EP2049255A2 - Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol - Google Patents

Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol

Info

Publication number
EP2049255A2
EP2049255A2 EP07787973A EP07787973A EP2049255A2 EP 2049255 A2 EP2049255 A2 EP 2049255A2 EP 07787973 A EP07787973 A EP 07787973A EP 07787973 A EP07787973 A EP 07787973A EP 2049255 A2 EP2049255 A2 EP 2049255A2
Authority
EP
European Patent Office
Prior art keywords
catalyst
hydrogenation
benzene
active metal
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07787973A
Other languages
German (de)
English (en)
French (fr)
Inventor
Jochem Henkelmann
Michael Becker
Michael Schoenherr
Wilhelm Ruppel
Ulrike Wegerle
Bianca Staeck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP07787973A priority Critical patent/EP2049255A2/de
Publication of EP2049255A2 publication Critical patent/EP2049255A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
EP07787973A 2006-07-31 2007-07-27 Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol Withdrawn EP2049255A2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07787973A EP2049255A2 (de) 2006-07-31 2007-07-27 Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06118202 2006-07-31
EP07787973A EP2049255A2 (de) 2006-07-31 2007-07-27 Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol
PCT/EP2007/057758 WO2008015170A2 (de) 2006-07-31 2007-07-27 Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol

Publications (1)

Publication Number Publication Date
EP2049255A2 true EP2049255A2 (de) 2009-04-22

Family

ID=38596333

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07787973A Withdrawn EP2049255A2 (de) 2006-07-31 2007-07-27 Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol

Country Status (5)

Country Link
US (1) US8889936B2 (zh)
EP (1) EP2049255A2 (zh)
KR (1) KR101424654B1 (zh)
CN (1) CN101522299B (zh)
WO (1) WO2008015170A2 (zh)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008012227A1 (de) * 2008-03-03 2009-09-17 Basf Se Regenerierung von Hydrierungskatalysatoren auf der Basis eines Platinmetalls
US20110144398A1 (en) 2009-12-11 2011-06-16 Basf Se Process for regenerating a ruthenium-containing supported hydrogenation catalyst
EP2512658A2 (de) 2009-12-15 2012-10-24 Basf Se Katalysator und verfahren zur hydrierung von aromaten
KR101359230B1 (ko) 2012-02-29 2014-02-07 한국화학연구원 4-아미노메틸사이클로헥산 카르복실산의 제조방법
CN103816923B (zh) * 2012-11-16 2016-01-20 万华化学集团股份有限公司 一种钌加氢催化剂再生的方法
CN102921410A (zh) * 2012-11-20 2013-02-13 中国海洋石油总公司 一种苯加氢制环己烷贵金属Ru催化剂的制法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2757128A (en) * 1951-04-27 1956-07-31 Exxon Research Engineering Co Low pressure hydrogenation and hydrogen regeneration of the catalyst
FR1504433A (fr) * 1965-11-17 1967-12-08 Inst Francais Du Petrole Procédé perfectionné de réactivation applicable aux catalyseurs d'hydrogénation
US3851004A (en) * 1973-09-27 1974-11-26 Union Carbide Corp Hydrocarbon alkylation process using catalyst regeneration
US4322315A (en) * 1980-04-25 1982-03-30 Phillips Petroleum Company Regeneration of a ruthenium containing hydrogenation catalyst
US4331557A (en) 1980-05-22 1982-05-25 Phillips Petroleum Company Regeneration of ruthenium-containing catalyst
US5817589A (en) * 1996-04-02 1998-10-06 Intevep, S.A. Regeneration of catalyst comprising flushing with inert gas followed by flushing with hydrogen
WO1997016249A1 (fr) 1995-11-01 1997-05-09 Asahi Kasei Kogyo Kabushiki Kaisha Procede de reactivation d'un catalyseur a base de ruthenium
DE19604791A1 (de) 1996-02-09 1997-08-14 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Hydroxylgruppe an einen aromatischen Kern gebunden ist
DE19624485A1 (de) 1996-06-19 1998-01-02 Basf Ag Verfahren zur Hydrierung einer aromatischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
US6248924B1 (en) 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
DE19917051A1 (de) 1999-04-15 2000-10-19 Basf Ag Verfahren zur Hydrierung von unsubstituierten oder alkylsubstituierten Aromaten unter Verwendung eines Makroporen aufweisenden Katalysators
DE10135490A1 (de) * 2001-07-20 2003-01-30 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen mit Restgas enthaltendem Wasserstoff
DE10216745A1 (de) * 2002-04-16 2003-10-30 Bayer Ag Ruthenium-Katalysatoren für die Hydrierung von aromatischen Kohlenwasserstoffen
JP2007534463A (ja) * 2003-12-22 2007-11-29 ビーエーエスエフ　アクチェンゲゼルシャフト ルテニウム−不均一系触媒、炭素環式芳香族基を水素化する方法及びビスフェノールａ及びｆの核水素化されたビスグリシジルエーテル
DE102005029200A1 (de) 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen
DE602006004279D1 (de) * 2005-09-09 2009-01-29 Mitsubishi Gas Chemical Co Verfahren zur Herstellung von Aminoverbindungen mit einem aromatischen Ring unter Verwendung eines Schalenkatalysators

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
WO2008015170A2 (de) 2008-02-07
CN101522299B (zh) 2012-10-31
US8889936B2 (en) 2014-11-18
WO2008015170A3 (de) 2008-03-13
US20090259083A1 (en) 2009-10-15
KR101424654B1 (ko) 2014-08-01
KR20090037904A (ko) 2009-04-16
CN101522299A (zh) 2009-09-02

Similar Documents

Publication Publication Date Title
EP2049254B1 (de) Verfahren zur regenerierung von rutheniumkatalysatoren für die kernhydrierung von phthalaten
EP2049253B1 (de) integriertes VERFAHREN bestehend aus Hydrierung mit RUTHENIUMKATALYSATOREN und REGENERIERUNG derselben
WO2011069933A2 (de) Verfahren zur regenerierung eines ruthenium-haltigen geträgerten hydrierkatalysators
EP1899051A2 (de) Katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen
EP0983794B1 (de) Katalysator und Verfahren zur Reinigung von Stoffströmen
EP3080071B1 (de) Verfahren zur hydrierung aromatischer verbindungen
WO2011082991A2 (de) Katalysator und verfahren zur hydrierung von aromaten
EP0985447A2 (de) Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen
EP3781307A1 (de) Platin-schwefel-basierter schalenkatalysator, dessen herstellung und verwendung in der dehydrierung von kohlenwasserstoffen
EP2049255A2 (de) Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol
EP1966111B1 (de) Verfahren zur umsetzung eines aromatischen kohlenwasserstoffs in gegenwart von wasserstoff
EP1412310B1 (de) Verfahren zur hydrierung von aromatischen verbindungen mit restgas enthaltendem wasserstoff
EP1703973A1 (de) Ruthenium-heterogenkatalysator, kernhydrierte bisglycidylether der bisphenole a und f und verfahren zu ihrer herstellung
EP1404444A2 (de) Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/sio2 katalysatoren
EP1169285A1 (de) Verfahren zur hydrierung von unsubstituierten oder alkylsubstituierten aromaten unter verwendung eines makroporen aufweisenden katalysators
DE19755347A1 (de) Verfahren zur Hydrierung von Alkinolen unter Verwendung eines Makroporen aufweisenden Katalysators
DE2030336B2 (de) Verfahren zur Herstellung von Kohlenwasserstoffprodukten mit erhöhter Oktanzahl
DE10361151A1 (de) Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung eines Bisglycidylethers der Formel I

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090302

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK RS

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20100406

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20190207