Classifications

• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
  • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
  • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
  • F01N3/36—Arrangements for supply of additional fuel
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
  • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
  • F01N13/0097—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
  • F01N13/011—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more purifying devices arranged in parallel
  • F01N13/017—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more purifying devices arranged in parallel the purifying devices are arranged in a single housing
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
  • F01N3/0231—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using special exhaust apparatus upstream of the filter for producing nitrogen dioxide, e.g. for continuous filter regeneration systems [CRT]
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
  • F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
  • F01N3/0253—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust adding fuel to exhaust gases
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
  • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
  • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
  • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
  • F01N2550/04—Filtering activity of particulate filters
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N2610/00—Adding substances to exhaust gases
  • F01N2610/03—Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N2610/00—Adding substances to exhaust gases
  • F01N2610/14—Arrangements for the supply of substances, e.g. conduits
  • F01N2610/1493—Purging the reducing agent out of the conduits or nozzle
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
  • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
  • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
  • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
  • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
  • F01N3/30—Arrangements for supply of additional air

Definitions

• the present invention relates generally to the field of particle filters and, more particularly, to a process for post-injecting regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or solution). ammonia) upstream of an exhaust gas filtration device for a diesel engine to regenerate this filter.
• the hydrocarbon type, alcohol and / or reducing agent eg diesel and / or urea and / or solution.
• ammonia upstream of an exhaust gas filtration device for a diesel engine to regenerate this filter.
• the present invention also relates to the management of this injection device which aims to inject a homogeneous mixture of air and regeneration liquid of the hydrocarbon, alcohol and / or reducing agent type (eg diesel and / or urea and / or ammonia solution) on the oxidation catalyst located upstream of the filtration system so as to increase the temperature of the exhaust gases as for combustion.
• a homogeneous mixture of air and regeneration liquid of the hydrocarbon, alcohol and / or reducing agent type eg diesel and / or urea and / or ammonia solution
• a high temperature level being necessary to oxidize and burn the carbonaceous particles produced by the engine and retained on this filtration system, in order to avoid their accumulation, this last phase constituting the regeneration, object of the process according to the invention.
• a special effort has been made on the development of new exhaust systems, intended to reduce the emission of unburnt pollutants and solid particles.
• catalytic converters or catalysts generally consisting of a stainless steel casing, a thermal insulator and a honeycomb support impregnated with precious metals such as platinum or rhodium.
• These catalysts make it possible, above all, to reduce the emissions of polycyclic hydrocarbons and CO, and this in a proportion of the order of 90%. However, they have no effect on the emission of solid particles. Thus, in particular in the case of diesel engines which produce numerous solid particles, these catalysts do not bring any significant improvement in the quality of the air.
• the particle filter allows the total mass of particles emitted by diesel engines to be reduced by more than 90%.
• the particle filter however requires regeneration to burn the particles that have been trapped.
• the particles are generally trapped by a filter cartridge that is part of the particle filter.
• This cartridge in order to withstand the high temperatures encountered, may consist of a porous body of cordierite, quartz or silicon carbide, generally of honeycomb structure to present a maximum filtration surface.
• a first technique consists in placing upstream of the filter, a catalyst for the oxidation of nitrogen monoxide (NO) contained in the exhaust gases into nitrogen dioxide (N0 2 ), the latter having the property of catalyzing combustion carbonaceous particles from 250 ° C.
• NO nitrogen monoxide
• N0 2 nitrogen dioxide
• this process requires the use of a diesel fuel with a sulfur content of less than 50 ppm (parts per million), in order to keep an efficiency of conversion of NO to N0 2 sufficient.
• the objective of the present invention is to provide a process for the post-injection of regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or ammonia solution) adaptable to all diesel engines allowing regeneration of a filtration device, which overcomes the drawbacks of the various existing techniques consisting in treating carbonaceous particles and soot emitted by diesel engines by increasing, when necessary, the temperature of the exhaust gases to obtain the correct oxidation temperature.
• the hydrocarbon type, alcohol and / or reducing agent eg diesel and / or urea and / or ammonia solution
• Another objective of the invention is to provide a process for post-injecting regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or ammoniacal solution), thus avoiding any risk of accumulation of particles in the filtration device and therefore any risk of uncontrolled regeneration.
• reducing agent eg diesel and / or urea and / or ammoniacal solution
• Yet another objective of the invention is to provide a process for post-injecting regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or ammoniacal solution), which is not subject the technical problem of thermal degradation and coking of the regeneration liquid, in particular when it is diesel, and this in particular at the level of the nozzles of the injectors belonging to the post-injection means.
• a process for post-injecting regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent eg diesel and / or urea and / or ammoniacal solution
• Yet another objective of the invention is to provide a process for post-injecting regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or ammoniacal solution) which does not lead to overconsumption. significant fuel and more generally, not resulting in additional financial cost for the user.
• reducing agent eg diesel and / or urea and / or ammoniacal solution
• Yet another objective of the invention is to provide a process for post-injection of regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or ammoniacal solution) which does not affect the performance of the engine. , in particular by pressure losses, due to the back pressure exerted by the exhaust gases on the engine, due to clogging of the filtration device.
• reducing agent eg diesel and / or urea and / or ammoniacal solution
• a final objective of the invention is to provide a filtration device making it possible to implement the method according to the invention of post-injection of regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or urea and / or ammonia solution).
• regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent eg diesel and / or urea and / or ammonia solution.
• the present invention which relates, first of all, to a process for post-injection of a regeneration liquid, in particular for the regeneration of an exhaust gas filtration device produced by a diesel engine, this process being of the type in which particles, after passing over an oxidation catalyst, are retained on a filtration means of said filtration device.
• the method according to the invention is characterized - in that the regeneration liquid comprises at least one hydrocarbon and / or at least one reducing agent, and in that this post-injection consists essentially of injecting, upstream of the catalyst, using post-injection means : * on the one hand, the regeneration liquid,
• this regeneration liquid and this gaseous fluid together forming an aerosol making it possible to spray the regeneration liquid in the exhaust gases and to increase their temperature, in order to ultimately accelerate the rate of oxidation of said particles and thus contribute to the regeneration of the filtration device.
• the method according to the invention makes it possible to obtain a quality aerosol, which guarantees very good regeneration of the exhaust particulate filter.
• the post-injection flow of the regeneration liquid and the post-injection flow of the gaseous fluid, preferably compressed air emanate from substantially concentric openings.
• part of the gaseous fluid preferably compressed air, borrows, until the postinjection opening, the same nozzle as the regeneration liquid.
• part of the gaseous fluid is mixed with the regeneration liquid before the post-injection.
• One of the advantageous arrangements of the invention for limiting the risks of clogging consists in maintaining the circulation of the gaseous fluid, preferably the compressed air, in the post-injection nozzle, after the interruption of the post-injection. of regeneration liquid through this nozzle, and this for a time necessary to rinse said nozzle.
• the temperature of at least part of the post-injection means remains less than or equal to 120 ° C., preferably 100 ° C., during engine operation. .
• At least a portion of the post-injection means is advantageously distant from (or) conduit (s) in (s) which (s) circulate the exhaust gases.
• the regeneration liquid is chosen: * from the group of hydrocarbons comprising petroleum refining products (preferably gasolines and diesel),
• the method comprises the following essential steps consisting in:
• the invention also relates to a device allowing in particular the implementation of the post-injection process as defined above.
• This device comprises at least one exhaust duct, at least one catalyst and filtration means. It is characterized in that it further comprises:
• post-injection means communicating with an exhaust gas evacuation pipe and including:
• - ⁇ - at least one injector preferably electromagnetic -, • ⁇ - at least one injector holder on which said injector is disposed, - ⁇ - at least one capillary or nozzle starting from the injector and opening into at least one conduit exhaust, through at least one opening, upstream of the catalyst,
• At least one post-injection control computer to which the means for supplying regeneration liquid, the means for supplying gaseous fluid under pressure, preferably compressed air, the post-injection means are subjected, and any temperature or pressure probe (s).
• the capillary (or nozzle) and the pipe are concentric and coaxial, as are their respective openings, which open into the exhaust duct (s),
• the capillary (or nozzle) is contained in the pipeline.
• at least part of the post-injection means, preferably at least the injector is designed in such a way, preferably is placed at a sufficient distance from the exhaust duct (s) so as not to not undergo thermal deterioration, that is to say remain during the operation of the engine at a temperature lower or equal to 120 ° C, preferably at 100 ° C,
• the post-injection of the regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent is assisted by a gaseous fluid under pressure (for example compressed air).
• a gaseous fluid under pressure for example compressed air.
• the injector and its support are located: • geographically at a location distant (for example 200 mm) from the exhaust duct, so as not to be subjected to high temperatures, • and upstream of the oxidation catalyst.
• the exhaust gas filtration means are themselves downstream of the oxidation (or combustion) catalyst.
• the catalyst and the filtration means are, in practice, contained in an enclosure, which is located in the path of the flow of the exhaust gases produced by an engine.
• the means for supplying gaseous fluid under pressure are designed to allow the admission of gaseous fluid to the outlet of the injector, in capillary head or nozzle, so that pressurized gaseous fluid, preferably compressed air, can circulate with the post-injected regeneration liquid, in the capillary or nozzle.
• the means for supplying gaseous fluid under pressure, preferably compressed air comprise a solenoid valve controlling the admission of the gaseous fluid under pressure, preferably compressed air to the outlet of the injector, at the capillary or nozzle head, to allow said fluid to circulate with the regeneration liquid, and, incidentally, to be able to rinse the capillary or nozzle, after the end of post-injection, maintaining for some time a flow of pressurized gaseous fluid, preferably compressed air, into the capillary or nozzle.
• the means for supplying gaseous fluid under pressure, preferably with compressed air, as well as the post-injection means - preferably the injector holder are designed such that is provided at least one calibrated orifice allowing to continuously supply a flow of gaseous fluid under pressure, preferably compressed air mixed with the regeneration liquid, at the inlet of the capillary or nozzle, so as to produce an emulsion and to ensure in addition and preferably the rinsing function, while maintaining some time after closing a flow in addition gaseous fluid, in the capillary or nozzle.
• the means for supplying regeneration liquid are connected to the supply conduit for at least one mechanical injection pump of the engine.
• the regeneration liquid is preferably chosen: * from the group of hydrocarbons comprising petroleum refining products (preferably gasolines and diesel),
• the device according to the invention comprises a temperature probe and a pressure probe.
• the computer which is connected to the temperature probe and to the pressure probe, is to compare the values ⁇ m and possibly P m measured respectively with the reference values ⁇ r and possibly P r , and triggers the post-injection of regeneration liquid into the exhaust duct, via the means for supplying regeneration liquid, means for supplying gaseous fluid under pressure, preferably compressed air , and post-injection means, when the measurements ⁇ m and possibly P m are greater than or equal to the reference values ⁇ r and possibly P r .
• the temperature probe and the possible pressure probe are located substantially at the same level on the exhaust duct.
• post-injection is carried out by a conventional electromagnetic injector of the same type as that used on petrol engines, this injector being disposed on an injector holder remote from the exhaust duct.
• the regeneration liquid of the hydrocarbon, alcohol and / or reducing agent type eg diesel and / or urea and / or ammoniacal solution
• this injector is brought by a capillary contained in a pipe formed eg by a metal tube to the conduit hot exhaust.
• This tube is supplied with compressed air so as to arrive concentrically around the capillary to open into the conduit exhaust and cause a good spraying of the regeneration liquid of the hydrocarbon type, alcohol and / or reducing agent (eg diesel and / or ethanol and / or urea and / or ammoniacal solution).
• the injection of regeneration liquid and the supply of compressed air are controlled by the electronic control unit, which governs the opening / closing of solenoid valves allowing the post-injection of regeneration liquid into the gas evacuation pipe. exhaust.
• a calibrated orifice in connection with the air inlet and facing the injector nose is arranged so as to generate an air / liquid regeneration emulsion at the inlet of the capillary and allow inject this regeneration liquid in perfectly nebulized form at the outlet, into the gas evacuation pipe.
• FIG. 1 represents a general schematic view of the system comprising the filtration device with its oxidation catalyst and upstream of this assembly the post-injection system allowing the implementation of the regeneration process.
• FIG. 2 represents a detailed view of the post-injection device according to a first embodiment.
• FIG. 3 represents a detailed view of a variant of the postinjection device according to a second embodiment.
• FIG. 4 represents a general view of the post-injection system integrated into a particle filter engine assembly.
• various mechanical elements of a particle filter collaborate which may or may not be part of the filtration device and which help to control the regeneration of the filtration system.
• the exhaust gases at the outlet of the diesel engine on the pipe 1 are controlled in temperature by the probe 2 and in pressure by the probe 3 to then be directed to the oxidation catalyst 4, then to the filtration cartridges 5, the assembly being contained in a metal envelope 6 and insulated by ceramic elements 7.
• a computer 8 will control when necessary the injections of diesel from the electromagnetic injector 9 mounted on an injector holder block 10, it will be supplied from a bypass of the diesel engine by the pipe 11, the diesel being directed towards the exhaust pipe by the capillary 12.
• This capillary 12 opens at the center of the piping 13 in the exhaust duct 14 upstream of the oxidation catalyst 4, so as to obtain a good spraying by the air which will arrive concentrically and which will be admitted from the solenoid valve. 15, supplied by a pressure regulator not shown.
• a second solenoid valve 16 will allow the capillary to be purged to prevent the diesel oil from stagnating inside it and being able to coke and lead to its obstruction near the exhaust duct which is very hot to it.
• FIG. 2 A detailed view of the post-injection device, in particular of the injector holder according to a first embodiment is shown in FIG. 2.
• the computer 8 on the basis of the temperature and pressure information collected by the probes 2 and 3 and according to the strategy which has been fixed to it will command a diesel injection from the electromagnetic injector 9 supplied with diesel by the engine circuit at 11 At the outlet of this electromagnetic injector, the volume of diesel fuel injected will be directed by the capillary 12 towards the exhaust duct 1 where it will be sprayed at 14 thanks to the air which will arrive concentrically by the pipe 13.
• the air flow spraying will be controlled by the solenoid valve 15 powered by a pressure regulator not shown, its opening will be simultaneous with that of the injector 11, so as to obtain a good spraying from the start, on the other hand its closing will be delayed by a few seconds so as to be able to perform the capillary flushing operation with air, which will be supplied from the solenoid valve 16 from the farm ture of the injector, a non-return valve 17 will prevent any accumulation of diesel in the pipe of the injector holder 10 so as to allow effective rinsing.
• FIG. 3 A variant of this embodiment is shown in FIG. 3.
• the injector holder 10 and supplied with air by a single solenoid valve the opening will be simultaneous with the diesel injector 9, but the closing of which will be delayed by a few seconds, as for the previous embodiment, so that the capillary rinsing operation is done automatically thanks to the air flow controlled by the calibrated air jet 18.
• This air flow will also, upon opening the solenoid valve 15, form an emulsion with the diesel from the injector 9 in the chamber 19 and then be directed by the capillary 12 to the outlet in the exhaust duct at 14.
• This emulsion will open at the center of the tube 13 where it will meet the air flow conveyed by this tube, to be sprayed finely and to obtain a qual ity of nebulization much higher, thanks to the emulsion already formed in the capillary.
• the injector closes, maintaining the air flow for a few additional seconds allows the capillary 12 to be completely rinsed.
• This stainless steel capillary eg, of 1/1, 6 mm had a length of 50 cm and was contained in a stainless steel tube of 4/6 mm, eg, the quality of the diesel fog obtained made it possible to carry out injections up to temperatures at l 'catalyst entry of 270 ° C, eg, without observing parasitic hydrocarbon emissions.
• Figure 4 is shown the post-injection device associated with a particle filtration system, the assembly being mounted on a diesel engine 20 powered by an air compressor 21, and escaping through a turbine 22 to evacuate the exhaust gas through a pipe 23, to the system at 1 where the temperature 2 and pressure 3 probes are arranged before spraying at 14 the diesel fuel with the air coming from the pipe 13.
• the injector 9 being supplied by a line 11 mounted as a bypass of the diesel fuel supply to the injection pump 24 of the engine.
• the temperature in the vicinity of the catalyst inlet is measured, using the probe 2, eg of the thermocouple or thermistor type placed at the inlet of the system.
• the temperature value ⁇ m measured is collected by the computer 8.
• the computer will compare this value ⁇ m to a reference value ⁇ r , corresponding to the temperature at which the combustion of diesel fuel on the catalyst with excess air , is done completely.
• ⁇ r is for example ⁇ 300 ° C.
• the electronic control unit triggers the opening of the injector 9 and of the solenoid valve 15. This opening causes the entry of diesel fuel into the capillary and compressed air in the tube 13. At the outlet of the tube 13 at 14, the diesel fuel mixes with the compressed air and the mixture, thus constituted, is sprayed, in the nebulized form in the gas evacuation pipe d exhaust 1.
• the fuel injected into the exhaust duct 1 enters the enclosure 6 and undergoes complete combustion at the level of the catalyst 4.
• This combustion induces a significant increase in temperature up to a temperature ⁇ c at which the combustion of the particles that clog the filtration media.
• the molecules of N0 2 produced in association with the excess residual oxygen contained in the gases exhaust will catalyze this oxidation reaction. Thus, this reaction occurs at a temperature below the normal combustion temperature.
• the solid particles are transformed into gases which are evacuated.
• the filtration means is then found free of deposits and recovers its full filtration capacity.
• the measurement of ⁇ m can be used by the electronic unit in order to evaluate the temperature of the particles at the level of the filtration means. Indeed, if ⁇ m is close to the temperature at which the combustion of particles can be done without post-injection of diesel, the computer can decide not to trigger this post-injection, which makes it possible to save substantial fuel .
• Another operational mode consists in simultaneously measuring the temperature and the pressure at the level of the catalyst production means, using the temperature probe 2 and the pressure probe 3.
• the pressure value P m measured reflects the degree of obstruction means of filtration by particles. In fact, if the filtration means is clogged, the exhaust gases pass more difficultly and then exert a back pressure. Thus, the measurement of the pressure P m corresponds to the best means of controlling the clogging of the filtration means.
• the probe 3 is a conventional probe for measuring the absolute pressure.
• the pressure probe 3 can be a differential pressure measurement probe, comprising a sensor located upstream of the filter and another downstream of said filter.
• the electronic control unit compares the measured value P m with a reference value P r , corresponding to the maximum acceptable degree of obstruction of the filtration means.
• P r indicative of clogging is made easily and arbitrarily by those skilled in the art. In practice, for example, the pressure P r corresponds to the pressure measured with a new filter increased by 100 mBar.
• the electronic control unit compares ⁇ m to ⁇ r . If ⁇ m is greater than or equal to ⁇ r , the box then triggers the post-injection of diesel which leads to the regeneration of the filtration means.
• This operational mode has the advantage of triggering post-injection only when the filtration means has reached a determined degree of clogging, which makes it possible to greatly limit the overconsumption of fuel.
• the computer always from the values entered in the setpoint, can, depending on the level of back pressure, increase the injection time so as to reach a higher temperature.
• a filtration device used with an industrial vehicle engine, the supercharged Renault VI 620-45 engine, with a capacity of 10 liters and a power of 180 kW. This engine is fitted to city buses.
• the filtration device is composed of:
• a metallic oxidation catalyst based on platinum allowing the total oxidation of CO and hydrocarbons at low temperature as well as the transformation of part of the NO into N0 2 , the platinum content was 90 g per foot cubic.
• the capillary 12 used was made of stainless steel with an internal diameter of 1 mm by an external diameter of 1.6 mm, as for the air supply tube 13, it was also made of stainless steel and was 4 mm inside by 6 mm outside for a total length of 50 cm.
• a time delay limits the duration of the post-injection to 20 s and corresponds to an injected quantity of 20 cm 3 then a specific programming of the housing makes it possible to obtain at most one post-injection every 7 minutes.
• the electromagnetic injector 9 was supplied by line 11 connected by a
• Tee at the supply line of the engine injection pump, allowing a supply pressure varying from 1 to 1.5 bars.
• the electronic unit has been adjusted so that post-injection is triggered as soon as the back pressure reaches 150 mb and the temperature of the gases exceeds 300 ° C.
• the bus has covered more than 45,000 km without any back pressure drift being observed, which shows that the post injection system has done its job by constantly maintaining a sufficient temperature level for regeneration of the filter is done continuously despite the severe conditions of use.
• the post injection process according to the invention associated with a filtration device using an oxidation catalyst is therefore particularly suitable for the treatment of exhaust gases from urban public transport vehicles.
• the gases produced by these vehicles are generally at a temperature lower than that necessary to allow the regeneration of conventional filtration devices, which leads to clogging of these devices and therefore their rapid deterioration by brutal combustion reactions.
• the results obtained with the present technique make it possible to envisage a minimum service life of the filtration device of 100,000 km, on vehicles of this type.
• the injection device according to the invention does not include new technical elements, the inventors have the merit of having been able to combine and adapt different existing techniques in order to potentiate their effects and to obtain a device having a very high efficiency and robustness to allow a reliable post-injection of diesel fuel generating no parasitic emission of hydrocarbons and making it possible to significantly increase the temperature of the exhaust gases to allow the oxidation of the carbon particles retained on the filter and obtain excellent results in terms of filter regeneration, even in the case of vehicles whose engine speeds do not allow exhaust gases to be obtained with a high temperature.

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• Engineering & Computer Science (AREA)
• Chemical & Material Sciences (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Combustion & Propulsion (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Toxicology (AREA)
• Health & Medical Sciences (AREA)
• Exhaust Gas After Treatment (AREA)
• Processes For Solid Components From Exhaust (AREA)
• Treating Waste Gases (AREA)
• Combined Controls Of Internal Combustion Engines (AREA)
• Filtering Of Dispersed Particles In Gases (AREA)

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• 2003
  • 2003-01-31 FR FR0301123A patent/FR2850704A1/fr not_active Withdrawn
  • 2003-12-23 JP JP2004569045A patent/JP2006514205A/ja active Pending
  • 2003-12-23 US US10/543,740 patent/US7481045B2/en not_active Expired - Fee Related
  • 2003-12-23 WO PCT/FR2003/050206 patent/WO2004079168A1/fr active IP Right Grant
  • 2003-12-23 AU AU2003302199A patent/AU2003302199A1/en not_active Abandoned
  • 2003-12-23 DE DE60320310T patent/DE60320310T2/de not_active Expired - Lifetime
  • 2003-12-23 ES ES03810015T patent/ES2306920T3/es not_active Expired - Lifetime
  • 2003-12-23 CN CN200380109402.5A patent/CN1780974A/zh active Pending
  • 2003-12-23 AT AT03810015T patent/ATE391839T1/de not_active IP Right Cessation
  • 2003-12-23 CA CA002514469A patent/CA2514469A1/fr not_active Abandoned
  • 2003-12-23 EP EP03810015A patent/EP1588032B1/de not_active Expired - Lifetime

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