EP1602743B1 - Nitrided valve lifter and method for manufacture thereof - Google Patents

Nitrided valve lifter and method for manufacture thereof Download PDF

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Publication number
EP1602743B1
EP1602743B1 EP04718747A EP04718747A EP1602743B1 EP 1602743 B1 EP1602743 B1 EP 1602743B1 EP 04718747 A EP04718747 A EP 04718747A EP 04718747 A EP04718747 A EP 04718747A EP 1602743 B1 EP1602743 B1 EP 1602743B1
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EP
European Patent Office
Prior art keywords
valve lifter
nitriding
compound layer
surface roughness
cam
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EP04718747A
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German (de)
English (en)
French (fr)
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EP1602743A1 (en
EP1602743A4 (en
Inventor
Katsuhiro c/o Kabushiki Kaisha Riken YAMASHITA
Yasushi c/o Kabushiki Kaisha Riken UENO
Kazuyuki c/o Kabushiki Kaisha Riken SHITO
Shinnosuke c/o Oriental Engineering Co. Ltd MUNEMURA
Chikara c/o Oriental Engineering Co. Ltd. SUGAWARA
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Riken Corp
Oriental Engineering Co Ltd
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Riken Corp
Oriental Engineering Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/28—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in one step
    • C23C8/30—Carbo-nitriding
    • C23C8/32—Carbo-nitriding of ferrous surfaces
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24—Nitriding
    • C23C8/26—Nitriding of ferrous surfaces
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/02—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/34—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases more than one element being applied in more than one step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
    • F01L1/00—Valve-gear or valve arrangements, e.g. lift-valve gear
    • F01L1/12—Transmitting gear between valve drive and valve
    • F01L1/14—Tappets; Push rods
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
    • F01L1/00—Valve-gear or valve arrangements, e.g. lift-valve gear
    • F01L1/12—Transmitting gear between valve drive and valve
    • F01L1/14—Tappets; Push rods
    • F01L1/16—Silencing impact; Reducing wear
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
    • F01L2303/00—Manufacturing of components used in valve arrangements

Definitions

  • the present invention relates to a valve lifter which is a valve driving component, subjected to nitriding, of an internal combustion engine, and a producing method thereof, and further relates to a combination of the valve lifter and a cam.
  • a valve lifter 1 for converting a rotating motion of a cam 11 into a reciprocating motion of a valve 12 is subjected to a sliding contact in a reciprocating motion with a cylinder block 14 and a shim 3 or an upper surface 2 (cf. Fig. 1) of the valve lifter coming into contact with the cam 11 is subjected to a sliding contact under a high load and an impact load, so that an improvement in a wear resistance and an impact resistance is indispensable.
  • the surface roughness of sliding surface of the cam 11 of which a material has a wear resistance and an impact resistance properties has to be improved to reduce an attacking nature against the valve lifter due to avoiding a boundary lubricating condition.
  • a nitriding process has been commonly employed as a simple method for improving the wear resistance of the valve lifter 1, but a compound layer (also called a white layer by those skilled in the art) formed on the outermost surface by nitriding, having a high hardness but being also very brittle, has been removed by grinding, polishing or the like, whereby a nitriding diffusion layer only is left for use.
  • a compound layer also called a white layer by those skilled in the art
  • the characteristics of the compound layer having a high hardness and a low friction coefficient are attracting attention as a measure for meeting recent requirements for a higher power or a lower fuel consumption of the internal combustion engine, and a sliding component specification, in which a compound layer is left even after a polishing for reducing friction on the upper surface 2 of the valve lifter 1 in sliding contact with the cam 11, and a producing method thereof is proposed and disclosed for example in JP-A No. 2002-97563 .
  • JP-A No. 2002-97563 employs a prior nitriding process; whereby a compound layer having a brittle surface layer with deteriorated surface roughness is formed relatively thick (5 to 15 ⁇ m) in the nitriding process, and relatively large deformation is occurred in the processed articles. Consequently it is necessary to improve the surface roughness while leaving the compound layer in a subsequent step, and there is required a very difficult and unstable polishing process of making a thin compound layer further thinner.
  • An ordinarily employed process for forming the compound layer is generally conducted for several hours at about 570°C aiming at a formation of compound layer of about 10 ⁇ m.
  • Such process forms a porous layer and is associated with drawbacks not only of forming a brittle ⁇ -phase (Fe 2-3 N) but also of causing a large deformation in a processed article and a significant deterioration in a surface roughness.
  • the compound layer is composed of a porous ⁇ -phase (Fe 2-3 N) of the outermost surface (porous layer), and a dense ⁇ '-phase (Fe 4 N) and/or a mixed phase of ⁇ -phase and ⁇ '-phase ( ⁇ + ⁇ ' phase) under the porous layer.
  • a porous ⁇ -phase Fe 2-3 N
  • a dense ⁇ '-phase Fe 4 N
  • a mixed phase of ⁇ -phase and ⁇ '-phase ⁇ + ⁇ ' phase
  • a polishing process after the nitriding is indispensable in order to reduce an attacking nature against the counterpart material, but a polishing margin has to be selected relatively large since the porous layer has an uneven thickness. Also since a uniform polishing is difficult to achieve for example because of an unevenness in the hardness, the porous layer may still remain after the polishing.
  • the state, in which the porous layer is remained on the upper surface results in a peeling or falling off of it, thus leading to a trouble.
  • JP-A No. 2002-97563 discloses polishing means such as buffing for eliminating the porous layer and for controlling a thickness and a surface roughness of the compound layer.
  • the compound layer is composed of an ⁇ -phase (Fe 2-3 N), a dense ⁇ '-phase (Fe 4 N), and a mixed ⁇ + ⁇ ' phase, and it is difficult to do a uniform polishing because of a phase distribution and a hardness variation, there tend to be given a portion where the compound layer is completely removed and a portion where the compound layer still remains within a same polished surface, so that a compound layer with uniform thickness cannot be obtained. Consequently there are encountered such drawbacks that the wear resistance varies and an effect of reducing the frictional torque cannot be obtained.
  • the ground surface roughness of the sliding surface (of the cam) is relatively rough so that it causes deterioration in a surface roughness of the brittle compound layer of the upper surface.
  • expensive equipments for paper-lapping machine, etc. and long machining time resulting in the high cost are required in order to reduce the frictional torque from the beginning of the operation and to avoid an unstable boundary lubricating condition.
  • An object of the present invention is to solve the aforementioned drawbacks, i.e., it is to provide a valve lifter in which a uniform and dense nitriding compound layer of a high wear resistance is formed on a surface, and a producing method thereof bringing about little deterioration in the surface roughness and little deformation in the processed article by the nitriding process and not requiring a polishing process for improving a wear resistance, a surface roughness and a dimensional accuracy. Furthermore, the object of the present invention is to provide a valve lifter, which is used in combination with the cam of which the sliding surface is not polished by the paper-lapping machine, etc.
  • a diffusion layer of a relatively low nitrogen concentration and a compound layer of a high nitrogen concentration there are generally formed, in layered manner, a diffusion layer of a relatively low nitrogen concentration and a compound layer of a high nitrogen concentration.
  • a high nitriding temperature forms a thick compound layer with a brittle porous outermost surface.
  • the brittle porous layer can be minimized by adopting a lower nitriding temperature, the diffusion layer also becomes thin in such case.
  • the diffusion layer in the valve lifter requires a thickness of 50 to 100 ⁇ m, it is desirable to obtain such diffusion layer of 50 to 100 ⁇ m as mentioned above and a compound layer of dense and a predetermined surface roughness showing high hardness and low frictional coefficient.
  • valve lifter with improved surface roughness and good wear resistance of the upper surface after nitriding can be obtained by improving surface roughness of that before nitriding, and by suppressing growth of the compound layer in the nitriding process.
  • the present inventors have further found that the combination of the valve lifter aforementioned and the cam improves the surface roughness of the cam in running-in without costly polishing of paper-lapping, etc. and totally improves wear resistance and reduces frictional torque, resulting in low cost process.
  • valve lifter according to the present invention subjected to gaseous nitriding or gaseous soft nitriding on the upper surface thereof, is characterized in that a compound layer formed on the outermost surface has a thickness of 1 to 5 ⁇ m and an upper surface roughness Ra of the compound layer is 0.05 or less.
  • the producing method of the valve lifter according to the present invention is characterized in that the surface roughness Ra of the upper surface before nitriding is finished in a range of 0.01 to 0.03 by a grinding or polishing process.
  • Such polished valve lifter is subjected to a nitriding process under a nitriding condition so selected as to obtain a thickness of a surface compound layer of 1 to 5 ⁇ m, thereby obtaining a valve lifter having nitrided compound layer of a high hardness and a low frictional coefficient on an outermost surface of the upper surface and also having a surface roughness Ra of 0.05 or less.
  • a thickness of the compound layer after the nitriding or less than 1 ⁇ m cannot provide a wear resistance or an effect of reducing the frictional torque.
  • a thickness larger than 5 ⁇ m results in a formation of a porous layer or a deterioration in the surface roughness and leads to a peeling problem of the compound layer in use because of a large thickness of the compound layer, so that an upper limit is selected as 5 ⁇ m.
  • a surface roughness Ra of 0.05 or less can be utilized without difficulty for a sliding component.
  • the surface roughness Ra of the upper surface is selected equal to or less than 0.05, since a surface roughness Ra higher than 0.05 results in increasing an attacking nature against a counterpart material and cannot obtain an effect of reducing the frictional torque.
  • the surface roughness Ra equal to or less than 0.045, its surface possesses a function of polishing the counterpart material of the cam, resulting in reducing the frictional torque. It is more desirable that the surface roughness Ra is equal to or less than 0.045.
  • a porosity in the compound layer after nitriding is 5 % or less, and, in an observation of a cross section almost perpendicular to the surface portion at a magnification of 8,000 times by SEM, as shown in Fig. 3, for example, the surface portion does not show a porous layer but consists of a relatively dense compound layer.
  • the porosity is selected equal to or less than 5 %, as a porosity of 5 % or less means a density sufficient for use in a sliding component such as a valve lifter.
  • a porosity higher than 5 % influences the surface roughness and cannot provide an wear resistance or an effect of reducing the frictional torque.
  • the present invention is characterized in that the surface has a lot of protrusions of 0.5 ⁇ m or less in average diameter, consisting of fine carbide, nitride, sulfide, oxide or a mixture of two or more thereof.
  • These protrusions improve the surface roughness of the cam (to Ra of around 0.02) due to its polishing function in sliding contact therewith, and fall out the surface of the valve lifter leaving dimples on the surface without increasing its surface roughness.
  • the surface roughness of the valve lifter itself remains as it is.
  • JP-A Hei6-2511 the surface roughness of the upper surface of silicon nitride valve lifter in sliding contact with the cam is between 0.2 of Rz and 0.7 of Rz. However, it is disclosed that an improvement of the surface roughness is not observed in the condition equal to or less than 0.2 of Rz. So the structure disclosed in JP-A Hei6-2511 is different from that according to the present invention.
  • camshaft i.e., casting iron, casting steel, those subjected to treatments of chilling, carburizing, quenching, etc., and iron-based sintered materials and those subjected to quenching treatment, are used as the counterpart material of the cam in combination with the valve lifter according to the present invention.
  • a porous layer harmful to the valve lifter is not formed in the nitriding process.
  • valve lifter owing to dense compound layer of uniform thickness formed by nitriding, is characterized in that the upper surface has a uniform surface hardness equal to or higher than Hv 660.
  • the producing method of the valve lifter according to the present invention is characterized in that the nitriding temperature is between 500 and 560°C. Nitriding at a temperature less than 500°C cannot form a sufficient nitrogen compound layer because of a low nitriding speed, while nitriding at a temperature exceeding 560°C causes a porous layer formation, thus requiring a polishing for removal of the porous layer after the nitriding. Another characteristic is that the nitriding atmosphere is suitably controlled to form a ⁇ '-phase and/or a mixed phase of a ⁇ '-phase and an ⁇ -phase on the upper surface of the valve lifter. Another characteristic is that the nitrogen compound layer comprises equiaxed crystals.
  • a base material for the valve lifter can be a carbon steel for general structure, an alloy steel or a tool steel commonly used for the valve lifter.
  • nitriding process applicable to such material in addition to a gaseous nitriding and a gaseous soft nitriding, there can also be employed an ion nitriding, a radical nitriding or a salt bath nitriding, but the ion nitriding and the radical nitriding do not provide an advantage in cost because of a very limited throughput, while the salt bath nitriding is associated with an environmental difficulty and is unable to secure the surface roughness, so that the gaseous nitriding and the gaseous soft nitriding are suitable in the present invention.
  • the gaseous nitriding or the gaseous soft nitriding generally uses NH 3 , but it is also possible to use a substance, such as urea, capable of forming an effective nitriding atmosphere to the steel material.
  • N 2 gas is used for controlling the atmosphere, however it is also possible to supply a decomposed gas of NH 3 , a modified gas (RX gas), a N 2 gas etc. singly or in a mixture in a necessary amount.
  • CO 2 gas is used as a gas for a soft nitriding, however there can also be employed a method using a CO-containing gas such as modified gas.
  • the effect of the present invention can be obtained as long as the nitrogen compound layer formed on the surface is composed of a ⁇ '-phase and/or a mixed phase of a ⁇ '-phase and an ⁇ -phase.
  • a gaseous nitriding method or a gaseous soft nitriding method is employed under a control of temperature, time and atmosphere to form a dense nitrided layer having a porosity of 5 % or less without a porous layer.
  • a dense nitrided layer having a porosity of 5 % or less without a porous layer.
  • the compound layer has an uniform thickness and a superior wear resistance.
  • valve lifter can be obtained with a low cost, since a costly polishing process is not required. Furthermore, when the valve lifter according to the present invention slides in combination with the cam, it improves the surface roughness of the cam due to its polishing function without increasing its surface roughness. The surface roughness of the valve lifter itself remains as it is.
  • the valve lifter includes a configuration of a valve lifter with shim in which a shim is provided between an upper face of the main body of the valve lifter and the cam and comes into a sliding contact with the cam, and a shimless configuration of a valve lifter in which a shim is not provided but an upper surface of the valve lifter comes into direct contact with the cam, and the valve lifter and the producing method thereof according to the present invention are applicable to both configurations.
  • the present invention is applicable to a valve lifter of which an upper surface or the like is provided with an oil hole, a hole for other objectives, a bevel portion or a groove.
  • the nitriding compound layer which is provided by the present invention is applicable also to a boss part 4 of the valve lifter, coming into sliding contact with a stem end or the like of the valve.
  • a valve lifter 1 according to the present invention shown in Figs. 1 and 2 is a sliding component which, in a direct drive valve actuating system of an internal combustion engine as shown in Fig. 10, is provided between a cam 11 and a valve 12 for converting a rotating motion of the cam 11 into a reciprocating motion of the valve 12.
  • the producing method for the valve lifter 1 according to the present invention is applicable to an upper sliding surface 2 of the valve lifter 1, coming into sliding contact with a cam (not shown) as shown in Fig. 1.
  • the present invention is applicable to a sliding surface 2 of a shim 3, coming into direct sliding contact with the cam, as shown in Fig. 2.
  • valve lifter 1 A specific example of the valve lifter 1 according to the present invention will be shown in the following.
  • a forged SCM material was subjected to a carburization and to a quenching/tempering treatment so as to have a surface hardness of HRC 58 or higher and an effective hardened layer depth of about 1.0 mm, and a surface roughness of the upper surface, i.e., the sliding surface 2 is finished to Ra 0.01 to 0.03 using a grinding machine with a grinding wheel and abrasives, wherein the upper surface is preferably finished in such a manner that the sliding surface 2 has a surface roughness of Ra 0.02.
  • a gaseous soft nitriding process was conducted at a temperature of 520°C for 70 minutes in such a manner that the sliding surface 2 had a surface hardness of Hv 660 or higher and a compound layer 6 (cf. Fig. 4) had a thickness of 1 to 5 ⁇ m.
  • the gaseous soft nitriding used a mixed gas of NH 3 , N 2 and CO 2 .
  • the gaseous soft nitriding was conducted, paying attention to homogeniety of temperature and atmospher, in order to form a compound layer uniformly within a range of 1 to 5 ⁇ m, to obtain a compound layer without a porous layer, and to obtain a surface roughness Ra of 0.05 or less with little deformation. It is also important to control the composition of the atmosphere gas and a decomposition rate of NH 3 in order to form a compound layer uniformly within a range of 1 to 5 ⁇ m and to obtain a compound layer without a porous layer.
  • the valve lifter is subjected to the nitriding in an atmosphere arriving at a predetermined decomposition rate of NH 3 .
  • the decomposition rate of NH 3 can be controlled by a gas exchange rate (flow rate) or a composition ratio of a mixed gas.
  • the nitriding process may be conducted using a gas regulated to a predetermined decomposition rate of NH 3 in another furnace.
  • the decomposition rate of NH 3 in the example according to the present invention was 23 %.
  • the gaseous soft nitriding was conducted under the aforementioned conditions, but compound layers without a porous layer of 3.5 and 2.5 ⁇ m were respectively obtained at conditions of a temperature of 560°C for 30 minutes, and a temperature of 500°C for 150 minutes.
  • the decomposition rate of NH 3 in these cases in comparison with the case of the condition at 520°C, had to be made larger in the case of the condition at 560°C, but was same in the case of the condition at 500°C.
  • the decomposition rate of NH 3 was controlled within a range of 5 to 50 % according to the nitriding temperature of 500 to 560°C.
  • valve lifters having a uniform compound layer and little deformation could be obtained by arranging the valve lifters in a row on a jig and by conducting the gaseous soft nitriding in such a manner that they were uniformly in contact with the atmospheric gas.
  • a nitrided layer composed of a diffusion layer 7 and a dense compound layer 6 having a porosity of 5% or less without a porous layer was formed on a base material as shown in Fig. 4.
  • a lot of protrusions consist of fine carbide, nitride, sulfide, oxide or two or more of these compounds of an average diameter of 0.5 ⁇ m or less.
  • This surface had a surface roughness of Ra 0.05 or less.
  • the compound layer comprises equi-axed crystals in diameter less than 0.5 ⁇ m as shown in Fig. 11.
  • the valve lifter according to the present invention obtained by this manner does not require polishing treatment for the improvement of wear resistance, surface roughness and dimensional accuracy.
  • valve lifters were prepared with same materials as in the aforementioned examples of the present invention, employing a method of a condition same as that of the nitriding process of the present invention, though the surface roughness values of the upper surfaces before the nitriding were different.
  • Table 1 shows examples of changes in the surface roughness values of the sliding surface 2 between before and after the nitriding process. It will be understood that, in the example of the present invention, the surface roughness Ra of the sliding surface after the nitriding can be maintained at 0.024 to 0.045 by polishing the sliding surface before the nitriding to a roughness Ra of 0.012 to 0.028. In contrast, in the comparative examples 1, 2 and 3, the surface roughness values after the nitriding exceeds Ra 0.05 in case the roughness values of the sliding surface before the nitriding exceeds Ra 0.03. Table 1 Surface roughness (Ra) Finish condition before nitriding Nitriding condition before nitriding after nitriding Present Invention Ex.
  • Figs. 5, 12 and 8 show micrographs of cross sections and a surface after nitriding on a valve lifter of comparative example 4 according to a prior art.
  • the valve lifter of the comparative example 4 is subjected to a gaseous soft nitriding at an ordinary temperature of 570°C and has a thick compound layer 6 compising columnar crystals and a large porous layer 8 on the surface (cf: Fig. 6). Also it shows a large deformation and a deterioration in the surface roughness, thus requiring a removal of the porous layer by a buff polishing in a subsequent step.
  • Fig. 12 shows a TEM micrograph of a cross section of the valve lifter after removing the porous layer by buff polishing.
  • the compound layer comprises relatively large columnar crystals oriented almost perpendicular to the surface.
  • Table 2 shows changes in the dimensional accuracy, and thickness values of the compound layer and the porous layer, before and after the nitriding, in the valve lifters of a present example 2 and a comparative example 4.
  • a deformation due to the nitriding is represented by a maximum displacement in an upper surface of the valve lifter as compared with an external periphery of the surface.
  • the valve lifter according to the present invention shows little deterioration in the surface roughness and little deformation by the nitriding, and does not form a porous layer on the compound layer. Thus, because the polishing is not necessary as a subsequent machining, an unevenness in the thickness of the compound layer is not occurred.
  • Table 2 Invention (Example 2) Comp. Ex.
  • FIG. 14 is a graph showing changes in surface roughness values of the upper surface of the valve lifter according to the present invention and the cam (nose portion of the cam) of counterpart material before and after the running-in operation in comparison with that according to the prior art.
  • sliding operation brings about deterioration in surface roughness of its upper surface and improvement in surface roughness of the cam due to its polishing function.
  • the surface roughness of the upper surface of the valve lifter is greatly increased after the running-in operation.
  • Fig. 15 is a graph showing changes in surface roughness values of the upper surface of the valve lifter according to the present invention and the chilled cam (nose portion of the cam) of the counterpart material from before the running-in operation to after the durability evaluation.
  • the change in surface roughness values of the upper surface is little.
  • the surface roughness of the cam of the counterpart material is improved due to its polishing function (to Ra of around 0.02 ⁇ m). Same improvement tendency is obtained in root mean square value of the surface roughness used as total sliding evaluation of the combination of valve lifter and the cam.
  • Fig. 13 shows a sliding surface after the durability evaluation.
  • Fig. 9 is a graph showing a relationship between a revolution and a frictional torque.
  • the valve lifter according to the present invention is characterized in that a thickness of a compound layer is between 1 and 5 ⁇ m after the gaseous nitriding, and a surface roughness Ra of the upper surface is 0.05 or lower after the nitriding, and the compound layer does not have a porous layer on the surface, so that a buff polishing is basically not required.
  • the producing method of the valve lifter 1 does not basically require a costly polishing treatment after the nitriding, and bring about superior wear resistance since a compound layer of a high hardness and a low friction coefficient can be uniformly formed on the sliding surface 2, thereby significantly reducing the manufacturing cost while maintaining high performances.
  • the formation of a dense and hard nitrided compound layer of 1 to 5 ⁇ m without a porous layer and the gaseous nitriding treatment with little deterioration in the surface roughness and little deformation in the upper surface shape does not require a polishing for controlling the compound layer after the nitriding such as for improving the surface roughness and removing the porous layer.
  • a polishing for controlling the compound layer after the nitriding such as for improving the surface roughness and removing the porous layer.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Valve-Gear Or Valve Arrangements (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
EP04718747A 2003-03-10 2004-03-09 Nitrided valve lifter and method for manufacture thereof Expired - Lifetime EP1602743B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2003063450 2003-03-10
JP2003063450 2003-03-10
PCT/JP2004/003022 WO2004081252A1 (ja) 2003-03-10 2004-03-09 窒化バルブリフタおよびその製造方法

Publications (3)

Publication Number Publication Date
EP1602743A1 EP1602743A1 (en) 2005-12-07
EP1602743A4 EP1602743A4 (en) 2007-01-24
EP1602743B1 true EP1602743B1 (en) 2007-12-26

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EP04718747A Expired - Lifetime EP1602743B1 (en) 2003-03-10 2004-03-09 Nitrided valve lifter and method for manufacture thereof

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Country Link
US (2) US20060144359A1 (zh)
EP (1) EP1602743B1 (zh)
JP (1) JP4141473B2 (zh)
KR (1) KR20050118175A (zh)
CN (1) CN1784505B (zh)
DE (1) DE602004010890T2 (zh)
ES (1) ES2295833T3 (zh)
TW (1) TW200506181A (zh)
WO (1) WO2004081252A1 (zh)

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JP5169822B2 (ja) * 2006-03-30 2013-03-27 株式会社ジェイテクト トルクリミッタ
KR20080108583A (ko) * 2006-03-30 2008-12-15 가부시키가이샤 제이텍트 토크 리미터
JP2008071738A (ja) * 2006-08-18 2008-03-27 Nissan Motor Co Ltd 遷移金属窒化物、燃料電池用セパレータ、遷移金属窒化物の製造方法、燃料電池用セパレータの製造方法、燃料電池スタック、及び燃料電池車両
KR100730615B1 (ko) * 2006-10-31 2007-06-20 다이모스(주) 변속기용 싱크로나이저 허브의 열처리 방법
KR100906414B1 (ko) * 2008-01-03 2009-07-09 주식회사 킹텍코리아 압축기용 사판 및 그 제조방법
KR100887851B1 (ko) 2008-07-18 2009-03-09 현대자동차주식회사 밸브리프터 및 그 표면처리방법
JP5898092B2 (ja) * 2010-12-13 2016-04-06 川崎重工業株式会社 駆動カム、その製造方法、及びエンジンの動弁装置
JP6445293B2 (ja) * 2014-09-26 2018-12-26 株式会社リケン バルブリフタ及びその製造方法
CN105033654B (zh) * 2015-07-17 2017-07-28 宜宾常达机械有限公司 一种内燃机气门挺柱及其制造方法
WO2017029921A1 (ja) * 2015-08-17 2017-02-23 Ntn株式会社 摺動部材及びその製造方法
CN105887000A (zh) * 2016-06-08 2016-08-24 连云港江南精工机械有限公司 一种压铸机配件氮化热处理方法
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CN113263178A (zh) * 2021-04-23 2021-08-17 广东工业大学 一种具有富立方相梯度结构的涂层刀具及其制备方法

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Also Published As

Publication number Publication date
TW200506181A (en) 2005-02-16
JPWO2004081252A1 (ja) 2006-06-15
EP1602743A1 (en) 2005-12-07
EP1602743A4 (en) 2007-01-24
CN1784505A (zh) 2006-06-07
DE602004010890T2 (de) 2008-12-11
ES2295833T3 (es) 2008-04-16
US20080066703A1 (en) 2008-03-20
JP4141473B2 (ja) 2008-08-27
WO2004081252A1 (ja) 2004-09-23
KR20050118175A (ko) 2005-12-15
CN1784505B (zh) 2010-11-03
US20060144359A1 (en) 2006-07-06
DE602004010890D1 (de) 2008-02-07

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