Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
  • B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
  • B22D11/003—Aluminium alloys
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
  • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
  • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
  • B22D11/0605—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two belts, e.g. Hazelett-process
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
  • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
  • B22D11/12—Accessories for subsequent treating or working cast stock in situ
  • B22D11/124—Accessories for subsequent treating or working cast stock in situ for cooling
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/02—Alloys based on aluminium with silicon as the next major constituent
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
  • C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
  • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
  • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
  • C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
  • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
  • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
  • C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions

Definitions

• the present invention relates to an aluminum alloy plate with excellent press-formability and continuous resistance spot weldability which is useful as a structural material for forming the outer panels of products such as household appliances or automobiles that are assembled by resistance spot welding before or after press molding.
• the structural materials and the outer panels of products of household appliances and automobiles are pressed firstly forming, then resistance spot welded to assemble the products.
• Al-Mg-Si type alloy plates show a relatively attractive surface appearance after press forming, and are therefore used in various types of outer panels and structural materials, but require good press-formability due to the diversity of product shapes.
• Japanese Patent Application, First Publication No. S62-207851 describes a method for manufacturing a rolled plate such as a body plate with good formability, comprising steps of preparing an aluminum alloy melt containing 0.4-2.5% of Si, 0.1-1.2% of Mg, one or more types chosen from among 1.5% or less of Cu, 2.5% or less of Zn, 0.3% or less of Cr, 0.6% or less of Mn and 0.3% or less of Zr, with the remainder consisting of Al and unavoidable impurities; continuously casting the melt into 3-15 mm thick slabs; performing cold rolling; and then performing a solution heat treatment and quenching.
• Japanese Patent Application, First Publication No. 2001-262264 describes Al-Mg-Si type aluminum alloy plates used for automobile panels with good bendability.
• the publication discloses an Al-Mg-Si type aluminum alloy plate with excellent toughness and bendability, basically comprising 0.1-2.0% of Mg, 0.1-2.0% of Si and 0.1-1.5% of Fe in % by mass, with the remainder consisting of Al, wherein the maximum size of Fe and Si containing compounds is 5 ⁇ m or less, and the average grain size is 30 ⁇ m or less.
• an Al-Mg-Si type aluminum alloy plate with excellent toughness and bendability basically comprising 0.1-2.0% of Mg, 0.1-2.0% of Si, 0.1-1.5% of Fe and 2.0% or less of Fe in % by mass, with the remainder consisting of Al, wherein the maximum size of Fe, Si and Cu containing compounds is 5 ⁇ m or less, and the average crystal grain size is 30 ⁇ m or less. Furthermore, it discloses an Al-Mg-Si type aluminum alloy plate with excellent toughness and bendability such as those described above, further comprising at least one element chosen from the group consisting of 1.0% or less of Mn, 0.3% or less of Cr, 0.3% or less of Zr, 0.3% or less of V and 0.03% or less of Ti.
• the technique described in Japanese Patent Application, First Publication No. S62-207851 uses a twin-roller casting process with casting at a cooling rate of at least 100 °C/sec, so that the size of intermetallic compounds that crystallize during casting is small, as a result of which the number of relatively large compounds that affect the grain size at recrsytallization is not sufficient, so that the grain size after solution heat treatment is large, thus degrading the press-formability, and the number of continuous resistance spot welds is reduced.
• the technique disclosed in Japanese Patent Application, First Publication No. 2001-262264 uses a continuous casting process, with casting at a cooling rate of at least 10 °C/sec, but in the examples, a maximum cooling rate of 30 °C/sec is used. Due to the slow cooling rate, the size of intermetallic compounds that crystallize during casting is large, as a result of which the number of relatively large compounds that affect the grain size at recrsytallization is not sufficient, so that the grain size after solution heat treatment is large, thus degrading the press-formability and reducing the number of continuous resistance spot welds.
• the purpose of the present invention is to offer an aluminum alloy plate with excellent press-formability and continuous resistance spot weldability, and a manufacturing process thereof.
• the present inventors achieved the present invention on the basis of the discovery that by selecting the optimum range for the cooling rate when casting a melt within an appropriate composition range, it is possible to optimize the size and number of intermetallic compounds that crystallize, so as to obtain excellent press-formability and continuous resistance spot weldability in an aluminum alloy plate after a solution heat treatment.
• the present invention offers an aluminum alloy plate with excellent press-forinability and continuous resistance spot weldability comprising, in % by mass, 0.3-1.0% of Mg, 0.3-1.2% of Si, 0.10-1.0% of Fe and 0.05-0.5% of Mn; where Fe + Mn > 0.2%; the remainder consisting of Al and unavoidable impurities; wherein an average value of recrystallized grain size is 25 ⁇ m or less; and there are at least 5000 particles/mm 2 of intermetallic compounds with a circle-equivalent diameter of 1-6 ⁇ m.
• the present invention excels in press-formability and continuous resistance spot weldability due to the fineness of the recrsytallization grain size and the large number of compounds of optimum size.
• the strength can be further improved by making the above composition contain Cu in an amount of 0.5-1.0%.
• the recrystallization grain size can be made finer and the strength further improved by making the above composition contain Zr in an amount of 0.1-0.4%.
• Casting cracks can be reliably prevented from occurring during casting by making the above composition contain Ti in an amount of 0.05% or less, or Ti in an amount of 0.05% or less and B in an amount of 0.01% or less.
• a second aspect of the present invention is a method of manufacturing an aluminum alloy plate with excellent press-formability and continuous resistance spot weldability, comprising steps of pouring a melt consisting of the above-claimed composition into an opposing rotating belt cast that is forcibly cooled; casting the melt at a cooling rate of 40-90 °C/sec to form a 5-10 mm thick slab; drawing said slab from the side opposite the side where the melt was poured; rolling directly or after winding into a coil; and subjecting to a solution heat treatment.
• a large number of compounds of optimum size can be crystallized by casting the alloy melt at an optimal cooling rate when casting, thereby refining the recrystallization grain size to result in aluminum alloy plates with excellent press-formability, and continuous spot weldability is good.
• Mg and Si are added to improve the strength and to provide press-formability.
• concentration is less than the indicated lower limit, the effects are inadequate, and when more than the indicated upper limit, the press -formability deteriorates.
• Cu is added to further improve the strength and press-formability.
• concentration is less than the lower limit, its effect is small, and when the quantity exceeds the upper limit, the corrosion resistance is degraded.
• Zr promotes the crystallization of the intermetallic compound Al 3 Zr, further induces crystallization of many compounds of specific size to increase the number of recrystallized nuclei, and thereby make the size of the recrsytallized grains smaller, so as to improve press-formability The effect is lost when the concentration is less than the lower limit, and when the quantity exceeds the upper limit, large compounds are formed so that the rollability is reduced.
• Rapid cooling during casting of the melt can cause casting cracks to occur, and the addition of Ti or Ti and B can prevent such cracks. It is possible to add either Ti alone at a quantity of 0.05% or less, or to also add 0.01% or less of B to obtain a composite with Ti, in which case there is a synergistic effect. The effect is most apparent when the lower limit of the Ti is at least 0.002%, and the lower limit of B is at least 0.0005%.
• the unavoidable impurities can come from the base aluminum, scrap and ingot jigs or the like, some of the typical elements including Cr, Ni, Zn, Ga and V. Since Cr is added to prevent stress corrosion of the Al-Mg alloy, it can easily be introduced from scrap, but is allowable in the present invention if less than 0.3%.
• the quantity of Ni should be held to less than 0.2%, that of Ga and V respectively less than 0.1%, and that of any other unavoidable impurities to less than 0.3% in order to maintain the formability.
• the recrystallization grain size should preferably be 20 ⁇ m or less, and 15 ⁇ m or less.
• Intermetallic compounds having a circle equivalent diameter of 1-6 ⁇ m are of a size promoting the accumulation the integration of dislocations during cold rolling and having an effect of refining the recrystallized grains, so that if the size and number is less than the lower limit, the dislocation accumulation rate is low, and if the number is less than 5000 particles/mm 2 , fine recrystallized grains of a preferable size cannot be obtained. Additionally, if the size exceeds the upper limit, the large compounds can cause streaks or cracks during rolling and thereby lower the rollability.
• the quantity of the compounds is more preferably at least 6000 particles/mm 2
• the melt is prepared by adjusting the composition, degassing, settling, making fine adjustments of the composition as needed, adding Ti or Ti and B as a mother alloy and casting.
• the melt is poured into forcibly cooled rotating belters facing each other, with the cooling rate 40-90 °C/sec, to form a 5-10 mm thick slab, then drawing the slab from the opposite side to where the melt was poured, to roll it directly or after winding into a coil.
• Continuous casting processes include a twin -roller casting process of pouring the melt between forcibly cooled rotating rollers that are facing each other, rapidly cooling the melt on the roller surfaces, and continuously withdrawing thin slabs from the opposite side, and a twin-belt casting process of pouring the melt between forcibly cooled rotating belts that are facing each other, rapidly cooling the melt on the belt surfaces, and continuously withdrawing thin slabs from the opposite side.
• the twin-roller casting process has a cooling rate during casting of at least 300 °C/sec which is considerably high, while the size of compounds in the resulting slab are small and the plates of the present invention are not obtained.
• the twin-belt casting process involves rapidly cooling the melt on the belt surface, but the cooling rate is not as high as with the twin-roller casting process.
• the casting conditions of the twin-belt casting process are adjusted so as to make the melt cooling rate 40-90 °C/sec (at a position of 1/4 thickness of the slab), so as to form more than 5000 particles/mm 2 of intermetallic compounds with a circle-equivalent diameter of 1-6 ⁇ m in the final plates. If the melt cooling rate is less than 40 °C/sec, larger compounds are crystallized, causing a deficiency of compounds in the above-defined size range, so that the recrystallized grains are not refined and plates with excellent press-formability cannot be obtained. Additionally, at more than 90 °C/sec, fine compounds are crystallized, causing a reduction of compounds in the above-defined size range, so that a plate with refined recrsytallized grains cannot be obtained.
• a slab obtained by a twin-belt casting process is cold-rolled to form a plate of a desired thickness, which undergoes a solution heat treatment and is recrsytallized. At this time, it is possible to provide an anneal during the cold rolling step, but the rolled plate provided for the solution heat treatment has at least a cold reduction of 55%.
• the solution heat treatment is performed in a continuous annealing furnace. The heating temperature is at least 500 °C, the cooling rate to 100 °C is set to at least 1 °C/sec.
• the recrystallized grains of the rolled plates that have undergone the solution heat treatment have an average grain size of 25 ⁇ m or less due to the size and number of the intermetallic compound and the reduction. Such plates can be used either as they are, or after passing through a skin pass or leveler of about 1-5% in order to obtain flatness.
• Example 13 7521 9 131 251 23 13.6 A Comp.
• Example 14 3924 26 112 215 26 13.5 C Comp.
• Example 15 36721 6 133 241 21 13.5 A Comp.
• Example 16 7820 11 134 248 20 13.7 A Comp.
• Example 17 7541 9 160 288 22 13.8 A Comp.
• Example 18 8783 7 142 235 21 13.9 A Comp.
• Example 19 2215 29 109 215 20 12.5 C
• Example (Note) A: at least 500 consecutive hits B: at least 200 less than 500 consecutive hits C: less than 200 consecutive hits Underlined values are outside the range of the present invention. Recrystallized grain size was measured by liner intercept method.
• the aluminum alloy plates according to the present invention excel in press-formability and continuous resistance spot weldability, and surface appearance after press is good, enabling continuous assembly by resistance spot welding, therefore productivity is high.
• This 6000 type alloy plate also has higher strength improves in a baking step after coating or the like, so as to have excellent industrial value in a wide range of applications such as in the body panels of automobiles.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Physics & Mathematics (AREA)
• Thermal Sciences (AREA)
• Crystallography & Structural Chemistry (AREA)
• Continuous Casting (AREA)

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• 2004
  • 2004-02-24 JP JP2004048360A patent/JP4379149B2/ja not_active Expired - Fee Related
  • 2004-04-08 TW TW093109748A patent/TW200504226A/zh not_active IP Right Cessation
  • 2004-04-13 WO PCT/JP2004/005258 patent/WO2004092432A1/fr not_active Application Discontinuation
  • 2004-04-13 EP EP04727133A patent/EP1614760A4/fr not_active Withdrawn
  • 2004-04-13 CA CA002521006A patent/CA2521006A1/fr not_active Abandoned
  • 2004-04-13 US US10/553,316 patent/US20070062618A1/en not_active Abandoned
  • 2004-04-13 KR KR1020057018560A patent/KR100710795B1/ko not_active IP Right Cessation

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