EP1348756A1 - Verfahren zur Herstellung fester Mittel - Google Patents
Verfahren zur Herstellung fester Mittel Download PDFInfo
- Publication number
- EP1348756A1 EP1348756A1 EP03006430A EP03006430A EP1348756A1 EP 1348756 A1 EP1348756 A1 EP 1348756A1 EP 03006430 A EP03006430 A EP 03006430A EP 03006430 A EP03006430 A EP 03006430A EP 1348756 A1 EP1348756 A1 EP 1348756A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- solid mixture
- mixture according
- alcohol
- solid
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
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- MJVXAPPOFPTTCA-UHFFFAOYSA-N beta-Sistosterol Natural products CCC(CCC(C)C1CCC2C3CC=C4C(C)C(O)CCC4(C)C3CCC12C)C(C)C MJVXAPPOFPTTCA-UHFFFAOYSA-N 0.000 description 1
- LGJMUZUPVCAVPU-UHFFFAOYSA-N beta-Sitostanol Natural products C1CC2CC(O)CCC2(C)C2C1C1CCC(C(C)CCC(CC)C(C)C)C1(C)CC2 LGJMUZUPVCAVPU-UHFFFAOYSA-N 0.000 description 1
- NJKOMDUNNDKEAI-UHFFFAOYSA-N beta-sitosterol Natural products CCC(CCC(C)C1CCC2(C)C3CC=C4CC(O)CCC4C3CCC12C)C(C)C NJKOMDUNNDKEAI-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- SGNBVLSWZMBQTH-PODYLUTMSA-N campesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]1(C)CC2 SGNBVLSWZMBQTH-PODYLUTMSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 1
- 229950010007 dimantine Drugs 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical class CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 150000003977 halocarboxylic acids Chemical class 0.000 description 1
- WZXYXXWJPMLRGG-UHFFFAOYSA-N hexadecyl benzenesulfonate Chemical class CCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 WZXYXXWJPMLRGG-UHFFFAOYSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- QMHNQZGXPNCMCO-UHFFFAOYSA-N n,n-dimethylhexan-1-amine Chemical compound CCCCCCN(C)C QMHNQZGXPNCMCO-UHFFFAOYSA-N 0.000 description 1
- UQKAOOAFEFCDGT-UHFFFAOYSA-N n,n-dimethyloctan-1-amine Chemical compound CCCCCCCCN(C)C UQKAOOAFEFCDGT-UHFFFAOYSA-N 0.000 description 1
- SFBHPFQSSDCYSL-UHFFFAOYSA-N n,n-dimethyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)C SFBHPFQSSDCYSL-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- FFDYDKFAQVYKSM-UHFFFAOYSA-N n-ethyl-n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)CC FFDYDKFAQVYKSM-UHFFFAOYSA-N 0.000 description 1
- OMEMQVZNTDHENJ-UHFFFAOYSA-N n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCNC OMEMQVZNTDHENJ-UHFFFAOYSA-N 0.000 description 1
- XJINZNWPEQMMBV-UHFFFAOYSA-N n-methylhexan-1-amine Chemical compound CCCCCCNC XJINZNWPEQMMBV-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-MDZDMXLPSA-N oleyl alcohol Chemical compound CCCCCCCC\C=C\CCCCCCCCO ALSTYHKOOCGGFT-MDZDMXLPSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- KZJWDPNRJALLNS-VJSFXXLFSA-N sitosterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](CC)C(C)C)[C@@]1(C)CC2 KZJWDPNRJALLNS-VJSFXXLFSA-N 0.000 description 1
- 235000015500 sitosterol Nutrition 0.000 description 1
- 229950005143 sitosterol Drugs 0.000 description 1
- NLQLSVXGSXCXFE-UHFFFAOYSA-N sitosterol Natural products CC=C(/CCC(C)C1CC2C3=CCC4C(C)C(O)CCC4(C)C3CCC2(C)C1)C(C)C NLQLSVXGSXCXFE-UHFFFAOYSA-N 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- QKHBMQWPOUUMQZ-BDQAORGHSA-M sodium;hydron;(2s)-2-(octadecanoylamino)pentanedioate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC([O-])=O QKHBMQWPOUUMQZ-BDQAORGHSA-M 0.000 description 1
- 239000004455 soybean meal Substances 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OQNGNXKLDCKIIH-UHFFFAOYSA-N tetradecyl benzenesulfonate Chemical class CCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 OQNGNXKLDCKIIH-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Definitions
- the present invention relates to solid mixtures which have at least one liquid or gelling Contain component, as well as a process for the preparation of such mixtures, and the Use of the mixtures.
- the object of the present invention was to provide fixed offer forms that contain higher proportions of liquid components at room temperature and yet flowable and are not adhesive.
- a solid mixture which comprises at least a) a solid mixture is claimed Carrier, b) a surfactant component, c) a component liquid at room temperature Hydrocolloid d) and e) optionally contain auxiliaries and additives.
- the solid carrier substance a) used is, in particular, finely crystalline, synthetic and bound water-containing zeolite such as zeolite NaA in detergent quality.
- zeolite NaX and mixtures of NaA and NaX are also suitable.
- the zeolite can be used as a spray-dried powder or as an undried stabilized suspension that is still moist from its production.
- the zeolite can contain small additions of nonionic surfactants as stabilizers, for example 1 to 3% by weight, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols with 2 to 5 ethylene oxide groups or ethoxylated isotridecanols.
- Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution; measurement method: Coulter Counter) and preferably contain 18 to 22, in particular 20 to 22% by weight of bound water.
- Suitable substitutes or partial substitutes for zeolites are crystalline, layered sodium silicates of the general formula NaMSi x O 2x + 1 .yH 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4.
- Preferred crystalline phyllosilicates are those in which M in the general formula represents sodium and x assumes the values 2 or 3.
- both ⁇ - and ⁇ -sodium disilicate Na 2 Si 2 O 5 .yH 2 O are preferred.
- the agents according to the invention preferably contain 10 to 60% by weight of zeolite and / or crystalline layered silicates as solid component a), mixtures of zeolite and crystalline layered silicates in any ratio being particularly advantageous.
- the agents contain 20 to 50% by weight of zeolite and / or crystalline layered silicates.
- Particularly preferred agents contain up to 40% by weight of zeolite and in particular up to 35% by weight of zeolite, in each case based on the anhydrous active substance.
- Suitable ingredients for a) are water-soluble amorphous silicates; they are preferably used in combination with zeolite and / or crystalline layered silicates.
- Particularly preferred are agents which contain, above all, sodium silicate with a molar ratio (module) Na 2 O: SiO 2 of 1: 1 to 1: 4.5, preferably of 1: 2 to 1: 3.5.
- the content of amorphous sodium silicates in the agents is preferably up to 15% by weight and preferably between 2 and 8% by weight.
- Phosphates such as tripolyphosphates, pyrophosphates and orthophosphates can also be present in small amounts in the compositions.
- the content of the phosphates in the compositions is preferably up to 15% by weight, but in particular 0 to 10% by weight.
- the compositions can additionally contain layered silicates of natural and synthetic origin. However, smectites, in particular bentonites, are preferred here.
- small amounts of iron can be incorporated into the crystal lattice of the layered silicates according to the above formulas.
- the layered silicates can contain hydrogen, alkali, alkaline earth ions, in particular Na + and Ca 2+ .
- the amount of water of hydration is usually in the range from 8 to 20% by weight and depends on the swelling condition or the type of processing.
- Layered silicates are preferably used which are largely free of calcium ions and strongly coloring iron ions due to an alkali treatment.
- Usable organic builders are, for example, the polycarboxylic acids preferably used in the form of their sodium salts, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitricotrylic acid (NTA), provided that such use is not objectionable for ecological reasons. and mixtures of these.
- Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures of these.
- Suitable polymeric polycarboxylates are, for example, the sodium salts of polyacrylic acid or polymethacrylic acid, for example those with a relative molecular weight of 800 to 150,000 (based on acid).
- Suitable copolymeric polycarboxylates are, in particular, those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable.
- Their relative molecular weight, based on free acids is generally 5,000 to 200,000, preferably 10,000 to 120,000 and in particular 50,000 to 100,000. The use of polymeric polycarboxylates is not absolutely necessary.
- agents are preferred which are biodegradable polymers, for example terpolymers, the monomers acrylic acid and maleic acid or salts thereof, and vinyl alcohol or vinyl alcohol derivatives, or the monomers acrylic acid and 2-alkylallylsulfonic acid or salts thereof as well as sugar derivatives.
- Further suitable builder substances are polyacetals, which can be obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 carbon atoms and at least 3 hydroxyl groups.
- Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.
- Other suitable solids a) are urea and its solid derivatives as well as phyrophosphates, sucrose, dextrose, cyclodextrins, glucose syrup, sorbitol, aldehydes, amines, organic and inorganic Ca salts.
- suitable components a) must be able to absorb or bind component c) due to their structure.
- the use of water glasses and zeolites or of sucrose is particularly preferred.
- mixtures of component a) is particularly preferred.
- water glass together with sucrose is particularly preferred.
- sucrose is particularly preferred.
- Quantities of sucrose to water glass from 3: 1 to 1: 1 preferred.
- the agents according to the invention contain as component b) a surfactant component, selected from anionic, non-ionic and / or amorphous surfactants. be preferred surfactants solid at room temperature are used as component b).
- Suitable anionic surfactants are, for example, alkylbenzenesulfonates, which preferably follow the formula (I) R'-Ph-SO 3 X (I) in which R 'is a branched, but preferably linear alkyl radical having 10 to 18 carbon atoms, Ph is a phenyl radical and X is X is an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
- alkylbenzenesulfonates which preferably follow the formula (I) R'-Ph-SO 3 X (I) in which R 'is a branched, but preferably linear alkyl radical having 10 to 18 carbon atoms, Ph is a phenyl radical and X is X is an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
- Dodecylbenzenesulfonates, tetradecylbenzenesulfonates, hexadecylbenzenesulfonates and their technical mixtures in the form of the sodium salts are preferably used.
- Alkyl and / or alkenyl sulfates which are also often referred to as fatty alcohol sulfates, are to be understood as meaning the sulfation products of primary alcohols which follow the formula (II) R "-O-SO 3 X (II) in which R "represents a linear or branched, aliphatic alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms and X represents an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
- Alkyl sulfates which can be used in the context of the invention are the sulfation products of capron alcohol, caprylic alcohol, capric alcohol, 2-ethylhexyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, eradyl alcohol, arachyl alcohol, petroyl alcohol, petroyl alcohol, petroyl alcohol, aryl alcohol alcohol, petroyl alcohol, and their technical mixtures which are obtained from high pressure hydrogenation of technical methyl ester fractions or aldehydes from Roelen's oxosynthesis
- the sulfation products can preferably be used in the form of their alkali metal salts and in particular their sodium salts f Basis of C 16/18 tallow fatty alcohols or vegetable fatty alcohols of comparable C chain distribution in the form of their sodium salts.
- ether sulfates are known anionic surfactants which are produced on an industrial scale by SO 3 - or chlorosulfonic acid (CSA) sulfation of fatty alcohol or oxo alcohol polyglycol ethers and subsequent neutralization.
- SO 3 - or chlorosulfonic acid (CSA) sulfation of fatty alcohol or oxo alcohol polyglycol ethers and subsequent neutralization.
- ether sulfates which follow the formula (III) are suitable R '''O- (CH 2 CH 2 O) m SO 3 X (IV) in which R '"stands for a linear or branched alkyl and / or alkenyl radical having 6 to 22 carbon atoms, n for numbers from 1 to 10 and X for an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
- Typical Examples are the sulfates of addition products with an average of 1 to 10 and in particular 2 to 5 moles of ethylene oxide with capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, elaalyl alcohol, oleyl alcohol , Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures in the form of their sodium and / or magnesium salts
- the ether sulfates can have both a conventional and a narrow homolog distribution, and the use of ether sulfates based on adducts with an average of 2 is particularly preferred up to 3 moles of ethylene oxide on technical grade C 12/14 or C 12/18 coconut fatty alcohol fractions in the form of their sodium and / or magnesium salts.
- Acylglutamates are known anionic surfactants which follow the formula (V) in which R "" CO represents a linear or branched acyl radical having 6 to 22 carbon atoms and 0 and / or 1, 2 or 3 double bonds and X represents hydrogen, an alkali metal and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium. They are produced, for example, by Schotten-Baumann acylation of glutamic acid with fatty acids, fatty acid esters or chlorides. Sales products are available, for example, from Hoechst AG, Frankfurt / DE or Ajinomoto Co. Inc., Tokyo / JP.
- acylglutamates which are suitable for the purposes of the invention are anionic surfactants which are derived from fatty acids having 6 to 22, preferably 12 to 18, carbon atoms, such as, for example, C 12/14 or C 12/18 coconut fatty acid, Lauric acid, myristic acid, palmitic acid and / or stearic acid.
- anionic surfactants which are derived from fatty acids having 6 to 22, preferably 12 to 18, carbon atoms, such as, for example, C 12/14 or C 12/18 coconut fatty acid, Lauric acid, myristic acid, palmitic acid and / or stearic acid.
- Sodium N-cocoyl and sodium N-stearoyl-L-glutamate are particularly preferred.
- Alcohol ethoxylates are to be mentioned as non-ionic surfactants.
- alcohol ethoxylates are referred to as fatty alcohol or oxo alcohol ethoxylates and preferably follow the formula (VI), R ''''O (CH 2 CH 2 O) n H (VI) in which R '"" represents a linear or branched alkyl and / or alkenyl radical having 6 to 22 carbon atoms and n is a number from 1 to 50.
- Typical examples are the adducts of on average 1 to 50, preferably 5 to 40 and in particular 10 to 25 moles of capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol, oleyl alcohol Petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, which are used, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from Roelen's oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols.
- Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation, of aminic compounds.
- the starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mol of salt being formed per mole of betaine.
- unsaturated carboxylic acids such as acrylic acid, is also possible.
- betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (VII) in the R b for alkyl and / or alkenyl radicals with 6 to 22 carbon atoms, R a for hydrogen or alkyl radicals with 1 to 4 carbon atoms, R c for alkyl radicals with 1 to 4 carbon atoms, n for numbers from 1 to 6 and X for a Alkali and / or alkaline earth metal or ammonium.
- R b for alkyl and / or alkenyl radicals with 6 to 22 carbon atoms
- R a for hydrogen or alkyl radicals with 1 to 4 carbon atoms
- R c for alkyl radicals with 1 to 4 carbon atoms
- n for numbers from 1 to 6
- X for a Alkali and / or alkaline earth metal or ammonium.
- Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, Dodecylethylmethylamin, C 12/14 -Kokosalkyldimethylamin, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearyl, oleyl, C 16/18 tallow alkyl dimethyl amine and technical mixtures thereof.
- surfactants used are alkoligoglycosides of the formula R 1 O- [G] p in which R 1 is an alkyl and / or alkenyl radical having 4 to 22 carbon atoms, G is a sugar radical having 5 or 6 carbon atoms and p is a number of 1 to 10.
- Preferred agents of the present invention contain as the surfactant component b) alkyl oligoglycosides of the above formula.
- Soybean oil is particularly preferred as component c). Soybean oil is a yellowish to brownish-yellow, fat, semi-drying oil, which can be obtained by pressing and / or extraction Hydrocarbons (e.g. hexane) is obtained from soybeans (Glycine max) or soybean meal. Soybean oil content: 17-22%. 55-65% of the total fatty acids in soybean oil are multiple unsaturated fatty acids. The sterol content of soybean oil averages 0.37% (of which Cholesterol 0.3-0.5%).
- soybean oil v. a Ergost-5-en-3b-ol, campesterin and the like.
- Sitosterol. Refining can reduce the sterol content by approx. 30%. It also contains Soybean oil free fatty acids, lecithin and up to 0.8% tocopherol. Soybean oil goes through like most oils that The individual steps of refining are processed for nutritional purposes, with the Entlecithination (enrichment of the phospholipids after adding water to the boundary layer u. Separation in separators) is of particular importance for the production of soy lecithin.
- hydrocolloids d) are used simultaneously or at different times, preferably selected from the group gelatin, alginates, pectins, modified starch, carrageenans, agar, Xanthan, galactomanane, gum arabic. These compounds show a viscosity build-up in Water and are therefore also used as thickeners.
- the component to a) is in amounts of 1 to 90, preferably 5 to 90, in particular 5 to 75 and particularly preferably in amounts of 20 to 65 wt .-%, based on the solid agent.
- the Surfactant component b) is preferably in amounts of 1 to 60% by weight, in particular 10 to 55 % By weight and very particularly in amounts of 15 to 45% by weight in the compositions.
- the Components c) and d) are preferably in a total amount of 2 to 65, preferably 5 to 50 % By weight, particularly preferably 5 to 40% by weight and in particular 10 to 35% by weight. It can be advantageous, a weight ratio between components c) and d) of 3: to 1: 1 adjust.
- Component c) is preferably used in excess compared to component d) used.
- auxiliaries and additives are contained, these are in amounts of typically 1 to 15, preferably 1 to 10% by weight and particularly preferably in amounts of 1 to 5% by weight.
- agents also contain water, but in minor amounts. The exact one Content depends on the type of drying. Water contents below 10% by weight are typical, preferably below 5% by weight and in particular below 3% by weight.
- Another object of the present invention relates to a method for producing Solid mixtures as described above.
- the process is characterized in that an aqueous emulsion is first prepared from components a) to d) and optionally e) and these Emulsion then dries at elevated temperature. Drying can all be done by a specialist common processes are used, in particular spray drying or the use of a Wirbel Anlagengranulationstrockners.
- the agents according to the invention can consequently be used as powder or preferably present as granules.
- Table 1 describes the compositions (in% by weight) of the aqueous emulsions.
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Saccharide Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Colloid Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Generell gilt, daß geeignete Komponenten a) aufgrund ihrer Struktur in der Lage sein müssen, die Komponente c) aufzusaugen bzw. zu binden. Besonders bevorzugt ist die Verwendung von Wassergläsern und Zeolithen oder von Saccharose.
Die Emulsion zu Versuch 10 wurde dagegen mit 700 g/h in einen Wirbelschichtgranulationstrockner (Fa. Glatt AGT 150) dosiert und über eine 2-Stoffdüse versprüht. Nach der Emulsion wurden noch 160 g/h einer Mischung aus Harnstoff, Kaliumpyrophosphat und Wasserglas über eine Feststoffdosierschnecke in den Trockner dosiert. Die Trocknung wurde bei einer Wirbelschichttemperatur von 75 °C und einer Lufttemperatur von 115 °C durchgeführt. Es wurden in jedem Fall ein freifließende, nichtklebende Feststoff erhalten.
In der Tabelle 1 sind die Zusammensetzungen (in Gew.-%) der wässerigen Emulsionen beschrieben.
Claims (15)
- Feststoffmischung, enthaltend mindestensa) einen festen Trägerstoffb) einen tensidischen Bestandteilc) einen bei Raumtemperatur flüssige Bestandteild) ein Hydrokolloid unde) optional Hilfs- und Zusatzstoffe
- Feststoffmischung nach Anspruch 1, dadurch gekennzeichnet, daß der feste Trägerstoff a) ausgewählt ist aus der Gruppe der Zeolithe, Wasssergläser, feste Polycarbonsäuren und Polycarboxylate, Saccharose, Dextrose, Cyclodextrine, Glucosesirup, Sorbit, Aldehyde, Amine, organische und anorganische Ca-Salze, Harnstoff oder Phyrophosphate
- Feststoffmischung nach den Ansprüchen 1 und 2, dadurch gekennzeichnet, daß der tensidischen Bestandteil ausgewählt ist aus der Gruppe der anionischen, nichtionischen und/oder amophteren Tenside.
- Feststoffmischung nach den Ansprüchen 1 bis 3, dadurch gekennzeichnet, daß als tensidischer Bestandteil Alkyloligoglycoside der allgemeinen Formel R1O-[G]p in der R1 für einen Alkyl- und/oder Alkenylrest mit 4 bis 22 Kohlenstoffatomen, G für einen Zuckerrest mit 5 oder 6 Kohlenstoffatomen und p für Zahlen von 1 bis 10 steht, enthalten sind.
- Feststoffmischung nach den Ansprüchen 1 bis 4, dadurch gekennzeichnet, daß die Bestandteile zu c) ausgewählt sind aus der Gruppe Lecithine, bei Raumtemperatur flüssige Fette und Öle, Parfümöle, flüssige nichtionische Tenside.
- Feststoffmischung nach den Ansprüchen 1 bis 5, dadurch gekennzeichnet, daß die Bestandteile zu d) ausgewählt sind aus gelierenden Substanzen, vorzugsweise Gelatine, Alginate, Pektine, modifizierte Stärke, Carrageenane, Agar, Xanthan, Galactomanane, Gummi arabicum.
- Feststoffmischung nach den Ansprüchen 1 bis 6, dadurch gekennzeichnet, daß die Komponenten zu a) in Mengen von 1 bis 90, vorzugsweise 5 bis 75 und insbesondere 20 bis 65 Gew.-% enthalten sind.
- Feststoffmischung nach den Ansprüchen 1 bis 7, dadurch gekennzeichnet, daß die tensidischen Komponente b) in Mengen von 1 bis 60, vorzugsweise 10 bis 55 und insbesondere 15 bis 45 Gew.-% enthalten ist.
- Feststoffmischung nach den Ansprüchen 1 bis 8, dadurch gekennzeichnet, daß die Komponenten c) und d) in Mengen von 2 bis 65, vorzugsweise 5 bis 50 und insbesondere 5 bis 40 Gew.-% enthalten sind.
- Feststoffmischung nach den Ansprüchen 1 bis 9, dadurch gekennzeichnet, daß die optionalen Hilfsund Zusatzstoffe in Mengen von insgesamt 1 bis 15, vorzugsweise 1 bis 10 und insbesondere 1 bis 5 Gew.-% enthalten sind.
- Feststoffmischung nach den Ansprüchen 1 bis 10, dadurch gekennzeichnet, daß es als Granulat vorliegt.
- Verfahren zur Herstellung von Feststoffen, enthaltend mindestens die Bestandteile a) bis d) und ggf. e) gemäß Anspruch 1, dadurch gekennzeichnet, daß man zunächst eine wässerige Emulsion aus den Komponenten a) bis d) und ggf. e) herstellt und diese Emulsion anschließend bei erhöhter Temperatur trocknet.
- Verfahren nach Anspruch 12, dadurch gekennzeichnet, daß die Emulsion mittels eines Wirbelschichtgranulationstrockner getrocknet wird.
- Verfahren nach Anspruch 12, dadurch gekennzeichnet, daß die Emulsion mittels Sprühtrocknung getrocknet wird.
- Verwendung von Feststoffmischungen gemäß Anspruch 1 zur Herstellung von Wasch- und Reinigungsmitteln.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10214388A DE10214388A1 (de) | 2002-03-30 | 2002-03-30 | Verfahren zur Herstellung fester Mittel |
DE10214388 | 2002-03-30 |
Publications (2)
Publication Number | Publication Date |
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EP1348756A1 true EP1348756A1 (de) | 2003-10-01 |
EP1348756B1 EP1348756B1 (de) | 2007-03-07 |
Family
ID=27798264
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EP03006430A Expired - Lifetime EP1348756B1 (de) | 2002-03-30 | 2003-03-21 | Verfahren zur Herstellung fester Mittel |
Country Status (5)
Country | Link |
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US (1) | US20040005994A1 (de) |
EP (1) | EP1348756B1 (de) |
AT (1) | ATE356192T1 (de) |
DE (2) | DE10214388A1 (de) |
ES (1) | ES2282535T3 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004085590A1 (en) * | 2003-03-24 | 2004-10-07 | The Procter & Gamble Company | Compositions comprising complexes of cyclodextrin and at least one laundry treatment active |
EP1689244A2 (de) * | 2003-11-17 | 2006-08-16 | Cargill, Incorporated | Granuläre, lecithin enthaltende zusammensetzungen und verfahren zur herstellung |
WO2007113326A1 (de) * | 2006-04-06 | 2007-10-11 | Henkel Ag & Co. Kgaa | Feste, textil-pflegende zusammensetzung mit einem wasserlöslichen polymer |
WO2007115872A1 (de) * | 2006-04-06 | 2007-10-18 | Henkel Ag & Co. Kgaa | Feste, textil-pflegende zusammensetzung mit einem wasserlöslichen polymer |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG10201402346UA (en) * | 2009-05-19 | 2014-10-30 | Vivia Biotech Sl | Methods for providing personalized medicine tests ex vivo for hematological neoplasms |
US8822403B2 (en) * | 2011-01-20 | 2014-09-02 | Ecolab Usa Inc. | Detergent composition including a saccharide or sugar alcohol |
CN111655830A (zh) | 2018-01-26 | 2020-09-11 | 埃科莱布美国股份有限公司 | 固化液体阴离子表面活性剂 |
AU2019210740B2 (en) | 2018-01-26 | 2022-02-17 | Ecolab Usa Inc. | Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a carrier |
CN111655829A (zh) | 2018-01-26 | 2020-09-11 | 埃科莱布美国股份有限公司 | 用粘合剂及任选载体固化液体氧化胺、甜菜碱和/或磺基甜菜碱表面活性剂 |
DE102018211691A1 (de) * | 2018-07-13 | 2020-01-16 | Henkel Ag & Co. Kgaa | Herstellung parfümhaltiger Formkörper |
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GB1380402A (en) * | 1971-07-30 | 1975-01-15 | Unilever Ltd | Detergent manufacture |
EP0118663A1 (de) * | 1983-01-19 | 1984-09-19 | Henkel Kommanditgesellschaft auf Aktien | Wasch- und Reinigungsmittel |
DE19601841A1 (de) * | 1996-01-19 | 1997-07-24 | Henkel Kgaa | Niotensidreiche Granulate und Verfahren zu ihrer Herstellung |
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US4155882A (en) * | 1973-08-01 | 1979-05-22 | Lever Brothers Company | Process for preparing particulate detergent compositions containing nonionic surfactants |
US4414130A (en) * | 1976-08-17 | 1983-11-08 | Colgate Palmolive Company | Readily disintegrable agglomerates of insoluble detergent builders and detergent compositions containing them |
US4439355A (en) * | 1976-12-02 | 1984-03-27 | Colgate-Palmolive Company | Elastic detergent product of improved foaming power after use |
JPS60126036A (ja) * | 1983-12-10 | 1985-07-05 | Fuji Oil Co Ltd | 粉末状大豆蛋白の製造法 |
US4946618A (en) * | 1988-11-02 | 1990-08-07 | The Procter & Gamble Company | Toilet bar composition containing cationic guar gum |
US5043091A (en) * | 1989-06-21 | 1991-08-27 | Colgate-Palmolive Co. | Process for manufacturing alkyl polysaccharide detergent laundry bar |
DE4209339A1 (de) * | 1992-03-23 | 1993-09-30 | Henkel Kgaa | Verfahren zur Herstellung rieselfähiger Wasch- und Reinigungsmittelgranulate und/oder -teilgranulate |
DE4216774A1 (de) * | 1992-05-21 | 1993-11-25 | Henkel Kgaa | Verfahren zur kontinuierlichen Herstellung eines granularen Wasch und/oder Reinigungsmittels |
ZA936554B (en) * | 1992-09-08 | 1995-03-06 | Unilever Plc | Detergent composition and process for its production. |
US5453215A (en) * | 1992-09-08 | 1995-09-26 | Lever Brothers Company, Division Of Conopco, Inc. | Process for producing concentrated laundry detergent by manufacture of low moisture content detergent slurries |
US6686328B1 (en) * | 1998-07-17 | 2004-02-03 | The Procter & Gamble Company | Detergent tablet |
DE19844523A1 (de) * | 1998-09-29 | 2000-03-30 | Henkel Kgaa | Granulationsverfahren |
MXPA01004750A (es) * | 1998-11-13 | 2005-07-01 | Genencor Int | Granulo de baja densidad de lecho fluidizado. |
-
2002
- 2002-03-30 DE DE10214388A patent/DE10214388A1/de not_active Withdrawn
-
2003
- 2003-03-21 ES ES03006430T patent/ES2282535T3/es not_active Expired - Lifetime
- 2003-03-21 DE DE50306714T patent/DE50306714D1/de not_active Expired - Fee Related
- 2003-03-21 EP EP03006430A patent/EP1348756B1/de not_active Expired - Lifetime
- 2003-03-21 AT AT03006430T patent/ATE356192T1/de not_active IP Right Cessation
- 2003-03-28 US US10/402,424 patent/US20040005994A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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GB1380402A (en) * | 1971-07-30 | 1975-01-15 | Unilever Ltd | Detergent manufacture |
EP0118663A1 (de) * | 1983-01-19 | 1984-09-19 | Henkel Kommanditgesellschaft auf Aktien | Wasch- und Reinigungsmittel |
DE19601841A1 (de) * | 1996-01-19 | 1997-07-24 | Henkel Kgaa | Niotensidreiche Granulate und Verfahren zu ihrer Herstellung |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004085590A1 (en) * | 2003-03-24 | 2004-10-07 | The Procter & Gamble Company | Compositions comprising complexes of cyclodextrin and at least one laundry treatment active |
EP1689244A2 (de) * | 2003-11-17 | 2006-08-16 | Cargill, Incorporated | Granuläre, lecithin enthaltende zusammensetzungen und verfahren zur herstellung |
WO2007113326A1 (de) * | 2006-04-06 | 2007-10-11 | Henkel Ag & Co. Kgaa | Feste, textil-pflegende zusammensetzung mit einem wasserlöslichen polymer |
WO2007115872A1 (de) * | 2006-04-06 | 2007-10-18 | Henkel Ag & Co. Kgaa | Feste, textil-pflegende zusammensetzung mit einem wasserlöslichen polymer |
Also Published As
Publication number | Publication date |
---|---|
US20040005994A1 (en) | 2004-01-08 |
ATE356192T1 (de) | 2007-03-15 |
DE50306714D1 (de) | 2007-04-19 |
ES2282535T3 (es) | 2007-10-16 |
EP1348756B1 (de) | 2007-03-07 |
DE10214388A1 (de) | 2003-10-16 |
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