EP1786393A1 - Composition de soin capillaire - Google Patents

Composition de soin capillaire

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Publication number
EP1786393A1
EP1786393A1 EP05782772A EP05782772A EP1786393A1 EP 1786393 A1 EP1786393 A1 EP 1786393A1 EP 05782772 A EP05782772 A EP 05782772A EP 05782772 A EP05782772 A EP 05782772A EP 1786393 A1 EP1786393 A1 EP 1786393A1
Authority
EP
European Patent Office
Prior art keywords
composition
hair
group
silicone
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05782772A
Other languages
German (de)
English (en)
Inventor
Christian Springob
Timothy Müller
Ursula Hehner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Publication of EP1786393A1 publication Critical patent/EP1786393A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a composition, a process for the preparation of a composition, the composition obtainable by this process, a process for the treatment of hair, the use of a composition for the treatment of hair and the use of a composition for the preparation of an agent for Treatment of hair.
  • the hair is adversely affected by the effects of various types in their physical, chemical and morphological properties.
  • the hair is replaced by cosmetic treatments such as repeated bleaching, perming and dyeing, but also by frequent washing of the hair with degreasing surfactants, by climatic influences such as differences in humidity and temperature or the intense action of sunlight and by mechanical treatment such as brushing, combing and Terry heavily damaged and damaged.
  • Cosmetic treatments such as repeated bleaching, perming and dyeing, but also by frequent washing of the hair with degreasing surfactants, by climatic influences such as differences in humidity and temperature or the intense action of sunlight and by mechanical treatment such as brushing, combing and Terry heavily damaged and damaged.
  • the hair becomes brittle and loses its shine.
  • Silky sheen, low porosity and a pleasant, smooth feel (good grip) are characteristic of natural, healthy hair.
  • the agents used for hair care can be formulated so that they not only serve the care and protection of the individual hair, but also improve the appearance of the hairstyle overall, for example, da ⁇ by that the hair supple and thus willing to be hairy him give a pleasant grip and make it silky shiny.
  • Such preparations are also commonly referred to as hair conditioners or hair conditioners.
  • Compositions suitable for these purposes are inter alia in the monograph by K. Schrader, bases and formulations of cosmetics, 2nd ed., (Hüthig book publishing house, 1989) on pages 722 to 781 under the keyword "hair aftertreatment" described.
  • Hair care products such as hair conditioners or hair conditioners are also known, for example, from WO 98/43599 A1 and DE 197 03 475 A1.
  • the hair care products described in this prior art are in the form of creamy emulsions or dispersions and consist of an aqueous, hydrophilic phase and a hydrophobic phase containing oil or wax.
  • these conventional emulsion-type hair care products have the disadvantage that they can be poorly distributed on the hair.
  • these emulsion- or dispersion-based hair care products often feel heavy, greasy and greasy.
  • the hair care products based on emulsions or dispersions lead to an unfavorable volume reduction of the dry hair due to the waxes normally contained in such products.
  • the present invention has the object to provide a usable as a hair care composition, which can be better distributed in hair compared to conventional hair care products and at the same time shows an intensive hair care effect, which is comparable to a Haarspü ⁇ treatment or hair cure.
  • a further object of the present invention was to provide a composition which can be used as a hair care composition, which feels less heavy, greasy and greasy than the hair-care products known from the prior art or emulsion or dispersion-type. Except- this hair care product should lead to no or at least to a lower volume reduction of the dry hair in comparison to conventional hair care products.
  • a composition according to the invention in particular as a hair care product, which is preferably liquid, contains as components
  • a) an organomodified silicone b) optionally a C 3 -C 2 2 -alkanol which is preferably different from the component e, the alcohol preferably being present in an amount in a range from 0.01 to 15% by weight, preferably in a range of 0.025 to 10 wt%, more preferably in a range of 0.05 to 5 wt%, and most preferably in a range of 0.1 to 2 wt%, each based on the total weight of the composition in which the composition may be present, c) optionally a cationic surfactant, d) optionally a volatile silicone oil, e) at least 30 wt .-%, preferably at least 40 wt .-%, preferably more than 47.5 wt .-%, particularly preferably at least 50 wt .-% and more preferably at least 60 wt .-%, each based on the total weight of the composition, ethanol or isopropanol, preferably ethanol, and f
  • 0.01 to 15 wt.% Preferably 0.025 to 10 wt.%, More preferably 0.05 to 5 wt.%, And most preferably 0.1 to 2 wt
  • component d 0.01 to 40% by weight, preferably 0.025 to 30% by weight, more preferably 0.05 to 20% by weight and most preferably 0.1 to 10% by weight of component d and
  • composition according to the invention is anhydrous or contains not more than 20% by weight, preferably not more than 15% by weight, more preferably not more than 10% by weight and most preferably not more than 5% by weight, in each case based on the total weight of the composition, of water.
  • the hair care composition according to the invention is particularly suitable for manual distribution and, in particular, massaging into the hair.
  • an "organomodified silicone” is understood as meaning a polysiloxane in which at least some of the groups bonded to the Si-O-Si backbone have atoms which are different from carbon and hydrogen and preferably have nitrogen the backbone bound groups preferably represent a side branch of the backbone, the side branch having a lower molecular weight than the backbone forming chain as such.
  • the organomodified silicone present as component a in the composition according to the invention preferably has a weight average molecular weight, preferably determined by gel permeation chromatography, in a range from 100 to 1,000,000 g / mol, more preferably in a range from 250 to 500,000 g / mol , moreover, preferably in a range of 500 to 100,000 g / mol, and most preferably in a range of 1,000 to 50,000 g / mol.
  • the organically modified silicone is a nitrogen-containing silicone
  • the nitrogen-containing silicone it is further preferred according to the invention for the nitrogen-containing silicone to be an amino-functional silicone which preferably has an amine content (meq / g) determined by titration with perchloric acid within a range of 0.01 to 3.0, more preferably in a range of 0.025 to 2.75, above preferably in a range of 0.05 to 2.3, and most preferably in a range of 0.1 to 0.5.
  • the organomodified silicone is a non-volatile silicone which has a vapor pressure at 21 ° C. of preferably less than 10 mbar, more preferably less than 1 mbar, even more preferably less than 0.5 mbar, more preferably less than 0.1 mbar, and most preferably less than 0.05 mbar.
  • the organomodified silicone is a linear, preferably nonvolatile, amino-functional silicone having the structure I,
  • the R 2 groups within the structures independently of each other may be the same or different and are a hydrogen atom, a Ci to Ci 0 -
  • Alkyl group preferably a C 1 to C 5 alkyl group and moreover preferably a C 1 to C 4 alkyl group, the methyl group being most preferred, an aryl group-containing radical, preferably a benzyl group or a phenyl group, a hydroxy group, a C] - to Cio alkoxy group or a C 2 - to Cio-acetoxy group, preferably a Ci- to Cs-alkoxy or a C 2 - to Cs-acetoxy group and moreover be ⁇ preferably a Cr to C 3 Alkoxy or a C 2 to C 3 acetoxy group, or a - (CH 2 ) a --NH 2 group with a being 1 to 10, preferably 1 to 6 and most preferably 1 to 4;
  • the groups R 3 in the structures may be the same or different and independently of one another and are a hydrogen atom or a Ci to C2o hydrocarbon, preferably a Ci to C20 alkyl group or a C 6 - to C 20 - aryl-containing radical , particularly preferably a Ci to Cio-alkyl group or a C 6 - to Ci 5 -aryl group-containing radical, even more preferably a C] - to C 4 -alkyl group or a C 6 - to C] 0 - aryl group-containing radical wherein the methyl group and the phenyl group and of which the methyl group is most preferred, wherein the Cj to C 20 hydrocarbon may also include heteroatoms, preferably oxygen or nitrogen, represent;
  • the groups X represent an -A-NR 4 R 5 or an -AN + R 4 R 5 R 6 group in which
  • A is an at least divalent, preferably a divalent, ci- bis
  • C 2 o-alkylene group preferably cis to cis-alkylene group and Sonders preferably C 1 - to C alkylene group O which hetero atoms also may contain group;
  • Hydrocarbon a Ci to C 20 alkyl group, preferably or a C 6 - to C 20 -Arylgrup ⁇ en-containing group, particularly preferably ei ⁇ ne C] - to Cio-alkyl group or a C 6 - to C Aryl weakness--containing radical, even more preferably a C 1 - to C 4 -alkyl group or a C 6 - to do-aryl-group-containing radical, the methyl group and the phenyl group and of these the methyl group being the most preferred,
  • R 7 is a C 1 - to C 22 - alkyl group, preferably a C 1 - to C 5 -Alkylgru ⁇ pe and most preferably a C r to Ci O alkyl group which can also OH groups aufwei ⁇ sen;
  • n is a number from 1 to 500, preferably from 1 to 250, even more preferably from 1 to 100 and most preferably from 1 to 50;
  • o is a number from 0 to 200, preferably from 5 to 150, even more preferably from 10 to 100 and most preferably from 20 to 50.
  • the individual structural units -OSiR 3 R 3 - and -OSiXR 3 - can be distributed randomly within the structures I and III or else arranged in blocks.
  • organomodified silicone is a linear, preferably non-volatile, amino-functional silicone which is obtainable by combining structures I and II, in which case the X groups can be located both terminally and laterally.
  • amodimethicone the commercially available products Dow Corning ® 939 Cationic Emulsion or the products Dow Corning ® 949 Cationic Emulsion, Silicone XF 49-703, silicones XF 42-Bl 989 or Mirasil ADM-E may be mentioned.
  • an amino-functional silicone with a quaternary amino group mention may be made of the dimethylsiloxanes having two terminal aminoalkyl groups mentioned under the INCI name Quaternium-80.
  • Other examples of amino functional silicones with a quaternary amino group are the commercially available products Abil ® Quat 3270, Abil ® Quat 3272 or Abil ® Quat 3274.
  • Similar ami ⁇ nofunktionelle silicones are also siloxane polyether amines such as Abil ® Soft AF 100th C 3 -C 22 -alcohol (component b)
  • C 3 -C 22 -alcohols which are preferred according to the invention are monohydric or polyhydric alcohols, particular preference being given to monohydric or dihydric alcohols and to dihydric alcohols.
  • monohydric alcohols include butanol, pentanol, hexanol, heptanol, octanol, nonanol, decanol, myristyl alcohol or behenyl alcohol.
  • dihydric alcohols are 1, 2-propanediol, 1,3-propanediol, 1, 2-butanediol, 1,3-butanediol or 1,4-butanediol, with 1,3-butanediol being most preferred. Also conceivable are mixtures of at least two of the abovementioned mono- or divalent C 3 -C 22 -alcohols.
  • cationic surfactants it is possible to use all surfactants having at least one cationic, functional group, particular preference being given to surfactants having a quaternary nitrogen group as the cationic, functional group.
  • R to R independently of one another are aliphatic groups, aromatic groups, alkoxy groups, polyoxyalkylene groups, alkylamido groups, hydroxyalkyl groups, aryl groups or alkaryl groups each having 1 to 22 C atoms, where at least one of the radicals R to R has at least 8 C atoms and X 'is a cosmetically acceptable anion, eg a halogen, Acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride.
  • the aliphatic groups may also contain cross-links or other groups, for example further amino groups.
  • Suitable cationic surfactants are the chlorides or bromides of alkyldimethylbenzylammonium salts, alkyltrimethylammonium salts, eg cetyltrimethylammonium chloride or bromide, tetradecyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chlorides or bromides, dialkyldimethylammonium chlorides or - bromides, alkylpyridinium salts, eg lauryl or cetylpyridinium chloride, alkyl amidoethyltrimethylammonium ether sulfates and compounds having a cationic character such as amine oxides, for example alkylmethylamine oxides or alkylaminoethyldimethylamine oxides. Cetryltrimethylammonium chloride is particularly preferred.
  • Suitable cationic surfactants are, in particular, the so-called esterquats, for example C.sub.2 to C.sub.16 alkyl esters of betaine, for example palmitylbetaine chloride.
  • esterquats for example C.sub.2 to C.sub.16 alkyl esters of betaine, for example palmitylbetaine chloride.
  • the use of these esterquats for the care of keratinic and other fibers is known from international patent application WO 96/03970 Al and European Patent Applications EP 0 636 356 A1, EP 0 689 532 A1 and EP 0 614 349 A1.
  • Esterquats are examples game, under the trade names Rewoquat ® WE 18, REWOQUAT ® WE 38 DPG (Witco Surfactants GmbH), Stepantex ® GS 90 (Stepan), Armocare ® VGH-70 (Akzo Nobel), or DEHYQUAT ® L-80 (Henkel ) available.
  • cationic or amine-substituted surfactants are those of the formula
  • R 12 is -NH- (CH 2 ) n -NR 13 R 14 or the formula
  • R 12 is an acyl or an alkyl radical having 8 to 24 C atoms, which may be branched or unbranched, saturated or unsaturated, wherein the acyl and / or the alkyl radical may contain one or more OH groups
  • R 13 , R 14 and R 15 independently of one another are hydrogen, alkyl or alkoxyalkyl radicals having 1 to 6 C atoms, which may be identical or different, saturated or unsaturated and substituted by one or more hydroxy groups
  • volatile silicone oils it is possible to use all silicone oils whose vapor pressure at a temperature of 21 ° C. is greater than 0.1 mbar, preferably greater than 0.5 mbar, more preferably greater than 1 mbar, even more preferably greater than 10 mbar, more preferably greater than 50 mbar, and most preferably greater than 100 mbar.
  • Volatile silicone oils which are preferred according to the invention are liquid, readily volatile silicones at room temperature, such as cyclic dimethylsiloxanes having 3 to 8, preferably 4 to 6, Si atoms, in particular cyclotetradimethylsiloxane, cyclopentadimethylsiloxane or cyclohexadimethylsiloxane.
  • Other preferred volatile silicone oils are dimethylsiloxane / methylalkylsiloxane cyclocopolymers, for example, Silicone FZ 3109 from Union Carbide, which is a dimethylsiloxane / methyloctyl cyclocopolymer.
  • linear volatile silicone oils have 2 to 9 Si atoms.
  • Volatile silicone oils include, for example, hexamethyldisiloxane or alkyltri- siloxanes such as hexylheptamethyltrisiloxane or octylheptamethyltrisiloxane.
  • Other preferred volatile silicone oils are low viscosity polydimethylsiloxanes having a viscosity of less than 1,000 mPaxs, preferably less than 500 mPaxs, more preferably less than 100 mPaxs and most preferably less than 50 mPaxs as determined by the test method described herein, and moreover preferred in a range of 0.1 to 50 mPaxs, and further preferably 0.25 to 25 mPaxs.
  • the preferred low-viscosity silicone oils for example, part of the commercially available product Dow Corning ® 200 Fluid and Dow Corning ® 5 CST 345 Fluid.
  • additives which are different from components a to e include further active ingredients, preferably active hair care agents.
  • Another hair care active ingredient is preferably an amidoamine or a quaternized amidoamine of the abovementioned formulas
  • R 12 is -NH- (CH 2 ) n -NR 13 R 14
  • R 12 is a branched or unbranched, saturated or unsaturated A- cylrest having 8 to 24 carbon atoms, which may contain at least one OH group.
  • the hair-care active ingredient is a quaternized amidoamine, this amidoamine serves both as a cationic surfactant (component a) and as an additive (component f).
  • These quaternized amidoamines can also be regarded as preferred cationic surfactants.
  • Suitable amines or amidoamines which may optionally be quaternized, are e.g. those with the INCI names Ricinoleamidopropyl Beetine, Ricinoleamidopropyl Dimethylamine, Ricinoleamidopropyl Dimethyl Lacete, Ricinoleamidopropyl Ethyldimonium Ethosulfate, Ricinoleamidopropyltrimonium Chloride, Ricineamidopropyltrimonium Methosulfate, Cocamidopropyl Betaine, Cocamidopropyl Dimethylamine, Cocamidopropyl Ethyldimonium Ethosulfate, Cocamidopropyltrimonium Chloride, Behenamidopropyl Dimethylamine, Isostearylamidopropyl Dimethylamine, Stearylamidopropyl Dimethylamine, Quaternium-33, Undecylenamidopropyltrimonium Methosulfate.
  • thickeners for adjusting the viscosity such as starch or cellulose derivatives, glycol ethers or glycols such as glycerol, Ketocar- bonklaren or their physiologically acceptable salts, sunscreens or UV absorbers, preservatives, antioxidants (for example tocopherols or esters thereof), dyes and perfumes ,
  • compositions according to the invention may be, for example, cationic or water-soluble nonionic polymers, vegetable and mineral fats and oils, perfume oils, dyes customary in hair cosmetics, further hair conditioning agents such as synthetic and natural phospholipids, quaternary derivatives of starch or DCmes, Proteins or protein derivatives such as protein hydrolysates (for example collagen, keratin, silk protein or wheat protein hydrolysates), amino acids (for example histidine, glycine, alanine, serine, threonine, arginine, cysteine and derivatives thereof, for example the fatty acid condensation products) , Plant extracts, vitamins or provitamins (for example biotin, vitamin C, D-panthenol of the derivatives thereof), allantoin, chitosan, viscosity regulators such as fatty acid alkanolamides, alkoxylated esters of polyols (for example glycerol, sorbitol, fruct
  • the composition has a viscosity determined according to the test method described here in a range from 0.1 to 1000 mPaxs, more preferably in a range from 0.5 to 500 mPaxs and most preferably in a range from 0.7 to 50 mPaxs, and moreover preferably in a range of 0.8 to 5 mPaxs and further preferably at 0.9 to 2.5 mPaxs.
  • the viscosity of the composition determined according to the test method described herein is less than 100 mPaxs, more preferably less than 50 mPaxs, more preferably less than 25 mPaxs, and most preferred is less than 10 mPaxs.
  • composition of the invention may be as preferably cosmetic
  • Hair care products are used and is sprayable or foamable.
  • the composition can be used for all known cosmetic uses, which usually affect the hair. For example in shape a spray cure, a foam cure, a conditioner or a treatment.
  • the hair care composition may also be used as a pretreatment agent prior to hair dyeing or before a perming treatment to maintain hair even during the hair-curing treatment.
  • the composition can also be used as a pre-treatment agent before a cream-cure application in order to intensify the conditioning effect of the cream-based cream.
  • composition according to the invention can also be used as a 2-phase product.
  • 2-phase products are described for example in DE 197 03 475.
  • the composition according to the invention forms a first, hydrophilic phase, while as the second, preferably optically distinguishable from the first phase, lipophilic phase, preferably a volatile Silikonver ⁇ bond or a volatile hydrocarbon, preferably a volatile Koh - Hydrogen, is used.
  • Preferred components of the lipophilic phase and preferred ratios of hydrophilic and lipophilic phase in the case of use of the composition of the invention as a 2-phase product are those components and proportions, which are disclosed in DE 197 03 475 Al.
  • the relevant disclosure of DE 197 03 475 A1 forms part of the disclosure of the present invention.
  • an organomodified silicone b) a C 3 -C 22 -alcohol which is preferably different from component e), c) optionally a cationic surfactant, d) optionally a volatile silicone oil, e) at least 30% by weight, preferably at least 40 Wt .-%, particularly preferably at least 50 wt .-% and moreover preferably at least
  • the components a to f are brought into contact with each other by mixing.
  • the bringing into contact of the individual components preferably takes place at room temperature, wherein the person skilled in the art can determine the most advantageous sequence of mixing of the individual components by routine preliminary tests.
  • the hair is brought into contact with the composition described at the outset or with the composition obtainable by the process according to the invention described above, in which case the composition according to the invention is used as a 2-phase product
  • This 2-phase product is preferably shaken onto the hair before application in order to effect mixing of the two phases.
  • the composition according to the invention may either remain in the hair after application to dry, damp or wet hair or it may be rinsed out again after a suitable exposure time.
  • the action times depend on the type from the hair as well as the temperature, the temperature is preferably in a range of 20 to 5O 0 C.
  • exposure times of between 0.5 and 60 minutes, in particular between 1 and 40 minutes, preferably between 5.0 and 20 minutes, can be assumed By heating the repair effect can be accelerated. After completion of the exposure time, the hair can be rinsed with water.
  • the composition according to the invention can advantageously be applied or sprayed or foamed onto dry or damp hair using conventional pumps and dosing aids, for example as an aerosol.
  • Suitable spraying or foaming device are known in the art, which can be operated with a propellant or by means of mechanically induced pressure generation. The application is preferably after a hair wash.
  • composition according to the invention is to be applied by means of a blowing agent, in particular sprayed or foamed, it can be filled together with customary blowing agents into a suitable pressure vessel, in particular into an aerosol can, in customary ratios or amounts ,
  • a ratio of composition according to the invention to blowing agent can be given as 92: 8.
  • the internal pressure depends on the container used. As a guideline, it can be considered to 8.0 bar at a temperature of 2O 0 C by a pressure in the range of 1.5.
  • the invention also relates to the use of the composition described above or the composition obtainable by the process described above for the preferably cosmetic treatment of hair, in which case the use of the composition as the rinse off product is particularly preferred.
  • Example 1 The preparation from Example 1 was subjected to a half-side test in a hairdressing assessment. Thereby the criteria became
  • composition according to the invention not only has a better dispersibility on the hair compared to a conventional creaming, moreover the load on the dry hair is lower (better) than in the case of cream application and the volume of the hair is greater (Better), wherein the composition according to the invention in comparison to the cream has no lower care effect (combability and feel of the wet hair).
  • the viscosity was determined by means of the following apparatus and under the following conditions:
  • Rheometer Bohlin Rheometer CS Measuring Program: Yield Stress Measuring System: DG 40/50 Shear Rate: 50 s "1 Delay Time: 5 s Integration Time: 5 s Temperature: 25 ° C HAIRDRESSER REVIEW AT THE HALF-PARTY TEST
  • the method is based on so-called half-page comparisons on several testers (models), which are carried out by a trained hairdresser.
  • the scalp hairs are divided into two sections with a central peak reaching from the forehead to the neck.
  • a random section remains untreated or receives a comparison product, on the other section, the test product is applied.
  • the hair of the models with different hair lengths are first washed twice with an effective neutral shampoo. After washing, the hair is easily rubbed with a towel. With a central peak reaching from the forehead to the neck, the towel-dried hairs are split into two sections. A random section receives the composition according to the invention; the same amount by weight of cream is applied to the other section.
  • the assessing hairdresser judges how easily the product to be evaluated can be distributed in towel-dried hair by distributing the respective product in the hair with both hands.
  • the wet hair grip is evaluated by the assessing hairdresser by sliding the hair from finger to toe under light pressure. If the hair slides without or with less resistance through the fingers than without the half side treated with a comparison product, this is referred to as an improved / smoother grip. Subsequently, the combability of the wet hair is evaluated by the assessing hairdresser by combing both sides with a hard rubber comb starting at the forehead to the neck, whereby care must be taken that the comb is guided on the scalp is, so that no different Kämmwinkel arise. If the hair can be combed without or with less resistance than in the case of the half side treated with or without a comparison product, this is referred to as a light, good, improved combability.
  • the hair volume is evaluated by the assessing hairdresser by optically determining the larger hair volume.
  • the assessor standing behind the model, compares both sections from a distance of one meter. Subsequently, the hair is combed through on both sides with a comb and the volume, also from a distance of one meter, is assessed conclusively by shaking the model twice.
  • the hair load is evaluated by the assessing hairdresser by allowing the hair to slide from the neck to the tips under light pressure. If no or a weaker film remains on the finger than on the half side treated with no or with a comparison product, this is defined as no or less load.
  • the assessment of the mentioned hairdressing technical criteria is carried out as described and can be re ⁇ produce each time exact adherence to the rule, whereby an objective product comparison is possible.

Abstract

La présente invention concerne une composition contenant a) une silicone organomodifiée, b) éventuellement un alcool C3-C22, c) éventuellement un tensio-actif cationique, d) éventuellement une huile de silicone volatile, e) au moins 30 % en poids, par rapport au poids total de la composition, éthanol, et f) éventuellement d'autres substances différentes des composantes a à e, la quantité totale des composantes a à f étant égale à 100 %. L'invention concerne également un procédé de production d'une composition, la composition obtenue par ce procédé, un procédé de traitement capillaire, l'utilisation d'une composition de traitement capillaire et l'utilisation d'une composition de production d'un produit de traitement capillaire.
EP05782772A 2004-09-09 2005-09-09 Composition de soin capillaire Withdrawn EP1786393A1 (fr)

Applications Claiming Priority (2)

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DE102004044005 2004-09-09
PCT/EP2005/009709 WO2006027258A1 (fr) 2004-09-09 2005-09-09 Composition de soin capillaire

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CN101018540A (zh) 2007-08-15
WO2006027258A1 (fr) 2006-03-16
US20080112912A1 (en) 2008-05-15
MX2007002722A (es) 2007-05-16
JP2008512418A (ja) 2008-04-24

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