EP1828254A1 - Procede de production d'hemicelluloses a partir d'un materiau lignocellulosique - Google Patents
Procede de production d'hemicelluloses a partir d'un materiau lignocellulosiqueInfo
- Publication number
- EP1828254A1 EP1828254A1 EP05818709A EP05818709A EP1828254A1 EP 1828254 A1 EP1828254 A1 EP 1828254A1 EP 05818709 A EP05818709 A EP 05818709A EP 05818709 A EP05818709 A EP 05818709A EP 1828254 A1 EP1828254 A1 EP 1828254A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- precipitation
- extract
- hemicelluloses
- organic liquid
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920002488 Hemicellulose Polymers 0.000 title claims abstract description 50
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000000463 material Substances 0.000 title abstract description 3
- 238000001556 precipitation Methods 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 29
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 21
- 238000000605 extraction Methods 0.000 claims description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 16
- 238000004061 bleaching Methods 0.000 claims description 13
- 239000003513 alkali Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000012978 lignocellulosic material Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 239000010903 husk Substances 0.000 claims description 6
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- 239000000243 solution Substances 0.000 description 12
- 238000005119 centrifugation Methods 0.000 description 10
- 238000001914 filtration Methods 0.000 description 10
- 238000003825 pressing Methods 0.000 description 10
- 238000011084 recovery Methods 0.000 description 10
- 229920005610 lignin Polymers 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 235000019641 whiteness Nutrition 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 7
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 6
- 238000006386 neutralization reaction Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000001720 carbohydrates Chemical class 0.000 description 5
- 235000014633 carbohydrates Nutrition 0.000 description 5
- 239000010902 straw Substances 0.000 description 5
- 235000013339 cereals Nutrition 0.000 description 4
- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 241000294754 Macroptilium atropurpureum Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- SYJRVVFAAIUVDH-UHFFFAOYSA-N ipa isopropanol Chemical compound CC(C)O.CC(C)O SYJRVVFAAIUVDH-UHFFFAOYSA-N 0.000 description 2
- COTNUBDHGSIOTA-UHFFFAOYSA-N meoh methanol Chemical compound OC.OC COTNUBDHGSIOTA-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000004537 pulping Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 240000003133 Elaeis guineensis Species 0.000 description 1
- 235000001950 Elaeis guineensis Nutrition 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000000359 Triticum dicoccon Species 0.000 description 1
- 240000003834 Triticum spelta Species 0.000 description 1
- 235000004240 Triticum spelta Nutrition 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- UGXQOOQUZRUVSS-ZZXKWVIFSA-N [5-[3,5-dihydroxy-2-(1,3,4-trihydroxy-5-oxopentan-2-yl)oxyoxan-4-yl]oxy-3,4-dihydroxyoxolan-2-yl]methyl (e)-3-(4-hydroxyphenyl)prop-2-enoate Chemical compound OC1C(OC(CO)C(O)C(O)C=O)OCC(O)C1OC1C(O)C(O)C(COC(=O)\C=C\C=2C=CC(O)=CC=2)O1 UGXQOOQUZRUVSS-ZZXKWVIFSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229920000617 arabinoxylan Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000011005 laboratory method Methods 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 229920001221 xylan Polymers 0.000 description 1
- 150000004823 xylans Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0057—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Xylans, i.e. xylosaccharide, e.g. arabinoxylan, arabinofuronan, pentosans; (beta-1,3)(beta-1,4)-D-Xylans, e.g. rhodymenans; Hemicellulose; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H8/00—Macromolecular compounds derived from lignocellulosic materials
Definitions
- the present invention relates to a process for the recovery of hemicelluloses from lignocellulosic material in high yield and purity.
- US 2,868,778 and US 2,801,955 disclose the recovery of hemicelluloses by extraction with calcium hydroxide solution or calcium hydroxide-containing solutions.
- the extract must be acidified before the precipitation in order to obtain low-colored products.
- US 4,038,481 discloses a process for recovering non-carbohydrate hemicellulose by extraction with alkaline solution and subsequent precipitation of the extract in a water-miscible organic liquid. To increase the yield and improve the product quality, however, the extract is also acidified before the precipitation, which makes it impossible to recover the alkali used.
- No. 5,112,964 describes a process for obtaining water-soluble hemicellulose from cereal parts.
- hemicellulose in the form of a gray powder can be obtained in very low yields of not more than 8%, which makes economic use difficult.
- EP 1 155 104 describes a process for the production of arabinoxylan from maize fibers by alkaline extraction.
- the hemicelluloses obtained by precipitation with alcohol in good yields are dark in color and have a very broad molar mass distribution which is unfavorable for subsequent reactions.
- a bleaching system comprising a liquid mixture containing the components water and organic liquid A.
- the hemicellulose obtained in the precipitation can be bleached. If this bleaching step is carried out in a bleach system whose liquid mixture has a similar or the same composition as the precipitation bath, it can be used immediately after the precipitation without further intermediate steps, e.g. Washes take place. With this simple, economically advantageous procedure can be achieved unexpectedly good bleaching results.
- the first step a) of the production according to the invention of hemicellulose from lignocellulose is an alkaline extraction known in principle.
- the lignocellulosic material is extracted with an aqueous alkaline solution.
- Solution are, for example, alkali metal hydroxides such as sodium hydroxide or potassium hydroxide,
- Alkaline earth hydroxides such as calcium hydroxide, alkali carbonates such as e.g. Sodium carbonate as well
- Ammonium Hydroxide ⁇ Preferred are alkali or alkaline earth hydroxides, more preferably sodium hydroxide
- the extraction process can be carried out at room temperature but also at higher temperatures, under normal pressure up to the boiling point of the extraction solution or in the non-fixed container and beyond the boiling point of the extraction liquid addition, treatment duration and possibly mixing intensity are dependent on the raw material.
- the alkali concentration to be adjusted is also dependent on the raw material and is preferably between 0.75 and 2.5 eq / l.
- the extraction can be carried out both in an extraction column with the lignocellulose to be extracted as a stationary phase as well as in the stirred tank.
- any form of lignocellulose can be used, depending on the desired quality of hemicellulose in upstream process steps cleaned and / or crushed.
- Lignocelluloses are substances that contain both cellulose fibers and lignin. Examples are virtually all structuring plant parts such as wood, cereal husks, stems of annual one-year plants (i.e., cereal straw) and plant fibers (e.g., jute, flax, cotton). Particularly suitable for the process according to the invention are lignocellulosic substances with only a low content of lignin, e.g. Corn spindles, wheat straw and in particular oat husks.
- a preferred raw material due to its low lignin content and the associated comparatively easy extractability of the hemicelluloses are oat spelts, more preferably oat hulls, which have been pretreated by roughening their surface by a roller mill.
- a hemicellulose-containing extract is obtained.
- the extract yield can be increased if the extraction residue undergoes an additional washing process and the loaded washing medium is then added to the extract.
- the extract may undergo further intermediate steps before the precipitation begins.
- the extract undergoes a nanofluidation or electrodialysis stage, whereby alkali is removed from the extract and thus in fact a concentration of the dissolved hemicelluloses occurs.
- the separation of the hemicelluloses takes place in step b) by introducing the extract into a precipitation medium consisting of water and an organic liquid H which is homogeneously miscible with water, the dissolved hemicelluloses precipitating out of the solution, likewise dissolved undesired, e.g. strongly colored minor components such as e.g. Lignin remain in solution.
- the composition of the precipitation bath decides to what extent this can be achieved. If the precipitation bath composition is selected accordingly, a large part of the unwanted secondary constituents can be kept in solution with barely reduced hemicellulose yield, as the examples below show.
- a preferred composition contains the precipitating bath after complete initiation of the extract between 25 and 75% by mass of the organic liquid A, more preferably between 30 and 60% by mass of the organic liquid A.
- the organic liquid A is preferably selected from the group of Water homogeneously miscible alcohols or ketones selected.
- suitable alcohols are methanol, ethanol, propanol, isopropanol, butanol and glycol and glycerol.
- suitable ketones are acetone, methyl ethyl ketone. Very particular preference is given to using methanol, ethanol, isopropanol or acetone.
- the mechanical separation of the precipitated hemicellulose can be carried out by different methods, for example filtration, centrifugation or filter pressing.
- the process according to the invention offers the possibility of connecting a bleaching stage in an additional step c) without further intermediate steps.
- the separated hemicellulose is preferably mixed with a liquid mixture which contains the same components as the precipitation bath, i. Water and organic, water-miscible liquid A contains.
- Suitable bleaching agents are, for example, chlorine, hypochlorites, chlorine dioxide, oxygen, peroxo compounds, potassium permanganate or ozone, preferably hydrogen peroxide or ozone.
- Typical concentrations of bleach are, for example, in the case of hydrogen peroxide 1 to 10% based on the solid to be bleached, in the case of ozone 0.01 to 1% based on the solid to be bleached.
- customary auxiliaries such as, for example, sodium hydroxide, can be used.
- This procedure offers the advantage that no medium change must be carried out and thus no additional substance components are included.
- the bleach system is particularly preferably adjusted so that its composition with respect to the components water and organic liquid A corresponds to that of the precipitation bath after completely introduced extract. This procedure offers not only a simplified storage but also the advantage of an additional cleaning effect.
- Oat husks are extracted with 5% sodium hydroxide solution at a solids content of 10% at 90 0 C for 60 min.
- the extract obtained by pressing, filtration or centrifugation is then subjected to a precipitation in differently composed methanol-water mixtures. In this case, 200 g of extract are introduced into each 600 g precipitation bath. Yields and kappa numbers of the hemicelluloses obtained by pressing, filtration or centrifugation are given in Table 1.
- the kappa number indicates the amount of 0.1 n-potassium permanganate solution in ml which is consumed in the treatment of 1 g of dry test substance.
- the kappa number gives an indication of the degree of pulping of pulps and pulp-like substances (such as hemicelluloses), in particular it gives an indication of the residual lignin content.
- Kappa number is a pulping method known to those skilled in the art and used internationally for pulps and is described e.g. according to Zellcheming leaflet FV / 37/80.
- Table 1 Yields and kappa numbers of hemicelluloses obtained by precipitation of an alkaline oat spelled extract in methanol-water mixtures
- Oat husks are extracted with 5% sodium hydroxide in a consistency of 10% at 90 0 C for 60 min.
- the extract obtained by pressing, filtration or centrifugation is then treated with conc. Neutralized sulfuric acid and then subjected to precipitation in differently composed methanol-water mixtures. In this case, 200 g of extract are introduced into each 600 g precipitation bath. Yields and kappa numbers of the hemicelluloses obtained by pressing, filtration or centrifugation are given in Table 2.
- Table 2 Yields and kappa numbers of hemicelluloses obtained by precipitation of a neutralized oat spelled extract in methanol-water mixtures
- Oat husks are extracted with 5% sodium hydroxide in a consistency of 10% at 9O 0 C for 60 min.
- the extract obtained by pressing, filtration or centrifugation is then subjected to a precipitation in differently composed isopropanol-water mixtures. In this case, 200 g of extract are introduced into each 600 g precipitation bath. Yields and Kappa numbers of the hemicelluloses obtained by pressing, filtration or centrifugation are given in Table 3.
- Table 3 Yields and kappa numbers of hemicelluloses obtained by precipitation of an alkaline oat spelled extract in isopropanol-water mixtures
- Precipitated hemicellulose from Example 2 (60% w / w MeOH content in the precipitation) is in methanol-water mixtures of different compositions with the addition of 4% sodium hydroxide solution and 6% hydrogen peroxide (each based on Rohxylan atro) in a consistency of 10% 90 0 C treated for 120 minutes.
- Kappa numbers and whiteness of the bleached hemicelluloses obtained by pressing, filtration or centrifugation are given in Table 4.
- Table 4 Whiteness and kappa numbers of hemicelluloses obtained after peroxide bleaching in methanol-water mixtures
- the best bleaching result is achieved with a methanol content in the bleaching slurry of 50 to 60% and is thus also in the range of the optimal composition for the precipitation.
- Precipitated hemicellulose from Example 3 (40% w / w IPA content in the precipitation) is in isopropanol-water mixtures of different compositions with the addition of 0.9% sodium hydroxide solution and 4% hydrogen peroxide (each based on Rohxylan atro) in a fabric density of 10% treated at 90 0 C for 120 min.
- Kappa numbers and degrees of whiteness of the bleached hemicelluloses obtained by pressing, filtration or centrifugation are given in Table 5.
- the best bleaching result is achieved with an isopropanol content in the bleach slurry of 40% and is therefore also in the range of optimum composition for the precipitation.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Compounds Of Unknown Constitution (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004060283A DE102004060283A1 (de) | 2004-12-15 | 2004-12-15 | Verfahren zur Gewinnung von Hemicellulosen aus lignocellulosischem Material |
PCT/EP2005/012974 WO2006066724A1 (fr) | 2004-12-15 | 2005-12-03 | Procede de production d'hemicelluloses a partir d'un materiau lignocellulosique |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1828254A1 true EP1828254A1 (fr) | 2007-09-05 |
Family
ID=36337673
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05818709A Withdrawn EP1828254A1 (fr) | 2004-12-15 | 2005-12-03 | Procede de production d'hemicelluloses a partir d'un materiau lignocellulosique |
Country Status (7)
Country | Link |
---|---|
US (1) | US20060128952A1 (fr) |
EP (1) | EP1828254A1 (fr) |
AU (1) | AU2005318574A1 (fr) |
CA (1) | CA2580414A1 (fr) |
DE (1) | DE102004060283A1 (fr) |
NO (1) | NO20071325L (fr) |
WO (1) | WO2006066724A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102388177A (zh) * | 2009-04-02 | 2012-03-21 | 奥本大学 | 包括半纤维素的提取方法和提取半纤维素的木质纤维素材料的处理方法的用于品质保护的制浆工艺 |
EP2643357B1 (fr) * | 2010-11-23 | 2017-02-22 | Ecohelix AB | Procédé pour augmenter le poids moléculaire de mannanes et de xylanes du bois comprenant des parties aromatiques |
JP2015086349A (ja) * | 2013-11-01 | 2015-05-07 | 株式会社ダイセル | 増粘剤 |
CA2933824C (fr) | 2014-03-19 | 2020-03-10 | Cnh Industrial Canada, Ltd. | Appareil et procede de lavage pour la preparation de fibres de cellulose destinees a etre utilisees pour la fabrication de materiaux biocomposites |
WO2016199042A1 (fr) * | 2015-06-10 | 2016-12-15 | Stora Enso Oyj | Procédés de traitement de matières lignocellulosiques |
EP3222779A1 (fr) | 2016-03-22 | 2017-09-27 | Jäckering Mühlen- und Nährmittelwerke GmbH | Masse de revetement amylacee |
CN110981993A (zh) * | 2019-11-21 | 2020-04-10 | 昆明理工大学 | 一种禾草类原料中提取分离半纤维素的集成处理设备及方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1819233A (en) * | 1930-04-10 | 1931-08-18 | Cornstalk Products Company Inc | Preparation of pentosans |
US2709699A (en) * | 1952-07-18 | 1955-05-31 | Michael J Wolf | Extracting hemicelluloses |
US2868778A (en) * | 1954-04-21 | 1959-01-13 | Corn Prod Refining Co | Process for extracting hemicellulose from corn coarse fiber |
US2801955A (en) * | 1955-11-17 | 1957-08-06 | Nat Starch Products Inc | Process for extraction of hemicellulose |
US3854995A (en) * | 1973-03-19 | 1974-12-17 | Sanyo Kokusaku Pulp Co | Process for the recovery of sugars from spent sulfite liquor |
FI49438C (fi) * | 1973-07-23 | 1980-12-23 | Keskuslaboratorio | Foerfarande foer avlaegsnande av hemicellulosa ur hemicellulosahaltiga alkaliloesningar i processcirkulation |
US4038481A (en) * | 1976-05-24 | 1977-07-26 | Standard Brands Incorporated | Method for treatment of corn hulls |
AT377679B (de) * | 1983-02-24 | 1985-04-25 | Chemiefaser Lenzing Ag | Verfahren zur herstellung von ballaststoff -angereicherten, joule-reduzierten backwaren |
JPH0611764B2 (ja) * | 1988-12-07 | 1994-02-16 | 雪印乳業株式会社 | 水溶性ヘミセルロースの製造方法 |
US5352264A (en) * | 1991-10-15 | 1994-10-04 | Medina Vega Luis R | Seed hull extracts |
US6589760B1 (en) * | 1999-02-10 | 2003-07-08 | Eastman Chemical Company | Methods of separating a corn fiber lipid fraction from corn fiber |
-
2004
- 2004-12-15 DE DE102004060283A patent/DE102004060283A1/de not_active Withdrawn
-
2005
- 2005-12-03 AU AU2005318574A patent/AU2005318574A1/en not_active Abandoned
- 2005-12-03 WO PCT/EP2005/012974 patent/WO2006066724A1/fr active Application Filing
- 2005-12-03 EP EP05818709A patent/EP1828254A1/fr not_active Withdrawn
- 2005-12-03 CA CA002580414A patent/CA2580414A1/fr not_active Abandoned
- 2005-12-13 US US11/301,775 patent/US20060128952A1/en not_active Abandoned
-
2007
- 2007-03-12 NO NO20071325A patent/NO20071325L/no not_active Application Discontinuation
Non-Patent Citations (1)
Title |
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See references of WO2006066724A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2006066724A1 (fr) | 2006-06-29 |
CA2580414A1 (fr) | 2006-06-29 |
NO20071325L (no) | 2007-04-03 |
DE102004060283A1 (de) | 2006-06-29 |
AU2005318574A1 (en) | 2006-06-29 |
US20060128952A1 (en) | 2006-06-15 |
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