写紙の製造 |
CN2010800224695A CN102448731A (zh) | 2009-03-30 | 2010-03-30 | 喷墨印刷用转印纸的制备 |
CY20121100969T CY1113213T1 (el) | 2009-03-30 | 2012-10-17 | Παρασκευη χαρτιου μεταφορας για την εκτυπωση με εγχυση μελανης |
HRP20120838AT HRP20120838T1 (hr) | 2009-03-30 | 2012-10-18 | Proizvodnja transfer papira za ispis tintom |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09004614A EP2236307B1 (de) | 2009-03-30 | 2009-03-30 | Herstellung von Transferpapier für den Tintenstrahldruck |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2236307A1 EP2236307A1 (de) | 2010-10-06 |
EP2236307B1 true EP2236307B1 (de) | 2012-07-18 |
Family
ID=40996697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09004614A Active EP2236307B1 (de) | 2009-03-30 | 2009-03-30 | Herstellung von Transferpapier für den Tintenstrahldruck |
Country Status (15)
Country | Link |
---|---|
US (1) | US20120160119A1 (pt) |
EP (1) | EP2236307B1 (pt) |
JP (1) | JP2012521909A (pt) |
CN (1) | CN102448731A (pt) |
AU (1) | AU2010230208A1 (pt) |
CA (1) | CA2757235A1 (pt) |
CY (1) | CY1113213T1 (pt) |
DK (1) | DK2236307T3 (pt) |
ES (1) | ES2391803T3 (pt) |
HR (1) | HRP20120838T1 (pt) |
PL (1) | PL2236307T3 (pt) |
PT (1) | PT2236307E (pt) |
RS (1) | RS52506B (pt) |
SI (1) | SI2236307T1 (pt) |
WO (1) | WO2010112507A1 (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2743091A1 (en) * | 2012-12-17 | 2014-06-18 | Martinovic Zvonimir | Improved transfer medium |
US9376584B2 (en) * | 2013-09-20 | 2016-06-28 | Xerox Corporation | Coating for aqueous inkjet transfer |
DE102014116550A1 (de) * | 2014-11-12 | 2016-05-12 | Papierfabrik August Koehler Se | Thermosublimationspapier |
CN105711280A (zh) | 2014-12-04 | 2016-06-29 | 全斯福新材料(苏州)有限公司 | 一种易用的喷墨热升华转印纸 |
WO2018061376A1 (ja) * | 2016-09-29 | 2018-04-05 | 三菱製紙株式会社 | 転写用紙 |
EP3521508B1 (en) | 2016-09-29 | 2021-09-01 | Mitsubishi Paper Mills Limited | Transfer paper |
WO2020104307A1 (en) | 2018-11-19 | 2020-05-28 | Kaspar Papir Pte Ltd | Light-stabilizing transfer medium |
EP3653393A1 (en) | 2018-11-19 | 2020-05-20 | Kaspar Papir Pte Ltd | Light-stabilizing transfer medium |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2675864B2 (ja) * | 1988-07-05 | 1997-11-12 | キヤノン株式会社 | 被記録材及びこれを用いたインクジェット記録方法 |
US5039598A (en) * | 1989-12-29 | 1991-08-13 | Xerox Corporation | Ionographic imaging system |
ES2171734T3 (es) * | 1995-11-13 | 2002-09-16 | Kimberly Clark Co | Recubrimiento receptor de imagenes. |
JPH09175001A (ja) * | 1995-12-28 | 1997-07-08 | Toyo Ink Mfg Co Ltd | インクジェット用記録媒体 |
US5798179A (en) * | 1996-07-23 | 1998-08-25 | Kimberly-Clark Worldwide, Inc. | Printable heat transfer material having cold release properties |
JPH1058638A (ja) * | 1996-08-22 | 1998-03-03 | Olympus Optical Co Ltd | 昇華転写捺染方法 |
US6022440A (en) | 1997-12-08 | 2000-02-08 | Imation Corp. | Image transfer process for ink-jet generated images |
IL141019A (en) | 1998-07-29 | 2004-09-27 | Sanders W A Papier | Transfer paper for ink-jet printing |
JP2002059693A (ja) * | 2000-08-21 | 2002-02-26 | Mikuni Color Ltd | インクジェット記録用感圧転写材 |
US6936316B2 (en) * | 2002-12-09 | 2005-08-30 | Asutosh Nigam | Ink-jet recording medium with an opaque or semi-opaque layer coated thereon, method for recording an image, and a recorded medium with at least one layer rendered clear or semi-opaque |
JP2004255717A (ja) * | 2003-02-26 | 2004-09-16 | Mitsubishi Paper Mills Ltd | 昇華インク転写用インクジェット被記録媒体およびその製造方法と転写記録方法 |
JP2007118532A (ja) * | 2005-10-31 | 2007-05-17 | Mitsubishi Paper Mills Ltd | 昇華インク転写用インクジェット記録媒体及び転写記録方法 |
JP2007178669A (ja) * | 2005-12-27 | 2007-07-12 | Sharp Corp | トナーの製造方法 |
US20080008864A1 (en) * | 2006-07-04 | 2008-01-10 | Yoshikatsu Itoh | Colored leather product and manufacturing method thereof |
-
2009
- 2009-03-30 SI SI200930364T patent/SI2236307T1/sl unknown
- 2009-03-30 DK DK09004614.5T patent/DK2236307T3/da active
- 2009-03-30 PT PT09004614T patent/PT2236307E/pt unknown
- 2009-03-30 EP EP09004614A patent/EP2236307B1/de active Active
- 2009-03-30 RS RS20120454A patent/RS52506B/en unknown
- 2009-03-30 PL PL09004614T patent/PL2236307T3/pl unknown
- 2009-03-30 ES ES09004614T patent/ES2391803T3/es active Active
-
2010
- 2010-03-30 CA CA2757235A patent/CA2757235A1/en not_active Abandoned
- 2010-03-30 WO PCT/EP2010/054204 patent/WO2010112507A1/de active Application Filing
- 2010-03-30 AU AU2010230208A patent/AU2010230208A1/en not_active Abandoned
- 2010-03-30 JP JP2012502638A patent/JP2012521909A/ja active Pending
- 2010-03-30 US US13/262,290 patent/US20120160119A1/en not_active Abandoned
- 2010-03-30 CN CN2010800224695A patent/CN102448731A/zh active Pending
-
2012
- 2012-10-17 CY CY20121100969T patent/CY1113213T1/el unknown
- 2012-10-18 HR HRP20120838AT patent/HRP20120838T1/hr unknown
Also Published As
Publication number | Publication date |
---|---|
ES2391803T3 (es) | 2012-11-30 |
DK2236307T3 (da) | 2012-10-29 |
EP2236307A1 (de) | 2010-10-06 |
HRP20120838T1 (hr) | 2012-11-30 |
CY1113213T1 (el) | 2016-04-13 |
CN102448731A (zh) | 2012-05-09 |
RS52506B (en) | 2013-04-30 |
PL2236307T3 (pl) | 2013-01-31 |
SI2236307T1 (sl) | 2012-12-31 |
US20120160119A1 (en) | 2012-06-28 |
JP2012521909A (ja) | 2012-09-20 |
PT2236307E (pt) | 2012-10-25 |
WO2010112507A1 (de) | 2010-10-07 |
AU2010230208A1 (en) | 2011-11-17 |
CA2757235A1 (en) | 2010-10-07 |
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