EP2067871A1 - Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication - Google Patents

Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication Download PDF

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Publication number
EP2067871A1
EP2067871A1 EP07023245A EP07023245A EP2067871A1 EP 2067871 A1 EP2067871 A1 EP 2067871A1 EP 07023245 A EP07023245 A EP 07023245A EP 07023245 A EP07023245 A EP 07023245A EP 2067871 A1 EP2067871 A1 EP 2067871A1
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EP
European Patent Office
Prior art keywords
aluminum
strip
aluminum strip
rolled
printing plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07023245A
Other languages
German (de)
English (en)
Other versions
EP2067871B1 (fr
EP2067871B2 (fr
Inventor
Bernhard Kernig
Henk-Jan Brinkman
Jochen Hasenclever
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Speira GmbH
Original Assignee
Hydro Aluminium Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Hydro Aluminium Deutschland GmbH filed Critical Hydro Aluminium Deutschland GmbH
Priority to SI200731221T priority Critical patent/SI2067871T2/sl
Priority to ES07023245T priority patent/ES2407655T5/es
Priority to EP07023245.9A priority patent/EP2067871B2/fr
Priority to CN2008801185883A priority patent/CN101883876A/zh
Priority to BRPI0819596A priority patent/BRPI0819596B8/pt
Priority to ES08853549.7T priority patent/ES2456269T3/es
Priority to EP08853549.7A priority patent/EP2220262B1/fr
Priority to DE202008018332U priority patent/DE202008018332U1/de
Priority to PCT/EP2008/066086 priority patent/WO2009068502A1/fr
Priority to JP2010535350A priority patent/JP5319693B2/ja
Publication of EP2067871A1 publication Critical patent/EP2067871A1/fr
Publication of EP2067871B1 publication Critical patent/EP2067871B1/fr
Priority to US15/494,285 priority patent/US11326232B2/en
Publication of EP2067871B2 publication Critical patent/EP2067871B2/fr
Application granted granted Critical
Active legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
    • B41N1/00—Printing plates or foils; Materials therefor
    • B41N1/04—Printing plates or foils; Materials therefor metallic
    • B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
    • B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12431—Foil or filament smaller than 6 mils

Definitions

  • the invention relates to a process for the production of aluminum strips for lithographic printing plate supports, wherein the aluminum strip is produced from a rolling bar, which after an optional homogenization hot rolled to a thickness of 2 mm to 7 mm and to a final thickness of 0.15 mm to 0.5 mm cold rolled.
  • the invention relates to a correspondingly produced aluminum strip having a thickness of 0.15 mm to 0.5 mm and a pressure plate carrier made of the aluminum strip according to the invention.
  • the aluminum strip for the production of lithographic printing plate supports is usually subjected to an electrochemical roughening, which should result in a blanket roughening and a structureless appearance without streaking effects.
  • the roughened structure is important for applying a photosensitive layer, which is subsequently exposed.
  • the photo-layer is baked at temperatures of 220 ° C to 300 ° C and annealing times of 3 to 10 minutes, typical combinations of burn-in times being for example 240 ° C at 10 minutes, 260 ° C at 6 minutes and 260 ° C for 4 minutes.
  • the pressure plate carrier must after burning as possible lose little strength, so that it is still easy to handle and can be easily clamped in a printing device.
  • the printing plate support and thus also the correspondingly produced aluminum strip must have the highest possible flexural fatigue strength, so that plate outlier can be virtually eliminated due to mechanical stresses on the printing plate. So far, these requirements have been well met with conventional aluminum strips.
  • the handling of large lithographic printing plate supports becomes more difficult with increasing size and consistent strength values.
  • the present invention has the object to provide a method for producing an aluminum strip for lithographic printing plate support and a corresponding aluminum band available, the coil set is easy to correct in hard-rolling condition and from which also oversized printing plate support can be produced, the easy to handle and only show a low tendency to plate tears.
  • the above-described object is procedurally achieved in that the aluminum strip consists of an aluminum alloy with the following alloy constituents in percent by weight: 0 . 3 % ⁇ Fe ⁇ 0 . 4 % . 0 . 2 % ⁇ mg ⁇ 0 . 6 % . 0 . 05 % ⁇ Si ⁇ 0 . 25 % . Mn ⁇ 0 . 05 % . Cu ⁇ 0 . 04 % .
  • Residual Al and unavoidable impurities individually max. 0.05%, in total max. 0.15%, during the cold rolling an intermediate annealing is carried out at a thickness of 1.5 mm to 0.5 mm, the aluminum strip is then rolled by cold rolling to a final thickness of 0.15 mm to 0.5 mm and for further processing to one lithographic printing plate support is rolled up in hard-rolled condition.
  • the aluminum strip produced according to the invention can provide a moderate increase in strength together with a very high bending fatigue resistance and at the same time very good thermal stability. Coilset corrections are possible without difficulty due to the moderate increase in strength. At the same time, however, the handling of the printing plate even in a baked state, for example when clamping in the printing press, is simple, since a good thermal stability of the aluminum strip is obtained by the method according to the invention. If the aluminum strip is used for the production of very large lithographic printing plate supports, preferably the aluminum strip is cold rolled to a final thickness of 0.25 to 0.5 mm after the intermediate annealing.
  • the properties according to the invention can be achieved particularly reliably by the fact that the aluminum alloy additionally has a titanium (Ti) content of max. 0.05% by weight, preferably max. 0.015 wt .-%, a zinc (Zn) content of max. 0.05 wt .-% and a chromium (Cr) content of less than 100 ppm, preferably a Cr content of max. 50 ppm.
  • Ti titanium
  • Zn zinc
  • Cr chromium
  • Chromium is recrystallization inhibiting and should therefore only in very small proportions of less than 100 ppm, preferably of max. 50 ppm contained in the aluminum alloy.
  • the aluminum alloy according to a next aspect of the present invention has an Mg content of 0.25 wt% to 0.6 wt%, preferably 0.25 to 0.4 wt%, maximum strengths at high Bending fatigue resistance can be provided. Higher Mg contents make it possible to further reduce the degrees of finish after the intermediate annealing, while at the same time maintaining or increasing the tensile strength values, in particular also transversely to the rolling direction.
  • the hot strip end temperature is 280 ° C to 350 ° C, a continuous recrystallization of the surface is achieved during hot rolling, which, for example, a good roughening of the wall surface during the production of lithographic Pressure plate carrier guaranteed.
  • the metal temperature of the aluminum strip is 200 ° C to 450 ° C.
  • the aluminum strip is then held at the metal temperature for at least one to two hours. This is usually done in batch ovens. Due to the intermediate annealing in the temperature range mentioned, the further processing of the aluminum strip can take place either in a recovered or recrystallized state or a combination of both.
  • the recrystallization starts at temperatures of about 300 to 350 ° C, which depends on the manufacturing parameters, in particular the introduced solidifications.
  • a regeneration annealing at lower temperatures merely results in a reduction of the solidifications, so that very low degrees of reduction after recovery annealing are possible.
  • a generic aluminum strip for the production of lithographic printing plate supports which consists of an aluminum alloy with the following alloy constituents in wt .-%: 0 . 3 % ⁇ Fe ⁇ 0 . 4 % . 0 . 2 % ⁇ mg ⁇ 0 . 6 % . 0 . 05 % ⁇ Si ⁇ 0 . 25 % . Mn ⁇ 0 . 05 % . Cu ⁇ 0 . 04 % .
  • the aluminum strip has a tensile strength of up to 200 MPa in hard-rolled condition along the rolling direction and after baking at a temperature of 240 ° C and a duration of 10 minutes of at least 145 MPa, as well as a bending resistance transverse to the rolling direction of at least 1850 cycles in the bending cycle test.
  • the aluminum strips according to the invention achieve bending cycle cycles of more than 1850, also transverse to the rolling direction, which means an increase of more than 70% compared with the standard alloys used hitherto. Due to the moderate increase in tensile strength measured to values up to 200 MPa in hard-rolling condition along the rolling direction, the coil set of the aluminum strip according to the invention can be further corrected in a simple manner.
  • the handling of the lithographic printing plate carrier produced from the aluminum strip is also good after a baking process. Even with very large lithographic printing plate supports can be facilitated by the increased strength after baking, the handling of the printing plates.
  • the high number of possible bending cycle cycles greater than 1850 both in the hard as well as in the baked state of the aluminum strip according to the invention that the tendency to As a result of mechanical stresses, plate cracks are small in the case of lithographic printing plate supports clamped transversely or longitudinally to the rolling direction.
  • the properties of the finished aluminum strip are thereby achieved process reliable, that the aluminum alloy has a Ti content of max. 0.05% by weight, preferably max. 0.015 wt .-%, a Zn content of max. 0.05 wt .-% and a Cr content of less than 100 ppm, preferably of max. 10 ppm.
  • the object indicated above is achieved by pressure plate carriers which are produced from an aluminum strip according to the invention.
  • the advantages of the pressure plate carrier according to the invention is based on the above statements on the method for producing a Referenced aluminum strip and the aluminum strip according to the invention.
  • Table 1 shows only the essential alloying constituents of the aluminum tapes tested, moreover, the various experimental alloys had a Ti content of less than 0.015 wt%, a Zn content of less than 0.05 wt%, and a Cr content of less than 100 ppm.
  • the ingots cast from the various aluminum alloys have been subjected to homogenization prior to rolling, the ingots being annealed to a temperature of about 580 ° C for more than four hours. Subsequently, the hot rolling was carried out at temperatures of 250 ° C to 550 ° C, the hot strip end temperature was between 280 ° C and 350 ° C.
  • the VRef alloy aluminum hot strip was subjected to intermediate annealing during cold rolling at a thickness of 2 to 2.4 mm, with the cold rolled strip being exposed to a temperature of 300 to 450 ° C for one to two hours.
  • the intermediate annealed ribbons continue to final thickness were cold-rolled without a final final annealing, they were rolled up in the state hard-rolling. Tab. 2 Leg.-Nr.
  • the correspondingly produced aluminum strips for lithographic printing plate supports or litho tapes were subjected to further tests. All four aluminum bands are characterized by a very good roughening behavior.
  • the tensile strength in the hard-rolled state was investigated. In order to test the practical handling of the printing plates, especially for oversized lithographic printing plates, tensile strengths were measured even after a baking process of 240 ° C for 10 minutes. In addition, a bending change test was carried out in which the in Fig. 1 schematically illustrated experimental design was used.
  • Fig. 1a shows in a schematic sectional view of the structure of the bending change test device 1 used, which was used to investigate the flexural fatigue resistance of the aluminum strips according to the invention.
  • Samples 2 made of the produced aluminum strips for lithographic printing plate supports are in a movable bending tester 1 on a movable Segment 3 and a fixed segment 4 attached. The segment is reciprocated on the fixed segment 4 by a rolling motion in the bending change test, so that the sample 2 is subjected to bends perpendicular to the extension of the sample 2.
  • the different bending states shows schematically Fig. 1b ). Samples 2 were cut either longitudinally or transversely to the rolling direction from the prepared aluminum platens for lithographic printing plate supports.
  • the radius of the segments 3,4 was 30 mm.
  • the conventional aluminum strip has a tensile strength which is sufficient for the correction of the coil set prior to the stoving process and for the handling of the lithographic printing plate support after the stoving process as well as a sufficient resistance to flexing along the rolling direction.
  • the conventionally manufactured aluminum strip reached only 1500 bending cycles transverse to the rolling direction.
  • the aluminum strips V582, V581 according to the invention show very good tensile strengths with regard to coil set correction and handling of the printing plate after a baking process as well as a very high bending fatigue resistance. Up to 78% higher number of bending cycles were achieved, alloy V582.
  • the comparative aluminum tape V580 also showed good values with respect to flexural fatigue resistance.
  • the very high tensile strengths of 218 and 228 MPa respectively longitudinal and transverse to the rolling direction, make it difficult to correct the coil set prior to baking the photo-layer of the lithographic printing plate supports.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Printing Plates And Materials Therefor (AREA)
  • Metal Rolling (AREA)
EP07023245.9A 2007-11-30 2007-11-30 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication Active EP2067871B2 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
SI200731221T SI2067871T2 (sl) 2007-11-30 2007-11-30 Aluminijev trak za litografske nosilce tiskarskih plošč in njegova izdelava
ES07023245T ES2407655T5 (es) 2007-11-30 2007-11-30 Banda de aluminio para soportes para planchas de impresión litográfica y su producción
EP07023245.9A EP2067871B2 (fr) 2007-11-30 2007-11-30 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication
ES08853549.7T ES2456269T3 (es) 2007-11-30 2008-11-24 Banda de aluminio para soportes para planchas de impresión litográfica y su producción
JP2010535350A JP5319693B2 (ja) 2007-11-30 2008-11-24 リソグラフ印刷プレート支持体用のアルミニウムストリップ及びその製造
BRPI0819596A BRPI0819596B8 (pt) 2007-11-30 2008-11-24 Método para produção de tiras de alumínio para suportes de clichês litográficos
CN2008801185883A CN101883876A (zh) 2007-11-30 2008-11-24 用于石板印刷印版载体的铝带及其制造
EP08853549.7A EP2220262B1 (fr) 2007-11-30 2008-11-24 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication
DE202008018332U DE202008018332U1 (de) 2007-11-30 2008-11-24 Aluminiumband für lithografische Druckplattenträger und dessen Herstellung
PCT/EP2008/066086 WO2009068502A1 (fr) 2007-11-30 2008-11-24 Feuillard d'aluminium pour supports de plaques d'impression lithographique et sa fabrication
US15/494,285 US11326232B2 (en) 2007-11-30 2017-04-21 Aluminum strip for lithographic printing plate carriers and the production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP07023245.9A EP2067871B2 (fr) 2007-11-30 2007-11-30 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication

Publications (3)

Publication Number Publication Date
EP2067871A1 true EP2067871A1 (fr) 2009-06-10
EP2067871B1 EP2067871B1 (fr) 2013-02-20
EP2067871B2 EP2067871B2 (fr) 2022-10-19

Family

ID=39400918

Family Applications (2)

Application Number Title Priority Date Filing Date
EP07023245.9A Active EP2067871B2 (fr) 2007-11-30 2007-11-30 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication
EP08853549.7A Revoked EP2220262B1 (fr) 2007-11-30 2008-11-24 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP08853549.7A Revoked EP2220262B1 (fr) 2007-11-30 2008-11-24 Bande d'aluminium pour supports de plaques d'impression lithographiques et sa fabrication

Country Status (9)

Country Link
US (1) US11326232B2 (fr)
EP (2) EP2067871B2 (fr)
JP (1) JP5319693B2 (fr)
CN (1) CN101883876A (fr)
BR (1) BRPI0819596B8 (fr)
DE (1) DE202008018332U1 (fr)
ES (2) ES2407655T5 (fr)
SI (1) SI2067871T2 (fr)
WO (1) WO2009068502A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012059362A1 (fr) 2010-11-04 2012-05-10 Novelis Inc. Feuille lithographique d'aluminium
US9914318B2 (en) 2005-10-19 2018-03-13 Hydro Aluminium Deutschland Gmbh Aluminum strip for lithographic printing plate supports
US10927437B2 (en) 2008-11-21 2021-02-23 Hydro Aluminium Deutschland Gmbh Aluminium strip for lithographic printing plate supports with high flexural fatigue strength
US11326232B2 (en) 2007-11-30 2022-05-10 Hydro Aluminium Deutschland Gmbh Aluminum strip for lithographic printing plate carriers and the production thereof
CN114729413A (zh) * 2019-11-12 2022-07-08 斯佩拉有限公司 经调节的箔材热处理
CN116635548A (zh) * 2020-12-18 2023-08-22 斯佩拉有限公司 具有改善的阻隔性的铝箔

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2495106B1 (fr) * 2011-03-02 2015-05-13 Hydro Aluminium Rolled Products GmbH Bande en aluminium pour support de plaques d'impression lithographique doté de revêtements à base d'eau
JP2013177685A (ja) * 2013-04-11 2013-09-09 Kobe Steel Ltd 自動製版印刷版用高強度アルミニウム合金板
CN103667819B (zh) * 2013-11-22 2015-09-16 中铝瑞闽股份有限公司 Ctp版基及其制作方法
BR112018070957B1 (pt) 2016-04-20 2022-08-30 Hydro Aluminium Rolled Products Gmbh Método para produção de uma faixa de alumínio para suportes de placa de impressão litográfica de uma liga de alumínio
CN107868887A (zh) * 2016-09-23 2018-04-03 镇江龙源铝业有限公司 一种led灯具用铝带新材料

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ES2407655T5 (es) 2007-11-30 2023-02-23 Speira Gmbh Banda de aluminio para soportes para planchas de impresión litográfica y su producción
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* Cited by examiner, † Cited by third party
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US3563815A (en) * 1967-12-29 1971-02-16 Alusuisse Process for the production of fine grained aluminum alloy strip
US4435230A (en) * 1981-09-03 1984-03-06 Furukawa Aluminum Co., Ltd. Aluminum alloy printing plate and method for manufacturing same
US4686083A (en) * 1984-04-27 1987-08-11 Fuji Photo Film Co., Ltd. Aluminum alloy support for a lithographic printing plate
EP1065071A1 (fr) * 1999-07-02 2001-01-03 VAW aluminium AG Bande en alliage d'aluminium pour plaques d'impression lithographique et procédé pour sa préparation
DE19956692A1 (de) * 1999-07-02 2001-01-11 Vaw Ver Aluminium Werke Ag Lithoband und Verfahren zu seiner Herstellung
WO2002048415A1 (fr) * 2000-12-11 2002-06-20 Alcan International Limited Alliage d'aluminium pour feuille lithographique
EP1676931A2 (fr) * 2000-12-11 2006-07-05 Novelis, Inc. Alliage d'aluminium pour feuille lithographique
WO2007045676A1 (fr) * 2005-10-19 2007-04-26 Hydro Aluminium Deutschland Gmbh Bande d'aluminium pour des supports de plaques d'impression lithographiques
WO2007115167A2 (fr) * 2006-03-31 2007-10-11 Alcoa Inc. processus de fabrication DE feuille lithographique

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9914318B2 (en) 2005-10-19 2018-03-13 Hydro Aluminium Deutschland Gmbh Aluminum strip for lithographic printing plate supports
US11326232B2 (en) 2007-11-30 2022-05-10 Hydro Aluminium Deutschland Gmbh Aluminum strip for lithographic printing plate carriers and the production thereof
US10927437B2 (en) 2008-11-21 2021-02-23 Hydro Aluminium Deutschland Gmbh Aluminium strip for lithographic printing plate supports with high flexural fatigue strength
WO2012059362A1 (fr) 2010-11-04 2012-05-10 Novelis Inc. Feuille lithographique d'aluminium
CN114729413A (zh) * 2019-11-12 2022-07-08 斯佩拉有限公司 经调节的箔材热处理
CN116635548A (zh) * 2020-12-18 2023-08-22 斯佩拉有限公司 具有改善的阻隔性的铝箔

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US20170253952A1 (en) 2017-09-07
US11326232B2 (en) 2022-05-10
BRPI0819596A2 (pt) 2020-08-25
ES2407655T5 (es) 2023-02-23
EP2067871B1 (fr) 2013-02-20
CN101883876A (zh) 2010-11-10
EP2067871B2 (fr) 2022-10-19
EP2220262B1 (fr) 2014-01-08
ES2407655T3 (es) 2013-06-13
EP2220262A1 (fr) 2010-08-25
DE202008018332U1 (de) 2013-02-07
JP5319693B2 (ja) 2013-10-16
SI2067871T2 (sl) 2023-01-31
BRPI0819596B8 (pt) 2023-01-10
ES2456269T3 (es) 2014-04-21
WO2009068502A1 (fr) 2009-06-04
SI2067871T1 (sl) 2013-06-28
BRPI0819596B1 (pt) 2021-03-02
JP2011505493A (ja) 2011-02-24

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