EP1768802A1 - Poudres et revetements en alliages resistants a l'usure - Google Patents

Poudres et revetements en alliages resistants a l'usure

Info

Publication number
EP1768802A1
EP1768802A1 EP05753987A EP05753987A EP1768802A1 EP 1768802 A1 EP1768802 A1 EP 1768802A1 EP 05753987 A EP05753987 A EP 05753987A EP 05753987 A EP05753987 A EP 05753987A EP 1768802 A1 EP1768802 A1 EP 1768802A1
Authority
EP
European Patent Office
Prior art keywords
weight percent
alloy
wear resistant
chromium
molybdenum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05753987A
Other languages
German (de)
English (en)
Other versions
EP1768802A4 (fr
Inventor
William J. C. Jarosinski
Lewis B. Temples
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Praxair ST Technology Inc
Praxair Technology Inc
Original Assignee
Praxair ST Technology Inc
Praxair Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Praxair ST Technology Inc, Praxair Technology Inc filed Critical Praxair ST Technology Inc
Publication of EP1768802A1 publication Critical patent/EP1768802A1/fr
Publication of EP1768802A4 publication Critical patent/EP1768802A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • C22C1/045—Alloys based on refractory metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/053—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 30% but less than 40%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/04—Alloys based on tungsten or molybdenum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06—Alloys based on chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy

Definitions

  • This invention relates to chromium-molybdenum alloys and wear resistant alloy powders useful for deposition through thermal spray devices.
  • the wear resistant alloy powders are useful for forming coatings having the same composition.
  • Hard surface coating metals and alloys are known in the art.
  • chromium metal has been used as an electroplated coating for many years to restore worn or damaged parts to their original dimensions, to increase wear and corrosion resistance, and to reduce friction.
  • Hard chromium electroplate has a number of limitations. When the configuration of the part becomes complex, obtaining a uniform coating thickness by electro-deposition is difficult. A non- uniform coating thickness necessitates grinding to a finished surface configuration, which is both difficult and expensive with electroplated chromium because of its inherent brittleness and hardness. The rate of deposition by electroplating is relatively low, and thus a substantial capital investment in plating equipment is required.
  • 3,846,084 discloses coatings made by the plasma or detonation gun process that are superior to hard chromium electroplate in compatibility, frictional characteristics and wear resistance by incorporating a dispersion of chromium carbide particles in a chromium matrix. Coatings of this type can be made from mechanical mixtures of powders. However, there are certain limitations to the quality of coatings made from them. Plasma, HVOF and detonation-gun coatings result in a multilayer structure of overlapping lamellae or "splats." Each splat is derived from a single particle of the powder used to produce the coating. There appears to be little, if any, combining or alloying of two or more powder particles during the coating deposition process. U.S. Patent No.
  • 6,562,480 Bl discloses a wear resistant coating for protecting a surface undergoing sliding contact with another surface such as piston rings and cylinder liners of internal combustion engines.
  • the wear resistant coating is applied by HVOF deposition of a powder which comprises a blend of about 13 weight percent to about 43 weight percent of a nickel -chromium alloy, about 25 weight percent to about 64 weight percent chromium carbide, and about 15 weight percent to about 50 weight percent molybdenum.
  • U.S. Patent No. 6,503,290 Bl discloses a corrosion resistant powder useful for deposition through thermal spray devices.
  • the powder comprises about 30 to 60 weight percent tungsten, about 27 to 60 weight percent chromium, about 1.5 to 6 weight percent carbon, a total of about 10 to 40 weight percent cobalt plus nickel and incidental impurities plus melting point suppressants.
  • the corrosion resistant powder is useful for forming coatings having the same composition.
  • a need continues to exist for powders and coatings that can be deposited by thermal spray devices and that exhibit excellent wear and/or corrosion resistance. Therefore, a need continues to exist for developing new powders and for exploring their potential for thermal spray deposition of wear and corrosion resistant coatings. It would therefore be desirable in the art to provide powders and coatings that can be deposited by thermal spray devices and that exhibit excellent wear and corrosion resistance .
  • the alloys include precipitated carbides (and optionally nitrides) of chromium and molybdenum interspersed throughout.
  • This invention also relates to wear resistant alloy powders useful for deposition through thermal spray devices.
  • the powders comprise an alloy of about 20 to 65 weight percent chromium, about 20 to 65 weight percent molybdenum, about 0.5 to 3 weight percent carbon, and about 10 to 45 weight percent nickel.
  • the wear resistant alloy powders are useful for forming coatings having the same composition.
  • this invention relates to wear resistant alloy powders useful for deposition through thermal spray devices such as plasma, HVOF or detonation gun.
  • the powders are made from alloys comprising about 20 to 65 weight percent chromium, about 20 to 65 weight percent molybdenum, about 0.5 to 3 weight percent carbon, and about 10 to 45 weight percent nickel .
  • the alloys include precipitated carbides and optionally nitrides of chromium and molybdenum interspersed throughout.
  • the alloys are useful for forming wear resistant powders and coatings having the same composition.
  • the alloys herein rely upon a large concentration of chromium and molybdenum for excellent wear resistance.
  • the alloys contain at least about 20 weight percent chromium, preferably at least about 30 weight percent chromium, and more preferably at least about 35 weight percent chromium. Powders containing less than about 20 weight percent chromium may exhibit inadequate wear resistance for many applications. Chromium levels in excess of about 65 weight percent may tend to detract from the wear resistance of the coating because the coating may become too brittle. Similarly, the alloys contain at least about 20 weight percent molybdenum, preferably at least about 25 weight percent molybdenum, and more preferably about 30 or 35 weight percent molybdenum. Powders containing less than about 20 weight percent molybdenum may exhibit inadequate wear resistance for many applications.
  • the alloys comprise about 20 to 65, preferably about 30 to 60, and more preferably about 35 to 55, weight percent chromium; about 20 to 65, preferably about 25 to 60, and more preferably about 30 to 55, weight percent molybdenum; about 0.5 to 3, preferably about 1 to 2.5, and more preferably about 1.5 to 2, weight percent carbon; and about 10 to 45, preferably about 15 to 35, and more preferably about 20 to 35, weight percent nickel.
  • These alloys are useful for forming wear resistant powders and coatings having the same composition.
  • the alloys comprise about 50 to 90, preferably about 60 to 80, and more preferably about 65 to 75, weight percent chromium and molybdenum; about 0.5 to 3, preferably about 1 to 2.5, and more preferably about 1.5 to 2, weight percent carbon; and about 10 to 45, preferably about 15 to 35, and more preferably about 20 to 35, weight percent nickel.
  • These alloys are useful for forming wear resistant powders and coatings having the same composition.
  • the carbon concentration controls the hardness and wear properties of coatings formed with the powders. A minimum of about 0.5 weight percent carbon may be necessary to impart adequate hardness into the coatings. If the carbon exceeds about 3 weight percent, the melting temperature of the powder may become too high and it may become too difficult to atomize the powder.
  • cobalt may be included in the alloys, powders and coatings.
  • the powders may contain about 10 to 45, preferably about 15 to 35, and more preferably about 20 to 35, weight percent nickel plus cobalt. This may facilitate the melting of the chromium/molybdenum/carbon combination that, if left alone, would form carbides having too high of melting temperatures for atomization.
  • Increasing the concentration of cobalt and nickel may also tend to increase the deposition efficiency for thermal spraying the powder. Because total nickel plus cobalt levels above about 45 weight percent may tend to soften the coating and limit the wear resistance of the coating, the total concentration of nickel plus cobalt may best be maintained below about 45 weight percent.
  • the alloys may contain only nickel or cobalt since coatings with only nickel (e.g., about 10 to 45 weight percent nickel) or only cobalt (e.g., about 10 to 45 weight percent cobalt) may form powders with wear resistance tailored for specific applications. But for most applications, cobalt and nickel appear to be interchangeable.
  • boron, silicon and/or manganese may be included in the alloys, powders and coatings.
  • the alloys may contain about 0.5 to 3, preferably about 1 to 2.5, and more preferably about 1.5 to 2, weight percent carbon plus boron, silicon and/or manganese.
  • the alloys may optionally contain melting point suppressants such as boron, silicon and manganese.
  • the alloys include precipitated carbides (and optionally nitrides) of chromium and molybdenum interspersed throughout .
  • the alloys may contain a volume fraction of the precipitated carbides and optionally nitrides in excess of 0.25.
  • the volume fraction of the precipitated carbides and optionally nitrides dispersed in the alloys may be 0.25 or greater and more preferably between 0.35 and 0.80.
  • the precipitated carbide and optionally nitride grains may be of micrometer and submicrometer size, for example, between 0.5 or less and 20 micrometers, more preferably between 1 and 10 micrometers in its largest dimensions.
  • the size and volume fraction of the precipitated carbides and optionally nitrides can be adjusted by varying the chromium, molybdenum and carbon content.
  • the alloys of this invention may be blended with molybdenum to form powders with wear resistance tailored for specific applications.
  • the amount of molybdenum that may be blended with the alloys of this invention is not narrowly critical and may range from about 10 to 50, preferably about 15 to 45, and more preferably about 20 to 40, weight percent of the total alloy/molybdenum blend composition.
  • the amount of blended molybdenum is in addition to the amount of alloy molybdenum.
  • the amount of blended molybdenum will depend upon the desired application.
  • the powders of this invention may be produced by means of inert gas atomization of a mixture of elements in the proportions stated herein.
  • Preferred atomization methods that may be employed in making the powders of this invention are described in U.S. Patent 5,863,618, the disclosure of which is incorporated herein by reference.
  • the alloys of these powders are typically melted at a temperature of about 1600°C and then atomized in a protective atmosphere (e.g., argon, helium or nitrogen). Most advantageously the atmosphere is argon.
  • a nitrogen atmosphere may be employed which may result in the formation of additional hard phases interspersed throughout the alloys, e.g., nitrides.
  • the alloy may optionally contain melting point suppressants like boron, silicon and manganese.
  • melting point suppressants like boron, silicon and manganese.
  • gas atomization however represents the most effective method for manufacturing the powder. Gas atomization techniques typically produce a powder having a size distribution of about 1 to 500 microns. For thermal spray applications, the powder is classified to a size of about 1 to 100 microns. Coatings may be produced using the alloys of this invention by a variety of methods well known in the art.
  • Thermal spray is a preferred method for deposition of powders to form the coatings of this invention.
  • the wear resistant alloy powders of this invention are useful for forming coatings having the same composition.
  • the alloy powders of this invention are useful for forming coatings or objects having excellent wear properties, for example, wear resistant coatings for protecting surfaces undergoing sliding contact with other surfaces such as piston rings and cylinder liners of internal combustion engines.
  • the examples that follow are intended as an illustration of certain preferred embodiments of the invention, and no limitation of the invention is implied.
  • Example 1 The alloy powders listed in Table I were made by processes alike to those described in U.S. Patent 5,863,618.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Powder Metallurgy (AREA)

Abstract

Cette invention concerne des alliages et des poudres d'alliage résistant à l'usure utiles pour un dépôt au moyen de dispositifs de pulvérisation thermique. Les alliages contiennent environ 20 à 65 % en poids de chrome, environ 20 à 65 % en poids de molybdène, environ 0,5 à 3 % en poids de carbone et environ 10 à 45 % en poids de nickel. Les poudres d'alliages résistant à l'usure sont utiles pour former des revêtements ayant la même composition.
EP05753987A 2004-05-28 2005-05-26 Poudres et revetements en alliages resistants a l'usure Withdrawn EP1768802A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US57492904P 2004-05-28 2004-05-28
PCT/US2005/018423 WO2005118185A1 (fr) 2004-05-28 2005-05-26 Poudres et revetements en alliages resistants a l'usure

Publications (2)

Publication Number Publication Date
EP1768802A1 true EP1768802A1 (fr) 2007-04-04
EP1768802A4 EP1768802A4 (fr) 2009-07-22

Family

ID=35462777

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05753987A Withdrawn EP1768802A4 (fr) 2004-05-28 2005-05-26 Poudres et revetements en alliages resistants a l'usure

Country Status (8)

Country Link
US (1) US20080274010A1 (fr)
EP (1) EP1768802A4 (fr)
JP (1) JP5222553B2 (fr)
CN (1) CN1997474A (fr)
BR (1) BRPI0511582A (fr)
CA (1) CA2567089C (fr)
MX (1) MXPA06013558A (fr)
WO (1) WO2005118185A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006042549C5 (de) * 2006-09-11 2017-08-17 Federal-Mogul Burscheid Gmbh Nasse Zylinderlaufbuchse mit kavitationsresistenter Oberfläche
JP5626947B2 (ja) * 2008-09-22 2014-11-19 独立行政法人物質・材料研究機構 大気中プラズマ溶射及び溶線式アーク溶射に使用される合金粒子及び線材
DE102009035210B3 (de) * 2009-07-29 2010-11-25 Federal-Mogul Burscheid Gmbh Gleitelement mit thermisch gespritzter Beschichtung und Herstellungsverfahren dafür
US8906130B2 (en) 2010-04-19 2014-12-09 Praxair S.T. Technology, Inc. Coatings and powders, methods of making same, and uses thereof
FI124135B (fi) * 2010-06-08 2014-03-31 Wärtsilä Finland Oy Mäntämoottorin sylinteriholkki
BRPI1101402A2 (pt) * 2011-03-29 2013-06-04 Mahle Metal Leve Sa elemento deslizante
KR20140083020A (ko) 2011-10-25 2014-07-03 가부시키가이샤 아이에이치아이 피스톤 링
US9611532B2 (en) * 2013-07-03 2017-04-04 Mahle International Gmbh Coating additive
CN103981398B (zh) * 2014-05-27 2016-11-23 湘潭大学 一种高性能金属陶瓷覆层材料及其制备方法
CN108085550A (zh) * 2017-12-21 2018-05-29 厦门佰事兴新材料科技有限公司 一种超音速火焰喷涂用喷管

Citations (4)

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Publication number Priority date Publication date Assignee Title
US4692305A (en) * 1985-11-05 1987-09-08 Perkin-Elmer Corporation Corrosion and wear resistant alloy
DE3802920C1 (fr) * 1988-02-02 1989-05-03 Goetze Ag, 5093 Burscheid, De
US6248292B1 (en) * 1998-02-25 2001-06-19 Toyota Jidosha Kabushiki Kaisha Overlay welding alloy and engine valve overlayed therewith
DE10061751C1 (de) * 2000-12-12 2002-07-25 Federal Mogul Burscheid Gmbh Verschleißschutzschicht für Kolbenringe

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Publication number Priority date Publication date Assignee Title
US4692305A (en) * 1985-11-05 1987-09-08 Perkin-Elmer Corporation Corrosion and wear resistant alloy
DE3802920C1 (fr) * 1988-02-02 1989-05-03 Goetze Ag, 5093 Burscheid, De
US6248292B1 (en) * 1998-02-25 2001-06-19 Toyota Jidosha Kabushiki Kaisha Overlay welding alloy and engine valve overlayed therewith
DE10061751C1 (de) * 2000-12-12 2002-07-25 Federal Mogul Burscheid Gmbh Verschleißschutzschicht für Kolbenringe

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Title
See also references of WO2005118185A1 *

Also Published As

Publication number Publication date
JP2008501073A (ja) 2008-01-17
CA2567089C (fr) 2010-04-20
EP1768802A4 (fr) 2009-07-22
BRPI0511582A (pt) 2008-01-02
MXPA06013558A (es) 2007-02-08
CA2567089A1 (fr) 2005-12-15
US20080274010A1 (en) 2008-11-06
CN1997474A (zh) 2007-07-11
WO2005118185A1 (fr) 2005-12-15
JP5222553B2 (ja) 2013-06-26

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