EP1626822A1 - Verfahren und vorrichtung zum kühlen bzw. abschrecken von brammen und blechen mit wasser in einem kühlbecken - Google Patents
Verfahren und vorrichtung zum kühlen bzw. abschrecken von brammen und blechen mit wasser in einem kühlbeckenInfo
- Publication number
- EP1626822A1 EP1626822A1 EP04731341A EP04731341A EP1626822A1 EP 1626822 A1 EP1626822 A1 EP 1626822A1 EP 04731341 A EP04731341 A EP 04731341A EP 04731341 A EP04731341 A EP 04731341A EP 1626822 A1 EP1626822 A1 EP 1626822A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling
- water
- slabs
- sheets
- basin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001816 cooling Methods 0.000 title claims abstract description 110
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 40
- 238000010791 quenching Methods 0.000 title claims abstract description 20
- 230000000171 quenching effect Effects 0.000 title claims abstract description 20
- 239000000498 cooling water Substances 0.000 claims abstract description 22
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 description 10
- 238000004364 calculation method Methods 0.000 description 9
- 239000013505 freshwater Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/63—Quenching devices for bath quenching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0203—Cooling
- B21B45/0209—Cooling devices, e.g. using gaseous coolants
- B21B45/0215—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes
- B21B45/023—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes by immersion in a bath
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0203—Cooling
- B21B45/0209—Cooling devices, e.g. using gaseous coolants
- B21B45/0215—Cooling devices, e.g. using gaseous coolants using liquid coolants, e.g. for sections, for tubes
- B21B45/0233—Spray nozzles, Nozzle headers; Spray systems
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/667—Quenching devices for spray quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
Definitions
- the invention relates to a method and a device for cooling or quenching slabs and sheets with water in a cooling basin, into which the slabs and sheets previously vertically erected by a tilting device are lowered in an upright position and temporarily adjusted.
- a cooling device For cooling slabs, a cooling device has become known from DE 25 48 154 A, which consists of a cooling basin for holding cooling water and an adjustment scaffold in the cooling basin for vertical adjustment of the slabs by means of a crane vehicle which can be moved over or along the cooling basin. This detects the slabs in an upright position with suitable gripping devices, places the slabs in the setting frame and lifts them out again after cooling.
- a tilting device is arranged at the front end of the cooling basin for erecting the slab in an upright position pushed over by a feed roller table in an upright position.
- Two independent tipping devices are also located in the area of feed and discharge roller tables for uprighting and storing slabs.
- the cooling rate that can be achieved with this leads to a longer quenching process when quenching (hardening and tempering) metal sheets and slabs.
- quenching hardening and tempering
- Due to uneven cooling rates over the sheet or slab surface it cannot be avoided that the material used becomes wavy and unplanned. An additional straightening process is therefore usually required after the quenching.
- the invention has for its object to provide a method and an apparatus of the type mentioned, with which the disadvantages mentioned can be avoided and the quenching can be achieved with better quality.
- This object is achieved with a method according to the invention in that the slabs and sheets are irradiated with cooling water.
- the slabs and sheets are irradiated with cooling water.
- a preferred embodiment of the invention provides that the slabs and sheets are completely immersed in a cooling basin filled with water and are additionally irradiated with cooling water in the water bath of the cooling basin.
- a kind of whirlpool quenching or cooling can be carried out here.
- An alternative embodiment provides that the water level in the cooling basin is lowered and the slabs and sheets are introduced into the cooling basin at a distance from their lower edge to the water level and are irradiated with cooling water.
- One and the same system thus makes it possible to change the cooling process depending on, for example, the material quality and to carry out the cooling process on the same cooling system without other or additional devices, either as a nozzle operation or in a whirlpool operation, while still taking into account different fresh water requirements and the temperature of the goods to be cooled as well as the water temperature, in each case based on a start and an end temperature, which can also vary.
- the cooling system can advantageously be based on a physical-mathematical cooling model.
- a fundamental problem with accelerated cooling is the exact description of the time course of the temperature fields within the rolling stock.
- the calculation using mathematical models is a suitable tool for planning, controlling and optimizing the process.
- the physical-mathematical cooling model describes the transient time-temperature behavior of the sheet with the boundary conditions of the temperature-dependent material values and the heat transfer coefficient, which depends on the local surface temperature of the slab / sheet.
- the material characteristics are determined according to the alloy components or the material class for each good to be cooled. The corresponding calculations are then carried out with these temperature-dependent material characteristics.
- the required amount of water or cooling rate and the corresponding cooling curves for the slab / sheet are calculated.
- the cooling model it is also possible to simulate calculations offline. Here, e.g. the different cooling rates for different amounts of water are compared to optimize the cooling process. These offline calculations can be triggered from the dialog described above. This makes it possible to return a log with the most important parameters and operating results to the PLS system. Parameters and coefficients for material as well as boundary conditions, e.g. in the temperature model.
- the cooling basin according to the invention has nozzle means arranged on both sides of the lowered slabs / sheets with alignment on their broadside surfaces, which are connected to a cooling water circuit, the means for lowering the water filling from a maximum , upper water level to a low, lower water level.
- nozzles of nozzle bars fed centrally with cooling water can provide the additional cooling water directly at the scene after setting the slab or sheet onto it.
- a constant nozzle distance is maintained over the entire surface; depending on the requirement profile, this can be between 10 and 500 mm.
- the plate or slab can be aligned accordingly by means of a hydraulically operated pressing device.
- a preferred embodiment of the invention provides that the cooling basin is designed with tracks for a slab or a sheet-receiving, liftable and lowerable slide.
- the sled can be brought in and out very quickly.
- the dwell time for quenching slabs or sheets in the cooling basin is greater than 30 minutes.
- the carriage is connected to a cable drive.
- This preferably has ropes guided over rope drums attached to the carriage, the rope drums being mechanically coupled to a frequency-controlled three-phase motor.
- Vertical lowering and lifting can be done with the cable drive in the shortest possible time; the time interval for completely immersing a slab / sheet is less than 10 seconds.
- the good running ability of the slide is favored here if it is guided over the tracks by rollers / wheels.
- Fig. 1 of a cooling system having two adjacent cooling pools as a detail with a cross section through the cooling pools this associated tilting device and lowering and lifting device for setting slabs / sheets;
- FIG. 2 shows the two cooling pools according to FIG. 1, with the cooling water circuit for slab / sheet quenching being shown;
- Fig. 3 in a schematic representation as a detail of Figure 1 shows a cross section through the right there, the set refrigerated receiving basin.
- FIG. 4 shows a very simplified basic illustration of a cooling process to be carried out in the cooling system according to FIG. 1;
- Fig. 5 in a very simplified schematic representation of another cooling process to be carried out in the cooling system according to Fig. 2.
- a cooling system 20 shown in FIG. 1 consists of a cooling basin 1 and an adjacent pump supply basin 14.
- the two basins 1 and 14 are connected to one another by flow connections in the form of a lower and an upper overflow 15a and 15b.
- the cooling system 20, e.g. after the austenitizing, the hot slabs / sheets 2 are positioned on a bogie car 16 coming from a heating furnace and are positioned over a sliding platform 17.
- a hydraulically actuated tilting device 18 the hot slab / sheet 2 is lifted off the bogie wagon 16 and, in an upright position, is transferred to a carriage 3 which can be raised and lowered in the cooling basin 1.
- the tilting device 18 assigned to the front right-hand cooling or quenching basin 1 has a rotatably mounted shaft 19 on which lifting arms 21 are mounted, which are in a horizontal position for taking over the slab / sheet 2 and with the slab / sheet lying thereon 2 can be run over by the bogie wagon 16.
- the lifting arms 21 are moved by hydraulic cylinders 22 from the horizontal position by 90 ° into the transfer position, in which the slab / sheet 2 is upright, rotated or pivoted.
- the slab / sheet 2 is supported on the lower edge by pawls 23 which can be acted upon by hydraulic cylinders 24.
- the position is detected by a position sensor (not shown), the slabs / sheets 2 being fed up being carried out in an automatic sequence after manual triggering.
- the carriage 3 is raised slightly, whereby the slab / sheet 2 is released from the pawls 23, which can thus be pivoted away.
- the carriage 3 is then lowered very quickly to cool the slab / sheet 2.
- the removal of the slab / sheet 2 takes place in the reverse manner as previously described for the setting in automatic mode.
- the cooled slab / sheet 2 then either rests against the bogie wagon 16 or can be transported away by the indoor crane, for which purpose the transfer platform 17 has to be moved laterally when the indoor crane is transported away.
- FIG. 3 shows a slab 2 placed in the upright position and introduced into the carriage 3 in the manner described above.
- the carriage 3 is connected to a cable drive 4 which Has on ropes 5 attached to the carriage 3 and previously running over deflection 6 ropes 7.
- a frequency-controlled three-phase motor (not shown) with a reduction gear acts mechanically coupled to the cable drums 5 by means of cardan shafts.
- the carriage 3 runs with rollers or wheels 8 on tracks 9 provided in the cooling basin 1.
- the slab 2 completely into the cooling basin 1 lowered position of carriage 3 and slab 2 is illustrated in Fig. 3 by dotted lines.
- the slabs / sheets 2 set as described above are located in the cooling tank 1 between the raceways 9 with the alignment of nozzles 10 to each
- the cooling water circuit 12 enables variable cooling or cooling processes and ensures the supply of the nozzle bars 11a, 11b in the quenching basin 1 for cooling slabs / sheets 2 both in a pure nozzle operation and in the manner of a whirlpool operation. There are three cases, for example:
- the slab / sheet 2 is irradiated with cooling water through the nozzle bars 11a, 11b.
- the maximum, low water level 13a here in the quenching basin 1 - as well as the adjacent pump supply basin 14 - is below the lower edge of the slab / sheet 2 during the cooling process.
- the cooling water is sucked out of the pump reservoir 14 by the pumps 25a, 25b and conveyed via a filter 26 to the nozzle bars 11a, 11b.
- a speed control for the pumps 25a, 25b enables defined pressurization with cooling water depending on the sheet size and thickness.
- the function of the filter 26 is to retain scale particles that are larger than the nozzle openings and thus to avoid blockages. It is rinsed with its own medium after each cooling process. The rinse water is led to a sintering channel 27 and supports the lowering of the water level after the cooling process. The majority of the scale settles on the bottom of the cooling basin 1, so that the basin floor is cleaned from time to time.
- the water running off the slab / from the sheet 2 is collected in the basin 1 and from there reaches the pump reservoir 14 via an overflow 15a.
- the setback and fresh water volume depend on the end temperature of the last process and the start temperature of the next cooling program.
- the set / fresh water quantity is switched via the fill level in the pump displacement basin 14. If there is a high cooling requirement, basin 1 can also be lowered via a bypass 31 (cf. FIG. 2).
- FIG. 4 Another cooling process is shown in a very schematic manner in FIG. 4.
- a quenching process by whiripool operation i.e. with constant strong flow - as also indicated in Fig. 3 by the wavy lines in the cooling basin 1 - made possible.
- the slab / sheet 2 is immersed in basin 1 filled with high water level 13b and at the same time with water from the
- the function of the filter 26 and the pumps 25a, 25b or the pump 29 is the same as in nozzle operation, as is the fresh water control. However, due to the larger storage volume in the whirlpool pool operation, a higher cooling start temperature is possible or several cooling processes can be carried out at a low cooling start temperature until the permissible upper water temperature limit is reached.
- cooling processes for which a cooling model is stored without additional units on the same cooling system 20 it is thus possible to change the cooling processes for which a cooling model is stored without additional units on the same cooling system 20.
- the entire cooling process runs according to a physical-mathematical cooling model via a higher-level computer, which also allows controls of the water temperature, water pressure, volume flow and the distance between the nozzles of the nozzle bars and the slab or sheet surface.
- cooling by immersion operation without jet radiation can optionally also be carried out in the same cooling system 20.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10320651 | 2003-05-07 | ||
| DE102004023031A DE102004023031A1 (de) | 2003-05-07 | 2004-05-06 | Verfahren und Vorrichtung zum Kühlen bzw. Abschrecken von Brammen und Blechen mit Wasser in einem Kühlbecken |
| PCT/EP2004/004830 WO2004098804A1 (de) | 2003-05-07 | 2004-05-06 | Verfahren und vorrichtung zum kühlen bzw. abschrecken von brammen und blechen mit wasser in einem kühlbecken |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1626822A1 true EP1626822A1 (de) | 2006-02-22 |
| EP1626822B1 EP1626822B1 (de) | 2006-10-25 |
Family
ID=33435963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04731341A Expired - Lifetime EP1626822B1 (de) | 2003-05-07 | 2004-05-06 | Verfahren und vorrichtung zum kühlen bzw. abschrecken von brammen und blechen mit wasser in einem kühlbecken |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8043086B2 (de) |
| EP (1) | EP1626822B1 (de) |
| AT (1) | ATE343438T1 (de) |
| BR (1) | BRPI0410088A (de) |
| CA (1) | CA2532719C (de) |
| DE (1) | DE502004001860D1 (de) |
| ES (1) | ES2274451T3 (de) |
| RU (1) | RU2353673C2 (de) |
| WO (1) | WO2004098804A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5121039B2 (ja) * | 2005-01-19 | 2013-01-16 | 新日鐵住金株式会社 | 鋼片の水冷方法 |
| ITMI20111072A1 (it) * | 2011-06-14 | 2012-12-15 | Eagle Tech S R L | Dispositivo atto a consentire il raffreddamento controllato di billette metalliche da estrudere a caldo e metodo di trattamento relativo. |
| CN107388694A (zh) * | 2017-08-31 | 2017-11-24 | 盛红梅 | 一种工件冷却系统 |
| WO2020012222A1 (en) * | 2018-07-11 | 2020-01-16 | Arcelormittal | Method to control the cooling of a metal product |
| US11203492B2 (en) * | 2019-12-11 | 2021-12-21 | Symbotic Canada, Ulc | Case reorientation system and method |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2341766A (en) * | 1941-12-12 | 1944-02-15 | Vernie A Fox | Rapid-quench heat-treating oven |
| US3186698A (en) * | 1963-06-14 | 1965-06-01 | Midland Ross Corp | Heat treating apparatus |
| US3323577A (en) * | 1965-05-05 | 1967-06-06 | Olin Mathieson | Process for cooling metal |
| US3556877A (en) * | 1967-04-03 | 1971-01-19 | Mitsubishi Heavy Ind Ltd | Method for hardening a tubular shaped structure |
| BE756498A (fr) * | 1970-01-20 | 1971-03-01 | Bwg Bergwerk Und Walzwerkmasch | Dispositif de refroidissement de brames |
| US3725024A (en) * | 1971-01-21 | 1973-04-03 | Ppg Industries Inc | Tempering glass sheets with liquid flows |
| US3738629A (en) * | 1971-03-04 | 1973-06-12 | Dorn Co V | Bar quench fixture |
| US3706544A (en) * | 1971-07-19 | 1972-12-19 | Ppg Industries Inc | Method of liquid quenching of glass sheets |
| BE788789A (fr) * | 1971-09-13 | 1973-03-10 | Triplex Safety Glass Co | Perfectionnements a la fabrication de feuilles de verre trempeset cintrees |
| US3870570A (en) * | 1972-11-13 | 1975-03-11 | Arthur H Fieser | Method for conditioning metal slabs |
| US3829072A (en) * | 1972-11-13 | 1974-08-13 | A Fieser | Metal slab conditioning system |
| GB1442314A (en) * | 1973-07-20 | 1976-07-14 | Triplex Safety Glass Co | Heat treatment of glass sheets |
| AT342546B (de) * | 1975-07-07 | 1978-04-10 | Bwg Bergwerk Walzwerk | Greif- und transportvorrichtung fur ein wasserkuhlbecken von rechteckigem grundriss mit einem aus zinken gebildeten fachartigen einstellgerust zum lotrechten einstellen von brammen |
| DE2548154B2 (de) | 1975-10-28 | 1979-12-13 | Sack Gmbh, 4000 Duesseldorf | Kühlvorrichtung für Brammen mit Brammenkippstuhlen zum Wenden des Walzgutes |
| JPS5819728B2 (ja) | 1975-12-01 | 1983-04-19 | 新日本製鐵株式会社 | コウハンノコウキレイキヤクホウホウ |
| JPS5934771A (ja) | 1982-08-20 | 1984-02-25 | Casio Comput Co Ltd | ポ−タブルテレビジヨン受像機 |
| JPS609834A (ja) | 1983-06-28 | 1985-01-18 | Nippon Steel Corp | 鋼ストリツプの冷却方法及びその装置 |
| JPS61217531A (ja) | 1985-03-22 | 1986-09-27 | Kawasaki Steel Corp | 鋼帯の冷却方法 |
| SU1320245A1 (ru) * | 1986-10-14 | 1987-06-30 | Днепропетровский Металлургический Институт Им.Л.И.Брежнева | Устройство дл закалки металлических изделий |
| SU1502638A1 (ru) * | 1987-01-21 | 1989-08-23 | Колпинское Отделение Всесоюзного Научно-Исследовательского И Проектно-Конструкторского Института Металлургического Машиностроения Им. А.И.Целикова | Устройство дл охлаждени толстых листов |
| US5795538A (en) * | 1993-01-27 | 1998-08-18 | Dowa Mining Co., Ltd. | Apparatus for steel hardening and process therefor |
| JP3621101B2 (ja) * | 1993-05-18 | 2005-02-16 | アルミナム カンパニー オブ アメリカ | 溶解ガスを含む冷却液による金属の熱処理方法 |
| IT1277364B1 (it) * | 1995-07-27 | 1997-11-10 | Pomini Spa | Impianto perfezionato per il trattamento termico in linea di prodotti laminati a caldo |
| JP3726506B2 (ja) | 1998-05-28 | 2005-12-14 | Jfeスチール株式会社 | 鋼片の水冷方法 |
-
2004
- 2004-05-06 WO PCT/EP2004/004830 patent/WO2004098804A1/de not_active Ceased
- 2004-05-06 US US10/555,854 patent/US8043086B2/en not_active Expired - Fee Related
- 2004-05-06 DE DE502004001860T patent/DE502004001860D1/de not_active Expired - Lifetime
- 2004-05-06 CA CA2532719A patent/CA2532719C/en not_active Expired - Fee Related
- 2004-05-06 ES ES04731341T patent/ES2274451T3/es not_active Expired - Lifetime
- 2004-05-06 BR BRPI0410088-3A patent/BRPI0410088A/pt not_active Application Discontinuation
- 2004-05-06 AT AT04731341T patent/ATE343438T1/de active
- 2004-05-06 EP EP04731341A patent/EP1626822B1/de not_active Expired - Lifetime
- 2004-05-06 RU RU2005138038/02A patent/RU2353673C2/ru active
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2004098804A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE502004001860D1 (de) | 2006-12-07 |
| CA2532719A1 (en) | 2004-11-18 |
| CA2532719C (en) | 2010-10-19 |
| BRPI0410088A (pt) | 2006-05-16 |
| US8043086B2 (en) | 2011-10-25 |
| RU2353673C2 (ru) | 2009-04-27 |
| RU2005138038A (ru) | 2006-05-10 |
| ATE343438T1 (de) | 2006-11-15 |
| ES2274451T3 (es) | 2007-05-16 |
| EP1626822B1 (de) | 2006-10-25 |
| WO2004098804A1 (de) | 2004-11-18 |
| US20060292513A1 (en) | 2006-12-28 |
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