EP1404576B1 - Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente - Google Patents

Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente Download PDF

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Publication number
EP1404576B1
EP1404576B1 EP02748849A EP02748849A EP1404576B1 EP 1404576 B1 EP1404576 B1 EP 1404576B1 EP 02748849 A EP02748849 A EP 02748849A EP 02748849 A EP02748849 A EP 02748849A EP 1404576 B1 EP1404576 B1 EP 1404576B1
Authority
EP
European Patent Office
Prior art keywords
container
cage
filling
woven fabric
finely divided
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02748849A
Other languages
German (de)
English (en)
Other versions
EP1404576A1 (fr
Inventor
Roland Schaffer
Johannes Andreas Joze Middelman
Gerd Theodor Brand
Frank Dieter HÜNIG
Hans-Jürgen Strempel
Hans-Joachim Seydel
Michael Hirschhäuser
Thomas Riedemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10133666A external-priority patent/DE10133666A1/de
Application filed by Degussa GmbH filed Critical Degussa GmbH
Priority to EP02748849A priority Critical patent/EP1404576B1/fr
Priority to EP06101462A priority patent/EP1661612A1/fr
Priority to EP06101459A priority patent/EP1666377B1/fr
Publication of EP1404576A1 publication Critical patent/EP1404576A1/fr
Application granted granted Critical
Publication of EP1404576B1 publication Critical patent/EP1404576B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42—Details of containers or of foldable or erectable container blanks
    • B65D5/4295—Ventilating arrangements, e.g. openings, space elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B1/00—Packaging fluent solid material, e.g. powders, granular or loose fibrous material, loose masses of small articles, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
    • B65B1/28—Controlling escape of air or dust from containers or receptacles during filling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B65D65/403—Applications of laminates for particular packaging purposes with at least one corrugated layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00—Large containers
    • B65D88/16—Large containers flexible
    • B65D88/1612—Flexible intermediate bulk containers [FIBC]
    • B65D88/1618—Flexible intermediate bulk containers [FIBC] double-walled or with linings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00—Large containers
    • B65D88/16—Large containers flexible
    • B65D88/1612—Flexible intermediate bulk containers [FIBC]
    • B65D88/1668—Flexible intermediate bulk containers [FIBC] closures for top or bottom openings

Definitions

  • the present invention relates to an apparatus and a process for filling containers with granular or powdered materials, in particular with finely divided solids with a high air content, as well as to the container itself.
  • finely divided silica is a product having an extremely low compacted bulk density of about 40 to 50 g/l. Owing to its fine structure, finely divided silica is capable of binding a very large amount of gas, for example air, so the product is put into a quasi-fluid state of about 20 to 30 g/l.
  • the bags consist of three to four plies of paper, and one ply of the paper may additionally be laminated with polyethylene as a barrier against penetrating moisture. To achieve the desired air permeability during the filling process, all plies are microperforated. This has the effect that the product is compressed as it is introduced into the bag and its filling density increases relative to the natural pour density.
  • a process and a receptacle for repeated filling with and emptying of pourable product having a low pouring density is known from EP-A-0 773 159.
  • the woven fabric receptacle described therein, the so-called big bag or also super bag consists of flexible air-permeable woven fabric, preferably a single or multiple ply of plastic woven fabric with at least one inlet.
  • This woven fabric receptacle is also filled using vacuum filling systems.
  • a vacuum is applied to the woven fabric receptacle and the product is aspirated through the open inlet into the woven fabric receptacle until a predetermined filling weight is achieved.
  • the issuing gas is distributed over the entire surface of the woven fabric receptacle.
  • the product is reversibly compacted, as when being poured into bags, without its structure being destroyed in the process.
  • DE-A-198 39 106 describes flexible large containers for finely divided solids having a high air content for repeated filling using vacuum filling systems, which consist of at least two superimposed plies, an inner ply consisting of uncoated air-permeable woven fabric and an outer ply being dustproof and being coated with a moisture barrier and these plies being mutually connected by a special seam in such a way that the container may only be aerated through it.
  • the DE-A-198 39 106 describes a particular process for filling this large container, with which the filling material is subjected to preliminary deaeration prior to filling and a further deaeration via the seams of the fabric is carried out during filling.
  • the preliminary deaeration and therefore partial compaction of the filling product are also effected by the application of vacuum.
  • a drawback of the process described in DE-A-198 39 106 is the extremely high expenditure on apparatus as vacuum systems are required for both preliminary compaction and filling of the large container. Despite this expenditure, the filling capacity is still too low, so the process described in DE-A-198 39 106 is uneconomical overall.
  • the present invention also relates to a process for filling containers, in particular with finely divided solids having a high air content, by arranging an air-permeable container in an apparatus according to the invention, air-tight connection of the container to the feed nozzle, filling of the container under pressure and removal of the filled container.
  • the air-permeable, supporting material can be arranged on the outside and filter material on the inside.
  • the container according to the invention can be designed for optional amounts of finely divided filler materials.
  • the apparatus according to the invention has a special feed nozzle which is equipped with a flexible sealing skin and therefore allows dust-free pressure filling.
  • the feed nozzle may be deformable and may therefore allow the filling of containers of various sizes.
  • the cage which is an important component of the apparatus according to the invention has to withstand, in particular, the pressure required. At the same time, the cage gives the container adequate support during the filling process, to ensure that the container withstands the pressure applied and keeps its shape during the filling process.
  • Containers of a wide variety of shapes and of various materials may be filled in the apparatus according to the invention.
  • the materials may be: air-permeable plastic woven fabric, preferably polypropylene woven fabric, plastic woven fabric, textile woven fabric, cardboard, paper, paper plastic woven material, plastic non-woven fabric, textile non-woven fabric or composites of the aforementioned materials.
  • the filling pressure is generally 0 to 8 bar, preferably 0 to 2 bar and particularly preferably 0.2 to 1.2 bar.
  • the containers employed in the apparatus according to the invention using the process according to the invention may be of any conventional shapes and materials.
  • the containers may have a base area selected from a group consisting of polygon, circle, semicircle, ellipse, trapezium, triangle, rhombus, square and rectangle or a star-shaped base area.
  • the containers may also have the shape of a hood, of assembled pockets or the shape of a tied-up bag.
  • the cage contacts the container to be filled, as uniformly and snugly as possible. It is therefore expedient if the cage substantially corresponds to the shape of the container. Additional fittings in the cage allow adaptation to the respective container to be filled.
  • the cage (3) itself is also gas-permeable.
  • the cage may have walls with openings or with adequate porosity. This may be achieved, for example, by openings in the cage walls. It is particularly advantageous if the cage walls are produced from a material selected from perforated plate, mesh or netting, woven fabric or sintered material or a mesh material, because this allows high gas permeability with adequate stability to ensure that the container does not explode even under high filling pressures.
  • the cage may be in several parts, preferably two parts.
  • the cage (3) may have a bottom and may be designed without a bottom. Preferably, the cage (3) has no bottom.
  • the apparatus comprises additional devices with which the two parts (3a, 3b) of the cage may be separated from one another and may be driven apart manually or automatically, preferably electro-pneumatically, to release the filled container.
  • the cage can be separated along a diagonal as this prevents damage to.the container.
  • the cage has no bottom, in other words the cage is open at the bottom.
  • This embodiment allows particularly simple management of the filling process.
  • the container can then be positioned directly on a plate or a pallet, the feed nozzle can then be introduced into the feed orifice of the container and can be connected in an airtight manner to the container.
  • the two cage wedges can then be separated from one another and driven apart to release the filled container. As the filled container is then standing on a plate or pallet, it can easily be removed by a transportation device.
  • Fig. 1 is a side view of a preferred embodiment of the present invention.
  • Fig. 2 is a plan view of the embodiment according to Fig. 1 with opened cage.
  • the preferred embodiment of the present invention comprises a framework 1 with two rails 2 at the top, along which the two halves 3a and 3b of the cage (3) may be moved by conventional drive devices.
  • the cage has a square base area and is divided along the diagonal into the two halves 3a and 3b. This ensures that the two halves can easily be separated from the filled container, even when the [sic] has been pressed against the cage owing to the high filling pressure.
  • the cage also has two half shells 4a and 4b which surround the feed nozzle (not shown) when closed.
  • the cage 3 is open at the bottom and the container is positioned on a pallet or plate during the filling process. It is also advantageous, as shown in the figures, if the filling nozzle is arranged symmetrically with respect to the frame 1 so a cage half 3a may be removed further from the pallet or plate 5 to allow easy access, for example for a transportation device for removing the filled container.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Basic Packing Technique (AREA)
  • Packages (AREA)
  • Bag Frames (AREA)
  • Filtration Of Liquid (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)
  • Supplying Of Containers To The Packaging Station (AREA)
  • Filtering Materials (AREA)
  • Filters For Electric Vacuum Cleaners (AREA)
  • Cartons (AREA)

Claims (13)

  1. Appareil de remplissage de contenants, en particulier avec des matières solides granulaires, poudreuses ou finement divisées présentant une haute teneur en air, comprenant une buse d'alimentation pouvant être introduite dans l'orifice d'alimentation du contenant, l'appareil comprenant en outre une cage en deux parties ou plus appropriée pour entourer un contenant, la buse d'alimentation étant conçue de telle sorte que les matières solides puissent être introduites sous pression, dans lequel la buse d'alimentation est équipée d'une pellicule d'étanchéité flexible permettant un remplissage sous pression exempt de poussière, et dans lequel la cage (3) est perméable au gaz.
  2. Appareil selon la revendication 1, caractérisé en ce que la région de base de la cage (3) présente une forme sélectionnée dans le groupe qui comprend les formes polygonale, circulaire, semi-circulaire, elliptique, trapézoïdale, triangulaire, rhomboïdale, carrée et rectangulaire, ou la région de base est en forme d'étoile.
  3. Appareil selon l'une quelconque des revendications précédentes, caractérisé en ce que la cage (3) est en deux parties, ou plus, et l'appareil comprend des dispositifs supplémentaires avec lesquels les deux parties, ou plus, (3a, 3b) de la cage peuvent être séparées les unes des autres et peuvent être écartées pour libérer le contenant rempli.
  4. Appareil selon la revendication 3, caractérisé en ce que les dispositifs sont écartés manuellement ou à l'aide de systèmes d'entraînement.
  5. Appareil selon la revendication 1, caractérisé en ce que la cage (3) comporte des parois présentant des orifices ou une porosité adéquate.
  6. Appareil selon la revendication 5, caractérisé en ce que les parois sont produites à partir d'une matière sélectionnée dans le groupe comprenant une plaque perforée, un maillage, une nappe de filet, un tissu tissé et un matériau fritté.
  7. Appareil selon l'une quelconque des revendications précédentes, caractérisé en ce que la cage est conçue avec un fond ou, de préférence, sans fond.
  8. Procédé pour remplir des contenants, en particulier avec des matières poudreuses, granulaires, finement divisées présentant une teneur en air élevée, en:
    - disposant un contenant perméable à l'air dans un appareil selon l'une quelconque des revendications 1 à 7;
    - connectant d'une façon étanche à l'air le contenant à la buse d'alimentation;
    - remplissant le contenant sous pression; et en
    - retirant le contenant rempli.
  9. Procédé selon la revendication 8, caractérisé en ce qu'un appareil selon l'une quelconque des revendications 2 à 6 est utilisé et, pour sortir le contenant des multiples parties, de préférence les deux moitiés de la cage sont séparées l'une de l'autre et sont écartées.
  10. Procédé selon l'une quelconque des revendications 8 et 9, caractérisé en ce que le contenant est produit à partir d'un tissu tissé à base de plastique perméable à l'air, de préférence du polypropylène, d'un tissu tissé à base de plastique, d'un tissu tissé à base de textile, de carton, de papier, d'un tissu tissé à base de papier et de plastique, d'un tissu non tissé à base de plastique, d'un tissu non tissé à base de textile ou de composites des matières mentionnées ci-dessus.
  11. Procédé selon l'une quelconque des revendications 8 à 10, caractérisé en ce que la pression de remplissage est essentiellement comprise entre 0 et 8 bars, de préférence entre 0 et 2 bars, et de façon particulièrement préférée entre 0,2 et 1,2 bars.
  12. Procédé selon l'une quelconque des revendications 8 à 10, caractérisé en ce que toute matière solide poudreuse, granulaire, finement divisée présentant une teneur en air élevée et sélectionnée dans un groupe comprenant des oxydes pyrogènes, des oxydes précipités, du noir de carbone et des modifications de ceux-ci peut être utilisée pour le remplissage.
  13. Procédé selon l'une quelconque des revendications 8 à 11, caractérisé en ce que le contenant présente une région de base d'une forme sélectionnée dans le groupe comprenant les formes polygonale, circulaire, semi-circulaire, elliptique, trapézoïdale, triangulaire, rhomboïdale, carrée et rectangulaire, ou une région de base en forme d'étoile ou ayant la forme d'une capuche, de poches assemblées ou d'un sac noué.
EP02748849A 2001-07-11 2002-07-09 Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente Expired - Lifetime EP1404576B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP02748849A EP1404576B1 (fr) 2001-07-11 2002-07-09 Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente
EP06101462A EP1661612A1 (fr) 2001-07-11 2002-07-09 Appareil et procédé pour remplir de grands récipients de différentes tailles et formes
EP06101459A EP1666377B1 (fr) 2001-07-11 2002-07-09 Conteneur flexible à deux couches

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE10133666A DE10133666A1 (de) 2001-07-11 2001-07-11 Vorrichtung und Verfahren zum Befüllen von Großgebinden unterschiedlicher Größen und Formen
DE10133666 2001-07-11
EP01122734 2001-09-21
EP01122734 2001-09-21
PCT/EP2002/007615 WO2003006314A1 (fr) 2001-07-11 2002-07-09 Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente
EP02748849A EP1404576B1 (fr) 2001-07-11 2002-07-09 Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP06101462A Division EP1661612A1 (fr) 2001-07-11 2002-07-09 Appareil et procédé pour remplir de grands récipients de différentes tailles et formes
EP06101459A Division EP1666377B1 (fr) 2001-07-11 2002-07-09 Conteneur flexible à deux couches

Publications (2)

Publication Number Publication Date
EP1404576A1 EP1404576A1 (fr) 2004-04-07
EP1404576B1 true EP1404576B1 (fr) 2006-11-15

Family

ID=26009681

Family Applications (3)

Application Number Title Priority Date Filing Date
EP06101459A Expired - Lifetime EP1666377B1 (fr) 2001-07-11 2002-07-09 Conteneur flexible à deux couches
EP06101462A Withdrawn EP1661612A1 (fr) 2001-07-11 2002-07-09 Appareil et procédé pour remplir de grands récipients de différentes tailles et formes
EP02748849A Expired - Lifetime EP1404576B1 (fr) 2001-07-11 2002-07-09 Appareil et procede de remplissage de contenants avec une matiere granulaire ou pulverulente

Family Applications Before (2)

Application Number Title Priority Date Filing Date
EP06101459A Expired - Lifetime EP1666377B1 (fr) 2001-07-11 2002-07-09 Conteneur flexible à deux couches
EP06101462A Withdrawn EP1661612A1 (fr) 2001-07-11 2002-07-09 Appareil et procédé pour remplir de grands récipients de différentes tailles et formes

Country Status (12)

Country Link
EP (3) EP1666377B1 (fr)
JP (1) JP4088668B2 (fr)
KR (1) KR100599026B1 (fr)
CN (1) CN1248912C (fr)
AT (2) ATE345266T1 (fr)
CA (2) CA2452775C (fr)
DE (2) DE60231261D1 (fr)
DK (1) DK1404576T3 (fr)
ES (1) ES2276943T3 (fr)
PL (1) PL207558B1 (fr)
UA (1) UA76169C2 (fr)
WO (1) WO2003006314A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007036389A1 (de) 2007-07-31 2009-02-12 Evonik Degussa Gmbh Verfahren zum Verdichten von pyrogen hergestellten Oxiden
DE102007036388A1 (de) 2007-07-31 2009-02-05 Evonik Degussa Gmbh Verfahren zum Verdichten von pyrogen hergestellten Oxiden
DE102009008984B4 (de) * 2009-02-14 2016-09-29 Empac GmbH Flexibler Schüttgutbehälter
JO3416B1 (ar) 2009-04-27 2019-10-20 Jeneil Biosurfactant Co Llc تركيبات مضادة للبكتيريا وطرق استخدامها
US20100290721A1 (en) * 2009-05-13 2010-11-18 E. I. Du Pont De Nemours And Company Industrial bag having a fluid drainage layer
WO2018029079A2 (fr) * 2016-08-09 2018-02-15 Lodestone Engineering Limited Compacteur
US12063928B2 (en) 2020-01-31 2024-08-20 Jeneil Biosurfactant Company, Llc Antimicrobial compositions for modulation of fruit and vegetable tissue necrosis

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US2452935A (en) * 1943-06-07 1948-11-02 Kemp Harold Jesse Apparatus for treating seeds with chemical dust and bagging the seeds
US2531743A (en) * 1945-09-14 1950-11-28 Ray Don Method of filling flexible containers with finely divided materials and machine therefor
US2609134A (en) * 1949-01-21 1952-09-02 Quaker Oats Co Machine for bagging cereals or grain
US2901007A (en) * 1951-06-07 1959-08-25 John P Hubbell Apparatus for handling mixtures of solid materials
BE654444A (fr) * 1963-10-17 1965-02-01
US3789897A (en) * 1970-09-11 1974-02-05 Shinwa Kagaku Kogyo Kk Packing containers
SE410399B (sv) * 1976-10-08 1979-10-15 Lectrostatic Ab Naetfilter avsett att arbeta med hoega pulserande tryck
DE3145259A1 (de) * 1981-11-14 1983-05-26 Nordenia-Kunststoffe Peter Mager Kg, 2841 Steinfeld Als verpackungsmittel fuer schuettgueter verwendbarer sack aus vorzugsweise kunststoffolie
FR2604160B1 (fr) * 1986-09-23 1988-12-30 Reynaud Baches Enveloppe interieure amovible pour silo
GB9002836D0 (en) * 1990-02-08 1990-04-04 Stott L E Ltd Powder dispensing apparatus
US5007541A (en) * 1990-03-16 1991-04-16 The Procter & Gamble Company Carton for granular materials
EP0598166A1 (fr) * 1992-11-16 1994-05-25 Ciba-Geigy Ag Sac flexible d'emballage réutilisable
DE19526743A1 (de) 1995-07-21 1997-01-23 Wacker Chemie Gmbh Verfahren zum Befüllen und Entleeren eines Behälters
EP0761566B1 (fr) 1995-09-12 2001-04-11 Degussa-Hüls Aktiengesellschaft Méthode et appareil pour l'alimentation de particules à partir d'un récipient
DE19715230A1 (de) * 1997-04-12 1998-10-15 Peter Dipl Ing Dinter Flexibler Schüttgutbehälter mit Indikatoren zum Nachweis von Materialschädigungen durch UV-Strahlen
US6155772A (en) * 1997-11-14 2000-12-05 Beale; Aldon Evans Lift-liner apparatus with improved weight-carrying capacity
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DE19843430A1 (de) * 1998-09-22 2000-03-23 Wipf Ag Volketswil Staubdichter Beutel für feinpulvrige Produkte

Also Published As

Publication number Publication date
UA76169C2 (en) 2006-07-17
PL207558B1 (pl) 2011-01-31
CA2452775C (fr) 2007-09-25
PL367330A1 (en) 2005-02-21
JP4088668B2 (ja) 2008-05-21
EP1666377A2 (fr) 2006-06-07
KR20040019054A (ko) 2004-03-04
ATE345266T1 (de) 2006-12-15
ATE423070T1 (de) 2009-03-15
KR100599026B1 (ko) 2006-07-12
CA2452775A1 (fr) 2003-01-23
CA2569061A1 (fr) 2003-01-23
EP1666377A3 (fr) 2006-09-13
CA2569061C (fr) 2010-09-28
EP1666377B1 (fr) 2009-02-18
ES2276943T3 (es) 2007-07-01
EP1661612A1 (fr) 2006-05-31
EP1404576A1 (fr) 2004-04-07
WO2003006314A1 (fr) 2003-01-23
CN1248912C (zh) 2006-04-05
CN1525921A (zh) 2004-09-01
DE60216095D1 (de) 2006-12-28
DE60216095T2 (de) 2007-06-21
JP2004533978A (ja) 2004-11-11
DE60231261D1 (de) 2009-04-02
DK1404576T3 (da) 2007-03-19

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