EP1483068B1 - Verfahren zur herstellung von verstärkungsdrähten aus beschichtetem stahl für flexible rohrförmige leitungen zum transport von kohlenwasserstoffen, sowie verstärkte leitung - Google Patents

Verfahren zur herstellung von verstärkungsdrähten aus beschichtetem stahl für flexible rohrförmige leitungen zum transport von kohlenwasserstoffen, sowie verstärkte leitung Download PDF

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Publication number
EP1483068B1
EP1483068B1 EP03722682A EP03722682A EP1483068B1 EP 1483068 B1 EP1483068 B1 EP 1483068B1 EP 03722682 A EP03722682 A EP 03722682A EP 03722682 A EP03722682 A EP 03722682A EP 1483068 B1 EP1483068 B1 EP 1483068B1
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EP
European Patent Office
Prior art keywords
steel
pipe
coating
hardening step
plating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03722682A
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English (en)
French (fr)
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EP1483068A2 (de
Inventor
François Dupoiron
Philippe Espinasse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Technip Energies France SAS
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Technip France SAS
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Publication date
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Publication of EP1483068A2 publication Critical patent/EP1483068A2/de
Application granted granted Critical
Publication of EP1483068B1 publication Critical patent/EP1483068B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • B21C37/12Making tubes or metal hoses with helically arranged seams
    • B21C37/124Making tubes or metal hoses with helically arranged seams the tubes having a special shape, e.g. with corrugated wall, flexible tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/04Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of bars or wire
    • B21C37/042Manufacture of coated wire or bars
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • B21C37/12Making tubes or metal hoses with helically arranged seams
    • B21C37/126Supply, or operations combined with supply, of strip material

Definitions

  • the present invention relates to a method of manufacturing plated steel armor wires for reinforcement of tubular pipes flexible for the transport of hydrocarbons, in particular non related ("unbonded flexible pipes"), according to the preamble of claim 1 as well as such a tubular pipe according to the the preamble of claim 10 (see, for example, JP-A-60 255 923).
  • These behaviors are defined in the API 17J and 17B recommendations from the American Petroleum Institute and have metal layers and separate polymeric layers, that is to say, not linked together so as to allow a certain relative displacement between the layers.
  • Such conduct may be smooth inside passage when the passage is directly formed by the sealing sheath (it is then called “smooth” boron ”) or non-smooth passage (" rough bore ”) when further inside the inner sealing sheath a carcass consisting of a staple-wrapped strap with a short pitch which serves to prevent crushing of the driving under external pressure.
  • a carcass consisting of a staple-wrapped strap with a short pitch which serves to prevent crushing of the driving under external pressure.
  • the pipe may optionally include in addition to these layers, other particular layers, a metal band (short-pitched) and forming part of the pressure vault, polymeric sheaths intermediaries, etc.
  • the driving generally comprises at the same time a carcass, a sealing sheath, a pressure vault, plies of tensile armor, and an outer sealing sheath.
  • the armor threads considered are the armor threads pulling armor tablecloths crossed or possibly the form wires or the hoop wires of the pressure vault, which will be called pressure armor wires.
  • pressure armor wires By extension, we will hear also by wire of a form wire obtained according to the method of the invention and which would be intended to be used for the manufacture of a carcass.
  • a corrosion-resistant steel H 2 S is used, but with medium mechanical characteristics for the armor wires of the pressure vault. , and a steel with high mechanical characteristics but not resistant to acid corrosion for traction armor plies.
  • This compromise seems acceptable if the H 2 S corrosion can not reach the layers of tensile armor; for this purpose, an intermediate H 2 S containment sheath separates the pressure vault that will be subjected to H 2 S corrosion and the tensile armor plies, which will not in principle be subjected to this corrosion.
  • safety is not guaranteed because of the risk of piercing the intermediate sheath.
  • the poor mechanical characteristics of the steel used for the pressure vault lead to the obligation to oversize it.
  • the object of the invention is to allow the reinforcement of the pipes flexible, including unbound pipes, by armor wires resistant to corrosion but also with good qualities to allow the use of the pipes at great depth. More specifically, the object of the invention is to find a method of Intimate coating or plating of the steel armor wires, compatible with the requirements of a use for a pipe of the aforementioned type used in acidic environment and in great depth.
  • the invention achieves its goal through a yarn manufacturing process plated steel armor for reinforcement of tubular conduits flexible, in particular unbound, for the transport of hydrocarbons, process of the type in which a veneer coating is intimately associated, by strong pressure, to a steel core, characterized in that the steel of the soul is chosen with medium mechanical characteristics and is what the coating is applied to the soul and intimately associated, then in that the plated wire obtained undergoes rapid quenching at high temperature followed by an income, so as to increase the mechanical characteristics plated wire.
  • the characteristics of steel and veneer coating, as well as the temperature and the time of quenching are selected in a related manner from to elevate the mechanical characteristics of the quenched wire without destroying the strength of the veneer bond.
  • One of the key factors of the invention is the rapidity of the high temperature heat treatment which, in connection with the other parameters, makes it possible to minimize the constraints at the level of the between the steel and the coating, in particular by avoiding the migration of the carbon and iron steel in the bond and coating.
  • the core of the armor wire is medium resistance, that is to say whose resistance Rm is between 500 and 1000 MPa, advantageously between 800 and 900 MPa. It must be a "hardenable" steel (able to undergo tempering improving its mechanical characteristics, the quench consisting, as we know, of a curing by heat treatment: austenization + cooling) carbon, alloyed or weakly alloyed.
  • the anti-corrosive coating is for example made of titanium or alloys of titanium, stainless steel, nickel or nickel alloys.
  • the veneer is made mechanically cold after a preparation adequate (mechanical or chemical deoxidation of surfaces), according to a technique allowing an intimate connection by pressure (for example co-extrusion or colaminage).
  • the steel thus coated is subjected to a treatment thermal device with a short temper at high temperature and an income in order to minimize the constraints on the connection between steel and coating.
  • the heat treatment according to the invention makes it possible to improve the characteristics of the bond, restore the characteristics of ductility plating and to obtain the high mechanical properties of the metal of basis for the applications envisaged for this type of product.
  • This heat treatment is characterized by a thermal cycle at high temperature (900 ° C to 1100 ° C) short (a few seconds to a few tens of seconds) followed by rapid cooling and treatment at a temperature of the order of 400 ° C to 700 ° C and which is adjusted in depending on the desired mechanical characteristics, the income being over a period of a few minutes, advantageously between 10 and 20 minutes.
  • This heat treatment has the following effects, depending on the components of the armor:
  • the treatment restores ductility without leading to precipitation prejudicial to the resistance to corrosion.
  • connection it allows an improvement of the resistance by relaxation of rolling or extrusion and diffusion stresses metallic.
  • income also allows a complementary improvement of the ductility by the relaxation of the differential stresses related to quenching.
  • the heat treatment will make it possible to obtain a hardened tempered structure associating very high characteristics mechanical properties (Rm greater than 1000 MPa and preferably 1400 MPa less) and sufficient ductility for the intended applications (approximately 5% elongation).
  • the invention also relates to a flexible tubular conduit for the transporting hydrocarbons, incorporating at least some armor threads manufactured according to the aforementioned manufacturing process. More precisely, the invention relates to a flexible tubular pipe for transport hydrocarbons, of the type comprising polymeric layers and unbound metal layers, metal layers with wound armor, characterized in that at least some of the armor threads are tempered and returned and are manufactured according to the method of the preceding claims.
  • the invention is intended in particular to conduct of the type comprising at least one carcass, an inner sheath, a pressure vault comprising armor wires of pressure, webs consisting of tensile armor wires and a sheath exterior, characterized in that at least some of the armor wires are manufactured according to the method of the invention.
  • Figure 1 shows a "rough bore” type pipe that includes from inside to outside: a metal carcass 1, usually made by a staple strap wound with a short pitch and intended for resistance crushing under external pressure; an internal sealing sheath polymeric 2, a metal pressure vault, constituted here so traditional winding with a short pitch helix (winding angle generally close to 90 ° to the axis of the pipe) of a wire stapled form metal 3 doubled by short pitch helical winding of a wire 4, an armor 5 resistant to axial traction in the direction longitudinal direction of the pipe and typically consists of a pair of cross plies of long armor pull wire 6,7 (typically less than 55 ° with respect to the axis of the pipe), and a outer polymer sheath 8.
  • Other layers such as other armor 9 and an intermediate sheath 10 may be provided according to the type and destination of the pipe.
  • the invention relates to the plating of the traction armor wires 6,7 also although pressure armor wires 3, 4 (where applicable), according to a treatment that is illustrated in Figure 2.
  • the starting wire 20 consists of a base metal core 21 to average mechanical characteristics (for example Rm from 800 to 900 MPa) and a coating 22 of metal plating.
  • the base metal can be, for example, a base steel type chrome silicon (55SiCr V) in the state globulized to allow plating.
  • the plating metal can be for example a nickel base (NiCrMo series 6x according to AISI) or an alloy nickel (8x series).
  • Starting wire 20 passes through a coextrusion die 23, from which it emerges having the coating 22 closely related to the soul. so plated wire goes into a post 24 heat treatment at high temperature, typically at least 800 ° C and preferably at 1100 ° C, by for example by heating the wire by induction.
  • This treatment is fast (from a few seconds to a few minutes at the most). There occurs a austenitization of the base steel.
  • This treatment is followed by rapid quenching in a quench station (for example by air, water or oil) which accompanied by a controlled martensitic transformation and thus allows obtaining high mechanical characteristics, with a Rm of the order 2000 MPa.
  • a quench station for example by air, water or oil
  • the speed of the treatment makes it impossible to leave to diffuse harmful elements (iron, carbon) in the link which would degrade the quality of it and degrade the resistance to corrosion of the veneer.
  • Induction heating is advantageous not only for its speed but also because it makes it possible to overcome problems related to the possible reflection of the coating.
  • the yarn thus obtained then passes through a station 26 of thermal income, at a temperature of the order of 450 ° C for about fifteen minutes.
  • the thickness plating is generally of the order of 200 ⁇ m to 500 ⁇ m; she must be thick enough to withstand mechanical aggression and corrosion. It represents in section less than about 10% of the section total of the wire.
  • Figure 3 illustrates, as examples, four types of sections possible for plated armor wires.
  • the round shape 30 is the most simple, but one can also consider a rectangular shape 31 or a in "zeta" 32 or “teta” 33, these forms being in themselves conventional for constitute driving reinforcement son.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Ropes Or Cables (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Wire Processing (AREA)
  • Reinforced Plastic Materials (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating With Molten Metal (AREA)
  • Laminated Bodies (AREA)

Claims (10)

  1. Verfahren zur Herstellung von Bewehrungsdrähten (20) aus plattiertem Stahl, die für die Verstärkung von flexiblen röhrenförmigen Leitungen für den Transport von Kohlenwasserstoffen bestimmt sind, des Typs, bei dem ein Plattierungsüberzug (22) durch hohen Druck mit einem Stahlkern (21) eng verbunden wird, dadurch gekennzeichnet, dass der Stahl des Kerns (21) mit mittleren mechanischen Eigenschaften gewählt wird und härtbar ist, dass der Überzug (22) auf den Kern (21) aufgebracht und mit ihm eng verbunden wird und dass dann der erhaltene plattierte Draht einer schnellen Härtung bei hoher Temperatur unterworfen wird, die von einer kontrollierten martensitischen Transformation begleitet wird, gefolgt von einem Anlassen.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Eigenschaften des Stahls und des Plattierungsüberzugs sowie die Härtungstemperatur und die Härtungszeit in der Weise gewählt werden, dass die mechanischen Eigenschaften des gehärteten Drahts erhöht werden, ohne die Festigkeit der Plattierungsverbindung zu zerstören.
  3. Verfahren nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass die Hochtemperaturhärtung bei einer Temperatur in der Größenordnung von 800 °C bis 1100 °C erfolgt.
  4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Hochtemperaturhärtung während einer Dauer im Bereich von einigen Sekunden bis zu höchstens einigen Minuten erfolgt.
  5. Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Hochtemperaturhärtung durch Induktion erfolgt.
  6. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das Anlassen während einer Dauer im Bereich von 10 Minuten bis 20 Minuten erfolgt.
  7. Verfahren nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass vor der schnellen Härtung ein Anlasszwischenschritt eingeführt wird.
  8. Verfahren nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Plattierungsmetall aus Titan und seinen Legierungen, rostfreiem Stahl, Nickel oder seinen Legierungen gewählt ist.
  9. Verfahren nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die konstitutiven Werkstoffe des Kerns (21) und des Überzugs (22) in der Weise gewählt sind, dass der Unterschied zwischen ihren jeweiligen mechanischen Widerstandseigenschaften Rm nicht größer als 200 MPa ist.
  10. Flexible röhrenförmige Leitung für den Transport von Kohlenwasserstoff, des Typs, der Polymerlagen (2, 8) und Metalllagen (1, 3, 4, 6, 7), die nicht verbunden sind, umfasst, wobei die Metalllagen gewickelte Bewehrungsdrähte (3, 4, 6, 7) umfassen, dadurch gekennzeichnet, dass wenigstens einige der Bewehrungslagen (3, 4, 3, 7) gehärtet und angelassen sind und gemäß dem Verfahren nach den vorhergehenden Ansprüchen hergestellt sind.
EP03722682A 2002-03-05 2003-02-28 Verfahren zur herstellung von verstärkungsdrähten aus beschichtetem stahl für flexible rohrförmige leitungen zum transport von kohlenwasserstoffen, sowie verstärkte leitung Expired - Lifetime EP1483068B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0202793 2002-03-05
FR0202793A FR2836847B1 (fr) 2002-03-05 2002-03-05 Procede de fabrication de fil d'armure en acier plaque pour conduite tubulaire flexible de transport d'hydrocarbures, et conduite ainsi armee
PCT/FR2003/000657 WO2003074206A2 (fr) 2002-03-05 2003-02-28 Procede de fabrication de fil d'armure en acier plaque pour conduite tubulaire flexible de transport d'hydrocarbures, et conduite ainsi armee

Publications (2)

Publication Number Publication Date
EP1483068A2 EP1483068A2 (de) 2004-12-08
EP1483068B1 true EP1483068B1 (de) 2005-07-20

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EP03722682A Expired - Lifetime EP1483068B1 (de) 2002-03-05 2003-02-28 Verfahren zur herstellung von verstärkungsdrähten aus beschichtetem stahl für flexible rohrförmige leitungen zum transport von kohlenwasserstoffen, sowie verstärkte leitung

Country Status (10)

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US (1) US7615124B2 (de)
EP (1) EP1483068B1 (de)
AT (1) ATE299760T1 (de)
AU (1) AU2003229847A1 (de)
BR (1) BR0307966B1 (de)
DE (1) DE60301062D1 (de)
DK (1) DK1483068T3 (de)
FR (1) FR2836847B1 (de)
NO (1) NO20043450L (de)
WO (1) WO2003074206A2 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2945099B1 (fr) 2009-05-04 2011-06-03 Technip France Procede de fabrication d'une conduite tubulaire flexible de grande longueur
FR2987666B1 (fr) 2012-03-01 2014-02-28 Technic France Conduite tubulaire flexible pour le transport d'hydrocarbures corrosifs
ITMI20131165A1 (it) 2013-07-10 2015-01-11 Prysmian Spa Submarine flexible pipe
FR3030678B1 (fr) * 2014-12-18 2017-01-13 Technip France Conduite tubulaire flexible legere pour le transport d'hydrocarbures corrosifs et son procede de fabrication
CN116464845B (zh) * 2023-04-17 2023-10-24 江苏润扬管件有限责任公司 一种镍基超合金防腐高压管件

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US3261724A (en) * 1965-06-28 1966-07-19 Composite Metal Products Inc Stainless steel clad aluminum and methods of making same
US3522111A (en) * 1967-10-24 1970-07-28 Republic Steel Corp Method of making a composite metal product
US3463620A (en) * 1968-02-28 1969-08-26 Olin Mathieson Cylindrical or rod-like composite article
GB2085330B (en) * 1980-10-20 1984-01-18 Sumitomo Metal Ind Method of preparing clad steels
FR2528733B1 (de) * 1982-06-22 1985-07-05 Coflexip
JPS60255923A (ja) * 1984-05-30 1985-12-17 Sumitomo Electric Ind Ltd ステンレス被覆鋼線の製造方法
GB8421237D0 (en) 1984-08-21 1984-09-26 Dunlop Ltd Hose(1)
JPS61126922A (ja) * 1984-11-22 1986-06-14 Hitachi Cable Ltd 銅被鋼線
DD268258A1 (de) * 1988-01-08 1989-05-24 Florin Stahl Walzwerk Hoeherfester stahl, insbesondere betonstahl bzw. ziehereivormaterial, mit verbesserten werkstoffeigenschaften und besserer verarbeitbarkeit
JPH04115956A (ja) * 1990-09-07 1992-04-16 Kanai Hiroyuki ドットプリンター用印字ワイヤ
US5503608A (en) * 1995-06-15 1996-04-02 Chang; Ta-Fang Horse riding type exerciser
FR2743573A1 (fr) * 1996-01-16 1997-07-18 Michelin & Cie Fil metallique pret a l'emploi et procede pour obtenir ce fil
FR2775050B1 (fr) 1998-02-18 2000-03-10 Inst Francais Du Petrole Conduite flexible pour une utilisation statique en ambiance corrosive
JP2000271639A (ja) * 1999-03-26 2000-10-03 Nisshin Steel Co Ltd めっき鋼管及びその製造方法

Also Published As

Publication number Publication date
US7615124B2 (en) 2009-11-10
FR2836847A1 (fr) 2003-09-12
DK1483068T3 (da) 2005-10-31
NO20043450L (no) 2004-11-26
EP1483068A2 (de) 2004-12-08
ATE299760T1 (de) 2005-08-15
FR2836847B1 (fr) 2004-05-14
BR0307966A (pt) 2004-12-21
US20050089637A1 (en) 2005-04-28
BR0307966B1 (pt) 2013-06-18
WO2003074206A3 (fr) 2004-04-15
WO2003074206A2 (fr) 2003-09-12
AU2003229847A1 (en) 2003-09-16
AU2003229847A8 (en) 2003-09-16
DE60301062D1 (de) 2005-08-25

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